C C Cross Couplings With 3d Base Metal Catalysts

Author : Xiao-Feng Wu
Publisher : Springer Nature
Page : 403 pages
File Size : 55,5 Mb
Release : 2023-06-13
Category : Science
ISBN : 9783031328671

Get Book

C-C Cross Couplings with 3d Base Metal Catalysts by Xiao-Feng Wu Pdf

This volume presents recent progress on 3d base metal catalyzed C-C cross coupling reactions. The contributions provide detailed discussions on the use of cheap metal catalysts such as Cr, Mn, Fe, Co, Ni, Cu, and Zn to construct Csp2-Csp2, Csp2-Csp3 and Csp3-Csp3 bonds with a variety of substrates. These non-noble metal catalyst have many advantages such as being inexpensive, having low toxicity and are environmentally benign. Therefore the use of cheap metal catalysts in organic synthesis has gained much attention in efforts to develop more sustainable synthetic green chemistry. Each chapter is written by international experts in the field and is a great resource for students, researchers and chemists working in industry to gain an overview on the latest developments.

Author : Janine Cossy
Publisher : de Gruyter
Page : 0 pages
File Size : 55,7 Mb
Release : 2023
Category : Science
ISBN : 311072877X

Get Book

Organozinc Derivatives and Transition Metal Catalysts by Janine Cossy Pdf

Organozinc derivatives are now easy to prepare and their reactivity can be modified with transition metals. They are used in cross-coupling reactions with halides and pseudo-halides to form C-C bonds. The advantage of organozinc derivatives over Gri

Author : James Arthur Anderson
Publisher : World Scientific
Page : 581 pages
File Size : 46,7 Mb
Release : 2012
Category : Science
ISBN : 9781848166783

Get Book

Supported Metals in Catalysis by James Arthur Anderson Pdf

With contributions from experts in supported metal catalysis from both the industry and academia, this book presents the latest developments in characterization and application of supported metals in heterogeneous catalysis. In addition to thorough and updated coverage of the traditional aspects of heterogeneous catalysis such as preparation, characterization and use in well-established technologies such as vehicle emission control, the book also includes emerging areas where supported metal catalysis will make significant contributions to future developments, such as fuel cells and fine chemicals synthesis. The second edition of Supported Metals in Catalysis comes complete with new and updated chapters containing important summaries of research in a rapidly evolving field. Very few other books deal with this highly pertinent subject matter and, as such, it is a must-have for anyone working in the field of heterogeneous catalysis.

Author : José Pérez Sestelo,Luis A. Sarandeses
Publisher : MDPI
Page : 234 pages
File Size : 42,7 Mb
Release : 2020-12-03
Category : Science
ISBN : 9783039435678

Get Book

Advances in Cross-Coupling Reactions by José Pérez Sestelo,Luis A. Sarandeses Pdf

In this Special Issue, recent advances in cross-coupling reactions are presented in the form of original research articles, reviews, and short communications. These contributions cover different topics in this area, including novel coupling reactions, reaction conditions, synthetic alternatives, metal ligands, and applications for new pharmaceutical compounds and organic materials. In particular, the reviews deal with methodologies such as the synthesis of diarylketones through palladium catalysis and the most relevant examples of Suzuki–Miyaura and Buchwald–Hartwig coupling reactions in the synthesis of bioactive compounds. The synthetic utility of cross-coupling reactions for the synthesis of medium-size rings and the utility of Stille and Suzuki coupling reactions for the synthesis of new molecular machines based on sterically hindered anthracenyl trypticenyl units are also summarized. The original research articles present the synthesis of 2-alkynylpyrrols by inverse Sonogashira coupling and the synthesis of indoles under oxidative dearomative cross-dehydrogenative conditions. The efficient combination of iridium-catalyzed C–H borylation of aryl halides with the Sonogashira coupling and a sequential iridium-catalyzed borylation of NH-free pyrroles followed by a Suzuki–Miyaura reaction are included. The synthesis of aryl propionic acids, a common structural motif in medicinal chemistry, and the synthesis of new organic dyes are also covered.

Author : Alagarsamy Pandikumar,C. Murugan,S. Vinoth
Publisher : Elsevier
Page : 568 pages
File Size : 51,6 Mb
Release : 2021-09-03
Category : Technology & Engineering
ISBN : 9780128230596

Get Book

Nanoscale Graphitic Carbon Nitride by Alagarsamy Pandikumar,C. Murugan,S. Vinoth Pdf

Nanoscale Graphitic Carbon Nitride focuses on multi-functional applications including energy conversion, storage and healthcare. Polymeric graphitic carbon nitride materials have attracted much attention in recent years because of their similarity to graphene. They are composed of carbon, nitrogen and some minor hydrogen content. In contrast to graphene, g-Graphitic carbon nitride is a medium band-gap semiconductor and in that role an effective photocatalyst and chemical catalyst for a broad variety of reactions and applications. This book covers the fundamentals and applications of graphitic carbon nitride (g-C3N4) in different sectors. It also covers the application of graphitic carbon nitride-based composites with metal, metal oxides, metal sulphide and carbon-based materials. This is an important resource for researchers in the fields of materials science, engineering, energy storage and chemical engineering who want to understand how nanoscale graphitic carbon nitride is being used for a range of industrial applications and processes. Outlines the major properties of nanoscale graphitic carbon nitride, along with their major application areas Assesses the challenges of manufacturing graphitic carbon nitride on a mass scale Explains major synthesis methods for nanoscale graphitic carbon nitride

Author : Martin Oestreich
Publisher : John Wiley & Sons
Page : 608 pages
File Size : 40,8 Mb
Release : 2009-02-11
Category : Science
ISBN : 0470716061

Get Book

The Mizoroki-Heck Reaction by Martin Oestreich Pdf

Exploring the importance of Richard F. Heck’s carbon coupling reaction, this book highlights the subject of the 2010 Nobel Prize in Chemistry for palladium-catalyzed cross couplings in organic synthesis, and includes a foreword from Nobel Prize winner Richard F. Heck. The Mizoroki-Heck reaction is a palladium-catalyzed carbon–carbon bond forming process which is widely used in organic and organometallic synthesis. It has seen increasing use in the past decade as chemists look for strategies enabling the controlled construction of complex carbon skeletons. The Mizoroki-Heck Reaction is the first dedicated volume on this important reaction, including topics on: mechanisms of the Mizoroki-Heck reaction intermolecular Mizoroki-Heck reactions focus on regioselectivity and product outcome in organic synthesis waste-minimized Mizoroki-Heck reactions intramolecular Mizoroki-Heck reactions formation of heterocycles chelation-controlled Mizoroki-Heck reactions the Mizoroki-Heck reaction in domino processes oxidative heck-type reactions (Fujiwara-Moritani reactions) Mizoroki-Heck reactions with metals other than palladium ligand design for intermolecular asymmetric Mizoroki-Heck reactions intramolecular enantioselective Mizoroki-Heck reactions desymmetrizing Mizoroki-Heck reactions applications in combinatorial and solid phase syntheses, and the development of modern solvent systems and reaction techniques the asymmetric intramolecular Mizoroki-Heck reaction in natural product total synthesis Several chapters are devoted to asymmetric Heck reactions with particular focus on the construction of otherwise difficult-to-obtain sterically congested tertiary and quaternary carbons. Industrial and academic applications are highlighted in the final section. The Mizoroki-Heck Reaction will find a place on the bookshelves of any organic or organometallic chemist. “I am convinced that this book will rapidly become the most important reference text for research chemists in academia and industry who seek orientation in the rapidly growing and – for the layman – confusing field described as the “’Mizoroki–Heck reaction’.” (Synthesis, March 2010)

Author : Ivica Cepanec
Publisher : Elsevier
Page : 364 pages
File Size : 44,5 Mb
Release : 2010-07-07
Category : Science
ISBN : 9780080474533

Get Book

Synthesis of Biaryls by Ivica Cepanec Pdf

Organic chemistry is one of the most rapidly growing sciences. There is a wide variety of applications of organic compounds, for instance, pharmaceutically active substances, agrochemicals, optoelectronics, etc. Within this group there are hundereds and thousands of new compounds synthesized or isolated from natural sources. Such important organic chemistry developments are accompanied by the profound break-through of new reactions, increasingly efficient methodologies, reagents and catalysts. The chemistry of biaryls is one of the most interesting fields in organic chemistry, this book looks at these reactions both new and old. Synthesis of Biaryls presents the description of a given method for the synthesis of biaryls: short introduction, reaction mechanism, application, representative synthetic procedures, conclusion and literature references. This book will be of interest to organic chemists in industry and academia. A topic of growing importance in organic synthesis The FIRST book to cover all reactions for the synthesis of biaryls, including the most recent The book provides detailed applications of each method described

Author : International Union of Pure and Applied Chemistry
Publisher : Unknown
Page : 524 pages
File Size : 48,7 Mb
Release : 1999
Category : Science
ISBN : UOM:39015050032583

Get Book

Transition Metal Catalysed Reactions by International Union of Pure and Applied Chemistry Pdf

Author : Takeo Kawabata
Publisher : Springer
Page : 236 pages
File Size : 43,6 Mb
Release : 2016-02-23
Category : Science
ISBN : 9783319263335

Get Book

Site-Selective Catalysis by Takeo Kawabata Pdf

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science.The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience.Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.Review articles for the individual volumes are invited by the volume editors.Readership: research chemists at universities or in industry, graduate students

Author : Bernd Plietker
Publisher : John Wiley & Sons
Page : 295 pages
File Size : 41,9 Mb
Release : 2008-09-08
Category : Science
ISBN : 9783527623280

Get Book

Iron Catalysis in Organic Chemistry by Bernd Plietker Pdf

This first comprehensive book to cover this exciting field also deals with the biological aspects, such as enzymes with iron. Following an introduction, this handy reference and handbook goes on to deal with reductions, oxidations of C, H- and C=C bonds, oxidative allylic oxygenation and amination, the oxidation of heteroatoms, cross coupling reactions, aromatic and nucleophilic substitutions, addition to carbonyl compounds, and cyclisations as well as ring opening reactions. The chapters are clearly classified according to the reaction type, allowing readers to quickly locate the desired information.

Author : Piet W.N.M. van Leeuwen,Carmen Claver
Publisher : Springer Nature
Page : 460 pages
File Size : 55,8 Mb
Release : 2020-07-01
Category : Science
ISBN : 9783030458232

Get Book

Recent Advances in Nanoparticle Catalysis by Piet W.N.M. van Leeuwen,Carmen Claver Pdf

This book provides an overview of the latest developments in the field of nanoparticle catalysis. It not only discusses established topics in detail, but also explores several emerging topics. Catalysis with nanoparticles is expanding exponentially and is attracting significant interest due to the many exciting findings being reported. Mastering the synthesis, characterization, stabilization and use of these catalysts offers numerous possibilities that far exceed those of classic heterogeneous and homogeneous catalysis.

Author : Arkaitz Correa
Publisher : Springer
Page : 338 pages
File Size : 53,5 Mb
Release : 2016-11-26
Category : Science
ISBN : 9783319497846

Get Book

Ni- and Fe-Based Cross-Coupling Reactions by Arkaitz Correa Pdf

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Author : Javier Magano,Joshua R. Dunetz
Publisher : Wiley-VCH
Page : 401 pages
File Size : 47,7 Mb
Release : 2013-10-14
Category : Science
ISBN : 3527332790

Get Book

Transition Metal-Catalyzed Couplings in Process Chemistry by Javier Magano,Joshua R. Dunetz Pdf

This one-stop reference source is the first on this new and exciting technology to focus on case studies of large-scale industrial applications, presenting the information and facts that are otherwise hard to find in the current literature. Authors from Pfizer, Merck, DSM, Novartis, Amgen, and Astra Zeneca, among others, use case studies to showcase project evolution from inception to early and late development, including commercial routes where applicable. Each case study details at least one transition metal-catalyzed cross-coupling step, with special emphasis on lessons learned from their implementation. The important issue of metal removal from the reaction mixtures to meet specifications and the different technologies available to accomplish this goal are also addressed. Finally, a small section covers novel technologies for cross-coupling with high future potential for applications on a large scale, such as metal removal on large scale, microwave and flow chemistry, as well as green chemistry. Of great interest to chemists working in the pharmaceutical, agrochemical and fine chemical industries, but also for every synthetic chemist working in academia.

Author : James Edward McEvoy
Publisher : Unknown
Page : 216 pages
File Size : 40,6 Mb
Release : 1975
Category : Catalysts
ISBN : PSU:000002989433

Get Book

Catalysts for the Control of Automotive Pollutants by James Edward McEvoy Pdf

Author : Bernd Plietker
Publisher : Springer Science & Business Media
Page : 227 pages
File Size : 54,9 Mb
Release : 2011-01-05
Category : Science
ISBN : 9783642146695

Get Book

Iron Catalysis by Bernd Plietker Pdf

Juan I. Padrón and Víctor S. Martín: Catalysis by means of Fe-based Lewis acids; Hiroshi Nakazawa*, Masumi Itazaki: Fe–H Complexes in Catalysis; Kristin Schröder, Kathrin Junge, Bianca Bitterlich, and Matthias Beller: Fe-catalyzed Oxidation Reactions of Olefins, Alkanes and Alcohols: Involvement of Oxo- and Peroxo Complexes; Chi-Ming Che, Cong-Ying Zhou, Ella Lai-Ming Wong: Catalysis by Fe=X Complexes (X=NR, CR2); René Peters, Daniel F. Fischer and Sascha Jautze: Ferrocene and Half Sandwich Complexes as Catalysts with Iron Participation; Markus Jegelka, Bernd Plietker: Catalysis by Means of Complex Ferrates.