Handbook Of Heterogeneous Catalytic Hydrogenation For Organic Synthesis

Author : Shigeo Nishimura
Publisher : Wiley-Interscience
Page : 728 pages
File Size : 50,5 Mb
Release : 2001-04-17
Category : Science
ISBN : UOM:39015050553554

Get Book

Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis by Shigeo Nishimura Pdf

A complete guide to the most important reduction method in organic synthesis The most comprehensive reference in the field, Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis provides synthetic chemists and chemical engineers in fine chemicals and pharmaceuticals with detailed experimental guidelines for heterogeneous catalytic hydrogenation. Organized by functional groups for ready reference and featuring detailed examples of hundreds of reactions, this handbook covers hydrogenations of alkenes, alkynes, aldehydes and ketones, nitriles, imines, nitro and nitroso compounds, carboxylic acids and esters, and aromatic and heterocyclic compounds. In addition, coverage includes the preparation of amines by reductive alkylation and the hydrogenolysis of a variety of compounds. Examples of hydrogenation of functional groups and reaction pathways are illustrated with numerous equations and schemes. Practitioners will appreciate the plenitude of experimental details given for most of the reactions selected, including amounts of reagents and catalysts, reaction temperatures, hydrogen pressures, and reaction times. They will also find helpful the more than one hundred tables included throughout the book detailing the effects of key factors governing rate and selectivity, such as compound structure, the nature of catalysts and supports, and the nature of solvents. Researchers will benefit from the introductory chapters covering an array of hydrogenation catalysts, including nickel, cobalt, copper, iron, platinum group metals, rhenium, and other oxide and sulfide catalysts, as well as reactors and reaction conditions.

Author : Rylander
Publisher : Elsevier
Page : 336 pages
File Size : 41,8 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323138536

Get Book

Catalytic Hydrogenation in Organic Syntheses by Rylander Pdf

Catalytic Hydrogenation in Organic Syntheses focuses on the process of catalytic hydrogenation in organic synthesis. This book gives the reader easy access to catalytic history, to show what can be done and how to do it. A variety of working generalities and common sense guides are given as aids in selecting catalytic metal, catalyst support, concentration of metal and catalyst, solvent, and reaction conditions. All manner of hydrogenation catalysts are considered and mechanisms of hydrogenation are presented at a level that is useful to the synthetic organic chemist. This volume is comprised of 15 chapters and begins with an overview of catalytic hydrogenation and heterogeneous hydrogenation catalysts, along with hydrogenation reactors and reaction conditions. The discussion then shifts to the hydrogenation of compounds such as acetylenes, olefins, aldehydes, ketones, nitriles, oximes, acids, esters, lactones, anhydrides, and nitro compounds as well as carbocyclic aromatics and heterocyclic compounds. The reader is also introduced to reductive alkylation, catalytic dehydrohalogenation, and hydrogenolysis of small rings. A chapter on miscellaneous hydrogenolyses concludes the book. This book will be of interest to organic chemists working in the field of catalytic hydrogenation.

Author : Morris Freifelder
Publisher : John Wiley & Sons
Page : 218 pages
File Size : 43,9 Mb
Release : 1978-11
Category : Science
ISBN : UOM:39015057357983

Get Book

Catalytic Hydrogenation in Organic Synthesis by Morris Freifelder Pdf

Based on over 22 years of experience, this book presents a substantial accumulation of knowledge. Clearly and understandably written, it gives detailed descriptions of many experiments, providing step-by-step procedures along with personal notes and observations, directions, suggestions, and safety precautions. The yields obtained in these experiments are good to excellent, and most of the hydrogenations discussed are carried out under very mild conditions.

Author : Mike G. Scaros,Michael L. Prunier
Publisher : CRC Press
Page : 632 pages
File Size : 54,8 Mb
Release : 1994-10-20
Category : Science
ISBN : 0824793641

Get Book

Catalysis of Organic Reactions by Mike G. Scaros,Michael L. Prunier Pdf

Based on the papers and posters presented at the 15th Conference on Catalysis of Organic Reactions, this work covers developments in the study of catalysis as it relates to organic synthesis, emphasizing applications in industrial processes. Over 1000 bibliographic citations and over 250 tables, drawings, and photographs are provided. Theoretical and practical aspects of the field are highlighted.

Author : Iyad Karamé
Publisher : BoD – Books on Demand
Page : 342 pages
File Size : 49,7 Mb
Release : 2012-10-10
Category : Science
ISBN : 9789535107859

Get Book

Hydrogenation by Iyad Karamé Pdf

The domain of catalytic hydrogenation continues to grow fast, reflecting the wide range of chemical applications that can be enhanced by the easy use of molecular hydrogen. The advances in characterization techniques and their application have improved our understanding of the catalytic processes and mechanisms occurring in both homogeneous and heterogeneous catalysis. The aim of this volume, although not exhaustive, is to provide a general overview of new progress of the hydrogenation reactions. This volume comprises a series of various contributions, as reviews or original articles, treating heterogeneously and homogeneously catalyzed hydrogenation reactions. It is composed of three parts: hydrogenation reactions in fine organic chemistry, hydrogenation reactions in environmental chemistry and renewable energy, and special topics in hydrogenation.

Author : L. Cervený
Publisher : Elsevier
Page : 676 pages
File Size : 43,7 Mb
Release : 1986-08-01
Category : Technology & Engineering
ISBN : 0080960618

Get Book

Catalytic Hydrogenation by L. Cervený Pdf

The collection of contributions in this volume presents the most up-to-date findings in catalytic hydrogenation. The individual chapters have been written by 36 top specialists each of whom has achieved a remarkable depth of coverage when dealing with his particular topic. In addition to detailed treatment of the most recent problems connected with catalytic hydrogenations, the book also contains a number of previously unpublished results obtained either by the authors themselves or within the organizations to which they are affiliated. Because of its topical and original character, the book provides a wealth of information which will be invaluable not only to researchers and technicians dealing with hydrogenation, but also to all those concerned with homogeneous and heterogeneous catalysis, organic technology, petrochemistry and chemical engineering.

Author : Gerhard Ertl,H. Knözinger,Jens Weitkamp
Publisher : Unknown
Page : 374 pages
File Size : 40,6 Mb
Release : 1997
Category : Heterogeneous catalysis
ISBN : UOM:39015040538715

Get Book

Handbook of Heterogeneous Catalysis by Gerhard Ertl,H. Knözinger,Jens Weitkamp Pdf

The first comprehensive survey of the principles and applications of heterogeneous catalysis! Starting with the invention of Döbereiner's tinder box and reaching importance with Haber's development of ammonia synthesis, heterogeneous catalysis has become a multi-billion dollar business. Simultaneously, literature on heterogeneous catalysis has become increasingly widespread and difficult to follow. This handbook collects the available knowledge on heterogeneous catalysis and provides the reader with easy-to-find yet comprehensive information. With contributions from more than 200 leading experts from all over the world it covers all aspects of the subject, from physico-chemical foundations to large-scale industrial applications. With its highly topical contributions, the straightforward presentation of the material and its comprehensive coverage, this handbook sets new standards. Saving you the time for laborious searches for information, it is an indispensable tool for every scientist working.

Author : Kuiling Ding,Yasuhiro Uozumi
Publisher : John Wiley & Sons
Page : 467 pages
File Size : 52,6 Mb
Release : 2008-10-20
Category : Science
ISBN : 9783527319138

Get Book

Handbook of Asymmetric Heterogeneous Catalysis by Kuiling Ding,Yasuhiro Uozumi Pdf

In this most up-to-date handbook each chapter contains a general introduction, followed by the principles of the immobilization and, finally, applications. In this way, it covers the most important approaches currently employed for the heterogenization of chiral catalysts, including data tables, applications, reaction types and literature citations. For chemists in both academia and industry as well as those working in the fine chemical and pharmaceutical industry.

Author : P.A. Chaloner,M.A. Esteruelas,Ferenc Joó,L.A. Oro
Publisher : Springer Science & Business Media
Page : 293 pages
File Size : 51,9 Mb
Release : 2013-11-11
Category : Science
ISBN : 9789401717915

Get Book

Homogeneous Hydrogenation by P.A. Chaloner,M.A. Esteruelas,Ferenc Joó,L.A. Oro Pdf

Homogeneous hydrogenation is one of the most thoroughly studied fields of homogeneous catalysis. The results of these studies have proved to be most important for an understanding of the underlying principles of the activation of small molecules by transition metal complexes. During the past three decades homogeneous hydrogenation has found widespread application in organic chemistry, including the production of important pharmaceuticals, especially where a sophisticated degree of selectivity is required. This volume presents a general account of the main principles and applications of homogeneous hydrogenation by transition metal complexes. Special attention is devoted to the mechanisms by which these processes occur, and the role of the recently discovered complexes of molecular hydrogen is described. Sources of hydrogen, other than H2, are also considered (transfer hydrogenation). The latest achievements in highly stereoselective hydrogenations have made possible many new applications in organic synthesis. These applications are documented by giving details of the reduction of important unsaturated substrates (alkenes, alkynes, aldehydes and ketones, nitrocompounds, etc.). Hydrogenation in biphasic and phase transfer catalyzed systems is also described. Finally, a discussion of the biochemical routes of H2 activation highlights the similarities and differences in performing hydrogenation in both natural and synthetic systems. For researchers working in the fields of homogeneous catalysis, especially in areas such as pharmaceuticals, plastics and fine chemicals.

Author : S. David Jackson
Publisher : Walter de Gruyter GmbH & Co KG
Page : 203 pages
File Size : 45,6 Mb
Release : 2018-09-24
Category : Science
ISBN : 9783110545210

Get Book

Hydrogenation by S. David Jackson Pdf

This book gives a comprehensive overview of modern hydrogenation methods used in organic synthesis.In clearly structured chapters, the authors cover the catalysts, scope and limitations of their application, and the techniques for hydrogenation of carbon-carbon, carbon-heteroatom and heteroatom-heteroatom multiple bonds.

Author : Johannes G. de Vries
Publisher : Thieme
Page : 678 pages
File Size : 40,9 Mb
Release : 2018-07-13
Category : Science
ISBN : 9783132406247

Get Book

Science of Synthesis: Catalytic Reduction in Organic Synthesis by Johannes G. de Vries Pdf

Catalytic reductions are among the most used synthetic transformations, and the past 15 years have seen great progress in this field. Science of Synthesis: Catalytic Reduction in Organic Synthesis includes the latest developments, as well as selective coverage of more well-established methods. Both heterogeneous and homogeneous catalytic systems are covered, and enantioselective methodology is well represented. There is a focus on the use of metal nanoparticles, both in suspension as well as on solid supports. Furthermore, the advent of research on the conversion of renewable resources into fuels and chemicals has given a great impetus to the field, as deoxygenations are often the first step in the conversion of biomass and this can often be achieved using hydrogenation or hydrogenolysis reactions. Scope, limitations, and mechanism of the reactions are discussed and key experimental procedures are included.

Author : Anonim
Publisher : Newnes
Page : 9815 pages
File Size : 52,8 Mb
Release : 2014-02-14
Category : Science
ISBN : 9780080977430

Get Book

Comprehensive Organic Synthesis by Anonim Pdf

The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition, Nine Volume Set an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively

Author : F.J. McQuillin
Publisher : Springer
Page : 154 pages
File Size : 45,6 Mb
Release : 1976
Category : Science
ISBN : UCAL:B4477523

Get Book

Homogeneous Hydrogenation in Organic Chemistry by F.J. McQuillin Pdf

Organic chemistry is constantly concerned with effecting reactions at a particular centre in a complex molecule, and if possible with a high and predictable level of stereoselectivity. In the light of much accumulated ex perience within organic chemistry it is usually possible to assess the likeli hood of alternative reaction pathways at least qualitatively. However, well based expectations can be falsified, and the experiments directed to the synthesis of vitamin B12 which led to Woodward's recognition of orbital symmetry control in organic chemistry are an instructive example. Our limi tations in this respect are very much accentuated in the case of hetero geneous reactions, which present additional problems, and except for very well studied instances, heterogeneous catalysis has remained a relatively empirical area of chemistry. Knowledge in this area has, however, been greatly improved by the development of transition metal complexes which replicate the catalytic properties of the metals, and are effective in a homo geneous reaction system. This development has advanced our understanding of catalysis by making it possible to interpret reactions in strictly molecular terms. In addition, these homogeneously active complexes are frequently more selective than their heterogeneous metallic counterparts either in discriminating between different functional centres in a molecule or in of fering better stereoselectivity. Homogeneous catalysts have now been devised for a number of organic chemical reactions, including hydrogenation, carbonylation, polymerisa tion, and isomerisation and dismutation of alkenes.

Author : Robert L. Augustine
Publisher : Unknown
Page : 214 pages
File Size : 47,6 Mb
Release : 1965
Category : Science
ISBN : UOM:39015028899253

Get Book

Catalytic Hydrogenation by Robert L. Augustine Pdf

Author : Dale W. Blackburn
Publisher : CRC Press
Page : 377 pages
File Size : 49,7 Mb
Release : 2020-07-24
Category : Science
ISBN : 9781000104370

Get Book

Catalysis of Organic Reactions by Dale W. Blackburn Pdf

This volume is a collection of the papers presented at the Twelfth Conference on the Catalysis of Organic Reactions, where all phases of catalysis, including heterogeneous catalytic hydrogenation, catalytic oxidation, homogeneous catalysis, carbonylation, and amination have been discussed.