Fischer Tropsch Synthesis On Supported Cobalt Based Catalysts

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Iron and Cobalt Catalysts

Author : Wilson D. Shafer,Gary Jacobs
Publisher : MDPI
Page : 414 pages
File Size : 46,7 Mb
Release : 2020-06-23
Category : Science
ISBN : 9783039283880

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Iron and Cobalt Catalysts by Wilson D. Shafer,Gary Jacobs Pdf

Since the turn of the last century when the field of catalysis was born, iron and cobalt have been key players in numerous catalysis processes. These metals, due to their ability to activate CO and CH, haev a major economic impact worldwide. Several industrial processes and synthetic routes use these metals: biomass-to-liquids (BTL), coal-to-liquids (CTL), natural gas-to-liquids (GTL), water-gas-shift, alcohol synthesis, alcohol steam reforming, polymerization processes, cross-coupling reactions, and photocatalyst activated reactions. A vast number of materials are produced from these processes, including oil, lubricants, waxes, diesel and jet fuels, hydrogen (e.g., fuel cell applications), gasoline, rubbers, plastics, alcohols, pharmaceuticals, agrochemicals, feed-stock chemicals, and other alternative materials. However, given the true complexities of the variables involved in these processes, many key mechanistic issues are still not fully defined or understood. This Special Issue of Catalysis will be a collaborative effort to combine current catalysis research on these metals from experimental and theoretical perspectives on both heterogeneous and homogeneous catalysts. We welcome contributions from the catalysis community on catalyst characterization, kinetics, reaction mechanism, reactor development, theoretical modeling, and surface science.

Fischer-Tropsch Synthesis, Catalysts, and Catalysis

Author : Burtron H. Davis,Mario L. Occelli
Publisher : CRC Press
Page : 424 pages
File Size : 47,7 Mb
Release : 2016-04-06
Category : Science
ISBN : 9781466555303

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Fischer-Tropsch Synthesis, Catalysts, and Catalysis by Burtron H. Davis,Mario L. Occelli Pdf

With petroleum prices spiraling upward, making synthetic fuels-or "synfuels"-from coal, natural gas, and biomass has become more economically competitive. Advanced energy companies now focus exclusively on alternative fuels, and many oil companies have programs dedicated to developing synthetic fuels. The Fischer-Tropsch process, which uses a colle

Advances in Fischer-Tropsch Synthesis, Catalysts, and Catalysis

Author : B. H. Davis,Mario L. Occelli
Publisher : CRC Press
Page : 424 pages
File Size : 42,6 Mb
Release : 2009-11-10
Category : Science
ISBN : 1420062573

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Advances in Fischer-Tropsch Synthesis, Catalysts, and Catalysis by B. H. Davis,Mario L. Occelli Pdf

Rising oil costs have stimulated significant interest in the Fischer-Tropsch synthesis (FTS) as a method for producing a synthetic petroleum substitute. Drawn from the proceedings at a symposium held during the 236th meeting of the American Chemical Society in Philadelphia in August 2008, Advances in Fischer-Tropsch Synthesis, Catalysts, and Catalysis explores the recent developments in Fischer-Tropsch technology, which holds great promise in the area of renewable resources. Expert contributors explore a range of issues The book focuses on three main themes: catalyst preparation and activation, reaction mechanism, and process-related topics. A panel of expert contributors discusses synthesis of catalysts, carbon nanomaterials, nitric oxide calcinations, the influence of carbon, catalytic performance issues, chelating agents, and Cu and alkali promoters. They also explore Co/silica catalysts, thermodynamic control, the Two Alpha model, co-feeding experiments, internal diffusion limitations, Fe-LTFT selectivity, and the effect of co-fed water. Lastly, the book examines cross-flow filtration, kinetic studies, reduction of CO2 emissions, syncrude, and low-temperature water-gas shift. Attaining the maximum catalytic activity and catalyst life The themes explored in the book demonstrate that while the Fischer-Tropsch synthesis (FTS) has advanced in maturity, many issues remain concerning the preparation of increasingly active catalysts and the method of activation to attain the maximum catalytic activity and catalyst life. The book includes coverage of the structural features, their changes, and the application of increasingly sophisticated characterization techniques, shedding light on the reaction mechanism and providing a glimpse into the processes and reaction rates under realistic commercial process conditions.

Fischer-Tropsch Technology

Author : André Steynberg,Mark Dry
Publisher : Elsevier
Page : 722 pages
File Size : 51,6 Mb
Release : 2004-10-30
Category : Technology & Engineering
ISBN : 9780080472799

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Fischer-Tropsch Technology by André Steynberg,Mark Dry Pdf

Fischer-Tropsch Technology is a unique book for its state-of-the-art approach to Fischer Tropsch (FT) technology. This book provides an explanation of the basic principles and terminology that are required to understand the application of FT technology. It also contains comprehensive references to patents and previous publications. As the first publication to focus on theory and application, it is a contemporary reference source for students studying chemistry and chemical engineering. Researchers and engineers active in the development of FT technology will also find this book an invaluable source of information. * Is the first publication to cover the theory and application for modern Fischer Tropsch technology * Contains comprehensive knowledge on all aspects relevant to the application of Fischer Tropsch technology* No other publication looks at past, present and future applications

Natural Gas Conversion VII

Author : Xinhe Bao,Yide Xu
Publisher : Elsevier
Page : 776 pages
File Size : 42,9 Mb
Release : 2004-05-11
Category : Technology & Engineering
ISBN : 9780080473543

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Natural Gas Conversion VII by Xinhe Bao,Yide Xu Pdf

This volume contains peer-reviewed manuscripts describing the scientific and technological advances presented at the 7th Natural gas Conversion Symposium held in Dalian, China, June 6-10, 2004, and a FREE CD-rom. This symposium continues the tradition of excellence and the status as the premier technical meeting in this area established by previous meetings.The manuscripts have been divided into eight different topics, Industrial Processes, Economics, Technology Demonstration and Commercial Activities;, Production of Hydrogen from Methane, Methanol, and Other Sources; Production of Synthesis; Fischer-Tropsch Synthesis of Hydrocarbons; From Synthesis Gas to; Catalytic Combustion; From Natural Gas to Chemicals; Light Hydrocarbons; and Production and Conversion . These are the most interesting subjects in the utilization of natural gas with recent scientific innovation and technological advances. The book is of interest to all students and researchers active in utilization of natural gas. - This book contains the papers of the symposium that is considered to be the premier technical meeting in this area. - The chapters give an overview of the latest developments in utilization of natural gas. - Topics included in the book are: Industrial Processes, Economics, Technology Demonstration and Commercial Activities;, Production of Hydrogen from Methane, Methanol, and Other Sources; Production of Synthesis; Fischer-Tropsch Synthesis of Hydrocarbons; From Synthesis Gas to; Catalytic Combustion; From Natural Gas to Chemicals; Light Hydrocarbons; and Production and Conversion.

Ordered Mesoporous Materials

Author : Dongyuan Zhao,Ying Wan,Wuzong Zhou
Publisher : John Wiley & Sons
Page : 544 pages
File Size : 42,9 Mb
Release : 2012-11-28
Category : Science
ISBN : 9783527647897

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Ordered Mesoporous Materials by Dongyuan Zhao,Ying Wan,Wuzong Zhou Pdf

Mesoporous materials are a class of molecules with a large and uniform pore size, highly regular nanopores, and a large surface area. This book is devoted to all aspects and types of these materials and describes, in an in-depth and systematic manner, the step-by-step synthesis and its mechanism, as well as the characterization, morphology control, hybridization, and applications, of mesoporous molecular sieves. In so doing, it covers silicates, metal-doped silicates, nonsilicates, and organic-inorganic hybrids. Although the emphasis is on synthesis, the expert authors also discuss characterization and applications, ranging from catalysis and biochemistry to optics and the use of these materials as templates for nanomaterial synthesis. Both the fundamentals and the latest research results are covered, ensuring that this monograph serves as a reference for researchers in and newcomers to the field.

Catalysis in the Refining of Fischer-Tropsch Syncrude

Author : Arno de Klerk,Edward Furimsky
Publisher : Royal Society of Chemistry
Page : 295 pages
File Size : 45,5 Mb
Release : 2010
Category : Science
ISBN : 9781849730808

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Catalysis in the Refining of Fischer-Tropsch Syncrude by Arno de Klerk,Edward Furimsky Pdf

The first book to provide a review of the literature on the catalysis needed to refine syncrude to transportation fuels.

The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide

Author : G. Henrici-Olive,S. Olive
Publisher : Springer Science & Business Media
Page : 239 pages
File Size : 40,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642696626

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The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide by G. Henrici-Olive,S. Olive Pdf

During the oil embargo, in the winter 1973174, parts of Western Europe present ed an almost war-like aspect on Saturdays and Sundays: no traffic on the high ways, no crowds at ski resorts and other weekend entertainment places, no gaso line at the pumps. Living and teaching then in that part of the world, and discussing the situa tion with our students, we came to the conclusion that it would be timely to col lect the fine chemistry already known at the time in the field of conversion of coal to gasoline and other chemicals, and by this way help to draw the attention to this important alternative to crude oil. The idea of this book was born. The energy shock of the early seventies has been healthy and of great conse quences in chemistry. Large amounts of research money have been put to work since, and our knowledge of the possibilities and limitations of coal-based chemistry has increased enormously. During several years it appeared inap propriate to write a monograph about a topic which was in the midst of such an impetuous development. Nevertheless, we collected, and critically selected, the upcoming work as it appeared in the literature, and also tried to provide some modest input ourselves. Now, ten years later, the situation seems to be settled to a certain degree.

Methane Conversion

Author : D.M. Bibby,C.D. Chang,S. Yurchak,R.F. Howe
Publisher : Elsevier
Page : 737 pages
File Size : 47,6 Mb
Release : 1988-03-01
Category : Technology & Engineering
ISBN : 0080960707

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Methane Conversion by D.M. Bibby,C.D. Chang,S. Yurchak,R.F. Howe Pdf

This proceedings volume comprises the invited plenary lectures, contributed and poster papers presented at a symposium organised to mark the successful inauguration of the world's first commercial plant for production of gasoline from natural gas, based on the Mobil methanol-to-gasoline process. The objectives of the Symposium were to present both fundamental research and engineering aspects of the development and commercialization of gas-to-gasoline processes. These include steam reforming, methanol synthesis and methanol-to-gasoline. Possible alternative processes e.g. MOGD, Fischer-Tropsch synthesis of hydrocarbons, and the direct conversion of methane to higher hydrocarbons were also considered. The papers in this volume provide a valuable and extremely wide-ranging overview of current research into the various options for natural gas conversion, giving a detailed description of the gas-to-gasoline process and plant. Together, they represent a unique combination of fundamental surface chemistry catalyst characterization, reaction chemistry and engineering scale-up and commercialization.

Recent Advances in Cobalt and Related Catalysts

Author : John Vakros
Publisher : Mdpi AG
Page : 118 pages
File Size : 44,8 Mb
Release : 2021-09-08
Category : Science
ISBN : 3036514228

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Recent Advances in Cobalt and Related Catalysts by John Vakros Pdf

Currently, cobalt and related catalysts are very attractive as they provide many advantages, such as low cost and high activity, in a variety of applications. Cobalt catalysts are among the most active catalysts for Fischer-Tropsch synthesis and they promote the catalytic activity of the hydrodesulfurization catalysts. They also found other significant applications in environmental protection such as oxidation of volatile organic compounds, VOC, persulfate activator, ammonia synthesis, electrocatalysis and many more. Cobalt catalysts are active, stable and exhibit significant oxidation-reduction activity, as the Co can be found either as Co(II) or Co(III). Additionally, many molecules can interact with the cobalt supported phase by co-ordination due to partially filled d-orbital. Co-catalysts can be supported in almost all the inorganic supports such as alumina, titania, zeolites, etc. The cobalt oxide phase can be stabilized on the surface of the support due to variable interactions between the support and cobalt phase. These interactions are crucial for catalytic activity and can be regulated by proper selection of the preparation parameters such as the type of support, the Co loading, impregnation method and thermal conditions.

Catalysis

Author : Jun Bao
Publisher : Royal Society of Chemistry
Page : 259 pages
File Size : 47,7 Mb
Release : 2013
Category : Reference
ISBN : 9781849735780

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Catalysis by Jun Bao Pdf

"Catalysis" is sure to be of interest to readers working in academia and industry that need an up-to-date critical analysis and summary of catalysis research and applications.