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Over the last two decades environmental concerns and energy shortages have focused increased attention on anaerobic digestion as a viable alternative process for pollution abatement and the treatment of wastewaters and sludges. The proceedings of an international symposium on the subject (the 6th in a series) are published here. This series of symposia has proved to be the leading forum for discussion and reports on the study of anaerobic processes. The topics included in this volume are: applied fundamentals of anaerobic processes; kinetics, modelling and process control; treatment of domestic and industrial wastewater; landfills, leachate and hazardous waste treatment; treatment of solid wastes and slurries; and reactor design and post-treatment.
BIOTECHNOLOGY - Volume VI by Horst W. Doelle,J. Stefan Rokem,Marin Berovic Pdf
This Encyclopedia of Biotechnology is a component of the global Encyclopedia of Life Support Systems (EOLSS), which is an integrated compendium of twenty one Encyclopedias. Biotechnology draws on the pure biological sciences (genetics, animal cell culture, molecular biology, microbiology, biochemistry, embryology, cell biology) and in many instances is also dependent on knowledge and methods from outside the sphere of biology (chemical engineering, bioprocess engineering, information technology, biorobotics). This 15-volume set contains several chapters, each of size 5000-30000 words, with perspectives, applications and extensive illustrations. It carries state-of-the-art knowledge in the field and is aimed, by virtue of the several applications, at the following five major target audiences: University and College Students, Educators, Professional Practitioners, Research Personnel and Policy Analysts, Managers, and Decision Makers and NGOs.
Anaerobic Digester Fluid Rheology and Process Efficiency by Luka Šafari? Pdf
As the anthropogenic greenhouse gas emissions continue imposing stress on our environment, it is becoming increasingly important to identify and implement new renewable technologies. Biogas production through anaerobic digestion has a great potential, since it links waste treatment with extraction of renewable energy, enabling circular bio-economies that are vital for a sustainable future. For biogas to have an important role as a renewable energy carrier in society, the scale of its production will need to be increased substantially. New substrates need to be introduced along with raising organic loading rates of the reactors to increase the rate of biogas production. This contributes to challenges in maintaining process stability, thus increasing the risk for process disturbances, including problems that were not commonly encountered before. These difficulties may be particularly pronounced when a broad range of new, largely untested substrates are introduced, leading to an increased heterogeneity of organic material entering the reactors. In the case of currently the most common reactor type; the continuous stirred-tank biogas reactor (CSTBR); such problems may include shifts in rheology (i.e. fluid behaviour) of the anaerobic digester sludge. This may lead to increased energy consumption and decreased digester mixing efficiencies, which in turn may lead to inefficient biogas processes, ultimately decreasing the economic and environmental viability of biogas production. Much is still unknown regarding how rheology shifts happen in biogas reactors, particularly when it comes to what role the substrate plays in rheological dynamics, as compared to the microbial community during varying levels of biogas process stability. This thesis elucidates the interactions between substrate type, microbial community and its metabolic activity, and anaerobic sludge rheology. A number of sludge samples from mesophilic and thermophilic CSTBRs digesting a broad range of substrates was analysed for their rheology. The specific effects of individual substrate types on CSTBR sludge rheology and the resulting implications for stirring power requirements and mixing efficiency were investigated. In order to also asses to which extent the microbial metabolism affects rheology at different levels of process disturbance, an experiment with a trace-element-induced inhibition of specific metabolic pathways under mesophilic reactor conditions was performed. This was used to identify the sequence of different interactions that occur in the reactor after the process begins to fail, and to evaluate how these interactions link to changes in digester sludge rheology. Finally, a case study of a disturbed thermophilic anaerobic digestion process was performed, including the monitoring of the response of rheology in relation to process stability, which was modified by changing trace element concentrations. The use of artificial substrate without polymeric compounds in both cases allowed for an evaluation of effects of the microbial community and its metabolic products on rheology without including the effects of complex substrates. The results showed that substrate type has a large effect on how different process parameters correlate with fluid behaviour. This was particularly apparent in the case of total solids and total volatile solids, which correlated well with rheological parameters for samples from reactors digesting agricultural waste, sewage sludge, paper mill waste, or food waste, but not for mesophilic co-digesters. Among the different substrates investigated, food waste was generally observed to lead to the highest limit viscosities (i.e. apparent viscosities at high shear rates, where it becomes linear and constant) of the anaerobic sludge, while digestion of paper mill waste and thermophilic co-digestion led to some of the lowest. No fluid type could be clearly coupled to a specific substrate, but it could be observed that increased solids content could generally be associated with more complex, non-Newtonian rheological behaviour. The differences in fluid characteristics between reactors corresponded to large differences in modelled stirring power requirements and mixing efficiency. The results indicated that fluids with high values of rheological parameters, such as the consistency index (K) or yield stress (?0), would likely require more power or an adapted stirring system to achieve complete mixing. The substrates generally contributed more to the rheology characteristics of the anaerobic sludge than microbial cells on their own. Trace element-induced process disturbance initially led to the inhibition of specific microbial groups among methanogenic archaea or their syntrophic partners, which later escalated to broader inhibition of many microbial groups due to the accumulation of fermentation products. This resulted in microbial cell washout with a corresponding decrease of the contribution of the cells to anaerobic sludge rheology. A recovery of the thermophilic anaerobic digestion process was possible after the supplementation of selenium and tungsten was increased, resulting in increased propionate turnover rates, growing cell densities, and higher viscosity. Major shifts in the methanogenic community were observed, corresponding to the level of process stability. It could be concluded based on these experiments that the specific effect of microbial cells and their activity on sludge rheology were linked to cell density, which corresponded to process stability. A conceptual scheme was developed based on the studies in this thesis, defining complex interactions between substrate, microbial metabolism, and anaerobic sludge rheology in biogas processes. The possible causes of rheology shifts are visualised and discussed. Med anledning av att antropogena utsläpp av växthusgaser fortsätter att påverka vår miljö negativt, blir det allt viktigare att identifiera och implementera förnybara teknologier. Biogasproduktion, genom anaerob rötning, bidrar till att sammanlänka avfallshantering med förnybar energiomvandling samt möjliggör för cirkulära bioekonomier, avgörande för en hållbar framtid. För att biogas ska utgöra en central roll som förnybar energibärare i samhället måste omfattningen av dess produktion ökas avsevärt. Nya substrat behöver introduceras, samtidigt som den organiska belastningen i existerande biogasreaktorer ökas, med syfte att öka produktionshastigheten. Detta bidrar emellertid till utmaningar avseende att upprätthålla processtabilitet, med ökad risk för processtörningar, inklusive nya typer av problem. Dessa svårigheter kan vara särskilt uttalade när nya, i stort sett otestade substrat, introduceras, vilket leder till ökad heterogenitet av organiskt material till reaktorerna. I tankreaktorer med omrörning (CSTBR), som i nuläget är den vanligast förekommande reaktortypen, kan sådana processförändringar innebära förändringar i reologiska egenskaper hos rötvätskor. Detta kan i sin tur leda till ökad energiförbrukning och lägre omrörningseffektivitet, vilket kan försämra biogasprocessens effektivitet samt bidra till minskad ekonomisk avkastning och minskade miljömässiga vinster. Det råder fortfarande oklarheter gällande reologiska förändringar av rötkammarmaterial i biogasreaktorer, särskilt med avseende på val av substrat i jämförelse med mikroorganismernas roll under varierade betingelser av processtabilitet. Denna avhandling belyser interaktioner mellan typ av substrat, mikrobiella samhällen och deras metaboliska aktivitet och reologiska egenskaper av rötslam. Reologisk karaktärisering av rötvätskor från mesofila och termofila CSTBRs, som rötade ett brett spektrum av substrat, genomfördes. De specifika effekterna av individuella substrattyper på korresponderande rötvätskors reologiska egenskaper och dess implikationer för omrörning undersöktes. För att även kunna bedöma i vilken utsträckning den mikrobiella metabolismen inverkar på rötvätskors reologi, vid olika nivåer av processtörning, genomfördes en fallstudie med spårelement-inducerad inhibering av specifika metaboliska vägar, under mesofila reaktorbetingelser. Denna studie användes för att identifiera sekvensen av olika interaktioner som uppträder i reaktorn när processtörningar uppstår och för att utvärdera hur dessa interaktioner kopplar till förändringar i slamreologi. Slutligen genomfördes en fallstudie av en termofil biogasprocess innefattande karaktärisering av reaktormaterialets reologi i respons till förändringar i processtabilitet orsakad av förändrade spårelementkoncentrationer. I båda dessa fallstudier, möjliggjorde användningen av ett artificiellt substrat utan komplexa polymerer, att mikrobiella effekter på förändringar i rötvätskans reologi kunde studeras frånkopplat effekter av komplexa substrat. Resultaten visade att substrattyp har stor inverkan på hur olika processparametrar korrelerar med rötvätskors reologiska egenskaper. Detta var särskilt tydligt med avseende på andelen totala respektive organiska fasta ämnen, vilka korrelerade väl med reologiska parametrar för rötvätskor från reaktorer som rötade jordbruksrester, avloppsslam, avfall från pappersbruk, respektive matavfall, men ej för rötvätskor från mesofila samrötningsanläggningar. Av de undersökta substrattyperna bidrog rötning av matavfall generellt till anaerobt slam med högst uppmätta värdena för gränsviskositet (dvs när viskositeten blir linjär och konstant vid ökade skjuvhastigheter), medan rötning av avfall från pappersbruk respektive termofil samrötning av olika substrat bidrog till de lägsta värdena för gränsviskoistet. Ingen reologisk vätsketyp kunde tydligt kopplas till en specifik substrattyp, men ökad mängd torrsubstans i rötvästkan kunde generellt associeras med komplexa, icke-newtonska, flödesegenskaper. Skillnaderna i flödesegenskaper motsvarade stora skillnader i behov av omrörningskraft och omrörningseffektivitet. Resultaten indikerade att rötvätskor med höga reologiska värden, exempelvis för konsistensindex (K) eller flytgräns (?0), sannolikt kräver mer energi eller ett anpassat system för effektivare omrörning. Generellt bidrog substratet mer till rötvätskans reologiska egenskaper än de mikrobiella cellerna på egen hand. Inducerad spårämnesbrist i genomfört reaktorförök ledde i början till en hämning av specifika mikrobiella grupper inom metanogena arkéer och deras syntrofa partners, vilket i sin tur bidrog till en bredare hämning av flera mikrobiella grupper orsakad av ackumulering av olika fermentationsprodukter. Detta resulterade i ursköljning av cellbiomassa vilket i sin tur minskade deras effekt på slammets reologiska egenskaper. En återhämtning av den termofila biogasprocessen var möjlig efter ökade tillsatser av spårelementen selen och volfram, vilket resulterade i snabbare omsättning av propionsyra, förhöjd celldensitet och viskositet. Stora förändringar observerades samtidigt inom det metanogena samhället, vilka var kopplade till olika nivåer av processtabilitet. Den specifika effekten av mikroorganismerna och deras aktivitet med avseende på slammens reologiska egenskaper var kopplad till celldensitet, vilket motsvarade processtabiliteten. Ett konceptuellt schema utvecklades baserat på resultat av beskrivna studier för att visualisera komplexa interaktioner mellan substrat, mikrobiell metabolism, och reologi av anaerobt slam i biogasprocesser. De möjliga orsakerna till reologiska förändringar visualiseras och diskuteras.
Anaerobic Digestion by Gavin Collins,Eric D. van Hullebusch,Giovanni Esposito,Cynthia Carliell-Marquet,Fernando G. Fermoso Pdf
Anaerobic digestion (AD) is a naturally-occurring biological process in soils, sediments, ruminants, and several other anoxic environments, that cycles carbon and other nutrients, and converts organic matter into a methane-rich gas. As a biotechnology, AD is now well-established for the treatment of the organic fraction of various waste materials, including wastewaters, but is also increasingly applied for an expanding range of organic feedstocks suitable for biological conversion to biogas. AD applications are classified in various ways, including on the basis of bioreactor design; and operating parameters, such as retention time, temperature, pH, total solids (TS) and volatile solids (VS) contents, and biodegradability of substrates. AD is an attractive bioenergy and waste / wastewater treatment technology. The advantages of AD for waste treatment include: production of a useable fuel (biogas/methane); possibility of high organic loading; reduced carbon footprint; and suitability for integration into a wide variety of process configurations and scales. Specifically, two important, and developing, applications exemplify the potential of AD technologies: (1) the integration of AD as the basis of the core technologies underpinning municipal wastewater, and sewage, treatment, to displace less sustainable, and more energy-intensive, aerobic biological treatment systems in urban water infrastructures; and (2) technical innovations for higher-rate conversions of high-solids wastestreams, and feedstocks, for the production of energy carriers (i.e. methane-biogas, but possibly also biohydrogen) and other industrially-relevant intermediates, such as organic acids. Internationally, the research effort to maximize AD biogas yield has increased ten-fold over the past decade. Depending on the feedstocks, bioreactor design and process parameters, fundamental and applied knowledge are still required to improve conversion rates and biogas yields. This Research Topic cover aspects related to AD processes, such as the effect of feedstock composition, as well as the effect of feedstock pre-treatment, bioreactor design and operating modes, on process efficiency; microbial community dynamics and systems biology; influence of macro- and micro-nutrient concentrations and availability; process control; upgrading and calibration of anaerobic digestion models (e.g. ADM1) considering the biochemical routes as well as the hydrodynamics in such ecosystems; and novel approaches to process monitoring, such as the development, and application, of novel, and rapid diagnostic assays, including those based on molecular microbiology. Detailed full-scale application studies were also particularly welcomed.
Waste Management and the Environment VI by V. Popov,H. Itoh,C. A. Brebbia Pdf
Waste management can be problematic. Especially with the emphasis in many countries now being on sustainability, there is a great need for more research on disposal methods. While we have found ways to reduce the volume of waste that needs to disposed. questions remain about the environmental and safety aspects of certain recycled materials and the by-products of waste management activities, current technology improvements, and regulatory and monitoring problems. Featuring papers published at the Sixth International Conference on Waste Management and the Environment, this book contains contributions on the topics such as: Advanced Waste Treatment Technology, Wastewater Treatment; Resources Recovery; Waste Incineration and Gasification; Waste Pre-Treatment; Separation and Transformation; Landfills; Soil and Groundwater Clean-up; Public Awareness; Air Pollution Control; Hazardous Waste, Waste Management; Construction and Demolition Waste Costs; Waste Reduction; Reuse and Recycling, Energy from Waste; Electrical Waste; Rare Metals; Computer Modelling; Methodologies and Practices; Risk Assessment; Nuclear Waste; Environmental Economics Assessment; Laws and Regulations; Biological Treatments; Agricultural Wastes.
The second edition of Comprehensive Biotechnology, Six Volume Set continues the tradition of the first inclusive work on this dynamic field with up-to-date and essential entries on the principles and practice of biotechnology. The integration of the latest relevant science and industry practice with fundamental biotechnology concepts is presented with entries from internationally recognized world leaders in their given fields. With two volumes covering basic fundamentals, and four volumes of applications, from environmental biotechnology and safety to medical biotechnology and healthcare, this work serves the needs of newcomers as well as established experts combining the latest relevant science and industry practice in a manageable format. It is a multi-authored work, written by experts and vetted by a prestigious advisory board and group of volume editors who are biotechnology innovators and educators with international influence. All six volumes are published at the same time, not as a series; this is not a conventional encyclopedia but a symbiotic integration of brief articles on established topics and longer chapters on new emerging areas. Hyperlinks provide sources of extensive additional related information; material authored and edited by world-renown experts in all aspects of the broad multidisciplinary field of biotechnology Scope and nature of the work are vetted by a prestigious International Advisory Board including three Nobel laureates Each article carries a glossary and a professional summary of the authors indicating their appropriate credentials An extensive index for the entire publication gives a complete list of the many topics treated in the increasingly expanding field
Trace element supplementation as a management tool for anaerobic digester operation by Jimmy Roussel,Fernando G. Fermoso,Gavin Collins,Eric Van Hullebusch,Giovanni Esposito,Ana Paula Mucha Pdf
This guide is intended for use by industry stakeholders, decision-makers and digester operators in navigating the topic of trace element (TE) supplementation as a management tool for anaerobic digester operation. The subject is the application of TE, and supplementation regimes in anaerobic waste-conversion biotechnologies, such as biogas digesters. TE is a term used to include a wide range of micronutrients essential for the microbial community underpinning AD. TE mostly includes elements from the metal groups (e.g. cobalt, nickel, zinc and tungsten) but also other elemental groups, such as metalloids (e.g. selenium). TE are dosed to anaerobic digesters to boost biological activity and to increase biogas production rates. Little is understood about the concentrations and dosing strategies best suited to sustained supplementation and stable performance in anaerobic biotechnologies. A range of companies offer proprietary blends of trace elements for supplementation of anaerobic digesters. Very little joined-up information is available on the concentrations of individual TE best suited to improved digester performance. Moreover, typically no attention whatsoever is paid to the bioavailability of TE dosed to digesters i.e. despite high concentrations, TE may not be available for uptake by the microorganisms underpinning the digestion process. Based on extensive engagement with a range of stakeholders throughout the course of the recent EU COST Action on ‘The ecological roles of trace metals in anaerobic biotechnologies’, and particularly on feedback from industrial partners, it is clear that such a guide is needed by industry stakeholders, decision-makers and operators of anaerobic digesters.
Solar Energy Research Institute. Technical Information Office
Author : Solar Energy Research Institute. Technical Information Office Publisher : Unknown Page : 488 pages File Size : 44,5 Mb Release : 1982 Category : Alcohol as fuel ISBN : UCR:31210008013847
Ecosystems and Sustainable Development VI by Enzo Tiezzi Pdf
Containing papers presented at the Sixth International Conference on Ecosystems and Sustainable Development, this book presents research related to different aspects of ecosystems and sustainable development, including physical sciences and modelling. A wide list of topics include: Thermodynamics and Ecology; Sustainability indicators; Mathematical and system modelling; Biodiversity; Sustainability development studies; Conservation and Management of Ecological Areas; Socio-Economic Factors; Energy Conservation and Generation; Environmental and Ecological Policies; Environmental Management; Environmental Risk; Natural Resources Management; Recovery of Damaged Areas; Biological Aspects; Complexity; Remote Sensing; Landscapes and Forestation Issues; Soil and agricultural issues; Water Resources; Sustainable Waste Management; Air pollution and its Effects on Ecosystems.
Handbook Biological Waste Water Treatment - Design and Optimisation of Activated Sludge Systems by Anonim Pdf
Since its conception almost a century ago, the activated sludge system has emerged as the dominant waste water treatment technology, with tens of thousands of implementations worldwide. The pivotal role played by the activated sludge system was originally due to its high efficiency in COD- and suspended solids removal, while more recently new processes for the removal of the macro-nutrients nitrogen and phosphorus have easily been accommodated.
Anaerobic Digestion Model No.1 (ADM1) by IWA Task Group for Mathematical Modelling of Anaerobic Digestion Processes Pdf
The IWA Task Group for Mathematical Modelling of Anaerobic Digestion Processes was created with the aim to produce a generic model and common platform for dynamic simulations of a variety of anaerobic processes. This book presents the outcome of this undertaking and is the result of four years collaborative work by a number of international experts from various fields of anaerobic process technology. The purpose of this approach is to provide a unified basis for anaerobic digestion modelling. It is hoped this will promote increased application of modelling and simulation as a tool for research, design, operation and optimisation of anaerobic processes worldwide. This model was developed on the basis of the extensive but often disparate work in modelling and simulation of anaerobic digestion systems over the last twenty years. In developing ADM1, the Task Group have tried to establish common nomenclature, units and model structure, consistent with existing anaerobic modelling literature and the popular activated sludge models (See Activated Sludge Models ASM1, ASM2, ASM2d and ASM3, IWA Publishing, 2000, ISBN: 1900222248). As such, it is intended to promote widespread application of simulation from domestic (wastewater and sludge) treatment systems to specialised industrial applications. Outputs from the model include common process variables such gas flow and composition, pH, separate organic acids, and ammonium. The structure has been devised to encourage specific extensions or modifications where required, but still maintain a common platform. During development the model has been successfully tested on a range of systems from full-scale waste sludge digestion to laboratory-scale thermophilic high-rate UASB reactors. The model structure is presented in a readily applicable matrix format for implementation in many available differential equation solvers. It is expected that the model will be available as part of commercial wastewater simulation packages. ADM1 will be a valuable information source for practising engineers working in water treatment (both domestic and industrial) as well as academic researchers and students in Environmental Engineering and Science, Civil and Sanitary Engineering, Biotechnology, and Chemical and Process Engineering departments. Contents Introduction Nomenclature, State Variables and Expressions Biochemical Processes Physicochemical Processes Model Implementation in a Single Stage CSTR Suggested Biochemical Parameter Values, Sensitivity and Estimation Conclusions References Appendix A: Review of Parameters Appendix B: Supplementary Matrix Information Appendix C: Integration with the ASM Appendix D: Estimating Stoichiometric Coefficients for Fermentation Scientific & Technical Report No.13
