Chemical Kinetics Of Solids

Author : Hermann Schmalzried
Publisher : John Wiley & Sons
Page : 450 pages
File Size : 55,5 Mb
Release : 2008-07-11
Category : Science
ISBN : 9783527615520

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Chemical Kinetics of Solids by Hermann Schmalzried Pdf

Many different chemical processes take place inside solids or at solid surfaces and interfaces. However, their quantitative description sometimes seems difficult to understand. This book by Professor Schmalzried, author of the eminently successful Solid State Reactions; bridges the gap between the 'physical' and 'chemical' approaches to this subject because it is written in a language which both sides understand. For the first time, a comprehensive coverage of the rapidly developing field of Solid State Kinetics is available. The topics covered in this book go far beyond diffusional transport. Homogeneous and heterogeneous solid-state reactions, phase transitions or the influence of external fields are also treated in detail. With this background, the author explains e.g. charge transport mechanisms in ionic conductors, principles of sensor technology, or oxidation processes clearly and comprehensibly. This book is a must for every solid-state chemist and an indispensable tool for academic and industrial readers alike. From reviews: 'a first-rate reference work that a must for any science library' (J. Am Chem. Soc.) 'can be recommended without restrictions ...' (Z. Phys. Chem.)

Author : C.H. Bamford,R.G. Compton,C.F.H. Tipper†
Publisher : Elsevier
Page : 236 pages
File Size : 44,7 Mb
Release : 1984-09-01
Category : Science
ISBN : 0080868150

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Reactions of Solids with Gases by C.H. Bamford,R.G. Compton,C.F.H. Tipper† Pdf

Reactions of Solids with Gases

Author : Michael E. Brown,D. Dollimore,A.K. Galwey
Publisher : Elsevier
Page : 355 pages
File Size : 46,6 Mb
Release : 1980-01-01
Category : Science
ISBN : 9780080868165

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Reactions in the Solid State by Michael E. Brown,D. Dollimore,A.K. Galwey Pdf

The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.

Author : C. H. Bamford,Charles Frank Howlett Tipper,R. G. Compton
Publisher : Unknown
Page : 237 pages
File Size : 51,6 Mb
Release : 1984
Category : Chemical kinetics
ISBN : 0444422889

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Comprehensive Chemical Kinetics by C. H. Bamford,Charles Frank Howlett Tipper,R. G. Compton Pdf

Author : V.I. Dybkov
Publisher : Trans Tech Publications Ltd
Page : 334 pages
File Size : 51,8 Mb
Release : 2010-03-18
Category : Technology & Engineering
ISBN : 9783038134459

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Reaction Diffusion and Solid State Chemical Kinetics by V.I. Dybkov Pdf

Volume is indexed by Thomson Reuters BCI (WoS). This monograph deals with a physico-chemical approach to the problem of the solid-state growth of chemical compound layers and reaction-diffusion in binary heterogeneous systems formed by two solids; as well as a solid with a liquid or a gas. It is explained why the number of compound layers growing at the interface between the original phases is usually much lower than the number of chemical compounds in the phase diagram of a given binary system. For example, of the eight intermetallic compounds which exist in the aluminium-zirconium binary system, only ZrAl3 was found to grow as a separate layer at the Al–Zr interface under isothermal conditions. The physico-chemical approach predicts that, in most cases, the number of compound layers should not exceed two; with the main factor, resulting in the appearance of additional layers, being crack formation due to thermal expansion and volume effects.

Author : Michael E. Brown,D. Dollimore,A.K. Galwey
Publisher : Elsevier Science
Page : 339 pages
File Size : 49,7 Mb
Release : 1980-01-15
Category : Science
ISBN : 0444418075

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Reactions in the Solid State by Michael E. Brown,D. Dollimore,A.K. Galwey Pdf

The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.

Author : Petr Petrovich Budnikov,Arkadiĭ Mikhaĭlovich Ginstling
Publisher : Unknown
Page : 472 pages
File Size : 52,7 Mb
Release : 1968
Category : Science
ISBN : UOM:39015038808153

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Principles of Solid State Chemistry by Petr Petrovich Budnikov,Arkadiĭ Mikhaĭlovich Ginstling Pdf

Author : James E. House
Publisher : Academic Press
Page : 336 pages
File Size : 47,6 Mb
Release : 2007-08-30
Category : Science
ISBN : 0080550509

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Principles of Chemical Kinetics by James E. House Pdf

James House's revised Principles of Chemical Kinetics provides a clear and logical description of chemical kinetics in a manner unlike any other book of its kind. Clearly written with detailed derivations, the text allows students to move rapidly from theoretical concepts of rates of reaction to concrete applications. Unlike other texts, House presents a balanced treatment of kinetic reactions in gas, solution, and solid states. The entire text has been revised and includes many new sections and an additional chapter on applications of kinetics. The topics covered include quantitative relationships between molecular structure and chemical activity, organic/inorganic chemistry, biochemical kinetics, surface kinetics and reaction mechanisms. Chapters also include new problems, with answers to selected questions, to test the reader's understanding of each area. A solutions manual with answers to all questions is available for instructors. A useful text for both students and interested readers alike, Dr. House has once again written a comprehensive text simply explaining an otherwise complicated subject. Provides an introduction to all the major areas of kinetics and demonstrates the use of these concepts in real life applications Detailed derivations of formula are shown to help students with a limited background in mathematics Presents a balanced treatment of kinetics of reactions in gas phase, solutions and solids Solutions manual available for instructors

Author : Julian Szekely
Publisher : Elsevier
Page : 415 pages
File Size : 40,9 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323151399

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Gas-Solid Reactions by Julian Szekely Pdf

Gas-Solid Reactions describes gas-solid reaction systems, focusing on the four phenomena—external mass transfer, pore diffusion, adsorption/desorption, and chemical reaction. This book consists of eight chapters. After the introduction provided in Chapter 1, the basic components of gas-solid reactions are reviewed in Chapter 2. Chapter 3 describes the reactions of individual nonporous solid particles, while Chapter 4 elaborates the reaction of single porous particles. Solid-solid reactions proceeding through gaseous intermediates are considered in Chapter 5. Chapter 6 deals with the experimental approaches to the study of gas-solid reaction systems. How information on single-particle behavior may be used for the design of multiparticle, large-scale assemblies, and packed- and fluidized-bed reaction systems is deliberated in Chapter 7. The last chapter covers the specific gas-solid reaction systems, including some statistical indices indicating the economic importance of the systems and processes it’s based on. This publication is recommended for practicing engineers engaged in process research, development, and design in the many fields where gas-solid reactions are important.

Author : H. Y. Sohn
Publisher : Elsevier
Page : 536 pages
File Size : 48,5 Mb
Release : 2020-08-12
Category : Science
ISBN : 9780128164662

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Fluid-Solid Reactions by H. Y. Sohn Pdf

Fluid-Solid Reactions, Second Edition takes a detailed and thorough look at the scope of fluid-solid reaction systems, focusing on the four phenomena: external mass transfer, pore diffusion, chemical reaction, and adsorption/desorption. This completely revised new edition builds on the classic original edition through the introduction of cutting-edge new theories and applications, including the formulation and application of a new and convenient law that governs fluid-solid reaction kinetics. This book will be of primary interest to practicing engineers engaged in process research, development, and design in the many fields where fluid-solid reactions are critical to workflow and research. Fluid-solid reactions play a major role in the technology of most industrialized nations. These reactions encompass a very broad field, including the extraction of metals from their ores, the combustion of solid fuels, coal gasification, and the incineration of solid refuse. Features 50% new and revised content, arming researchers with the latest developments in the field Details a new unified approach to modeling the rates of fluid-solid reaction systems Authored by one of the world’s foremost experts on fluid-solid reactions and their applications in the field

Author : Anonim
Publisher : Unknown
Page : 0 pages
File Size : 55,7 Mb
Release : 1984
Category : Electronic
ISBN : 0444422870

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Comprehensive Chemical Kinetics by Anonim Pdf

Author : Gordon Skinner
Publisher : Elsevier
Page : 225 pages
File Size : 42,7 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323159784

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Introduction to Chemical Kinetics by Gordon Skinner Pdf

Introduction to Chemical Kinetics is a compilation of lecture notes of the author about principles, concepts, and theories in chemical kinetics. The book tackles the nature of chemical kinetics, reaction rates and order, and thermodynamic consistency of rate laws. The effects of temperature on kinetics, prediction of reaction rates, gas-phase reactions, and controlled reactions are also discussed. The text also explains the reactions catalyzed by enzymes; reactions in solids and heterogenous systems; oxidation of metals; catalysis of reactions by solids; and methods for different reaction rates. The monograph is recommended as a textbook for undergraduate students in chemistry who are currently taking up kinetics, as it is an easily understood and concise book that can also be used as reference.

Author : Michel Soustelle
Publisher : John Wiley & Sons
Page : 484 pages
File Size : 49,7 Mb
Release : 2013-02-07
Category : Science
ISBN : 9781118604229

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An Introduction to Chemical Kinetics by Michel Soustelle Pdf

This book is a progressive presentation of kinetics of the chemical reactions. It provides complete coverage of the domain of chemical kinetics, which is necessary for the various future users in the fields of Chemistry, Physical Chemistry, Materials Science, Chemical Engineering, Macromolecular Chemistry and Combustion. It will help them to understand the most sophisticated knowledge of their future job area. Over 15 chapters, this book present the fundamentals of chemical kinetics, its relations with reaction mechanisms and kinetic properties. Two chapters are then devoted to experimental results and how to calculate the kinetic laws in both homogeneous and heterogeneous systems. The following two chapters describe the main approximation modes to calculate these laws. Three chapters are devoted to elementary steps with the various classes, the principles used to write them and their modeling using the theory of the activated complex in gas and condensed phases. Three chapters are devoted to the particular areas of chemical reactions, chain reactions, catalysis and the stoichiometric heterogeneous reactions. Finally the non-steady-state processes of combustion and explosion are treated in the final chapter.

Author : Andrzej Plonka
Publisher : Springer Science & Business Media
Page : 158 pages
File Size : 54,8 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642933264

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Time-Dependent Reactivity of Species in Condensed Media by Andrzej Plonka Pdf

These notes on the use of one particular form of the time-dependent rate constant to describe the reaction patterns in condensed media have been put together primarily to encourage chemists to try and accept this new way of experimental data treatment. A number of applications is shown and interpretative aspects are discussed. Emphasized are the problems that need to be currently solved. Some of them are also of current interest in condensed phase physics from which the chemical kinetics benefits a great deal. It was inevitable that the choice of subject matter from both rapidly expanding fields and its form of pre sentation reflect to some extent the author's own interests and some important topics are treated briefly or even omitted. Fully recognizing this, I would like to acknowledge with gratitude the contributions to the subject of all my coworkers in the Laboratories of Lodz, Detroit Mi, MUlheim/Ruhr, and Houston Tx, and of those who helped me in preparing this text. Dr. Wlodzi~ierz Lefik and my son WojciecQ recalculated most of the experimental results, Mrs. Aleksandra Karczewska redrew all the figures. Special thanks go to my wife Ewa for her invaluable assistance in all works and for the final form of the text. AP Lodz, February 1986 CONTENTS 1. Introduction 1 2. Reaction kinetics of species trapped in glassy matrices 6 Excess electrons (6): Post-irradiated decay (6). Spectral relaxation (11). Photostimulated decay (15). Photostimu lated conversion into trapped hydrogen atoms (17). Radio luminescence kinetics (21).

Author : Michael E. Brown,D. Dollimore,A.K. Galwey
Publisher : Elsevier Science
Page : 339 pages
File Size : 52,8 Mb
Release : 1980-01-15
Category : Science
ISBN : 0444418075

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Reactions in the Solid State by Michael E. Brown,D. Dollimore,A.K. Galwey Pdf

The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.