Disposal Of Activated Carbon From Chemical Agent Disposal Facilities

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Disposal of Activated Carbon from Chemical Agent Disposal Facilities

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Examine the Disposal of Activated Carbon from the Heating, Ventilation, and Air Conditioning Systems at Chemical Agent Disposal Facilities
Publisher : National Academies Press
Page : 86 pages
File Size : 43,5 Mb
Release : 2009-10-08
Category : Science
ISBN : 9780309138185

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Disposal of Activated Carbon from Chemical Agent Disposal Facilities by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Examine the Disposal of Activated Carbon from the Heating, Ventilation, and Air Conditioning Systems at Chemical Agent Disposal Facilities Pdf

For the last two decades, the United States has been destroying its entire stockpile of chemical agents. At the facilities where these agents are being destroyed, effluent gas streams pass through large activated carbon filters before venting to ensure that any residual trace vapors of chemical agents and other pollutants do not escape into the atmosphere in exceedance of regulatory limits. All the carbon will have to be disposed of for final closure of these facilities to take place. In March 2008, the Chemical Materials Agency asked the National Research Council to study, evaluate, and recommend the best methods for proper and safe disposal of the used carbon from the operational disposal facilities. This volume examines various approaches to handling carbon waste streams from the four operating chemical agent disposal facilities. The approaches that will be used at each facility will ultimately be chosen bearing in mind local regulatory practices, facility design and operations, and the characteristics of agent inventories, along with other factors such as public involvement regarding facility operations.

The Disposal of Activated Carbon from Chemical Agent Disposal Facilities

Author : Committee to Examine the Disposal of Activated Carbon from the Heating Ventilation and Air Conditioning Systems at Chemical Agent Disposal Facilities,Board on Army Science and Technology,Division on Engineering and Physical Sciences,National Research Council
Publisher : Unknown
Page : 86 pages
File Size : 41,6 Mb
Release : 2009-09-08
Category : Electronic
ISBN : 0309383250

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The Disposal of Activated Carbon from Chemical Agent Disposal Facilities by Committee to Examine the Disposal of Activated Carbon from the Heating Ventilation and Air Conditioning Systems at Chemical Agent Disposal Facilities,Board on Army Science and Technology,Division on Engineering and Physical Sciences,National Research Council Pdf

For the last two decades, the United States has been destroying its entire stockpile of chemical agents. At the facilities where these agents are being destroyed, effluent gas streams pass through large activated carbon filters before venting to ensure that any residual trace vapors of chemical agents and other pollutants do not escape into the atmosphere in exceedance of regulatory limits. All the carbon will have to be disposed of for final closure of these facilities to take place. In March 2008, the Chemical Materials Agency asked the National Research Council to study, evaluate, and recommend the best methods for proper and safe disposal of the used carbon from the operational disposal facilities. This volume examines various approaches to handling carbon waste streams from the four operating chemical agent disposal facilities. The approaches that will be used at each facility will ultimately be chosen bearing in mind local regulatory practices, facility design and operations, and the characteristics of agent inventories, along with other factors such as public involvement regarding facility operations.

Carbon Filtration for Reducing Emissions from Chemical Agent Incineration

Author : National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program
Publisher : National Academies Press
Page : 102 pages
File Size : 44,7 Mb
Release : 1999-09-12
Category : Science
ISBN : 9780309065955

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Carbon Filtration for Reducing Emissions from Chemical Agent Incineration by National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program Pdf

This report reviews the Army's evaluation of carbon filters for use in the baseline incineration PAS, as well as the Army's change management process (the Army's tool for evaluating major equipment and operational changes to disposal facilities). In preparing this report, members of the Stockpile Committee evaluated exhaust gas emissions testing at the two operating baseline incineration systems, JACADS and the TOCDF; evaluated the development of the dilute SOPC carbon filter simulation model; and evaluated the conceptual design of a modified PAS with an activated carbon filter. The two major risk assessments conducted for each continental disposal site that use the baseline system, namely, (1) the quantitative risk assessment, which evaluates the risks and consequences of accidental agent releases, and (2) the health risk assessment, which evaluates the potential effects of nonagent emissions on human health and the environment, were also examined.

Integrated Design of Alternative Technologies for Bulk-Only Chemical Agent Disposal Facilities

Author : National Research Council,Commission on Engineering and Technical Systems,Board on Army Science and Technology,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program
Publisher : National Academies Press
Page : 58 pages
File Size : 51,8 Mb
Release : 2000-06-19
Category : Technology & Engineering
ISBN : 9780309069458

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Integrated Design of Alternative Technologies for Bulk-Only Chemical Agent Disposal Facilities by National Research Council,Commission on Engineering and Technical Systems,Board on Army Science and Technology,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program Pdf

The U.S. Army is pilot testing chemical hydrolysis as a method for destroying the chemical agents stockpiled at Aberdeen, Maryland (HD mustard agent), and Newport, Indiana (VX nerve agent). The chemical agents at both locations, which are stored only in bulk ton containers, will be hydrolyzed (using aqueous sodium hydroxide for VX and water for HD) at slightly below the boiling temperature of the solution. The resulting hydrolysate at Aberdeen, which will contain thiodiglycol as the primary reaction product, will be treated by activated sludge biodegradation in sequencing batch reactors to oxidize organic constituents prior to discharge to an on-site federally owned wastewater treatment facility. The hydrolysate at Newport, which will contain a thiol amine and methyl phosphonic acid as the major reaction products, is not readily amenable to treatment by biodegradation. Therefore, organic constituents will be treated using supercritical water oxidation (SCWO). Integrated Design of Alternative Technologies for Bulk-Only Chemical Agent Disposal Facilities focuses on the overarching issues in the process designs integrating individual processing steps, including potential alternative configurations and process safety and reliability. This report reviews the acquisition design packages (ADPs) for the ABCDF and NECDF prepared by Stone and Webster Engineering Company for the U.S. Army.

Occupational Health and Workplace Monitoring at Chemical Agent Disposal Facilities

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program
Publisher : National Academies Press
Page : 56 pages
File Size : 50,7 Mb
Release : 2001-02-01
Category : Science
ISBN : 9780309075756

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Occupational Health and Workplace Monitoring at Chemical Agent Disposal Facilities by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program Pdf

In keeping with a congressional mandate (Public Law 104-484) and the Chemical Weapons Convention, the United States is currently destroying its chemical weapons stockpile. The Army must ensure that the chemical demilitarization workforce is protected from the risks of exposure to hazardous chemicals during disposal operations and during and after facility closure. Good industrial practices developed in the chemical and nuclear energy industries and other operations that involve the processing of hazardous materials include workplace monitoring of hazardous species and a systematic occupational health program for monitoring workers' activities and health. In this report, the National Research Council Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program examines the methods and systems used at JACADS and TOCDF, the two operational facilities, to monitor the concentrations of airborne and condensed-phase chemical agents, agent breakdown products, and other substances of concern. The committee also reviews the occupational health programs at these sites, including their industrial hygiene and occupational medicine components. Finally, it evaluates the nature, quality, and utility of records of workplace chemical monitoring and occupational health programs.

Review of Chemical Agent Secondary Waste Disposal and Regulatory Requirements

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review of Chemical Agent Secondary Waste Disposal and Regulatory Requirements
Publisher : National Academies Press
Page : 92 pages
File Size : 47,9 Mb
Release : 2007-07-13
Category : Political Science
ISBN : 9780309179843

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Review of Chemical Agent Secondary Waste Disposal and Regulatory Requirements by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review of Chemical Agent Secondary Waste Disposal and Regulatory Requirements Pdf

Under the direction of the U.S. Army's Chemical Materials Agency (CMA) and mandated by Congress, the nation is destroying its chemical weapons stockpile. Large quantities of secondary waste are being generated in the process, and managing these wastes safely and effectively is a critical part of CMA's weapons disposal program. To assist, the CMA asked the NRC to examine the environmental and regulatory requirements that secondary waste treatment is subject to, and to assess best practices by industry in meeting such requirements for similar facilities. This book presents an overview of secondary wastes from chemical agent disposal facilities (CDF), a comparison of CDF and industry experience, site-specific analysis of major secondary waste issues, an examination of closure wastes, and findings and recommendations.

Review of Secondary Waste Disposal Planning for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Review Secondary Waste Disposal and Regulatory Requirements for the Assembled Chemical Weapons Alternatives Program
Publisher : National Academies Press
Page : 84 pages
File Size : 55,5 Mb
Release : 2008-12-14
Category : Political Science
ISBN : 9780309120500

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Review of Secondary Waste Disposal Planning for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Review Secondary Waste Disposal and Regulatory Requirements for the Assembled Chemical Weapons Alternatives Program Pdf

The U.S. Army Program Manager for Assembled Chemical Weapons Alternatives (PMACWA) is charged with disposing of chemical weapons as stored at two sites: Pueblo, Colorado, and Blue Grass, Kentucky. In accordance with congressional mandates, technologies other than incineration are to be used if they are as safe and as cost effective. The weapons are to be disposed of in compliance with the Chemical Weapons Convention. Although an element of the U.S. Army, the PMACWA is responsible to the Assistant Secretary of Defense for Acquisitions, Technology, and Logistics for completing this mission. This book deals with the expected significant quantities of secondary wastes that will be generated during operations of the facilities and their closure. While there are only estimates for the waste quantities that will be generated, they provide a good basis for planning and developing alternatives for waste disposal while the plants are still in the design phase. Establishing efficient disposal options for the secondary wastes can enable more timely and cost-effective operation and closure of the facilities.

Disposal of Activated Carbon from Chemical Agent Disposal Facilities

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Examine the Disposal of Activated Carbon from the Heating, Ventilation, and Air Conditioning Systems at Chemical Agent Disposal Facilities
Publisher : National Academies Press
Page : 87 pages
File Size : 45,7 Mb
Release : 2009-09-08
Category : Science
ISBN : 9780309144773

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Disposal of Activated Carbon from Chemical Agent Disposal Facilities by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Examine the Disposal of Activated Carbon from the Heating, Ventilation, and Air Conditioning Systems at Chemical Agent Disposal Facilities Pdf

For the last two decades, the United States has been destroying its entire stockpile of chemical agents. At the facilities where these agents are being destroyed, effluent gas streams pass through large activated carbon filters before venting to ensure that any residual trace vapors of chemical agents and other pollutants do not escape into the atmosphere in exceedance of regulatory limits. All the carbon will have to be disposed of for final closure of these facilities to take place. In March 2008, the Chemical Materials Agency asked the National Research Council to study, evaluate, and recommend the best methods for proper and safe disposal of the used carbon from the operational disposal facilities. This volume examines various approaches to handling carbon waste streams from the four operating chemical agent disposal facilities. The approaches that will be used at each facility will ultimately be chosen bearing in mind local regulatory practices, facility design and operations, and the characteristics of agent inventories, along with other factors such as public involvement regarding facility operations.

Review of Closure Plans for the Baseline Incineration Chemical Agent Disposal Facilities

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Review and Assess Closure Plans for the Tooele Chemical Agent Disposal Facility and the Chemical Agent Munitions Disposal System
Publisher : National Academies Press
Page : 106 pages
File Size : 49,9 Mb
Release : 2011-01-02
Category : Science
ISBN : 9780309158589

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Review of Closure Plans for the Baseline Incineration Chemical Agent Disposal Facilities by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Review and Assess Closure Plans for the Tooele Chemical Agent Disposal Facility and the Chemical Agent Munitions Disposal System Pdf

This book responds to a request by the director of the U.S. Army Chemical Materials Agency (CMA) for the National Research Council to examine and evaluate the ongoing planning for closure of the four currently operational baseline incineration chemical agent disposal facilities and the closure of a related testing facility. The book evaluates the closure planning process as well as some aspects of closure operations that are taking place while the facilities are still disposing of agent. These facilities are located in Anniston, Alabama; Pine Bluff, Arkansas; Tooele, Utah; and Umatilla, Oregon. They are designated by the acronyms ANCDF, PBCDF, TOCDF, and UMCDF, respectively. Although the facilities all use the same technology and are in many ways identical, each has a particular set of challenges.

Tooele Chemical Agent Disposal Facility

Author : National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program
Publisher : National Academies Press
Page : 93 pages
File Size : 44,6 Mb
Release : 1999-11-24
Category : Science
ISBN : 9780309184403

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Tooele Chemical Agent Disposal Facility by National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program Pdf

This report reviews the status of the U.S. Army Chemical Stockpile Disposal Program (CSDP) operations at Tooele, Utah, with respect to previous recommendations and observations made by the National Research Council (NRC) Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program (Stockpile Committee). The committee recognizes actions that have satisfied recommendations, identifies recommendations that require further action, and provides additional recommendations for improving the overall CSDP performance at the Tooele Chemical Agent Disposal Facility (TOCDF), Tooele, Utah, and other sites.

Monitoring at Chemical Agent Disposal Facilities

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Monitoring at Chemical Agent Disposal Facilities
Publisher : National Academies Press
Page : 104 pages
File Size : 42,9 Mb
Release : 2005-10-13
Category : Science
ISBN : 9780309181587

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Monitoring at Chemical Agent Disposal Facilities by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Monitoring at Chemical Agent Disposal Facilities Pdf

Under the direction of the U.S. Army's Chemical Materials Agency (CMA) and mandated by Congress, the nation is destroying its chemical weapons stockpile. Over the past several years, the Army has requested several studies from the NRC to assist with the stockpile destruction. This study was requested to advise the CMA about the status of analytical instrumentation technology and systems suitable for monitoring airborne chemical warfare agents at chemical weapons disposal and storage facilities. The report presents an assessment of current monitoring systems used for airborne agent detection at CMA facilities and of the applicability and availability of innovative new technologies. It also provides a review of how new regulatory requirements would affect the CMA's current agent monitoring procedures, and whether new measurement technologies are available and could be effectively incorporated into the CMA's overall chemical agent monitoring strategies.

Review of Systemization of the Tooele Chemical Agent Disposal Facility

Author : National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program
Publisher : National Academies Press
Page : 135 pages
File Size : 51,6 Mb
Release : 1996-04-19
Category : Political Science
ISBN : 9780309054867

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Review of Systemization of the Tooele Chemical Agent Disposal Facility by National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program Pdf

In 1993, at Tooele Army Depot, Utah, the Army completed construction of the Tooele Chemical Agent Disposal Facility (TOCDF), the first complete facility for destruction of lethal unitary chemical agents and munitions to be built in the continental United States. The TOCDF will employ the Army's baseline incineration system to destroy the depot's increment of the nation's aging unitary chemical stockpile. This book assesses Army changes and improvements to the TOCDF in response to recommendations contained in earlier reports of the committee. It assesses aspects of the facility's readiness for safe agent handling and destruction operations, its agent monitoring system, and its site specific risk assessment.

Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants
Publisher : National Academies Press
Page : 192 pages
File Size : 49,8 Mb
Release : 2012-09-21
Category : Science
ISBN : 9780309259880

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Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants Pdf

January 2012 saw the completion of the U.S. Army's Chemical Materials Agency's (CMA's) task to destroy 90 percent of the nation's stockpile of chemical weapons. CMA completed destruction of the chemical agents and associated weapons deployed overseas, which were transported to Johnston Atoll, southwest of Hawaii, and demilitarized there. The remaining 10 percent of the nation's chemical weapons stockpile is stored at two continental U.S. depots, in Lexington, Kentucky, and Pueblo, Colorado. Their destruction has been assigned to a separate U.S. Army organization, the Assembled Chemical Weapons Alternatives (ACWA) Element. ACWA is currently constructing the last two chemical weapons disposal facilities, the Pueblo and Blue Grass Chemical Agent Destruction Pilot Plants (denoted PCAPP and BGCAPP), with weapons destruction activities scheduled to start in 2015 and 2020, respectively. ACWA is charged with destroying the mustard agent stockpile at Pueblo and the nerve and mustard agent stockpile at Blue Grass without using the multiple incinerators and furnaces used at the five CMA demilitarization plants that dealt with assembled chemical weapons - munitions containing both chemical agents and explosive/propulsive components. The two ACWA demilitarization facilities are congressionally mandated to employ noncombustion-based chemical neutralization processes to destroy chemical agents. In order to safely operate its disposal plants, CMA developed methods and procedures to monitor chemical agent contamination of both secondary waste materials and plant structural components. ACWA currently plans to adopt these methods and procedures for use at these facilities. The Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants report also develops and describes a half-dozen scenarios involving prospective ACWA secondary waste characterization, process equipment maintenance and changeover activities, and closure agent decontamination challenges, where direct, real-time agent contamination measurements on surfaces or in porous bulk materials might allow more efficient and possibly safer operations if suitable analytical technology is available and affordable.

Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants
Publisher : National Academies Press
Page : 192 pages
File Size : 53,9 Mb
Release : 2012-10-21
Category : Science
ISBN : 9780309259859

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Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants Pdf

January 2012 saw the completion of the U.S. Army's Chemical Materials Agency's (CMA's) task to destroy 90 percent of the nation's stockpile of chemical weapons. CMA completed destruction of the chemical agents and associated weapons deployed overseas, which were transported to Johnston Atoll, southwest of Hawaii, and demilitarized there. The remaining 10 percent of the nation's chemical weapons stockpile is stored at two continental U.S. depots, in Lexington, Kentucky, and Pueblo, Colorado. Their destruction has been assigned to a separate U.S. Army organization, the Assembled Chemical Weapons Alternatives (ACWA) Element. ACWA is currently constructing the last two chemical weapons disposal facilities, the Pueblo and Blue Grass Chemical Agent Destruction Pilot Plants (denoted PCAPP and BGCAPP), with weapons destruction activities scheduled to start in 2015 and 2020, respectively. ACWA is charged with destroying the mustard agent stockpile at Pueblo and the nerve and mustard agent stockpile at Blue Grass without using the multiple incinerators and furnaces used at the five CMA demilitarization plants that dealt with assembled chemical weapons - munitions containing both chemical agents and explosive/propulsive components. The two ACWA demilitarization facilities are congressionally mandated to employ noncombustion-based chemical neutralization processes to destroy chemical agents. In order to safely operate its disposal plants, CMA developed methods and procedures to monitor chemical agent contamination of both secondary waste materials and plant structural components. ACWA currently plans to adopt these methods and procedures for use at these facilities. The Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants report also develops and describes a half-dozen scenarios involving prospective ACWA secondary waste characterization, process equipment maintenance and changeover activities, and closure agent decontamination challenges, where direct, real-time agent contamination measurements on surfaces or in porous bulk materials might allow more efficient and possibly safer operations if suitable analytical technology is available and affordable.

Carbon Filtration for Reducing Emissions from Chemical Agent Incineration

Author : National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program
Publisher : National Academies Press
Page : 101 pages
File Size : 46,9 Mb
Release : 1999-08-12
Category : Science
ISBN : 9780309172714

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Carbon Filtration for Reducing Emissions from Chemical Agent Incineration by National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program Pdf

This report reviews the Army's evaluation of carbon filters for use in the baseline incineration PAS, as well as the Army's change management process (the Army's tool for evaluating major equipment and operational changes to disposal facilities). In preparing this report, members of the Stockpile Committee evaluated exhaust gas emissions testing at the two operating baseline incineration systems, JACADS and the TOCDF; evaluated the development of the dilute SOPC carbon filter simulation model; and evaluated the conceptual design of a modified PAS with an activated carbon filter. The two major risk assessments conducted for each continental disposal site that use the baseline system, namely, (1) the quantitative risk assessment, which evaluates the risks and consequences of accidental agent releases, and (2) the health risk assessment, which evaluates the potential effects of nonagent emissions on human health and the environment, were also examined.