Ferroelectric And Antiferroelectric Liquid Crystals
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The Physics of Ferroelectric and Antiferroelectric Liquid Crystals by I Muševic,R Blinc,B Zekš Pdf
This book presents the basic physics of ferroelectric and antiferroelectric liquid crystals in a simple and transparent way. It treats both the basic and the applied aspects of ferroelectric and antiferroelectric liquid crystal research, starting from the discovery of ferroelectricity in liquid crystals in 1975 and ending with the resonant X-ray experiment in ferrielectric and antiferrielectric phases in 1998. Particular attention is paid to the optical properties, electrooptic effects, phase transitions and experimental methods used in liquid crystal research. Special chapters are devoted to dielectric spectroscopy, light scattering, NMR, STM and AFM in complex fluids. The more than 300 illustrations help to present the basic physics of liquid crystalline ferroelectrics and antiferroelectrics in a way that can be easily followed by students, engineers and scientists dealing with liquid crystal research. Contents:Symmetry, ferroelectricity and antiferroelectricity in liquid crystalsChiral phases of achiral moleculesBroken symmetry and elementary excitationsLandau theory of ferroelectric and antiferroelectric liquid crystalsOrder parameter dynamics, soft modes and gapless phasonsFerroelectric liquid crystals in external magnetic and DC electric fieldsPhase transitions in thin cellsSurface-induced polaritySoliton and plane wave dynamics in thin cellsFreely suspended filmsLinear optics of helical structuresBirefringence, optical rotation and quasielastic light scattering in ferroelectric and antiferrolectric phasesLinear electrooptic response of ferroelectric and antiferroelectric liquid crystalsMagnetic-field induced biaxialityDielectric dispersionSoft and phase mode dynamicsDielectric response of a multisoliton latticePolarization noiseDeuteron NMR in ferroelectric and antiferroelectric liquid crystalsAnisotropy of the critical magnetic fieldPolar and quadrupolar biasing of molecular rotation around the long molecular axis14N NQR and 13C NMR in tilted smectic phasesSynclinic versus anticlinic ordering in tilted smecticsOrder parameter dynamics and a doubling of a smectic unit cell in antiferroelectric liquid crystalsOptical properties of the antiferroelectric phaseDielectric, linear and nonlinear electrooptic response of the antiferroelectric phaseFerroelectricity, antiferroelectricity and intermediate phasesDiscrete models of intermediate phasesSTM and AFM in complex liquidsSurface stabilized ferroelectric liquid crystal displaysUltrafast electroclinic effectDeformed helix mode ferroelectric displaysChevrons in SSFC displaysIon-director coupling and depolarization field in SSFLCDLandau theory of second order phase transitionsSurvey of different experimental methodsNuts and bolts collection Readership: Graduate students, engineers and scientists dealing with liquid crystals and optical display. keywords:Liquid Crystals;Soft Matter;Ferroelectricity;Antiferroelectricity;Ferroelectric;Antiferroelectric;Phase Transitions;Optics;High Magnetic Fields;Solitons;Light Scattering;Displays “… this is an excellent and comprehensive book, especially for those who prefer a more formal treatment of the topics … Because many of the topics apply to nonferroelectric liquid crystals as well, I believe that this book has an important place on the shelf of anybody who deals with liquid crystals; it is also an absolute 'must' for anybody who works on FLCs and AFLCs.” Charles Rosenblatt Case Western Reserve University “The structure of the book is extremely logical and has been well thought out … The real strength of the book is in the clear and concise explanations the authors give of many aspects of underlying theory and the implications of various experimental results. Many of the discussions of conflicting data and ideas are also presented in an unbiased way. This makes the book eminently readable, not only as a resource for advanced researchers in the area, but also as a first introduction for new graduate students … This is an essential reference work and should occupy a place on all liquid-crystal bookcases.” Journal of Applied Crystallography
Ferroelectric and Antiferroelectric Liquid Crystals by Sven T. Lagerwall Pdf
The study of ferroelectricity is a branch of solid state physics which has shown rapid growth during the recent years. Ferroelectric materials exhibit unusual electric properties which make them useful in modern (opto)electronic technology, esp. display technology. Ferroelectric and antiferroelectric liquid crystals, including also various polymer forms, are the hottest research topic today in liquid crystals. The field is at the very beginning of industrial exploitation - a sensitive phase in which a good reference work is needed and will have a broad spectrum of readers both at universities and in industry.
Dielectric Properties Of Liquid Crystals by Zbigniew Galewski Pdf
Introduction - This book, consisting of 10 chapters, should be treated as a complement that brings the reader up to date with the latest contributions to the rich literature on liquid crystals. A prominent place in this literature is occupied by the dielectric properties which are important in estimation of usefulness of these materials and in understanding the molecular processes determining various mesophases. In the field of dielectrics in general, and in connection with the structure and phase transitions the entries in references [1-14] can be recommended. With respect to general aspects of liquid-crystalline properties and molecular dynamics one can point out the references [15-36]. Most of them contain as well chapters on dielectric properties. In addition there is a number of books and monographs related strictly to the dielectric properties of liquid crystals, in particular references [37-45]. For the readers less familiar with this topic and interested in the basic knowledge of dielectric aspects of liquid crystals one can suggest the reviews [46-48]. Basic difference between properties of isotropic liquid and liquid crystal lies in the existence in the latter case of at least one degree of order. The ordering can be also considered with respect to a crystalline phase. Thus introducing at least one degree of disorder (rotational or translational) causes the occurrence of a mesophase which, however, is not identical with the liquid-crystalline phase. If the mesophase is to be liquid-crystalline, it should possess at least one translational degree of disorder. The disorder connected with further degrees of freedom leads to rich polymorphism. The most characteristic feature of liquid-crystalline phases is a precisely defined degree of disorder of molecules building these phases and their anisotropy which is exhibited in molecular structure and all measurable physical parameters such as polarizability. This is the reason why such phases are also called anisotropic liquids. The insertion into the molecules that form mesophases of fragments either chiral or influencing antagonistically already present fragments (e.g. by replacing one alkyl group by perfluorinated chain) leads to additional interactions which compete with interactions responsible for the stability of liquid-crystalline phases. This causes the frustration phenomena, i.e. the mutual overlapping of interactions frequently responsible for opposite effects. These induced phenomena conduce to unexpected structures (banana-type or columnar-type mesophases) and properties such as helicity, ferroelectricity or antiferroelectricity. Of particular interest seem to be ferroelectric liquid crystals (chiral tilted smectics such as SmC*, SmI* and others) showing collective modes: tilt fluctuations (soft modes) and phase fluctuations (Goldstone mode). Unusual progress observed in the last half-century has occurred due to use of some additional interacting fragments and structural details. Liquid crystalline polymers and metalomesogens present rapidly growing branches of knowledge of liquid crystal. Ferromagnetism and superconductivity of liquid crystals still pose a challenge. In this monograph we present different aspects of dielectric properties of mesogens. Chapter 1 presented by Otowski is dedicated to general problems of the molecular dipole s motion in electric field. Based on the broadband dielectric studies results of a few liquid-crystalline substances, their dielectric behavior is discussed by means of Nordio-Rigatti-Segre theory. The pretransitional anomalies observed in isotropic phase close to the phase transitions by means of dielectric measurements are described by Drozd-Rzoska, Rzoska and Janik in Chapter 2. An extended part of this book is devoted to chiral liquid crystals, the importance of which for applications and expectations for them are continuously increasing. The principles of the dielectric behavior of chiral liquid-crystalline compounds based on general considerations applying for other dipolar systems as well is presented by Hoffmann in Chapter 3. In general considerations based on the example of 12 selected substances showing extremely rich polymorphism Marzec, Mikulko, Wróbel and Haase analyze impressive behaviors of collective modes (Chapter 4). The problem of non-linear dielectric effects constitutes an important part of this book. A general introduction to the non-linear dielectric spectroscopy is contained in Chapter 5 elaborated by Kedziora, who concentrates himself on the isotropic phase, solutions and precritical phenomena. The problem of molecular properties of smectic materials and relaxation in ferroelectric liquid crystals with particular attention paid to electrooptic phenomena are discussed by Kuczynski in Chapter 6. Advantages of electrooptic methods applied to chiral tilted smectic liquid crystals with either ferroelectric or antiferroelectric dipole order are known. However, less popular problem of so called organic glass formers presented by Massalska-Arodz, Sciesinska, Sciesinski, Krawczyk, Inoba and Zielinski in Chapter 7 deserved attentions. Properties of these materials are discussed by using the results of complementary methods such as INS, QENS, adiabatic calorimetry and far-infrared spectra. Chapter 8, presented by Rózanski, is devoted to the dielectric properties of liquid crystals confined in porous matrices or dispersed throughout solid matrices. Such systems seem to be fascinating not only from the point of view of surface interactions but also due to attractive properties of dispersed systems in nanoscale. Of great value is also Chapter 9 by Kocot, Merkel, Sufin, Vij and Mehl describing dendrimeric liquid crystals built of molecules containing siloxane or carbosilazane cores. The problems of dynamics and ordering are discussed in terms of IR and dielectric spectroscopy results. Chapter 10, written by Urban, is committed to the relaxation processes in calamitic liquid crystals with emphasis on pressure and temperature effects. Finally let us direct readers attention to general references relating to the new liquid crystalline compounds [49] and IUPAC classification of these systems [50]. 1. Boettcher C. J. F., van Belle O.C., Bordewijk P. and Rip A., 1973, Theory of Electric Polarization, Vol.I: Dielectrics in Static Fields, 2nd revised edition, Elsevier Science Ltd, Amsterdam. 2. Boettcher C.J.F. and Bordewijk, 1978, Theory of Electric Polarization, Vol.II. Dielectrics in Time-dependent Fields, 2nd revised edition, Elsevier Science Ltd, Amsterdam. 3. Hill N., Vaughan W.E., Price A.H. and Davies M., 1969, Dielectric Properties and Molecular Behaviour, van Nostrand, London. 4. Froehlich H., 1958, Theory of Dielectrics, Oxford University Press, London. 5. von Hippel A.R., 1995, Dielectric Materials and Applications, Artech House Publishers. 6. Davies M., 1965, Some Electrical and Optical Aspects of Molecular Behaviour, Pergamon Press, Oxford. 7. Scaife B.K.P., 1998, Principle of Dielectrics, Revised edition, Oxford University Press, Clarendon, Oxford. 8. Riande E. and Diaz-Calleja R., 2004, Electrical Properties of Polymers, Marcel Dekker, NY. 9. Jonscher A.K., 1996, Universal Relaxation Law, Chelsea Dielectric Press Ltd, London. 10. Grigas J., 1996, Microwave Dielectric Spectroscopy of Ferroelectrics and Related Materials, Series: Ferroelectricity and Related Phenomena, Volume 9, Gordon and Breach Science Publishers, Philadelphia. 11. Runt J.P. and Fitzgerald J.J.(Eds.), 1997, Dielectric Spectroscopy of Polymeric Materials, American Chemical Society, Washington, DC. 12. Havriliak S. and Havriliak S.J., 1996, Dielectric and Mechanical Relaxation in Materials, Hanser Verlag, München. 13. Gaiduk V.I. and McConnel J.R., 1999, Dielectric Relaxation and Dynamics of Polar Molecules, World Scientific Pub. Co.Inc., Singapore. 14. Kremer F. and Schönhals A. (Eds) 2002, Broadband Dielectric Spectroscopy, Springer, NY. 15. Demus D., Goodby J., Gray G.W., Spiess H.W. and Vill V. (Eds.), 1998, Handbook of Liquid Crystals, 4-Volume Set, Wiley-VCH, Veinheim. 16. Demus D., Goodby J., Gray G.W., Spiess H.W. and Vill V (Eds.), 1999, Physical Properties of Liquid Crystals, Wiley-VCH, Veinheim. 17. Stegemeyer H. (Ed.), 1994, Liquid Crystals, Steinkopff, Darmstadt and Springer, NY. 18. Buka A. (Ed.), 1993, Modern Topics in Liquid Crystals. From Neutron Scattering to Ferroelectricity, World Scientific, Singapore. 19. Dierking I., 2003. Texture of Liquid Crystals, Wiley-VCH, Weinheim. 20. Luckhurst G.R. and Gray G.W. (Eds.), 1979, The Molecular Physics of Liquid Crystals, Academic Press, London. 21. de Gennes P.G. and Prost J., 1993, The Physics of Liquid Crystals, 2nd edition, Clarendon Press, Oxford. 22. Gray G.W. and Goodby J.W., 1984, Smectic Liquid Crystals. Textures and Structures, Leonard Hill, Glasgow. 23. Martellucci S. and Chester A.N. (Eds.), 1992, Phase Transitions in Liquid Crystals, NATO ASI Series, Vol.B290, Plenum Press, NY. 24. Luckhurst G.R. and Veracini C.A. (Eds.), 1994. The Molecular Dynamics of Liquid Crystals, NATO ASI Series, Vol.C431, Kluwer, Dordrecht. 25. Priestley E.B., Wojtowicz P.J. and Sheng P. (Eds.), 1975, Introduction to Liquid Crystals, Plenum Press, NY. 26. Lagerwall S.T., 1999, Ferroelectric and Antiferroelectric Liquid Crystals, Wiley-VCH, Weinheim. 27. Baus M., Rull L.F. and Ryckaert J.P. (Eds.), 1995, Observation, Prediction and Simulation of Phase Traansitions in Complex Fluids, Kluwer, Dordrecht. 28. Anisimov M.A., 1991, Critical Phenomena in Liquids and Liquid Crystals, Gordon & Breach, Philadelphia 29. Vertogen G. and de Jeu W.H., 1986, Thermotropic Liquid Crystals, Fundamentals, Springer, Berlin 30. de Jeu W.H., 1980, Physical Properties of Liquid Crystalline Materials, Gordon & Breach, NY 31. Helfrich W. and Heppke G., (Eds.), 1980, Liquid Crystals of One and Two Dimensional Order, Springer, Berlin. 32. Goodby J.W., Blinc R., Clark N.A., Lagerwall S.T., Osipov M.A., Pikin S.A., Sakurai T., Yoshino K. and }eka B., 1991, Ferroelectric Liquid Crystals. Principles, Properties and Applications, Series: Ferroelectricity and Related Phenomena, Volume 7. Gordon and Breach, Philadelphia. 33. Pikin S.A., 1991, Structural Transformations in Liquid Crystals, Gordon and Breach, NY. 34. Haberlandt R., Michel D., Poppel A. and Stannarius R., 2005, Molecules in interaction with surfaces and interfaces, Springer NY. 35. Crawford G.P. and }umer S., (Eds), Liquid Crystals in Complex Geometries, 1996, Taylor & Francis, London. 36. Muaevic I., Blinc R. and }eka B., 2000, The Physics of Ferroelectric and Antiferroelectric Liquid Crystals, World Scientific, Singapore. 37. Haase W. and Wróbel S. (Eds.), 2003, Relaxation Phenomena. Liquid Crystals, Magnetic Systems, Polymers, High-TC Superconductors, Metallic Glasses., Springer, NY. 38. Kresse H., 1983, in: Advances in Liquid Crystals, Vol.6, Brown G.H. (ed.), Academic Press, NY. 39. Coffey W.T. and Kalmykov Y.P. 2000, Adv.Chem.Phys. 111, 487. 40. de Jeu W.H., 1978, in: Solid State Physics, Supplement 14. Liebert L. (ed.), Academic Press. 41. Rzoska S.J. and Zhelezny V.P., (Eds), 2004, Nonlinear Dielectric Phenomena in Complex Liquids, Kluwer, Dordrecht. 42. Urban S. and Wuerflinger A., 1979, Adv.Chem.Phys., 98, 143. 43. Kresse H., 1982, Fortschrifte der Physik, 80, 507. 44. Urban S., 2001, in: Physical Properties of Liquid Crystals: Nematics, Dunmur D., Fukuda A. and Luckhurst G. (Eds.), Inspec, London, p.267. 45. Blinov L.M. and Chigrinov V.G., 1994, Electrooptic Effects in Liquid Crystal Materials, Springer, NY. 46. Meier G. and Saupe A., 1966, in: Liquid Crystals, Brown G.H., Dines G.J. and Labes M.M. (Eds.), Gordon and Breach, Philadelphia. 47. Kresse H., 1998, in: Handbook of Liquid Crystals, Demus D., Goodby J., Gray G.W., Spiess H.W. and Vill V. (Eds.), Vol.2, Wiley-VCH, Veinheim. 48. Dunmur D and Toriyama K., 1998, in: Handbook of Liquid Crystals, Demus D., Goodby J., Gray G.W., Spiess H.W. and Vill V. (Eds.), Vol. 1, Wiley-VCH, Veinheim. 49. Vill V., 2006, LiqCryst 4.6. Data Base, Fujitsu. 50. Byron M. et al. 2001, Pure Appl.Chem., 73, 845.
Chirality in Liquid Crystals by Heinz Kitzerow,Christian Bahr Pdf
Describes the main aspects of chirality in liquid crystals, and points out some of the open questions of current research. The chapters review the highlights of the important topics and questions.
Modern Topics In Liquid Crystals: From Neutron Scattering Ferroelectricity by Agnes Buka Pdf
This volume contains 19 review articles, written by leading experts in the field of neutron scattering, NMR, dielectric spectroscopy, ferroelectricity, liquid crystal polymers as well as related subjects. The articles cover a broad range of topics which are currently the center of focus and interest in this field. The book will be useful for experienced researchers as well as students and those who want to enter the field. Apart from the fact that such a publication covers a gap in the literature, there is also a personal actuality. This volume will be devoted to Professor L Bata, who started the liquid crystal research in Hungary some 25 years ago and who is still head of the department at KFKI today. He initiated a lot of new subjects in the field and supported many young scientists during these years. He is celebrating his 60th birthday this year.
Chirality in Liquid Crystals by Heinz Kitzerow,Christian Bahr Pdf
Describes the main aspects of chirality in liquid crystals, and points out some of the open questions of current research. The chapters review the highlights of the important topics and questions.
Functional Metal Oxides by Satishchandra Balkrishna Ogale,T. Venky Venkatesan,Mark Blamire Pdf
Functional oxides are used both as insulators and metallic conductors in key applications across all industrial sectors. This makes them attractive candidates in modern technology ? they make solar cells cheaper, computers more efficient and medical instrumentation more sensitive. Based on recent research, experts in the field describe novel materials, their properties and applications for energy systems, semiconductors, electronics, catalysts and thin films. This monograph is divided into 6 parts which allows the reader to find their topic of interest quickly and efficiently. * Magnetic Oxides * Dopants, Defects and Ferromagnetism in Metal Oxides * Ferroelectrics * Multiferroics * Interfaces and Magnetism * Devices and Applications This book is a valuable asset to materials scientists, solid state chemists, solid state physicists, as well as engineers in the electric and automotive industries.
Bent-Shaped Liquid Crystals by Hideo Takezoe,Alexey Eremin Pdf
Bent-Shaped Liquid Crystals: Structures and Physical Properties provides insight into the latest developments in the research on liquid crystals formed by bent-shaped mesogens. After a historical introduction, the expert authors discuss different kinds of mesophase structures formed by bent-shaped molecules. This book devotes the majority of its pages to physical properties such as polar switching, optics and non-linear optics, and behavior in restricted geometries. However, as chemistry is often highly relevant to the emergence of new phases, particularly with reflection symmetry breaking, it also involves a broad spectrum of interesting chemistry viewpoints.
