Functional Supramolecular Architectures

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Functional Supramolecular Architectures

Author : Paolo Samorì,Franco Cacialli
Publisher : John Wiley & Sons
Page : 1332 pages
File Size : 52,6 Mb
Release : 2014-06-13
Category : Technology & Engineering
ISBN : 9783527689910

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Functional Supramolecular Architectures by Paolo Samorì,Franco Cacialli Pdf

A comprehensive overview of functional nanosystems based on organic and polymeric materials and their impact on current and future research and technology in the highly interdisciplinary field of materials science. As such, this handbook covers synthesis and fabrication methods, as well as properties and characterization of supramolecular architectures. Much of the contents are devoted to existing and emerging applications, such as organic solar cells, transistors, diodes, nanowires and molecular switches. The result is an indispensable resource for materials scientists, organic chemists, molecular physicists and electrochemists looking for a reliable reference on this hot topic.

Functional Supramolecular Materials

Author : Rahul Banerjee
Publisher : Royal Society of Chemistry
Page : 461 pages
File Size : 54,6 Mb
Release : 2017-05-05
Category : Science
ISBN : 9781788010276

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Functional Supramolecular Materials by Rahul Banerjee Pdf

Supramolecular materials have a great number of applications due to the reversibility of their non-covalent molecular interactions, such as reversible hydrogen bonding, host–guest interactions and electrostatic interactions. This book provides a comprehensive source of information on the structure and function of organic and metal–organic supramolecular materials. The chapters of this book provide an overview of supramolecular material assembly at various scales, including the formation of 2D polymers and molecular cages. The role of intermolecular interactions in solid and solution state self-assembly is discussed, as is the role of mechanochemistry on molecular and supramolecular architectures. Finally, novel applications of these materials in molecular recognition, catalysis, light harvesting and environmental remediation are covered. Functional Supramolecular Materials will be of interest to graduate students and researchers in academia and industry in the fields of supramolecular chemistry and functional materials science.

Functional Supramolecular Materials

Author : Rahul Banerjee
Publisher : Royal Society of Chemistry
Page : 477 pages
File Size : 42,8 Mb
Release : 2017-05-05
Category : Science
ISBN : 9781788011419

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Functional Supramolecular Materials by Rahul Banerjee Pdf

Supramolecular materials have a great number of applications due to the reversibility of their non-covalent molecular interactions, such as reversible hydrogen bonding, host–guest interactions and electrostatic interactions. This book provides a comprehensive source of information on the structure and function of organic and metal–organic supramolecular materials. The chapters of this book provide an overview of supramolecular material assembly at various scales, including the formation of 2D polymers and molecular cages. The role of intermolecular interactions in solid and solution state self-assembly is discussed, as is the role of mechanochemistry on molecular and supramolecular architectures. Finally, novel applications of these materials in molecular recognition, catalysis, light harvesting and environmental remediation are covered. Functional Supramolecular Materials will be of interest to graduate students and researchers in academia and industry in the fields of supramolecular chemistry and functional materials science.

Orthogonal Supramolecular Interaction Motifs for Functional Monolayer Architectures

Author : Mahmut Deniz Yilmaz
Publisher : Springer Science & Business Media
Page : 115 pages
File Size : 49,9 Mb
Release : 2012-05-30
Category : Science
ISBN : 9783642302572

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Orthogonal Supramolecular Interaction Motifs for Functional Monolayer Architectures by Mahmut Deniz Yilmaz Pdf

Deniz Yilmaz' thesis describes a combination of orthogonal supramolecular interactions for the design of functional monolayer architectures on surfaces, that can be used as chemical and biosensors in a wide range of applications. The term “orthogonal supramolecular interactions” refers to non-covalent interactions that do not influence each other's assembly properties. Orthogonal self-assembly thus allows extended control over the self-assembly process and promotes new materials properties. The first part of the thesis employs orthogonal host-guest and lanthanide-ligand coordination interaction motifs to create supramolecular luminescent monolayers. The second part of the thesis describes the fabrication of functional monolayers on silicon and gold substrates for applications in electronics. The results illustrate the power of weak supramolecular interactions to direct the immobilization of functional systems on surfaces. The combination of host-guest and lanthanide-ligand coordination interaction motifs on surfaces demonstrates that hybrid, multifunctional supramolecular monolayers can be fabricated by integrating different non-covalent interactions in the same system. This combination opens up new avenues for the fabrication of complex hybrid organic-inorganic materials and stimuli-responsive surfaces. Their utility is demonstrated through applications of the functional interfaces to biosensing and nanotechnology.

Porphyrin-based Supramolecular Architectures

Author : Shengqian Ma,Gaurav Verma
Publisher : Royal Society of Chemistry
Page : 384 pages
File Size : 42,8 Mb
Release : 2021-12-03
Category : Science
ISBN : 9781839164941

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Porphyrin-based Supramolecular Architectures by Shengqian Ma,Gaurav Verma Pdf

Porphyrin-based Supramolecular Architectures focuses on the most recent developments in the field, emphasizing the cutting-edge research in a diverse range of applications. Designed for readers considering the unprecedented prosperity of porous materials research, chapters will cover both strategies for structure design (such as MOFs and COFs) as well as emerging applications including CO2 fixation, catalysis and photodynamic therapy. With contributions from global experts, this title will be of interest to graduate students and researchers in supramolecular chemistry, organic chemistry, inorganic chemistry, physical chemistry, organometallic chemistry, solid-state chemistry, catalysis and (porous) materials science.

Electrochemistry of Functional Supramolecular Systems

Author : Paola Ceroni,Alberto Credi,Margherita Venturi
Publisher : John Wiley & Sons
Page : 550 pages
File Size : 50,7 Mb
Release : 2010-01-26
Category : Science
ISBN : 0470583452

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Electrochemistry of Functional Supramolecular Systems by Paola Ceroni,Alberto Credi,Margherita Venturi Pdf

With contributions from the most prominent experts around the world, this resource provides an accessible summary of electrochemical techniques and the applications of electrochemical concepts to molecular-level systems. It describes the most important electro-active functional supramolecular systems developed so far, including rotaxanes and catenanes as molecular machines and as elements for information processing; dendrimers as molecular batteries, sensors, light harvesting antennae, and drug delivery systems; and bio-hybrid devices.

Functional Supramolecular Nanoassemblies of Π-Conjugated Molecules

Author : Penglei Chen,Bin Wu
Publisher : Frontiers Media SA
Page : 159 pages
File Size : 50,9 Mb
Release : 2020-01-13
Category : Electronic
ISBN : 9782889633609

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Functional Supramolecular Nanoassemblies of Π-Conjugated Molecules by Penglei Chen,Bin Wu Pdf

Π-conjugated systems of delocalized aromatic electrons along their backbones, including conjugated small molecules, oligomers, polymers, and carbonaceous materials, etc., have received considerable attention from a wide variety of scientific and technical communities. Compared to inorganic materials, the advantages of those based on π-tectons lie in their broad diversity, flexibility, and tunability with regard to structure/geometry/morphology, processability, composition, functionality, electronic/band structure, etc. In terms of sophisticated molecular engineering, these features endow them not only with excellent self-assembly properties but also with unique optical, electrical, mechanical, photophysical, photochemical, and biochemical attributes. This renders them promising scaffolds for advanced functional materials (AFMs) in numerous areas of general interest such as electronics, optics, optoelectronics, photovoltaics, magnetic and piezoelectric devices, sensors, catalysts, biomedicines, and others. With regard to the design/synthesis of novel π-tectons, the launch of diverse assembly/fabrication protocols, theoretical calculations, etc., the past several decades have witnessed tremendous advancements along this direction. Thus far, a vast array of high-performance π-tectons-based AFMs have been initiated. To some extent, the cooperative principle of π-πstacking and other noncovalent interactions has been revealed, and the structure-property relationships have been disclosed. Despite the existing progress, this field still faces challenges, for example: (i) the need for scalable assembly/manufacture under ambient conditions—with low-cost, facile, environmentally-friendly protocols (ii) clearer correlations bridging the underlying intricate relationships of each successive step in assembly/manufacture (iii) corresponding theoretical calculations for guiding the rational design of π-tectons that elucidate the cooperative principle of π-π stacking and other noncovalent interactions, as well as the principle of structure-performance correlation (iv) stability and durability, among the most important concerns regarding their commercialization The advancements accumulated during the past decades have established a solid foundation for the further development of π-conjugated systems-based AFMs. We believe that with unrelenting efforts from both scientific and technical communities of various backgrounds, their practical applications will eventually be fulfilled. This Research Topic aims to address the above-mentioned challenges

Supramolecular Nanotechnology

Author : Omar Azzaroni,Martin Conda-Sheridan
Publisher : John Wiley & Sons
Page : 1801 pages
File Size : 49,8 Mb
Release : 2023-04-25
Category : Technology & Engineering
ISBN : 9783527834051

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Supramolecular Nanotechnology by Omar Azzaroni,Martin Conda-Sheridan Pdf

Supramolecular Nanotechnology Provides up-to-date coverage of both current knowledge and new developments in the dynamic and interdisciplinary field of supramolecular nanotechnology In recent years, supramolecular nanotechnology has revolutionized research in chemistry, physics, and materials science. These easily manipulated molecular units enable the synthesis of novel nanomaterials for use in a wide range of current and potential applications including electronics, sensors, drug delivery, and imaging. Supramolecular Nanotechnology presents a state-of-the-art overview of functional self-assembling nanomaterials based on organic and polymeric molecules. Featuring contributions by an international panel of experts in the field, this comprehensive volume covers the design of self-assembled materials, their synthesis and diverse fabrication methods, the characterization of supramolecular architectures, and current and emerging applications in chemistry, biology, and medicine. Detailed chapters discuss the synthesis of peptide-based supramolecular structures and polymeric self-assembling materials, their characterization, advanced microscopy techniques, nanostructures made of porphyrins, polyelectrolytes, silica, their application in catalysis and cancer, atomistic and coarse-grained simulations, and more. Presents cutting-edge research on rationally designed, self-assembled supramolecular structures Discusses the impact of supramolecular nanotechnology on current and future research and technology Highlights applications of self-assembled supramolecular systems in catalysis, biomedical imaging, cancer therapies, and regenerative medicine Provides synthetic strategies for preparing the molecular assemblies and various characterization techniques for assessing the supramolecular morphology Describes theoretical modeling and simulation techniques for analyzing supramolecular nanostructures Supramolecular Nanotechnology: Advanced Design of Self-Assembled Functional Materials is essential reading for materials scientists and engineers, polymer and organic chemists, pharmaceutical scientists, molecular physicists and biologists, and chemical engineers.

Supramolecular Chemistry in the 3rd Millennium

Author : Catherine E. Housecroft
Publisher : MDPI
Page : 264 pages
File Size : 44,5 Mb
Release : 2021-08-18
Category : Science
ISBN : 9783036514635

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Supramolecular Chemistry in the 3rd Millennium by Catherine E. Housecroft Pdf

This Special Issue is one of the first for the new MDPI flagship journal Chemistry (ISSN 2624-8549) which has a broad remit for publishing original research in all areas of chemistry. The theme of this issue is Supramolecular Chemistry in the 3rd Millennium and I am sure that this topic will attract many exciting contributions. We chose this topic because it encompasses the unity of contemporary pluridisciplinary science, in which organic, inorganic, physical and theoretical chemists work together with molecular biologists and physicists to develop a systems-level understanding of molecular interactions. The description of supramolecular chemistry as 'chemistry beyond the molecule' (Jean-Marie Lehn, Nobel Lecture and Gautam R. Desiraju, Nature, 2001, 412, 397) addresses the wide variety of weak, non-covalent interactions that are the basis for the assembly of supramolecular architectures, molecular receptors and molecular recognition, programed molecular systems, dynamic combinatorial libraries, coordination networks and functional supramolecular materials. We welcome submissions from all disciplines involved in this exciting and evolving area of science.

Metallofoldamers

Author : Galia Maayan,Markus Albrecht
Publisher : John Wiley & Sons
Page : 446 pages
File Size : 40,7 Mb
Release : 2013-01-18
Category : Science
ISBN : 9781118517437

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Metallofoldamers by Galia Maayan,Markus Albrecht Pdf

Metallofoldamers are oligomers that fold into three-dimensional structures in a controlled manner upon coordination with metal ions. Molecules in this class have shown an impressive ability to form single-handed helical structures and other three-dimensional architectures. Several metallofoldamers have been applied as sensors due to their selective folding when binding to a specific metal ion, while others show promise for applications as responsive materials on the basis of their ability to fold and unfold upon changes in the oxidation state of the coordinated metal ion, and as novel catalysts. Metallofoldamers: From Helicates to Biomimetic Architectures describes the variety of interactions between oligomers and metal species, with a focus on non-natural synthetic molecules. Topics covered include: the major classes of foldamers and their folding driving force metalloproteins and metalloenzymes helicates: self-assembly, structure and applications abiotic metallo-DNA metallo-PNA and iDNA metallopeptides interactions of biomimetic oligomers with metal ions applications of metallofoldamers

Photophysics of Supramolecular Architectures

Author : Paulpandian Muthu Mareeswaran,Palaniswamy Suresh,Seenivasan Rajagopal
Publisher : Bentham Science Publishers
Page : 237 pages
File Size : 45,5 Mb
Release : 2022-08-12
Category : Science
ISBN : 9789815049206

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Photophysics of Supramolecular Architectures by Paulpandian Muthu Mareeswaran,Palaniswamy Suresh,Seenivasan Rajagopal Pdf

This reference provides collective information about the physical andphotophysical changes of supramolecules after encapsulation. It coversluminescent systems involving a range of host molecules such as calixarenes, cyclodextrin, resorcinanene-crowns, pillararenes, cucurbituril, andmetallacycles. Chapters also discuss the effect of the macrocyclic environment onthe properties of functionalized molecules, including the variations in foldingand unfolding patterns. Each chapter is supplemented with detailed references,making this an ideal resource for scholars interested in supramolecularphotophysics.

Photoactive Functional Soft Materials

Author : Quan Li
Publisher : John Wiley & Sons
Page : 496 pages
File Size : 48,7 Mb
Release : 2019-04-29
Category : Technology & Engineering
ISBN : 9783527344826

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Photoactive Functional Soft Materials by Quan Li Pdf

This book covers the design, synthesis, properties, and applications of functional photoactive soft materials, including aspects of polymers, block copolymers, elastomers, biomaterials, liquid crystals, chemical and physical gels, colloids, and host-guest systems. It combines, in a unified manner, authoritative accounts describing various structural and functional aspects of photoactive soft materials. Photoactive Functional Soft Materials: Preparation, Properties, and Applications: * Brings together the state-of-the-art knowledge on photoactive functional soft materials in a unified manner * Covers a vibrant research field with tremendous application potential in areas such as optoelectronics, photonics, and energy generation * Appeals to a large interdisciplinary audience because it is highly useful for researchers and engineers working on photonics, optoelectronics, imaging and sensing, nanotechnology, and energy materials Photoactive Functional Soft Materials: Preparation, Properties and Applications focuses on the design and fabrication of photoactive functional soft materials for materials science, nanophotonics, nanotechnology, and biomedical applications.

Supramolecular Chemistry in Corrosion and Biofouling Protection

Author : Viswanathan S. Saji
Publisher : CRC Press
Page : 448 pages
File Size : 51,7 Mb
Release : 2021-12-24
Category : Technology & Engineering
ISBN : 9781000516708

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Supramolecular Chemistry in Corrosion and Biofouling Protection by Viswanathan S. Saji Pdf

Supramolecular chemistry, "the chemistry beyond the molecule", is a fascinating realm of modern science. The design of novel supramolecular structures, surfaces, and techniques are at the forefront of research in different application areas, including corrosion and biofouling protection. A team of international experts provide a comprehensive view of the applications and potential of supramolecular chemistry in corrosion and biofouling prevention. Chapter topics include types and fundamentals of supramolecules, supramolecular polymers and gels, host-guest inclusion compounds, organic-inorganic hybrid materials, metallo-assemblies, cyclodextrins, crown ethers, mesoporous silica and supramolecular structures of graphene and other advances. Additional Features include: Focuses on different aspects of supramolecular chemistry in corrosion and biofouling prevention. Comprehensively covers supramolecular interactions that can provide better corrosion and biofouling protection. Provides the latest developments in self-healing coatings. Explores recent research advancements in the suggested area. Includes case studies specific to industries. The different supramolecular approaches being investigated to control corrosion and biofouling are gathered in one well-organized reference to serve senior undergraduate and graduate students, research students, engineers, and researchers in the fields of corrosion science & engineering, biofouling, and protective coatings.

Applications of Supramolecular Chemistry

Author : Hans-Jorg Schneider
Publisher : CRC Press
Page : 454 pages
File Size : 48,6 Mb
Release : 2012-03-28
Category : Medical
ISBN : 9781439840153

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Applications of Supramolecular Chemistry by Hans-Jorg Schneider Pdf

Applications of Supramolecular Chemistry introduces the use of non-covalent interactions and molecular recognition for many fields. Applications include the analysis of technically, medically, and environmentally important chemical compounds, their separation, purification and removal, and the design of new materials, including supramolecular elect