C H Bond Activation And Catalytic Functionalization I

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C-H Bond Activation and Catalytic Functionalization I

Pierre H. Dixneuf,Henri Doucet
C H Bond Activation and Catalytic Functionalization I Book PDF

Author : Pierre H. Dixneuf,Henri Doucet
Publisher : Springer
Page : 264 pages
File Size : 51,5 Mb
Release : 2015-12-18
Category : Science
ISBN : 9783319246307

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C-H Bond Activation and Catalytic Functionalization I by Pierre H. Dixneuf,Henri Doucet Pdf

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.

C-H Bond Activation and Catalytic Functionalization II

Pierre H. Dixneuf,Henri Doucet
C H Bond Activation and Catalytic Functionalization II Book PDF

Author : Pierre H. Dixneuf,Henri Doucet
Publisher : Springer
Page : 212 pages
File Size : 46,6 Mb
Release : 2016-03-10
Category : Science
ISBN : 9783319293196

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C-H Bond Activation and Catalytic Functionalization II by Pierre H. Dixneuf,Henri Doucet Pdf

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.

Activation and Functionalization of C-H Bonds

Karen I. Goldberg,Alan S. Goldman,American Chemical Society. Meeting
Activation and Functionalization of C H Bonds Book PDF

Author : Karen I. Goldberg,Alan S. Goldman,American Chemical Society. Meeting
Publisher : ACS Symposium
Page : 0 pages
File Size : 41,6 Mb
Release : 2004
Category : Science
ISBN : 0841238499

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Activation and Functionalization of C-H Bonds by Karen I. Goldberg,Alan S. Goldman,American Chemical Society. Meeting Pdf

Activation and Functionalization of C-H Bonds explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationally leading research groups contributed to this volume, and their chapters cover such topics as fundamental theoretical and mechanistic studies of C-H bond activation by metal complexes, catalytic systems for alkane functionalization, and new applications in synthetic organic chemistry. An introductory chapter offers an overview of stoichiometric and catalytic reactions of C-H bonds with transition metal complexes. The C-H bond is the most widespread linkage in organic chemistry, present in virtually every organic molecule. Unfortunately, C-H bonds are famously resistant to selective chemical transformations. The development of methods for their selective transformations has enormous potential value in fields ranging from the chemistry of fuels (for example, the conversion of methane to methanol) to the synthesis of the most complex organic molecules.

C-H Activation

Jin-Quan Yu,Zhangjie Shi
C H Activation Book PDF

Author : Jin-Quan Yu,Zhangjie Shi
Publisher : Springer
Page : 380 pages
File Size : 46,5 Mb
Release : 2010-06-16
Category : Science
ISBN : 9783642123566

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C-H Activation by Jin-Quan Yu,Zhangjie Shi Pdf

Table of Contents - Synthesis in the Key of Catellani: Norbornene-Mediated ortho C–H Functionalization - Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation - Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds - Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus - Remote C–H Activation via Through-Space Palladium and Rhodium Migrations - Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation - Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins - Ruthenium-Catalyzed Direct Arylations Through C–H Bond Cleavages - Rhodium-Catalyzed C–H Bond Arylationof Arenes - Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C–H Bonds - Functionalization of Carbon–Hydrogen Bonds Through Transition Metal Carbenoid Insertion - Metal-Catalyzed Oxidations of C–H to C–N Bonds

C-H Bond Activation in Organic Synthesis

Jie Jack Li
C H Bond Activation in Organic Synthesis Book PDF

Author : Jie Jack Li
Publisher : CRC Press
Page : 327 pages
File Size : 44,6 Mb
Release : 2015-04-07
Category : Medical
ISBN : 9781482233117

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C-H Bond Activation in Organic Synthesis by Jie Jack Li Pdf

Greener than conventional methods, C–H activation methods have flourished during the last decade and become especially attractive to organic chemists. Edited by a practioner in this rapidly developing field, C–H Bond Activation in Organic Synthesis provides an overview of this exciting playground of chemistry. The book summarizes the state of the art in C–H activation for functionalization, enabling you to carry out reactions in the most environmentally friendly fashion with the least contamination of by-products. The most popular C–H activation reactions are catalyzed by transition metals. This book dedicates a chapter to each of the following catalysts: palladium, rhodium, nickel, iron, copper, and cobalt. In addition, it covers radical-mediated C–H activation, fluorination via C–H activation, and C–H activation of heterocycles. Using a pedagogically practical approach, each chapter is divided by the transition metal catalyst, not a specific transformation. This gives you an up-to-date review of the most important topics of C–H activation. The area of C–H activation has experienced a flurry of activity over the past two decades, so the time is right for a resource that summarizes these powerful tools with which you can design and construct heteroaromatic molecules. Thus, direct C–H functionalization methods are expected to continue to greatly contribute to the mission of green chemistry: low-energy, waste-free, and atom-economic transformations for the synthesis of organic materials and biologically active molecules in the twenty-first century. Using this book, you can carry out environmentally friendly reactions that enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds.

Alkane C-H Activation by Single-Site Metal Catalysis

Pedro J. Pérez
Alkane C H Activation by Single Site Metal Catalysis Book PDF

Author : Pedro J. Pérez
Publisher : Springer Science & Business Media
Page : 277 pages
File Size : 55,7 Mb
Release : 2012-09-15
Category : Science
ISBN : 9789048136988

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Alkane C-H Activation by Single-Site Metal Catalysis by Pedro J. Pérez Pdf

Over the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C−H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds. Alkane C-H Activation by Single-Site Metal Catalysis presents the current state-of-the-art development in the catalytic systems for the catalytic trans-formations of alkanes under homogeneous conditions. Chapter 1 offers a comprehensive summary of the main discoveries realized so far. Chapter 2 reviews the so-called electrophilic activation, initiated by Shulpín in the late 60s, and the base for the Catalytica system. Chapter 3 examines the catalytic borylation of alkanes, discovered by Hartwig, whereas chapter 4 provides an updated vision of the alkane dehydrogenation reaction. Chapter 5 covers the oxygenation of C-H bonds, a field of enormous interest with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. The history of C-H bond activation, and the current research described in this book, highlight the current research and present the reader with an outlook of this field which continues to be explored by an increasingly visionary and enthusiastic group of organic, organometallic, biological and physical chemists.

Strategies for Palladium-Catalyzed Non-directed and Directed C-H Bond Functionalization

Anant R. Kapdi,Debabrata Maiti
Strategies for Palladium Catalyzed Non directed and Directed C H Bond Functionalization Book PDF

Author : Anant R. Kapdi,Debabrata Maiti
Publisher : Elsevier
Page : 500 pages
File Size : 40,8 Mb
Release : 2017-06-23
Category : Science
ISBN : 9780128052556

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Strategies for Palladium-Catalyzed Non-directed and Directed C-H Bond Functionalization by Anant R. Kapdi,Debabrata Maiti Pdf

Strategies for Palladium-Catalyzed Non-directed and Directed C-H Bond Functionalization portrays the complete scope of these two aspects of C-H bond functionalization in a single volume for the first time. Featured topics include the influence of palladacyclic systems in C-H bond functionalization (need for newer catalytic systems for better efficiency), mechanistic aspect of the functionalization strategies leading to better systems, and applications of these methodologies to natural product synthesis and material synthesis. Addresses the involvement of catalytic systems (palladacycles) for better functionalization of (hetero)arenes to emphasize the need for developing better, more selective systems Covers the use of powerful mechanistic tools for understanding and assisting the development of better functionalization strategies Discusses the finer aspects of C-H bond functionalization, such as control of regioselectivity with or without directing groups Includes a chapter detailing the synthesis of naturally occurring molecules or functional molecules via both pathways for assessing the applicability of the functionalization strategies

Alkane C-H Activation by Single-Site Metal Catalysis

Pedro J. Pérez
Alkane C H Activation by Single Site Metal Catalysis Book PDF

Author : Pedro J. Pérez
Publisher : Springer Science & Business Media
Page : 277 pages
File Size : 55,8 Mb
Release : 2012-09-15
Category : Science
ISBN : 9789048136971

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Alkane C-H Activation by Single-Site Metal Catalysis by Pedro J. Pérez Pdf

Over the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C−H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds. Alkane C-H Activation by Single-Site Metal Catalysis presents the current state-of-the-art development in the catalytic systems for the catalytic trans-formations of alkanes under homogeneous conditions. Chapter 1 offers a comprehensive summary of the main discoveries realized so far. Chapter 2 reviews the so-called electrophilic activation, initiated by Shulpín in the late 60s, and the base for the Catalytica system. Chapter 3 examines the catalytic borylation of alkanes, discovered by Hartwig, whereas chapter 4 provides an updated vision of the alkane dehydrogenation reaction. Chapter 5 covers the oxygenation of C-H bonds, a field of enormous interest with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. The history of C-H bond activation, and the current research described in this book, highlight the current research and present the reader with an outlook of this field which continues to be explored by an increasingly visionary and enthusiastic group of organic, organometallic, biological and physical chemists.

C-H and C-X Bond Functionalization

Xavi Ribas
C H and C X Bond Functionalization Book PDF

Author : Xavi Ribas
Publisher : Royal Society of Chemistry
Page : 350 pages
File Size : 49,8 Mb
Release : 2013-05-24
Category : Science
ISBN : 9781849737166

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C-H and C-X Bond Functionalization by Xavi Ribas Pdf

Cross-coupling reactions involving C-H and C-X bond functionalisation are commonplace in natural product synthesis and natural products, therapeutic agents, biological probes, and advanced materials. Much attention has been given to understanding the mechanistic strategies used to achieve this, making this a hot topic in recent years. In this edited book, contributions from across the globe examine these strategies, with a particular focus on palladium and copper, as well as iron – an emerging element in this field. Reviewing the recent literature, the book presents an in-depth understanding of the field, guiding the reader to achieving the best synthetic strategies for aromatic functionalisation. Organic and Organometallic chemists, as well as natural product and pharmaceutical scientists, will find this an essential guide to a major transformation currently underway in synthetic chemistry.

C-H Activation for Asymmetric Synthesis

Françoise Colobert,Joanna Wencel-Delord
C H Activation for Asymmetric Synthesis Book PDF

Author : Françoise Colobert,Joanna Wencel-Delord
Publisher : John Wiley & Sons
Page : 356 pages
File Size : 45,8 Mb
Release : 2019-08-29
Category : Science
ISBN : 9783527810864

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C-H Activation for Asymmetric Synthesis by Françoise Colobert,Joanna Wencel-Delord Pdf

Provides, in one handbook, comprehensive coverage of one of the hottest topics in stereoselective chemistry Written by leading international authors in the field, this book introduces readers to C-H activation in asymmetric synthesis along with all of its facets. It presents stereoselective C-H functionalization with a broad coverage, from outer-sphere to inner-sphere C-H bond activation, and from the control of olefin geometry to the induction of point, planar and axial chirality. Moreover, methods wherein asymmetry is introduced either during the C-H activation or in a different elementary step are discussed. Presented in two parts?asymmetric activation of C(sp3)-H bonds and stereoselective synthesis implying activation of C(sp2)-H bonds?CH-Activation for Asymmetric Synthesis showcases the diversity of stereogenic elements, which can now be constructed by C-H activation methods. Chapters in Part 1 cover: C(sp3)-H bond insertion by metal carbenoids and nitrenoids; stereoselective C-C bond and C-N bond forming reactions through C(sp3)?H bond insertion of metal nitrenoids; enantioselective intra- and intermolecular couplings; and more. Part 2 looks at: C-H activation involved in stereodiscriminant step; planar chirality; diastereoselective formation of alkenes through C(sp2)?H bond activation; amongst other methods. -Covers one of the most rapidly developing fields in organic synthesis and catalysis -Clearly structured in two parts (activation of sp3- and activation of sp2-H bonds) -Edited by two leading experts in C-H activation in asymmetric synthesis CH-Activation for Asymmetric Synthesis will be of high interest to chemists in academia, as well as those in the pharmaceutical and agrochemical industry.

Computational Advances of Rh-Catalyzed C–H Functionalization

Yu Lan,Cheng-Xing Cui,Song Liu,Chun-Xiang Li,Ruopeng Bai
Computational Advances of Rh Catalyzed C H Functionalization Book PDF

Author : Yu Lan,Cheng-Xing Cui,Song Liu,Chun-Xiang Li,Ruopeng Bai
Publisher : Springer Nature
Page : 132 pages
File Size : 47,7 Mb
Release : 2021-02-26
Category : Science
ISBN : 9789811604324

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Computational Advances of Rh-Catalyzed C–H Functionalization by Yu Lan,Cheng-Xing Cui,Song Liu,Chun-Xiang Li,Ruopeng Bai Pdf

This book offers a comprehensive overview of recent theoretical studies on rhodium-catalyzed C-H functionalization, a topic that has attracted considerable attention over the years. It includes a brief experimental history, elementary reactions, and theoretical perspectives and describes in detail recent advanced computational studies on different types of Rh-catalyzed C-H functionalization, the underlying mechanisms, and the origin of regioselectivity in a series of such reactions. Providing examples shows readers how to use theoretical tools to solve problems related to mechanisms of organometallic reactions. As such, the book is an interesting and useful resource for a wide readership in various fields involving synthetic organic, organometallic, and catalysis reactions.

Asymmetric Functionalization of C-H Bonds

Shu-Li You
Asymmetric Functionalization of C H Bonds Book PDF

Author : Shu-Li You
Publisher : Royal Society of Chemistry
Page : 432 pages
File Size : 54,6 Mb
Release : 2015-07-30
Category : Science
ISBN : 9781782621966

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Asymmetric Functionalization of C-H Bonds by Shu-Li You Pdf

Asymmetric C-H direct functionalization reactions are one of the most active and fascinating areas of research in organic chemistry due to their significance in the construction of molecular complexity without pre-activation, and the step economy and atom economy features in potential synthetic application. Distinguishing the reactivity among numerous C–H bonds in one single molecule represents one of the most challenging issues in organic synthesis and requires precise reaction design. As such, this field is now receiving increasing attention from researchers. This book provides the first comprehensive review of this field, summarizing the origin, mechanism, scope and applications of the asymmetric C-H bond functionalization reaction. It covers organocatalytic reactions and transition-metal-catalyzed reactions, as well as asymmetric C-H functionalization reactions not described in other books. Written by a leading expert in this field, the book is ideal for postgraduates and researchers working in organic synthesis, catalysis, and organometallic chemistry.

Transition Metal-Catalyzed Heterocycle Synthesis via C-H Activation

Xiao-Feng Wu
Transition Metal Catalyzed Heterocycle Synthesis via C H Activation Book PDF

Author : Xiao-Feng Wu
Publisher : John Wiley & Sons
Page : 596 pages
File Size : 43,6 Mb
Release : 2016-03-07
Category : Technology & Engineering
ISBN : 9783527338887

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Transition Metal-Catalyzed Heterocycle Synthesis via C-H Activation by Xiao-Feng Wu Pdf

Reflecting the tremendous growth of this hot topic in recent years, this book covers C-H activation with a focus on heterocycle synthesis. As such, the text provides general mechanistic aspects and gives a comprehensive overview of catalytic reactions in the presence of palladium, rhodium, ruthenium, copper, iron, cobalt, and iridium. The chapters are organized according to the transition metal used and sub-divided by type of heterocycle formed to enable quick access to the synthetic route needed. Chapters on carbonylative synthesis of heterocycles and the application of C-H activation methodology to the synthesis of natural products are also included. Written by an outstanding team of authors, this is a valuable reference for researchers in academia and industry working in the field of organic synthesis, catalysis, natural product synthesis, pharmaceutical chemistry, and crop protection.

Alkane Functionalization

Armando J. L. Pombeiro,Maria de Fatima Costa Guedes da Silva
Alkane Functionalization Book PDF

Author : Armando J. L. Pombeiro,Maria de Fatima Costa Guedes da Silva
Publisher : John Wiley & Sons
Page : 680 pages
File Size : 49,8 Mb
Release : 2019-03-11
Category : Science
ISBN : 9781119378808

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Alkane Functionalization by Armando J. L. Pombeiro,Maria de Fatima Costa Guedes da Silva Pdf

Presents state-of-the-art information concerning the syntheses of valuable functionalized organic compounds from alkanes, with a focus on simple, mild, and green catalytic processes Alkane Functionalization offers a comprehensive review of the state-of-the-art of catalytic functionalization of alkanes under mild and green conditions. Written by a team of leading experts on the topic, the book examines the latest research developments in the synthesis of valuable functionalized organic compounds from alkanes. The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. This important resource: Presents a guide to the most recent advances concerning the syntheses of valuable functionalized organic compounds from alkanes Contains information from leading experts on the topic Offers information on the catalytic functionalization of alkanes that allows for improved simplicity and sustainability compared to current multi-stage industrial processes Explores the challenges inherent with the application of alkanes as starting materials for syntheses of added value functionalized organic compounds Written for academic researchers and industrial scientists working in the fields of coordination chemistry, organometallic chemistry, catalysis, organic synthesis and green chemistry, Alkane Functionalization is an important resource for accessing the most up-to-date information available in the field of catalytic functionalization of alkanes.

Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds

Lutz Ackermann,T. Brent Gunnoe,Laurel Goj Habgood
Catalytic Hydroarylation of Carbon Carbon Multiple Bonds Book PDF

Author : Lutz Ackermann,T. Brent Gunnoe,Laurel Goj Habgood
Publisher : John Wiley & Sons
Page : 414 pages
File Size : 40,8 Mb
Release : 2018-02-20
Category : Technology & Engineering
ISBN : 9783527340132

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Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds by Lutz Ackermann,T. Brent Gunnoe,Laurel Goj Habgood Pdf

Filling a gap in the literature, this book comprehensively reviews catalytic C-H addition reactions of (hetero)aromatic hydrocarbons across carbon-carbon multiple bonds. In so doing, it summarizes both the scope as well as the limitations of different catalyst systems and building blocks, while highlighting their application to the synthesis of pharmaceuticals as well as commodity chemicals. Focusing on the latest developments, the team of authors comprising leaders in the field covers such topics as the hydroarylation of olefins, alkyne hydroarylation in the presence of transition metal catalysts, reaction of alkynes with arylboronic acids, and allene hydroarylation, as well as the synthesis of functionalized arenes and heteroaromatics. A must-have for synthetic chemists in academia and industry dealing with catalysis, organometallic chemistry, the synthesis of natural products, fine chemicals, pharmaceuticals, products of the chemical industry and organic materials.