Biomimetic Oxidations Catalyzed By Transition Metal Complexes

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Biomimetic Oxidations Catalyzed by Transition Metal Complexes

Bernard Meunier
Biomimetic Oxidations Catalyzed by Transition Metal Complexes Book PDF

Author : Bernard Meunier
Publisher : World Scientific
Page : 696 pages
File Size : 53,8 Mb
Release : 2000-03-08
Category : Science
ISBN : 9781783262380

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Biomimetic Oxidations Catalyzed by Transition Metal Complexes by Bernard Meunier Pdf

Since the classic work Metal-Catalyzed Oxidations of Organic Compounds (edited by R A Sheldon and J K Kochi, 1991), no book has been devoted to advances in the field of biomimetic oxidations, which was created nearly 18 years ago. This expanding research field is covered in this volume. All the different aspects of the modeling of oxidations catalyzed by metalloenzymes are dealt with. This invaluable book will be useful to postgraduates as well as researchers in academia and industry, and will also benefit second year university students. Contents:Thermodynamic Influences of C–H Bond Oxidation (J M Mayer)Distinguishing Biomimetic Oxidations from Oxidations Mediated by Freely Diffusing Radicals (K U Ingold & P A MacFaul)Biomimetic Oxygenations Related to Cytochrome P450: Metal-Oxo and Metal-Peroxo Intermediates (J L McLain et al.)Models of Heme Peroxidases and Catalases (B Meunier)Non-Heme Peroxidases and Catalases: Mechanistic Implications from the Studies of Manganese and Vanadium Model Compounds (C Slebodnick et al.)Methane Monooxygenase Models (Z-B Hu & S M Gorun)Models of Copper Enzymes and Heme-Copper Oxidases (M A Kopf & K D Karlin)Iron-Containing Models of Catechol Dioxygenases (H-J Krüger)Biomimetic Chemistry of Molybdenum (C G Young)Models of Superoxide Dismutases (D E Cabelli et al.)Modeling the Oxygen-Evolving Complex in Photosystem II (J Limburg et al.)Asymmetric Biomimetic Oxidations (A Robert & B Meunier)Bioinspired Oxidations Catalyzed by Ruthenium Complexes (S-I Murahashi & N Komiya)Biocatalytic and Biomimetic Oxidations from an Industrial Perspective (R A Sheldon) Readership: Postgraduate students and researchers in biochemistry and chemistry. Keywords:EPR Spectroscopy;Functional Model Chemistry;Isotope Labeling;Manganese Complexes;Mechanism;Oxygen Evolution;Photosystem II;Redox Chemistry;Water Splitting Chemistry;X-Ray Spectroscopy;Oxidation;Oxygenation;Transition Metal Complexes;Asymmetric Oxidation;Oxidase;Oxygenase;Metal-Oxo;Peroxide, Peroxo;Metalloporphyrin;MMO Models;P450 Models

Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis

S. Ted Oyama
Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis Book PDF

Author : S. Ted Oyama
Publisher : Elsevier
Page : 528 pages
File Size : 55,9 Mb
Release : 2011-10-13
Category : Technology & Engineering
ISBN : 0080558011

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Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis by S. Ted Oyama Pdf

The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. * Comprehensive listing of epoxide products * Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts * Analysis of the general strengths and weaknesses of varied catalytic systems * Detailed description of the mechanisms of reaction for classical and emerging catalysts

Advances in Inorganic Chemistry

Anonim
Advances in Inorganic Chemistry Book PDF

Author : Anonim
Publisher : Elsevier
Page : 458 pages
File Size : 51,9 Mb
Release : 2004-05-06
Category : Science
ISBN : 9780080493664

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Advances in Inorganic Chemistry by Anonim Pdf

Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry ranging from bio-inorganic to solid state studies. Thisacclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced. Comprehensive reviews written by leading experts in the field An indispensable reference to advanced researchers Includes 7 contributions covering important advances in inorganic chemistry

Alkane C-H Activation by Single-Site Metal Catalysis

Pedro J. Pérez
Alkane C H Activation by Single Site Metal Catalysis Book PDF

Author : Pedro J. Pérez
Publisher : Springer Science & Business Media
Page : 277 pages
File Size : 48,7 Mb
Release : 2012-09-15
Category : Science
ISBN : 9789048136971

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Alkane C-H Activation by Single-Site Metal Catalysis by Pedro J. Pérez Pdf

Over the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C−H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds. Alkane C-H Activation by Single-Site Metal Catalysis presents the current state-of-the-art development in the catalytic systems for the catalytic trans-formations of alkanes under homogeneous conditions. Chapter 1 offers a comprehensive summary of the main discoveries realized so far. Chapter 2 reviews the so-called electrophilic activation, initiated by Shulpín in the late 60s, and the base for the Catalytica system. Chapter 3 examines the catalytic borylation of alkanes, discovered by Hartwig, whereas chapter 4 provides an updated vision of the alkane dehydrogenation reaction. Chapter 5 covers the oxygenation of C-H bonds, a field of enormous interest with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. The history of C-H bond activation, and the current research described in this book, highlight the current research and present the reader with an outlook of this field which continues to be explored by an increasingly visionary and enthusiastic group of organic, organometallic, biological and physical chemists.

Environmentally Sustainable Catalytic Asymmetric Oxidations

Konstantin Bryliakov
Environmentally Sustainable Catalytic Asymmetric Oxidations Book PDF

Author : Konstantin Bryliakov
Publisher : CRC Press
Page : 160 pages
File Size : 55,8 Mb
Release : 2014-09-17
Category : Science
ISBN : 9781466588592

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Environmentally Sustainable Catalytic Asymmetric Oxidations by Konstantin Bryliakov Pdf

Catalysis plays a vital role in chemical, petroleum, agriculture, polymer, electronics, pharmaceutical, and other industries. Over 90 percent of chemicals originate from catalytic processes. Toughening economic and environmental constraints have proven to be a challenge for meeting the demand of novel efficient and sustainable regio- and stereosele

Innovations in Green Chemistry and Green Engineering

Paul T. Anastas,Julie B. Zimmerman
Innovations in Green Chemistry and Green Engineering Book PDF

Author : Paul T. Anastas,Julie B. Zimmerman
Publisher : Springer Science & Business Media
Page : 336 pages
File Size : 42,9 Mb
Release : 2012-12-13
Category : Science
ISBN : 9781461458173

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Innovations in Green Chemistry and Green Engineering by Paul T. Anastas,Julie B. Zimmerman Pdf

Processes that meet the objectives of green chemistry and chemical engineering minimize waste and energy use, and eliminate toxic by-products. Given the ubiquitous nature of products from chemical processes in our lives, green chemistry and chemical engineering are vital components of any sustainable future. Gathering together ten peer-reviewed articles from the Encyclopedia of Sustainability Science and Technology, Innovations in Green Chemistry and Green Engineering provides a comprehensive introduction to the state-of-the-art in this key area of sustainability research. Worldwide experts present the latest developments on topics ranging from organic batteries and green catalytic transformations to green nanoscience and nanotoxicology. An essential, one-stop reference for professionals in research and industry, this book also fills the need for an authoritative course text in environmental and green chemistry and chemical engineering at the upper-division undergraduate and graduate levels.

New Trends in Enzyme Catalysis and Biomimetic Chemical Reactions

Gertz I. Likhtenshtein
New Trends in Enzyme Catalysis and Biomimetic Chemical Reactions Book PDF

Author : Gertz I. Likhtenshtein
Publisher : Springer Science & Business Media
Page : 230 pages
File Size : 40,7 Mb
Release : 2007-05-08
Category : Science
ISBN : 9780306481109

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New Trends in Enzyme Catalysis and Biomimetic Chemical Reactions by Gertz I. Likhtenshtein Pdf

"This book is a view of enzyme catalysis by a physico-chemist with long-term experience in the investigation of structure and action mechanism of biological catalysts. This book is not intended to provide an exhaustive survey of each topic but rather a discussion of their theoretical and experimental background, and recent developments. The literature of enzyme catalysis is so vast and many scientists have made important contribution in the area, that it is impossible in the space allowed for this book to give a representative set of references. The author has tried to use reviews, and general principles of articles. He apologizes to those he has not been able to include. . ... The monograph is intended for scientists working on enzyme catalysis and adjacent areas such as chemical modeling of biological processes, homogeneous catalysis, biomedical research and biotechnology. The book can be use as a subsidiary manual for instructors, graduate and undergraduate students of university biochemistry and chemistry departments."--Pages ix-x.

Advances in Catalysis

Anonim
Advances in Catalysis Book PDF

Author : Anonim
Publisher : Academic Press
Page : 228 pages
File Size : 48,7 Mb
Release : 2021-12-04
Category : Science
ISBN : 9780128245729

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Advances in Catalysis by Anonim Pdf

Advances in Catalysis, Volume 69 fills the gap between journal papers and textbooks across the diverse areas of catalysis research. For more than 60 years, this series has dedicated itself to record and present the latest progress in the field of catalysis, providing the scientific community with comprehensive and authoritative reviews. This series is an invaluable and comprehensive resource for chemical engineers and chemists working in the field of catalysis in both academia and industry, with this release focusing on solid acids, surface acidity and heterogeneous acid catalysis. Contains authoritative reviews written by experts in the field Explores topics that reflect progress in the field, such as catalyst synthesis, catalyst characterization, catalytic chemistry, reaction engineering, computational chemistry and physics Provides insightful and critical articles that are fully edited to suit various backgrounds

Organometallic Chemistry and Catalysis

Didier Astruc
Organometallic Chemistry and Catalysis Book PDF

Author : Didier Astruc
Publisher : Springer Science & Business Media
Page : 598 pages
File Size : 51,5 Mb
Release : 2007-08-02
Category : Science
ISBN : 9783540461289

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Organometallic Chemistry and Catalysis by Didier Astruc Pdf

This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.

Advances in Inorganic Chemistry

Rudi van Eldik,Jan Reedijk
Advances in Inorganic Chemistry Book PDF

Author : Rudi van Eldik,Jan Reedijk
Publisher : Elsevier
Page : 298 pages
File Size : 52,6 Mb
Release : 2006-01-18
Category : Science
ISBN : 0080462170

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Advances in Inorganic Chemistry by Rudi van Eldik,Jan Reedijk Pdf

Advances in Inorganic Chemistry Volume 58 focuses on homogeneous biomimetic oxidation catalysis. Contributions by leading experts in the field cover important advances in inorganic and bioinorganic chemistry. Contributions include diversity-based approaches to selective biomimetic oxidation catalysis; the selective conversion of hydrocarbons with H2O2 using biomimetic non-heme iron and manganese oxidation catalysis; DNA oxidation by copper and manganese complexes; influences of the ligand in copper-dioxygen complex-formation and substrate oxidations; biomimetic oxidations by dinuclear and trinuclear copper complexes. In the final contribution the authors focus on green oxidation of alcohols using biomimetic copper complexes and enzymes as catalysts. Volume 58 provides another welcomed addition to the widely acclaimed series, Advances in Inorganic Chemistry. * Includes new information on the important advances in inorganic and bioinorganic chemistry * Each chapter is fully referenced * Contains comprehensive reviews written by leading experts in the field

Metal-Catalyzed Oxidations of Organic Compounds

Roger Sheldon,Jay K. Kochi
Metal Catalyzed Oxidations of Organic Compounds Book PDF

Author : Roger Sheldon,Jay K. Kochi
Publisher : Academic Press
Page : 456 pages
File Size : 47,7 Mb
Release : 1981-10-28
Category : Science
ISBN : UOM:39015016043005

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Metal-Catalyzed Oxidations of Organic Compounds by Roger Sheldon,Jay K. Kochi Pdf

Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation-reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds. This book is intended for chemists involved in organic synthesis, catalysis, and organometallic chemistry, both in academic institutions and in industrial laboratories.

Handbook of Porphyrin Science (Volumes 11 – 15): With Applications to Chemistry, Physics, Materials Science, Engineering, Biology and Medicine

Karl M Kadish,Kevin M Smith,Roger Guilard
Handbook of Porphyrin Science Volumes 11 15 With Applications to Chemistry Physics Materials Science Engineering Biology and Medicine Book PDF

Author : Karl M Kadish,Kevin M Smith,Roger Guilard
Publisher : World Scientific
Page : 2588 pages
File Size : 52,5 Mb
Release : 2011-02-21
Category : Science
ISBN : 9789814464154

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Handbook of Porphyrin Science (Volumes 11 – 15): With Applications to Chemistry, Physics, Materials Science, Engineering, Biology and Medicine by Karl M Kadish,Kevin M Smith,Roger Guilard Pdf

This is the third set of Handbook of Porphyrin Science.Porphyrins, phthalocyanines and their numerous analogues and derivatives are materials of tremendous importance in chemistry, materials science, physics, biology and medicine. They are the red color in blood (heme) and the green in leaves (chlorophyll); they are also excellent ligands that can coordinate with almost every metal in the Periodic Table. Grounded in natural systems, porphyrins are incredibly versatile and can be modified in many ways; each new modification yields derivatives, demonstrating new chemistry, physics and biology, with a vast array of medicinal and technical applications.As porphyrins are currently employed as platforms for study of theoretical principles and applications in a wide variety of fields, the Handbook of Porphyrin Science represents a timely ongoing series dealing in detail with the synthesis, chemistry, physicochemical and medical properties and applications of polypyrrole macrocycles. Professors Karl Kadish, Kevin Smith and Roger Guilard are internationally recognized experts in the research field of porphyrins, each having his own separate area of expertise in the field. Between them, they have published over 1500 peer-reviewed papers and edited more than three dozen books on diverse topics of porphyrins and phthalocyanines. In assembling the new volumes of this unique Handbook, they have selected and attracted the very best scientists in each sub-discipline as contributing authors.This Handbook will prove to be a modern authoritative treatise on the subject as it is a collection of up-to-date works by world-renowned experts in the field. Complete with hundreds of figures, tables and structural formulas, and thousands of literature citations, all researchers and graduate students in this field will find the Handbook of Porphyrin Science an essential, major reference source for many years to come.

Copper-Oxygen Chemistry

Kenneth D. Karlin,Shinobu Itoh,Steven Rokita
Copper Oxygen Chemistry Book PDF

Author : Kenneth D. Karlin,Shinobu Itoh,Steven Rokita
Publisher : John Wiley & Sons
Page : 417 pages
File Size : 40,7 Mb
Release : 2011-08-24
Category : Science
ISBN : 9781118094358

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Copper-Oxygen Chemistry by Kenneth D. Karlin,Shinobu Itoh,Steven Rokita Pdf

Covers the vastly expanding subject of oxidative processes mediated by copper ions within biological systems Copper-mediated biological oxidations offer a broad range of fundamentally important and potentially practical chemical processes that cross many chemical and pharmaceutical disciplines. This newest volume in the Wiley Series on Reactive Intermediates in Chemistry and Biology is divided into three logical areas within the topic of copper/oxygen chemistry— biological systems, theory, and bioinorganic models and applications—to explore the biosphere for its highly evolved and thus efficient oxidative transformations in the discovery of new types of interactions between molecular oxygen and copper ion. Featuring a diverse collection of subject matter unified in one complete and comprehensive resource, Copper-Oxygen Chemistry probes the fundamental aspects of copper coordination chemistry, synthetic organic chemistry, and biological chemistry to reveal both the biological and chemical aspects driving the current exciting research efforts behind copper-oxygen chemistry. In addition, Copper-Oxygen Chemistry: Addresses the significantly increasing literature on oxygen-atom insertion and carbon-carbon bond-forming reactions as well as enantioselective oxidation chemistries Progresses from biological systems to spectroscopy and theory, and onward to bioinorganic models and applications Covers a wide array of reaction types such as insertion and dehydrogenation reactions that utilize the cheap, abundant, and energy-containing O2 molecule With thorough coverage by prominent authors and researchers shaping innovations in this growing field, this valuable reference is essential reading for bioinorganic chemists, as well as organic, synthetic, and pharmaceutical chemists in academia and industry.

Innovative Catalysis in Organic Synthesis

Pher G. Andersson
Innovative Catalysis in Organic Synthesis Book PDF

Author : Pher G. Andersson
Publisher : John Wiley & Sons
Page : 375 pages
File Size : 54,5 Mb
Release : 2012-04-16
Category : Science
ISBN : 9783527646609

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Innovative Catalysis in Organic Synthesis by Pher G. Andersson Pdf

C-H, C-O, C-C, and C-Heteroatom bond forming processes by using metal-ligand approaches for the synthesis of organic compounds of biological, pharmacological and organic nanotechnological utility are the key areas addressed in this book. Authored by a European team of leaders in the field, it brings together innovative approaches for a variety of catalysis reactions and processes frequently applied in organic synthesis into a handy reference work. It covers all major types of catalysis, including homogeneous, heterogeneous, and organocatalysis, as well as mechanistic and computational studies. Special attention is paid to the improvements in efficiency and sustainability of important catalytic processes, such as selective oxidations, hydrogenation, and cross-coupling reactions, and to their utilization in industry. The result is a valuable resource for advanced researchers in both academia and industry, as well as graduate students in organic chemistry aiming for chemo-, regio- or stereoselective synthesis of organic compounds by using novel catalytic systems.

Comprehensive Coordination Chemistry II

J. A. McCleverty,T.J. Meyer
Comprehensive Coordination Chemistry II Book PDF

Author : J. A. McCleverty,T.J. Meyer
Publisher : Newnes
Page : 17046 pages
File Size : 52,6 Mb
Release : 2003-12-03
Category : Science
ISBN : 9780080913162

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Comprehensive Coordination Chemistry II by J. A. McCleverty,T.J. Meyer Pdf

Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.