Author : Anonim
Publisher : Unknown
Page : 128 pages
File Size : 48,7 Mb
Release : 2016-12-01
Category : Electronic
ISBN : 0841231826
Boron Reagents in Synthesis
Anonim
Boron Reagents In Synthesis
Boron Reagents In Synthesis Book in PDF, ePub and Kindle version is available to download in english. Read online anytime anywhere directly from your device. Click on the download button below to get a free pdf file of Boron Reagents In Synthesis book. This book definitely worth reading, it is an incredibly well-written.
Boron Reagents in Synthesis
Adiel Coca
Author : Adiel Coca
Publisher : ACS Symposium
Page : 544 pages
File Size : 49,7 Mb
Release : 2018-02-02
Category : Science
ISBN : 0841231834
Boron Reagents in Synthesis by Adiel Coca Pdf
Boron compounds have been used extensively in organic synthesis for more than sixty years. Some of the best known reactions in synthesis, such as the Suzuki-Miyaura cross-coupling and the hydroboration reaction, involve boron compounds. Several natural products containing boron have been isolated in the last fifty years, including ionophoric macrodiolide antibiotics boromycin, borophycin, aplasmomycins A, B, and C, and tartrolons B, C, and E, as well as autoinducer-2. The study of compounds containing boronic acids for application in pharmaceuticals and materials science has grown tremendously over the last few decades. These include bortezomib, ixazomib, and tavaborole. Several more boron-based drugs are currently in clinical trials. Boron neutron capture therapy has the potential to provide a treatment for various cancers. In addition, materials bearing boronic acids are been studied as potential sensors for biological molecules, such as saccharides and glycoproteins that possess cis-1,2- or cis-1,3-diols.
Stereodirected Synthesis with Organoboranes
Donald S. Matteson
Author : Donald S. Matteson
Publisher : Springer Science & Business Media
Page : 417 pages
File Size : 50,7 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642797095
Stereodirected Synthesis with Organoboranes by Donald S. Matteson Pdf
This monograph has been written to demonstrate to organic chemists and graduate students the strategies for controlling stereochemistry in carbon-carbon bond formations with borane intermediates. The boranes were initially found to be useful reagents by Nobel Laureate H.C. Brown. Their precursors are commercially available and derivatization is fast, clean and simple.
Organic Reactions, Volume 73
Dennis G. Hall,Hugo Lachance
Author : Dennis G. Hall,Hugo Lachance
Publisher : John Wiley & Sons
Page : 6 pages
File Size : 52,6 Mb
Release : 2012-05-29
Category : Science
ISBN : 9781118344453
Organic Reactions, Volume 73 by Dennis G. Hall,Hugo Lachance Pdf
Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Brønsted acid catalyzed manifolds recently, has opened new doors for further development of this important reaction. This book provides an up-to-date, comprehensive survey of the literature of this rich chemistry as it pertains to organic synthesis. Consistent with the goal of Organic Reactions, the content and presentation emphasize the preparative aspects of the reactions, giving considerable attention to the scope and limitations of the individual transformations along with detailed experimental procedures. A tabular survey of all examples of carbonyl allylboration used in organic synthesis is presented in nine tables organized by type of allylic boron reagent with listings within each table according to increasing carbon number of the carbonyl substrates. The literature is covered through December 2010, including a new listing of nearly 200 literature citations that supplement the original coverage of 834 references used in the earlier hard cover version of the chapter. Allylboration of Carbonyl Compounds is intended to be a useful, easily read reference book for all practitioners of synthetic organic chemistry working in academic and industrial laboratories.
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 6
Dieter E. Kaufmann,Donald S. Matteson
Author : Dieter E. Kaufmann,Donald S. Matteson
Publisher : Thieme
Page : 2230 pages
File Size : 53,5 Mb
Release : 2014-05-14
Category : Science
ISBN : 9783131779519
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 6 by Dieter E. Kaufmann,Donald S. Matteson Pdf
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations is the entirely new edition of the acclaimed reference series, Houben-Weyl, the standard synthetic chemistry resource since 1909. This new edition is published in English and will comprise 48 volumes published between the years 2000 and 2008. Science of Synthesis is a quality reference work developed by a highly esteemed editorial board to provide a comprehensive and critical selection of reliable organic and organometallic synthetic methods. This unique resource is designed to be the first point of reference when searching for a synthesis strategy. Contains the expertise of presently 400 leading chemists worldwide Critically evaluates the preparative applicability and significance of the synthetic methods Discusses relevant background information and provides detailed experimental procedures For full information on the Science of Synthesis series, visit the Science of Synthesis Homepage.
Organic Chemistry of Boron
William Gerrard
Author : William Gerrard
Publisher : Unknown
Page : 318 pages
File Size : 44,7 Mb
Release : 2013-03
Category : Electronic
ISBN : 1258620049
Organic Chemistry of Boron by William Gerrard Pdf
Organometallic Chemistry
Ian Fairlamb,Jason M Lynam,Nathan J Patmore,Paul Elliott
Author : Ian Fairlamb,Jason M Lynam,Nathan J Patmore,Paul Elliott
Publisher : Royal Society of Chemistry
Page : 171 pages
File Size : 52,9 Mb
Release : 2017-07-25
Category : Science
ISBN : 9781788012201
Organometallic Chemistry by Ian Fairlamb,Jason M Lynam,Nathan J Patmore,Paul Elliott Pdf
With the increase in volume, velocity and variety of information, researchers can find it difficult to keep up to date with the literature in their field. This interdisciplinary field has the potential to provide answers to problems and challenges faced in catalysis, synthetic organic chemistry and the development of therapeutic agents and new materials. Providing an invaluable volume, Organometallic Chemistry Volume 41 contains analysed, evaluated and distilled information on the latest in organometallic chemistry research including developments and applications of Lewis acidic boron reagents, masked low-coordinate main group species in synthesis and the diiron centre.
Hydroboration and Organic Synthesis
Ranjit S. Dhillon
Author : Ranjit S. Dhillon
Publisher : Springer Science & Business Media
Page : 582 pages
File Size : 41,8 Mb
Release : 2007-05-01
Category : Science
ISBN : 9783540490760
Hydroboration and Organic Synthesis by Ranjit S. Dhillon Pdf
This book offers a systematic compilation of the vast data available to synthetic chemists. It provides easy access to the necessary information required for chemical transformations.
Synthesis and Application of Organoboron Compounds
Elena Fernández,Andrew Whiting
Author : Elena Fernández,Andrew Whiting
Publisher : Springer
Page : 331 pages
File Size : 49,9 Mb
Release : 2015-03-04
Category : Science
ISBN : 9783319130545
Synthesis and Application of Organoboron Compounds by Elena Fernández,Andrew Whiting Pdf
The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis
E. Fernández
Author : E. Fernández
Publisher : Thieme
Page : 582 pages
File Size : 46,9 Mb
Release : 2020-05-22
Category : Science
ISBN : 9783132429734
Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis by E. Fernández Pdf
The widespread use of organoboron compounds justifies the efforts devoted to their synthesis, as well as toward developing an understanding of their reactivity. The nature of the mono- or diboron species is of paramount importance in determining the reversible covalent binding properties of the boron atom with both nucleophiles and electrophiles. By wedding the rich chemical potential of organoboron compounds to the ubiquity of organic scaffolds, advanced borylation reactions have the potential to open unprecedented synthetic alternatives, and new knowledge in the field should encourage chemists to use organoboron compounds. In this volume, the main objective is to provide a collection of the most useful, practical, and reliable methods, reported mainly within the last decade, for boron activation and boron reactivity. The volume covers the main concepts of organoboron compounds and includes experimental procedures, enabling newcomers to the field the instant and reliable application of the new tools in synthesis. Rather than aiming for a comprehensive coverage, the most advanced solutions for challenging transformations are introduced. To this end, a team of pioneers and leaders in the field have been assembled who discuss both the practical and conceptual aspects of this rapidly growing field.
Boron
Meng Li,John S Fossey,Tony D James
Author : Meng Li,John S Fossey,Tony D James
Publisher : Royal Society of Chemistry
Page : 416 pages
File Size : 51,7 Mb
Release : 2015-11-03
Category : Science
ISBN : 9781782622123
Boron by Meng Li,John S Fossey,Tony D James Pdf
The ability to monitor analytes within physiological, environmental, and industrial scenarios is of prime importance in many scenarios. Chemists have striven to mimic nature’s ability to produce robust chemosensors with the capacity to detect molecules and signal their presence. The covalent coupling interaction between boronic acids and saccharides has been exploited to monitor saccharides. The boronic acid–and Lewis acid base interaction is also suitable for the capture and recognition of anions, which are involved in fundamental processes in all living things. There have been significant advances in the field of boronic acid based receptors and this book provides a comprehensive overview and update on the topic. Not only are the applications of boron in chemical molecular sensors covered in detail, but their synthesis and supramolecular self-assembly are also presented. Topics include: the molecular recognition of saccharides, the complexation of boronic acids with saccharides, fluorescent sensors and the modular construct of fluorescent sensors, further sensory systems for saccharide recognition and an extensive bibliography. Edited by experts in the area and containing international contributions from leading research groups on the subject, this book provides a useful resource for graduate students, academic and industrial researchers in organic chemistry, supramolecular chemistry, materials science and bio-organic chemistry.
Contemporary Boron Chemistry
Matthew G Davidson,Ken Wade,T B Marder,Andrew K Hughes
Author : Matthew G Davidson,Ken Wade,T B Marder,Andrew K Hughes
Publisher : Royal Society of Chemistry
Page : 555 pages
File Size : 42,9 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847550644
Contemporary Boron Chemistry by Matthew G Davidson,Ken Wade,T B Marder,Andrew K Hughes Pdf
The continued and evolving significance of boron chemistry to the wider chemical community is demonstrated by the international and interdisciplinary nature of the research reported in this book. Contemporary Boron Chemistry encompasses inorganic and organic compounds as well as polymers, solid-state materials, medicinal aspects and theoretical studies. Covering many areas of chemistry with boron at its centre, topics include applications to polyolefin catalysis, medicine, materials and polymers; boron cluster chemistry, including carboranes and metal-containing clusters; organic and inorganic chemistry of species containing only 1 or 2 boron atoms; and theoretical studies of boron-containing compounds. New materials with novel optical and electronic properties are also discussed. Comprehensive and up to date, graduates and researchers in a wide range of fields, particularly those in organometallic and organic chemistry and materials science, will welcome this book.
Boronic Acids
Dennis G. Hall
Author : Dennis G. Hall
Publisher : John Wiley & Sons
Page : 571 pages
File Size : 41,5 Mb
Release : 2006-05-12
Category : Science
ISBN : 9783527606825
Boronic Acids by Dennis G. Hall Pdf
For the first time, the whole field of organoboronic acids is presented in one comprehensive handbook. Professor Dennis Hall, a rising star within the community, covers all aspects of this important substance class, including applications in chemistry, biology and medicine. Starting with an introduction to the structure, properties, and preparation of boronic acid derivatives, together with an overview of their reactions and applications, the book goes on to look at metal-catalyzed borylation of alkanes and arenas, coupling reactions and rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds. There follows chapters on copper-promoted C-O and C-N cross-coupling of boronic acids, recent applications in organic synthesis, as well as alpha-haloalkylboronic esters in asymmetric synthesis. Later sections deal with cycloadditions, organoboronic acids, oxazaborolidines as asymmetric inducers, and boronic acid based receptors and sensors. The whole is rounded off with experimental procedures, making this invaluable reading for organic, catalytic and medicinal chemists, as well as those working in organometallics.
Synthesis of Functionalized Organoboron Compounds Through Copper(I) Catalysis
Koji Kubota
Author : Koji Kubota
Publisher : Springer
Page : 213 pages
File Size : 53,9 Mb
Release : 2017-06-27
Category : Science
ISBN : 9789811049354
Synthesis of Functionalized Organoboron Compounds Through Copper(I) Catalysis by Koji Kubota Pdf
This book describes state-of-the-art borylation chemistry using copper(I) catalysis. Enantioselective reactions are included to afford a variety of functionalized, complex organoboronate esters, which will find wide application in asymmetric synthesis, drug discovery, and material science. Organoboron compounds are recognized as useful reagents in organic synthesis; therefore, great effort has been devoted to the development of a simple, mild, and efficient method for their preparation in the past several years. However, the synthesis of functionalized organoboron compounds remains a challenging issue because known reactions often require the use of highly reactive organometallic carbon nucleophiles. This book focuses on conceptually new, formal nucleophilic copper(I)-catalyzed borylation reactions with diboron compounds that show high selectivity and excellent functional group compatibility. Theoretical studies based on density functional theory calculations to understand the reaction mechanisms have also been described. Advances in this novel borylation chemistry will allow the rapid and efficient synthesis of complex molecules with potentially interesting properties in combination with the boron functionalization process.
Borane Reagents
Andrew Pelter,Keith Smith,Herbert Charles Brown
Author : Andrew Pelter,Keith Smith,Herbert Charles Brown
Publisher : Unknown
Page : 544 pages
File Size : 47,5 Mb
Release : 1988
Category : Science
ISBN : UOM:39015068676991