Catalytic Oxidation Reagents

Author : Philip L. Fuchs
Publisher : John Wiley & Sons
Page : 2037 pages
File Size : 41,7 Mb
Release : 2013-07-29
Category : Science
ISBN : 9781118704844

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Catalytic Oxidation Reagents by Philip L. Fuchs Pdf

The Handbook is part of the Handbook of Reagents for Organic Chemistry series, aiming at collecting articles on a particular theme that individual researchers in academia or industry can use on a daily basis. The Handbook starts with a section discussing the most important aspects of heteroarene functionalization. The introduction is followed by the alphabetical listing of the most relevant reagents drawn from the EROS database. The Editor, André Charette from the University of Montreal, has selected 120 reagent descriptions, many of them updated with heteroarene-specific reactions for this Handbook. Following the standard format for EROS, each article contains an overview of the synthesis and physical properties of the reagents or catalyst, conditions for its storage, and purification methods. Given the importance of heteroarenes in biology and especially in medicinal chemistry, a Handbook that focuses exclusively on heteroarene functionalization has been long overdue. This Handbook will have a broad appeal to many individuals engaged in the area of medicinal chemistry, fine chemical synthesis and industrial-scale chemistry. Key features: Builds on the success of the previously published Handbooks of Reagents for Organic Synthesis Compares the numerous new C-H functionalization reactions that have been developed in the past decade Heteroarene functionalization is widely used in the development of pharmaceuticals and other bioactive compounds Contains listings of secondary reagents for which more information is available in the online edition

Author : Philip L. Fuchs
Publisher : Wiley
Page : 0 pages
File Size : 41,9 Mb
Release : 2013-10-07
Category : Science
ISBN : 1119953278

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Catalytic Oxidation Reagents by Philip L. Fuchs Pdf

The Handbook is part of the Handbook of Reagents for Organic Chemistry series, aiming at collecting articles on a particular theme that individual researchers in academia or industry can use on a daily basis. The Handbook starts with a section discussing the most important aspects of heteroarene functionalization. The introduction is followed by the alphabetical listing of the most relevant reagents drawn from the EROS database. The Editor, André Charette from the University of Montreal, has selected 120 reagent descriptions, many of them updated with heteroarene-specific reactions for this Handbook. Following the standard format for EROS, each article contains an overview of the synthesis and physical properties of the reagents or catalyst, conditions for its storage, and purification methods. Given the importance of heteroarenes in biology and especially in medicinal chemistry, a Handbook that focuses exclusively on heteroarene functionalization has been long overdue. This Handbook will have a broad appeal to many individuals engaged in the area of medicinal chemistry, fine chemical synthesis and industrial-scale chemistry. Key features: Builds on the success of the previously published Handbooks of Reagents for Organic Synthesis Compares the numerous new C-H functionalization reactions that have been developed in the past decade Heteroarene functionalization is widely used in the development of pharmaceuticals and other bioactive compounds Contains listings of secondary reagents for which more information is available in the online edition

Author : Duprez Daniel,Cavani Fabrizio
Publisher : World Scientific
Page : 1036 pages
File Size : 44,8 Mb
Release : 2014-07-24
Category : Science
ISBN : 9781783263349

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Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry by Duprez Daniel,Cavani Fabrizio Pdf

This book offers a comprehensive overview of the most recent developments in both total oxidation and combustion and also in selective oxidation. For each topic, fundamental aspects are paralleled with industrial applications. The book covers oxidation catalysis, one of the major areas of industrial chemistry, outlining recent achievements, current challenges and future opportunities. One distinguishing feature of the book is the selection of arguments which are emblematic of current trends in the chemical industry, such as miniaturization, use of alternative, greener oxidants, and innovative systems for pollutant abatement. Topics outlined are described in terms of both catalyst and reaction chemistry, and also reactor and process technology.

Author : D.H.R. Barton,Arthur E. Martell,Donald T. Sawyer
Publisher : Springer Science & Business Media
Page : 503 pages
File Size : 46,8 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781461530008

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The Activation of Dioxygen and Homogeneous Catalytic Oxidation by D.H.R. Barton,Arthur E. Martell,Donald T. Sawyer Pdf

This monograph consists of the proceedings of the Fifth International Symposium on the Activation of Dioxygen and Homogeneous Catalytic Oxidation, held in College Station, Texas, March 14-19, 1993. It contains an introductory chapter authored by Professors D. H. R. Barton and D. T. Sawyer, and twenty-nine chapters describing presentations by the plenary lecturers and invited speakers. One of the invited speakers, who could not submit a manuscript for reasons beyond his control, is represented by an abstract of his lecture. Also included are abstracts of forty-seven posters contributed by participants in the symposium. Readers who may wish to know more about the subjects presented in abstract form are invited to communicate directly with the authors of the abstracts. This is the fifth international symposium that has been held on this subject. The first was hosted by the CNRS, May 21-29, 1979, in Bendor, France (on the Island of Bandol). The second meeting was organized as a NATO workshop in Padova, Italy, June 24-27, 1984. This was followed by a meeting in Tsukuba, Japan, July 12-16, 1987. The fourth symposium was held at Balatonfured, Hungary, September 10-14, 1990. The sixth meeting is scheduled to take place in Delft, The Netherlands (late Spring, 1996); the organizer and host will be Professor R. A. Sheldon.

Author : Kilian Muñiz
Publisher : Thieme
Page : 1425 pages
File Size : 42,6 Mb
Release : 2018-03-23
Category : Science
ISBN : 9783132012714

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Science of Synthesis: Catalytic Oxidation in Organic Synthesis by Kilian Muñiz Pdf

The development of catalytic systems for the oxidation of organic compounds continues to be of great importance. There is an ongoing and increasing demand for methods that are selective, proceed under mild conditions, and adhere to green chemistry principles. "Science of Synthesis: Catalytic Oxidation in Organic Synthesis" includes the latest developments in the field, as well as selective coverage of more well-established methods. Systems based on metal catalysts, organocatalysts, and biomimetic oxidation are covered, and there is a particular focus on asymmetric processes. Scope, limitations, and mechanism of the reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications.

Author : G. Strukul
Publisher : Springer Science & Business Media
Page : 287 pages
File Size : 44,5 Mb
Release : 2013-03-14
Category : Science
ISBN : 9789401709842

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Catalytic Oxidations with Hydrogen Peroxide as Oxidant by G. Strukul Pdf

Hydrogen peroxide is a chemical that is becoming increasingly fashionable as an oxidant, both in industry and in academia and whose production is expected to increase significantly in the next few years. This growth in interest is largely due to environmental considerations related to the clean nature of hydrogen peroxide as an oxidant, its by-product being only water. To date this chemical has largely been employed as a non-selective oxidant in operations like the bleaching of paper, cellulose and textiles, or in the formulation of detergents, and only to a minimal extent in the manufacture of organic chemicals. This book has been organized to cover the different aspects of the chemistry of hydrogen peroxide. The various chapters into which the book is divided have been written critically by the authors with the general aim of stimulating new ideas and emphasizing those aspects that are likely to lead to new developments in organic synthesis in the coming future.

Author : Wenjun Lu,Lihong Zhou
Publisher : John Wiley & Sons
Page : 528 pages
File Size : 55,8 Mb
Release : 2017-02-03
Category : Science
ISBN : 9781119092513

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Oxidation of C-H Bonds by Wenjun Lu,Lihong Zhou Pdf

A combination of oxidation methods and C‒H bond functionalization, this book emphasizes mechanistic understanding and critical analysis of synthetic reactions to offer a guide or manual for practicing chemists. • Combines oxidation methods and C‒H bond functionalization, two of the most important aspects of organic synthesis • Deals with C‒H bonds, an area of dynamic and continuous research across chemistry and catalysis • Helps readers understand the fundamental and applied differences among various oxidation methods and reactions • Covers mechanistic details, conditions, oxidation reagents, and practical aspects of different reactions

Author : R A Sheldon,Rutger A Van Santen
Publisher : World Scientific
Page : 392 pages
File Size : 42,5 Mb
Release : 1995-10-30
Category : Electronic
ISBN : 9789814579711

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Catalytic Oxidation: Principles And Applications - A Course Of The Netherlands Institute For Catalysis Research (Niok) by R A Sheldon,Rutger A Van Santen Pdf

This book consists of lectures presented by international authorities in the field, at a course on Oxidation Catalysis organized by the Dutch Research School in Catalysis at Rolduc in June 1994.The material covered spans the whole range of the subject from the fundamental principles of gas and liquid phase oxidations to reactor engineering for industrial processing. The use of catalytic oxidation in both bulk and fine chemicals manufacture and the different types of catalysis — heterogeneous-gas phase, homogeneous-liquid phase and heterogeneous-liquid phase — are discussed. In addition, a few special topics, such as electrocatalytic and high-temperature oxidation are dealt with.The book is intended for graduate students or industrial researchers who wish to acquaint themselves with the underlying principles of catalytic oxidations and the numerous applications of this important technology.

Author : André B. Charette
Publisher : John Wiley & Sons
Page : 706 pages
File Size : 51,9 Mb
Release : 2017-06-26
Category : Science
ISBN : 9781119952299

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Handbook of Reagents for Organic Synthesis by André B. Charette Pdf

The Handbook is a compilation of 99 articles on diverse reagents and catalysts that describe the synthesis of heteroarenes, the building blocks of a wide range of chemicals used in pharma and chemical industries. Articles are selected from the e-EROS database and edited to make sure that it includes only the material relevant to the topic of the book and focus on the synthetic aspects. This makes the articles very focused on the needs of readers wanting information on specific syntheses of specific heteroarenes. In addition, the chemistry of each parent heteroarene is also included to ensure that the reader rapidly finds important information. The Handbook is a part of the Handbook of Reagents for Organic Chemistry series, aiming at collecting articles on a particular theme that individual researchers in academia or industry can use on a daily basis.

Author : Leroy Frank Marek,Dorothy Anna Hahn
Publisher : Unknown
Page : 506 pages
File Size : 45,6 Mb
Release : 1932
Category : Catalysis
ISBN : UCAL:$B241281

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The Catalytic Oxidation of Organic Compounds in the Vapor Phase by Leroy Frank Marek,Dorothy Anna Hahn Pdf

Author : Roger Sheldon
Publisher : Elsevier
Page : 447 pages
File Size : 44,8 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323150040

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Metal-Catalyzed Oxidations of Organic Compounds by Roger Sheldon Pdf

Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation–reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds. This book is intended for chemists involved in organic synthesis, catalysis, and organometallic chemistry, both in academic institutions and in industrial laboratories.

Author : Kilian Muñiz
Publisher : Thieme Chemistry
Page : 0 pages
File Size : 46,9 Mb
Release : 2018
Category : Catalysis
ISBN : 3132012416

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Catalytic Oxidation in Organic Synthesis by Kilian Muñiz Pdf

The development of catalytic systems for the oxidation of organic compounds continues to be of great importance. There is an ongoing and increasing demand for methods that are selective, proceed under mild conditions, and adhere to green chemistry principles. "Science of Synthesis: Catalytic Oxidation in Organic Synthesis" includes the latest developments in the field, as well as selective coverage of more well-established methods. Systems based on metal catalysts, organocatalysts, and biomimetic oxidation are covered, and there is a particular focus on asymmetric processes. Scope, limitations, and mechanism of the reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications.

Author : Ronald Michael Painter
Publisher : Stanford University
Page : 110 pages
File Size : 53,8 Mb
Release : 2011
Category : Electronic
ISBN : STANFORD:ds322sz8050

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The Chemoselective Catalytic Oxidation of Alcohols, Diols, and Polyols to Ketones and Hydroxyketones by Ronald Michael Painter Pdf

The chemoselective oxidation of vicinal diols to α-hydroxyketones is a challenge in organic syntheses because not only does the diol need to be oxidized selectively to a monocarbonyl compound, but diols are also prone to overoxidation and oxidative cleavage. Employing a cationic palladium complex, [(neocuproine)Pd(OAc)]2(OTf)2, we were able to demonstrate the selective oxidation of glycerol to dihydroxyacetone mediated by either benzoquinone or O2 as the terminal oxidant, an accomplishment that has little precedent in homogeneous catalysis. Mechanistic studies were undertaken to uncover the nature of this remarkable chemoselectivity. Kinetic and deuterium-labeling studies implicate reversible β-hydride elimination from isomeric Pd alkoxides and turnover-limiting displacement of the dihydroxyacetone product by benzoquinone. We successfully extended this methodology to other terminal 1,2-diols and symmetric vicinal 1,2-diols and have carried out aerobic oxidation of these substrates catalyzed by 1. Examination of the reactivity of 1 with conformationally-restricted 1,2-cyclohexanediols suggests that the diol must chelate to the Pd center for effective oxidation to the hydroxyketone product. In a separate project, we have also investigated the electrocatalytic reduction of dioxygen by several dinuclear copper complexes, an important reaction for fuel cell applications.

Author : K. Muñiz
Publisher : Unknown
Page : 128 pages
File Size : 49,8 Mb
Release : 2018
Category : Electronic
ISBN : 3132403717

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Catalytic Oxidation in Organic Synthesis by K. Muñiz Pdf

Author : V. Cortés Corberán,S. Vic Bellón
Publisher : Elsevier
Page : 883 pages
File Size : 53,6 Mb
Release : 1994-06-21
Category : Technology & Engineering
ISBN : 008087990X

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New Developments in Selective Oxidation II by V. Cortés Corberán,S. Vic Bellón Pdf

This volume contains invited papers and communications presented at the Second World Congress and Fourth European Workshop Meeting on New Developments in Selective Oxidation. The purpose of the meeting was to present new topics and recent advances as well as the discussion of new aspects of fundamental and applied aspects of partial selective oxidation in heterogeneous and homogeneous catalysis. The following topics were discussed: New processes for fine chemicals by catalytic oxidation; Recent developments in surface chemistry of oxide catalysts; Novel catalytic systems and preparation methods; Heterogenized homogeneous oxidation catalysts; Selective oxidation and oxidative dehydrogenation of alkanes; New industrial developments based on catalytic oxidation reactions; Bio-, photo-, and electro-catalytic oxidation; Oxidation by other agents than dioxygen; Bifunctional metal-on-metal oxide catalysts for selective oxidation. This book provides a valuable set of data on selective oxidation reactions which will be extremely useful to catalyst and related practitioners, whether fundamentalists or highly applied, and to process engineers who wish to evaluate current findings in this field.