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Visible light is an abundant source of energy. While the conversion of light energy into electrical energy (photovoltaics) is highly developed and commercialized, the use of visible light in chemical synthesis is far less explored. Chemical photocatalysts that mimic principles of biological photosynthesis utilize visible light to drive endothermic or kinetically hindered reactions. This work summarizes in 16 chapters the state of the art and the challenges of this emerging future technology.
Visible light is an abundant source of energy. While the conversion of light energy into electrical energy (photovoltaics) is highly developed and commercialized, the use of visible light in chemical synthesis is far less explored. Chemical photocatalysts that mimic principles of biological photosynthesis utilize visible light to drive endothermic or kinetically hindered reactions.
Visible Light Photocatalysis in Organic Chemistry by Corey R.J. Stephenson,Tehshik P. Yoon,David W.C. MacMillan Pdf
Filling the need for a ready reference that reflects the vast developments in this field, this book presents everything from fundamentals, applications, various reaction types, and technical applications. Edited by rising stars in the scientific community, the text focuses solely on visible light photocatalysis in the context of organic chemistry. This primarily entails photoinduced electron transfer and energy transfer chemistry sensitized by polypyridyl complexes, yet also includes the use of organic dyes and heterogeneous catalysts. A valuable resource to the synthetic organic community, polymer and medicinal chemists, as well as industry professionals.
Heterogeneous Photocatalysis by Jennifer Strunk Pdf
Discover the latest research in photocatalysis combined with foundational topics in basic physical and chemical photocatalytic processes In Heterogeneous Photocatalysis: From Fundamentals to Applications in Energy Conversion and Depollution, distinguished researcher and editor Jennifer Strunk delivers a rigorous discussion of the two main topics in her field—energy conversion and depollution reactions. The book covers topics like water splitting, CO2 reduction, NOx abatement and harmful organics degradation. In addition to the latest research on these topics, the reference provides readers with fundamental information about elementary physical and chemical processes in photocatalysis that are extremely practical in this interdisciplinary field. It offers an excellent overview of modern heterogeneous photocatalysis and combines concepts from different viewpoints to allow researchers with backgrounds as varied as electrochemistry, material science, and semiconductor physics to begin developing solutions with photocatalysis. In addition to subjects like metal-free photocatalysts and photocarrier loss pathways in metal oxide absorber materials for photocatalysis explored with time-resolved spectroscopy, readers will also benefit from the inclusion of: Thorough introductions to kinetic and thermodynamic considerations for photocatalyst design and the logic, concepts, and methods of the design of reliable studies on photocatalysis Detailed explorations of in-situ spectroscopy for mechanistic studies in semiconductor photocatalysis and the principles and limitations of photoelectrochemical fuel generation Discussions of photocatalysis, including the heterogeneous catalysis perspective and insights into photocatalysis from computational chemistry Treatments of selected aspects of photoreactor engineering and defects in photocatalysis Perfect for photochemists, physical and catalytic chemists, electrochemists, and materials scientists, Heterogeneous Photocatalysis will also earn a place in the libraries of surface physicists and environmental chemists seeking up-to-date information about energy conversion and depollution reactions.
Photocatalysis by Jinlong Zhang,Baozhu Tian,Lingzhi Wang,Mingyang Xing,Juying Lei Pdf
This book describes the photocatalytic mechanism, factors affecting photocatalytic activity, design and preparation of different kinds of nanostructured photocatalysts, and their applications in the environmental and energy fields. Further, it illustrates a broad range of modification methods including ion-doping, heterojunction, noble metal deposition, morphological control and sensitizations, which are used to extend the light absorption range of photocatalysts and reduce recombination between electrons and holes. Promising applications include water splitting, contaminant decomposition and photocatalytic reduction of CO2, which are closely related to environmental redemption and new energy development. The book offers an intriguing and useful guide for a broad readership in various fields of catalysis, material sciences, environment and energy.
Introduction to Photocatalysis by Yoshio Nosaka,Atsuko Nosaka Pdf
Presenting the basic science of semiconductor photocatalysis together with the various practical applications, this textbook is ideal for graduate students. It covers fundamental principles and applicable techniques of light, solid state physics, electrochemistry, reaction kinetics, and materials processing. A solid understanding of semiconductor photoelectrochemistry is developed through discussing the basic properties of a representative photocatalytic material, TiO2; the basic science of the light absorption phenomenon and the application to the powder suspension useful for the photocatalytic research; and the electronic state of semiconductors. Following this, the textbook moves on to explore photoelectrochemistry; the mechanism and kinetic analysis of photocatalytic reactions; typical fabrication methods of common photocatalysts and the factors for improving photocatalytic activity; and evaluation methods of photocatalytic activity. The textbook concludes by looking at the future prospects of the applications of photocatalysis. This introductory textbook provides a foundation in photocatalysis to supplement graduate courses in catalysis, environmental science, materials science and chemical engineering.
Nanomaterials and Photocatalysis in Chemistry by Muhammad Bilal Tahir,Khalid Nadeem Riaz Pdf
This book demonstrates the basic and fundamental aspects of nanotechnology and potential application as a photocatalysis in multiple application especially in environment and energy harvesting. This book also contains methods of preparation and characterization of unique nanostructured photocatalysts, and details about their catalytic action. The book consists of seven chapters, including the principles and fundamentals of heterogeneous photocatalysis; the mechanisms and dynamics of surface photocatalysis; research on pure and composites based materials with unique nanostructures; the latest developments and advances in exploiting photocatalyst alternatives to WO3; and photocatalytic materials for applications other than the traditional degradation of pollutants, such as carbon dioxide reduction, water oxidation, a complete spectrum of selective organic transformations and water splitting by photocatalytic reduction. This book will appeal to a wide readership of the academic and industrial researchers and it can also be used in the classroom for undergraduate and graduate students focusing on heterogeneous photocatalysis, sustainable chemistry, energy conversion and storage, nanotechnology, chemical engineering, environmental protection, optoelectronics, sensors, and surface and interface science.
Heterogeneous Photocatalysis by Juan Carlos Colmenares,Yi-Jun Xu Pdf
The book explains the principles and fundamentals of photocatalysis and highlights the current developments and future potential of the green-chemistry-oriented applications of various inorganic, organic, and hybrid photocatalysts. The book consists of eleven chapters, including the principles and fundamentals of heterogeneous photocatalysis; the mechanisms and dynamics of surface photocatalysis; research on TiO2-based composites with unique nanostructures; the latest developments and advances in exploiting photocatalyst alternatives to TiO2; and photocatalytic materials for applications other than the traditional degradation of pollutants, such as carbon dioxide reduction, water oxidation, a complete spectrum of selective organic transformations and water splitting by photocatalytic reduction. In addition, heterogeneized polyoxometalate materials for photocatalytic purposes and the proper design of photocatalytic reactors and modeling of light are also discussed. This book appeals to a wide readership of the academic and industrial researchers and it can also be used in the classroom for undergraduate and graduate students focusing on heterogeneous photocatalysis, sustainable chemistry, energy conversion and storage, nanotechnology, chemical engineering, environmental protection, optoelectronics, sensors, and surface and interface science. Juan Carlos Colmenares is a Professor at the Institute of Physical Chemistry, Polish Academy of Sciences, Poland. Yi-Jun Xu is a Professor at the State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, China.
Visible Light Photocatalysis in Organic Chemistry by Corey R.J. Stephenson,Tehshik P. Yoon,David W.C. MacMillan Pdf
Filling the need for a ready reference that reflects the vast developments in this field, this book presents everything from fundamentals, applications, various reaction types, and technical applications. Edited by rising stars in the scientific community, the text focuses solely on visible light photocatalysis in the context of organic chemistry. This primarily entails photoinduced electron transfer and energy transfer chemistry sensitized by polypyridyl complexes, yet also includes the use of organic dyes and heterogeneous catalysts. A valuable resource to the synthetic organic community, polymer and medicinal chemists, as well as industry professionals.
Photocatalysis by Dionysios D. Dionysiou,Gianluca Li Puma,Jinhua Ye,Jenny Schneider,Detlef Bahnemann Pdf
From environmental remediation to alternative fuels, this book explores the numerous important applications of photocatalysis. The book covers topics such as the photocatalytic processes in the treatment of water and air; the fundamentals of solar photocatalysis; the challenges involved in developing self-cleaning photocatalytic materials; photocatalytic hydrogen generation; photocatalysts in the synthesis of chemicals; and photocatalysis in food packaging and biomedical and medical applications. The book also critically discusses concepts for the future of photocatalysis, providing a fascinating insight for researchers. Together with Photocatalysis: Fundamentals and Perspectives, these volumes provide a complete overview to photocatalysis.
Photocatalysis by Rakshit Ameta,Suresh C. Ameta Pdf
Photocatalysis, reactions carried out in the presence of a semiconductor and light, is rapidly becoming one of the most active areas of chemical research, with applications in areas such as electrochemistry, medicine, and environmental chemistry, Photocatalysis: Principles and Applications stresses the development of various types of photocatalytic semiconductors, including binary, ternary, quaternary, and composite, and their modifications by metallization, sensitization, and doping to enhance their photocatalytic activities. In addition to describing the principles and mechanisms of photocatalysis, it also discusses other possible applications of photocatalysis such as use as antifouling agents, controlling air pollution by degrading contaminants present in the environment, self-cleaning of glasses and tiles in the presence of light/artificial light, green composites, wastewater treatment, hydrogen generation, and inactivation of microorganisms. The book also describes medical applications and summarizes efforts in the field of photosplitting of water as a newer energy source and photoreduction of carbon dioxide for providing synthetic fuels and also a step towards mimicking photosynthesis. Introduces the basic principle of photocatalysis. Provides an overview of the types of semiconductors, their immobilization, and modifications to make them more active. Gives possible applications of photocatalysis in wastewater treatment and strategy to combat against different kinds of pollutions like water, air, and soil. Summarizes efforts in the field of photosplitting of water as a newer energy source and photoreduction of carbon dioxide for providing synthetic fuels and as a step towards mimicking photosynthesis. Discusses inactivation of different kinds of microorganisms. Covers medical applications. Features Introduces the basic principle of photocatalysis. Provides an overview of the types of semiconductors, their immobilization, and modifications to make them more active. Gives possible applications of photocatalysis in wastewater treatment and strategy to combat against different kinds of pollutions like water, air, and soil. Summarizes efforts in the field of photosplitting of water as a newer energy source and photoreduction of carbon dioxide for providing synthetic fuels and as a step towards mimicking photosynthesis. Discusses inactivation of different kinds of microorganisms. Covers medical applications.
Photocatalysis: Fundamental Processes and Applications by Mehrorang Ghaedi Pdf
Photocatalysis: Fundamental Processes and Applications, Volume 32 in the Interface Science and Technology Series, discusses the fundamental aspects of photocatalysis and its process and applications to the decontamination of wastewater, hydrogen production via water splitting, and photo reduction of carbon dioxide to hydrocarbon. The book discusses the fundamental aspects of all applications together with their proper mechanisms, thus providing essential information for deep research in the area of clean environment and green energy production. Provides background on the fundamental and experimental processes of photocatalysis Covers photocatalysis and its impact on creating a clean environment and energy sources Applies photocatalysis to the decontamination of wastewater, hydrogen production via water splitting, and photo reduction of carbon dioxide to hydrocarbon Edited by a world-leading researcher in interface science
Materials Science in Photocatalysis by Elisa I. Garcia Lopez,Leonardo Palmisano Pdf
Materials Science in Photocatalysis provides a complete overview of the different semiconductor materials, from titania to third-generation photocatalysts, examining the increasing complexity and novelty of the materials science in photocatalytic materials. The book describes the most recommended synthesis procedure for each of them and the suitable characterization techniques for determining the optical, structural, morphological, and physical-chemical properties. The most suitable applications of the photocatalysts are described in detail, as well as their environmental applications for wastewater treatment, gaseous effluents depollution, water splitting, CO2 ?xation, selective organic synthesis, coupling reactions, and other selective transformations under both UV light and visible-light irradiation. This book offers a useful reference for a wide audience from students studying chemical engineering and materials chemistry to experienced researchers working on chemical engineering, materials science, materials engineering, environment engineering, nanotechnology, and green chemistry. Includes a complete overview of the different semiconductor materials used as photocatalysts Describes methods of preparation and characterization of photocatalysts and their applications Examines new possibilities to prepare effective photocatalysts
Photocatalytic Systems by Design by Mohan Sakar,R. Geetha Balakrishna,Trong-On Do Pdf
Photocatalytic Systems by Design: Materials, Mechanisms and Applications explores various aspects of photocatalysis, including the photocatalytic phenomenon and process, applications, and the design of photocatalysts via band gap engineering. The book also covers band edge position engineering for multiple photocatalytic applications, such as pollutant degradations, hydrogen production, CO2 reduction into hydrocarbon fuels, antimicrobial disinfections, organic synthesis, N2 fixation, and more. This book is designed to enable beginners to learn the concepts and applications of photocatalysis. Unlike conventional books on photocatalysis, the book provides a 360° perspective into the field of photocatalysis and serves as an informative handbook for all audiences. Addresses all concepts and applications of photocatalysis Covers the fundamentals, including mechanisms of photocatalytic materials Describes the various material systems and engineering of photocatalysts Offers insight into the schemes for photocatalysis of various materials Discusses the application-specific design of photocatalysts