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Author : H. L. Finston,Allen C. Rychtman
Publisher : John Wiley & Sons
Page : 232 pages
File Size : 47,8 Mb
Release : 1982
Category : Acid-base chemistry
ISBN : UCAL:B4476800
Author : Anonim
Publisher : Unknown
Page : 128 pages
File Size : 48,9 Mb
Release : 1991
Category : Acid-base chemistry
ISBN : OCLC:906583654
Author : K. L. Mittal
Publisher : VSP
Page : 910 pages
File Size : 45,5 Mb
Release : 2000-09-28
Category : Technology & Engineering
ISBN : 9067643254
This book documents the proceedings of the Second International Symposium on Acid-Base Interactions: Relevance to Adhesion Science and Technology held in Newark, New Jersey, October 19--21, 1998. Since the first symposium on this topic was held on the occasion of the 75th birthday of Professor Frederick M. Fowkes in 1990, it was deemed opportune and necessary to hold the second symposium on this topic. This symposium was organized with the following objectives in mind: (i) to consolidate the R&D activity carried out since the first symposium, (ii) to provide a forum for discussion of latest research results, (iii) to provide an opportunity for cross-pollination of ideas, (iv) to identify topics where there was discordance of opinion or discrepancy, and (v) to highlight areas which needed intensified R&D activities. The final technical program contained a total of 36 papers by researchers and technologists from academia, industry and other organizations. This book contains a total of 32 papers, which were rigorously peer reviewed and suitably revised before inclusion in this book. The book is divided into three parts as follows: Part 1: Fundamental Aspects of Acid-Base Interactions; Part 2: Characterization of the Acid-Base Properties of Materials; and Part 3: Applications of Acid-Base Interactions. The topics covered include: Surface free energy acid-base theory applied to solid surfaces; Good, van Oss and Chaudhury theory; contact angle measurements and interpretation; acid-base theory of contact angles; acid-base strength of solid surfaces; acid-base interactions at solid surfaces; acid-base interactions at the molecular level; characterization of acid-base properties of a host of materials (polymers, wood, glass, ceramics, silica particles, textile fibers, rocks) by XPS, inverse gas chromatography, immersion calorimetry, contact angle titration, and thin layer wicking; and relevance of acid-base interactions to bioadhesion, microbial adhesion, polymer adhesion, and adhesion in reinforced polymer composites.
Author : Adam Hulanicki
Publisher : Ellis Horwood
Page : 320 pages
File Size : 45,8 Mb
Release : 1987
Category : Science
ISBN : UOM:39015016056924
Author : David W. Oxtoby
Publisher : Harcourt Brace College Publishers
Page : 244 pages
File Size : 54,5 Mb
Release : 1998-07-01
Category : Electronic
ISBN : 0030247527
PRINCIPLES OF MODERN CHEMISTRY has dominated the honors and high mainstream general chemistry courses and is considered the standard for the course. The fifth edition is a substantial revision that maintains the rigor of previous editions but reflects the exciting modern developments taking place in chemistry today. Authors David W. Oxtoby and H. P. Gillis provide a unique approach to learning chemical principles that emphasizes the total scientific process'from observation to application'placing general chemistry into a complete perspective for serious-minded science and engineering students. Chemical principles are illustrated by the use of modern materials, comparable to equipment found in the scientific industry. Students are therefore exposed to chemistry and its applications beyond the classroom. This text is perfect for those instructors who are looking for a more advanced general chemistry textbook.
Author : Tribunal international du droit de la mer
Publisher : Martinus Nijhoff Publishers
Page : 288 pages
File Size : 42,9 Mb
Release : 2003-03-31
Category : Law
ISBN : 9041119973
The International Tribunal for the Law of the Sea is an independent judicial body established by the United Nations Convention on the Law of the Sea to adjudicate disputes arising out of the interpretation and application of the Convention. The Tribunal is open to States Parties to the Convention and, in certain cases, to entities other than States Parties (such as international organizations and natural or legal persons). The jurisdiction of the Tribunal comprises all disputes submitted to it in accordance with the Convention. It also extends to all matters specifically provided for in any other agreement which confers jurisdiction on the Tribunal. This volume contains the Judgments and Orders delivered by the Tribunal in the year 2001 in English and French.
Author : Irina A. Starostina,Oleg V. Stoyanov,Rustam Ya Deberdeev
Publisher : CRC Press
Page : 199 pages
File Size : 41,7 Mb
Release : 2014-05-20
Category : Science
ISBN : 9781482239287
This book presents the analysis of up-to-date techniques used for the determination of acid-base properties in view of their applicability to examination of solid organic and inorganic surfaces. The studies have been carried out by the authors since 1993, showing experimental data on surface properties of more than 150 polymers, such as carbocatena
Author : Russell S. Drago,Nicholas A. Matwiyoff
Publisher : Unknown
Page : 130 pages
File Size : 49,5 Mb
Release : 1968
Category : Science
ISBN : MINN:31951000480910Y
Author : Christian Laurence,Jean-François Gal
Publisher : John Wiley & Sons
Page : 476 pages
File Size : 49,8 Mb
Release : 2009-12-23
Category : Science
ISBN : 0470681896
The Lewis concept of acids and bases is discussed in every general, organic and inorganic chemistry textbook. This is usually just a descriptive treatment, as it is not possible to devise a single numerical scale suitable for all occasions. However quantitative Lewis acid-base chemistry can be developed by compiling reaction-specific basicity scales which can be used in specific branches of chemistry and biochemistry. Lewis Basicity and Affinity Scales: Data and Measurementbrings together for the first time a comprehensive range of Lewis basicity/affinity data in one volume. More than 2400 equilibrium constants of acid-base reactions, 1500 complexation enthalpies, and nearly 2000 infrared and ultraviolet shifts upon complexation are gathered together in 25 thermodynamic and spectroscopic scales of basicity and/or affinity. For each scale, the definition, the method of measurement, an exhaustive database, and a critical discussion are given. All the data have been critically examined; some have been re-measured; literature gaps have been filled by original measurements; and each scale has been made homogeneous. This collection of data will enable experimental chemists to better understand and predict the numerous chemical, physical and biological properties that depend upon Lewis basicity. Chemometricians will be able to apply their methods to the data matrices constructed from this book in order to identify the factors which influence basicity and basicity-dependent properties. In addition, measured experimental basicities and affinities are essential to computational chemists for the validation, calibration and establishment of reliable computational methods for quantifying and explaining intermolecular forces and the chemical bond. Lewis Basicity and Affinity Scales: Data and Measurement is an essential single-source desktop reference for research scientists, engineers, and students in academia, research institutes and industry, in all areas of chemistry from fundamental to applied research. "The book is a noteworthy piece of work and represents a timely and vast accumulation of knowledge regarding Lewis bases that brings together accurate thermodynamic and spectroscopic data on typical reference Lewis acids. As such, it should serve as a useful and general guide to basicity." J. AM. CHEM. SOC. 2011, 133, 642
Author : Bruce Averill,Patricia Eldredge
Publisher : Unknown
Page : 1233 pages
File Size : 42,5 Mb
Release : 2007
Category : Chemistry
ISBN : 0321413709
Emphasises on contemporary applications and an intuitive problem-solving approach that helps students discover the exciting potential of chemical science. This book incorporates fresh applications from the three major areas of modern research: materials, environmental chemistry, and biological science.
Author : Brian G. Cox
Publisher : OUP Oxford
Page : 160 pages
File Size : 53,8 Mb
Release : 2013-01-31
Category : Science
ISBN : 9780191649332
Acids and bases are ubiquitous in chemistry. Our understanding of them, however, is dominated by their behaviour in water. Transfer to non-aqueous solvents leads to profound changes in acid-base strengths and to the rates and equilibria of many processes: for example, synthetic reactions involving acids, bases and nucleophiles; isolation of pharmaceutical actives through salt formation; formation of zwitter- ions in amino acids; and chromatographic separation of substrates. This book seeks to enhance our understanding of acids and bases by reviewing and analysing their behaviour in non-aqueous solvents. The behaviour is related where possible to that in water, but correlations and contrasts between solvents are also presented. Fundamental background material is provided in the initial chapters: quantitative aspects of acid-base equilibria, including definitions and relationships between solution pH and species distribution; the influence of molecular structure on acid strengths; and acidity in aqueous solution. Solvent properties are reviewed, along with the magnitude of the interaction energies of solvent molecules with (especially) ions; the ability of solvents to participate in hydrogen bonding and to accept or donate electron pairs is seen to be crucial. Experimental methods for determining dissociation constants are described in detail. In the remaining chapters, dissociation constants of a wide range of acids in three distinct classes of solvents are discussed: protic solvents, such as alcohols, which are strong hydrogen-bond donors; basic, polar aprotic solvents, such as dimethylformamide; and low-basicity and low polarity solvents, such as acetonitrile and tetrahydrofuran. Dissociation constants of individual acids vary over more than 20 orders of magnitude among the solvents, and there is a strong differentiation between the response of neutral and charged acids to solvent change. Ion-pairing and hydrogen-bonding equilibria, such as between phenol and phenoxide ions, play an increasingly important role as the solvent polarity decreases, and their influence on acid-base equilibria and salt formation is described.
Author : Jean-Charles Joud,Marie-Geneviève Barthés-Labrousse
Publisher : John Wiley & Sons
Page : 170 pages
File Size : 40,7 Mb
Release : 2015-11-04
Category : Technology & Engineering
ISBN : 9781119145417
The first part of this book looks at the consequence of chemical and topological defects existing on real surfaces, which explain the wettability of super hydrophilc and super hydrophobic surfaces. There follows an in-depth analysis of the acido-basicity of surfaces with, as an illustration, different wettability experiments on real materials. The next chapter deals with various techniques enabling the measurement of acido basicity of the surfaces including IR and XPS technics. The last part of the book presents an electrochemical point of view which explains the surface charges of the oxide at contact with water or other electrolyte solutions in the frame of Bronsted acido-basicity concept. Various consequences are deduced from such analyses illustrated by original measurement of the point of zero charge or by understanding the basic principles of the electrowetting experiments.
Author : Ilya G. Shenderovich
Publisher : MDPI
Page : 216 pages
File Size : 49,8 Mb
Release : 2021-03-30
Category : Science
ISBN : 9783036504308
Noncovalent interactions are the bridge between ideal gas abstraction and the real world. For a long time, they were covered by two terms: van der Waals interactions and hydrogen bonding. Both experimental and quantum chemical studies have contributed to our understanding of the nature of these interactions. In the last decade, great progress has been made in identifying, quantifying, and visualizing noncovalent interactions. New types of interactions have been classified—their energetic and spatial properties have been tabulated. In the past, most studies were limited to analyzing the single strongest interaction in the molecular system under consideration, which is responsible for the most important structural properties of the system. Despite this limitation, such an approach often results in satisfactory approximations of experimental data. However, this requires knowledge of the structure of the molecular system and the absence of other competing interactions. The current challenge is to go beyond this limitation. This Special Issue collects ideas on how to study the interplay of noncovalent interactions in complex molecular systems including the effects of cooperation and anti-cooperation, solvation, reaction field, steric hindrance, intermolecular dynamics, and other weak but numerous impacts on molecular conformation, chemical reactivity, and condensed matter structure.
Author : Mark R. Leach
Publisher : Unknown
Page : 108 pages
File Size : 52,7 Mb
Release : 1999
Category : Chemical reaction, Conditions and laws of
ISBN : STANFORD:36105028914971
Author : L.H. Lee
Publisher : Springer Science & Business Media
Page : 466 pages
File Size : 43,5 Mb
Release : 2013-06-29
Category : Science
ISBN : 9781489920737