Author : Heekyung Han
Publisher : National Library of Canada = Bibliothèque nationale du Canada
Page : 490 pages
File Size : 41,9 Mb
Release : 2004
Category : Electronic
ISBN : 0612917053
Decoherence, Quantum-classical Correspondence, and Coherent Control in Molecular Dynamics [microform] by Heekyung Han Pdf
Next, quantum-classical correspondence in intrinsic decoherence dynamics is examined via purities and reduced density matrices in both the position and energy representations. Dependence of the correspondence on the nature of the coupling potentials and on the initial conditions are discussed. Decoherence effects on quantum and classical dynamics in reactive scattering problems are investigated. Through the study of dynamics of the isotopic analogues of the collinear H + H2 reaction and transmission over simple one-dimensional barrier potentials, the role of decoherence in improving quantum-classical correspondence is identified with suppressing resonance and tunnelling. Finally, the efficiency of 1+3 photon phase control in the presence of decoherence effects phase is carefully examined in several model cases which include from a population inversion in a two-level bound system to IBr photodissociation. Further, the ways to overcome the control loss caused by dephasing are discussed.