Homogeneous Gold Catalysis

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Gold Catalysis

F Dean Toste,Véronique Michelet
Gold Catalysis Book PDF

Author : F Dean Toste,Véronique Michelet
Publisher : World Scientific
Page : 564 pages
File Size : 49,7 Mb
Release : 2014-06-20
Category : Science
ISBN : 9781783265558

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Gold Catalysis by F Dean Toste,Véronique Michelet Pdf

Research on designing new catalytic systems has been one of the most important fields in modern organic chemistry. One reason for this is the predominant contribution of catalysis to the concepts of atom economy and green chemistry in the 21st century. Gold, considered catalytically inactive for a long time, is now a fascinating partner of modern chemistry, as scientists such as Bond, Teles, Haruta, Hutchings, Ito and Hayashi opened new perspectives for the whole synthetic chemist community. This book presents the major advances in homogeneous catalysis, emphasizing the methodologies that create carbon–carbon and carbon–heteroatom bonds, the applications that create diversity and synthesize natural products, and the recent advances and challenges in asymmetric catalysis and computational research. It provides readers with in-depth information about homogeneous gold-catalyzed reactions and presents several explanations for the scientific design of a catalyst. Readers will be able to understand the entire gold area and find solutions to problems in catalysis. Gold Catalysis — An Homogeneous Approach is part of the Catalytic Science Series and features prominent authors who are experts in their respective fields. Contents:From Gold in Nature to Gold Catalysts (Søren Kramer and Fabien Gagosz)Homogeneous Gold-Catalyzed Oxidation and Reduction Reactions (Liming Zhang)Gold-Catalyzed Addition of Carbon Nucleophiles to C–C Multiple Bonds, Carbonyls, and other Electrophiles (Bryon L Simmons and Hong C Shen)Gold-Catalyzed Addition of Heteroatom Nucleophile to C–C Multiple Bond (Naoki Asao, Naoya Hatakeyama and Yoshinori Yamamoto)Gold-Catalyzed Synthesis of Heterocycles (Antonio Arcadi)Gold-Catalyzed Multi-Component Reactions (Rachid Skouta and Chao-Jun Li)Gold Catalysis on Tandem and Cascade Reactions (Rai-Shung Liu)Cycloisomerization Reactions of 1, N-Enynes (Núria Huguet and Antonio M Echavarren)Gold-Catalyzed Reactions of Propargylic Esters (Louis Fensterbank, Jean-Philippe Goddard, Max Malacria and Antoine Simonneau)Gold-Catalyzed Cross-Coupling Reactions (Suzanne A Blum)Gold-Catalyzed Reactions: A Computational Approach (Elena Soriano and José Marco-Contelles)Recent Developments in Asymmetric Catalysis (Patrick Y Toullec, Alexandre Pradal and Véronique Michelet)Gold Catalysis in Natural Product Synthesis (Michael R Gesinski and F Dean Toste) Readership: Graduate students and researchers in organic chemistry. Key Features:First book on homogeneous gold catalysisProminent authorsFrom catalysts design to target-oriented applicationsA fascinating partner for modern chemistryKeywords:Gold;Catalysis;Heterocycles;Tandem;Cascade ReactionsReviews: “Gold Catalysis gives an excellent overview of a rapidly growing field. All of the thirteen chapters are written by the best practitioners. This book is certainly a “must” for laboratories working with coinage metals, but also for any organometallic group.” Guy Bertrand Distinguished Professor, University of California, San Diego Director of the UCSD/CNRS Joint Research Chemistry Laboratory (UMI 3555)

Homogeneous Gold Catalysis

LeGrande M. Slaughter
Homogeneous Gold Catalysis Book PDF

Author : LeGrande M. Slaughter
Publisher : Springer
Page : 288 pages
File Size : 48,8 Mb
Release : 2015-03-30
Category : Science
ISBN : 9783319137223

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Homogeneous Gold Catalysis by LeGrande M. Slaughter Pdf

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.

Gold Catalysis

F. Dean Toste
Gold Catalysis Book PDF

Author : F. Dean Toste
Publisher : Unknown
Page : 564 pages
File Size : 40,6 Mb
Release : 2014-08-01
Category : Catalysis
ISBN : 1848168535

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Gold Catalysis by F. Dean Toste Pdf

Research on designing new catalytic systems has been one of the most important fields in modern organic chemistry, and one reason for this is the predominant contribution of catalysis to the concepts of atom economy and green chemistry in the 21st century. Gold, considered catalytically inactive for a long time, is now a fascinating partner of modern chemistry, as scientists such as Bond, Haruta, Hutchings, Ito and Hayashi opened new perspectives for the whole synthetic chemist community. This book presents the major advances in homogeneous catalysis, emphasizing the methodologies that create carbon-carbon and carbon-heteroatom bonds, the applications that create diversity and synthesize natural products, and the recent advances and challenges in asymmetric catalysis and computational research. The Handbook of Homogeneous Gold Catalysis provides readers with in-depth information about gold-catalyzed reactions and presents several explanations for the scientific design of a catalyst. Readers will be able to understand the entire gold area and find solutions to problems in catalysis. Featuring prominent authors, who are experts in their respective fields, this is the first book dedicated to homogeneous gold chemistry. Contents: From Gold in Nature to Gold Catalysts (S Kramer and F Gagosz); Oxidation and Reduction Reactions (L Zhang); Gold-Catalyzed Addition of Carbon Nucleophile to C-C Multiple Bond (B Simmons and H C Shen); Gold-Catalyzed Addition of Heteroatom Nucleophile to C-C Multiple Bond (N Asao, N Hatakeyama and Y Yamamoto); Gold-Catalyzed Synthesis of Heterocycles (A Arcadi); Multi-Component Reactions (R Skouta and C J Li); Gold Catalyzed Tandem and Cascade Reactions (R-S Liu); Cycloisomerization Reactions of 1, n -Enynes (N Huguet and A Echavarren); Gold-Catalyzed Reaction of Propargylic Esters (L Fensterbank, J-P Goddard, M Malacria and S Simonneau); Gold-Catalyzed Cross-Coupling Reactions (S Blum); Gold-Catalyzed Reactions: A Computational Approach (E Soriano & J Marco-Contelles); Asymmetric Gold-Catalyzed Reactions (P Y Toullec, A Pradal and V Michelet); Gold Catalysis in Natural Product Synthesis (M Gesinski and F D Toste). Readership: Student, professionals.

Modern Gold Catalyzed Synthesis

A. Stephen K. Hashmi,F. Dean Toste
Modern Gold Catalyzed Synthesis Book PDF

Author : A. Stephen K. Hashmi,F. Dean Toste
Publisher : John Wiley & Sons
Page : 419 pages
File Size : 48,5 Mb
Release : 2012-05-21
Category : Science
ISBN : 9783527319527

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Modern Gold Catalyzed Synthesis by A. Stephen K. Hashmi,F. Dean Toste Pdf

With its impressive features, gold has led to completely new reaction types in recent years, which in turn have strongly influenced both organic catalysis and material science. Other fields where a significant amount of new results has been obtained include nanotechnology, self assembly/supramolecular systems and biochemical/medicinal chemistry. As a result, gold is one of the hottest topics in catalysis at the moment, with an increasing amount of research being carried out in this field. While focusing on homogeneous catalysis, this monograph also covers the main applications in heterogeneous catalysis. Following a look at the gold-catalyzed addition of heteroatom nucleophiles to alkynes, it goes on to discuss gold-catalyzed additions to allenes and alkenes, gold-catalyzed benzannulations, cycloisomerization and rearrangement reactions, as well as oxidation and reduction reactions. The whole is finished off with a section on gold-catalyzed aldol and related reactions and the application of gold-catalyzed reactions to natural product synthesis. Of interest to synthetic chemists and inorganic chemists, as well as organic chemists working in homogeneous catalysis, physical and technical chemists.

Catalysis By Gold

Geoffrey C Bond,Catherine Louis,David Thompson
Catalysis By Gold Book PDF

Author : Geoffrey C Bond,Catherine Louis,David Thompson
Publisher : World Scientific
Page : 383 pages
File Size : 46,8 Mb
Release : 2006-08-15
Category : Science
ISBN : 9781908979858

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Catalysis By Gold by Geoffrey C Bond,Catherine Louis,David Thompson Pdf

Gold has traditionally been regarded as inactive as a catalytic metal. However, the advent of nanoparticulate gold on high surface area oxide supports has demonstrated its high catalytic activity in many chemical reactions. Gold is active as a heterogeneous catalyst in both gas and liquid phases, and complexes catalyse reactions homogeneously in solution. Many of the reactions being studied will lead to new application areas for catalysis by gold in pollution control, chemical processing, sensors and fuel cell technology. This book describes the properties of gold, the methods for preparing gold catalysts and ways to characterise and use them effectively in reactions. The reaction mechanisms and reasons for the high activities are discussed and the applications for gold catalysis considered./a

Bridging Heterogeneous and Homogeneous Catalysis

Can Li,Yan Liu
Bridging Heterogeneous and Homogeneous Catalysis Book PDF

Author : Can Li,Yan Liu
Publisher : John Wiley & Sons
Page : 860 pages
File Size : 51,6 Mb
Release : 2014-04-03
Category : Technology & Engineering
ISBN : 9783527675920

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Bridging Heterogeneous and Homogeneous Catalysis by Can Li,Yan Liu Pdf

There are two main disciplines in catalysis research -- homogeneous and heterogeneous catalysis. This is due to the fact that the catalyst is either in the same phase (homogeneous catalysis) as the reaction being catalyzed or in a different phase (heterogeneous catalysis). Over the past decade, various approaches have been implemented to combine the advantages of homogeneous catalysis (efficiency, selectivity) with those of heterogeneous catalysis (stability, recovery) by the heterogenization of homogeneous catalysts or by carrying out homogeneous reactions under heterogeneous conditions. This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts. As such, it highlights structural analogies and shows mechanistic parallels between the two, while additionally presenting kinetic analysis methods and models that either work for both homogeneous and heterogeneous catalysis. Chapters cover asymmetric, emulsion, phase-transfer, supported homogeneous, and organocatalysis, as well as in nanoreactors and for specific applications, catalytic reactions in ionic liquids, fluorous and supercritical solvents and in water. Finally, the text includes computational methods for investigating structure-reactivity relations. With its wealth of information, this invaluable reference provides academic and industrial chemists with novel concepts for innovative catalysis research.

Transition Metal-Catalyzed Couplings in Process Chemistry

Javier Magano,Joshua R. Dunetz
Transition Metal Catalyzed Couplings in Process Chemistry Book PDF

Author : Javier Magano,Joshua R. Dunetz
Publisher : John Wiley & Sons
Page : 1 pages
File Size : 44,6 Mb
Release : 2013-07-03
Category : Science
ISBN : 9783527658923

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Transition Metal-Catalyzed Couplings in Process Chemistry by Javier Magano,Joshua R. Dunetz Pdf

Transition metal-catalyzed coupling reactions have a rich history that led to the awarding of the 2010 Nobel Prize in Chemistry to Professors Suzuki, Heck, and Negishi for their pioneering contributions to the field. The coming of age of this active area of research is showcased in this book through case studies in which process chemists from the pharmaceutical industry share their personal experiences developing their own transition metal-catalyzed couplings for the large-scale manufacture of active pharmaceutical ingredients. Authors from Pfizer, Merck, Boehringer-Ingelheim, Novartis, Amgen, GSK, AstraZeneca, and other companies describe the evolution of robust coupling processes from inception through early and late development, including commercial routes where applicable. This book covers a wide range of coupling transformations while capturing the lessons learned from each process. Every case study details the optimization of at least one transition metal-catalyzed coupling while elaborating on issues such as design of experiments, scalability and throughput, product purification, process safety, and waste management. The important issue of metal removal and the different technologies available to accomplish this goal are also addressed. Finally, a section covers novel technologies for cross-coupling with high potential for future applications on a large scale, such as microwave and flow chemistry as well as green cross-couplings performed in water. With Forewords by Stephen L. Buchwald, Massachusetts Institute of Technology, Trevor Laird, Editor of Organic Process Research and Development and Neal G. Anderson, Anderson's Process Solutions LLC.

Carbon Dioxide Electrochemistry

Marc Robert,Kim Daasbjerg,Cyrille Constentin
Carbon Dioxide Electrochemistry Book PDF

Author : Marc Robert,Kim Daasbjerg,Cyrille Constentin
Publisher : Royal Society of Chemistry
Page : 461 pages
File Size : 46,8 Mb
Release : 2020-10-20
Category : Science
ISBN : 9781788015462

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Carbon Dioxide Electrochemistry by Marc Robert,Kim Daasbjerg,Cyrille Constentin Pdf

Homogeneous and Heterogeneous Catalysis

Gold

Hubert Schmidbaur
Gold Book PDF

Author : Hubert Schmidbaur
Publisher : John Wiley & Sons
Page : 924 pages
File Size : 49,9 Mb
Release : 1999
Category : Science
ISBN : UOM:39015048766441

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Gold by Hubert Schmidbaur Pdf

For thousands of years the human race has been fascinated by gold. Initially gold was used extensively in coinage and jewellery but today the applications for gold are vast, ranging from metallurgy to physics, chemistry, biochemistry and medicine. Gold: Progress in Chemistry, Biochemistry and Technology is an extremely comprehensive work covering the history of gold, from the work of the early prospectors to the use of gold in decorative effects and dentistry. Further chapters present a complete overview of the current knowledge of gold technology from mineral deposits to technical applications and emphasise the developments in coordination, organometallic and cluster chemistry of gold and its applications in synthesis. An international group of contributors have reviewed the modern advances in the science of gold to produce the first comprehensive monograph reflecting the state of the art, the impact and applications of recent developments in gold research.

Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis

S. Ted Oyama
Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis Book PDF

Author : S. Ted Oyama
Publisher : Elsevier
Page : 528 pages
File Size : 50,7 Mb
Release : 2011-10-13
Category : Technology & Engineering
ISBN : 0080558011

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Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis by S. Ted Oyama Pdf

The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. * Comprehensive listing of epoxide products * Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts * Analysis of the general strengths and weaknesses of varied catalytic systems * Detailed description of the mechanisms of reaction for classical and emerging catalysts

Advances in Organometallic Chemistry and Catalysis

Armando J. L. Pombeiro
Advances in Organometallic Chemistry and Catalysis Book PDF

Author : Armando J. L. Pombeiro
Publisher : John Wiley & Sons
Page : 848 pages
File Size : 52,5 Mb
Release : 2013-10-11
Category : Science
ISBN : 9781118742891

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Advances in Organometallic Chemistry and Catalysis by Armando J. L. Pombeiro Pdf

A contemporary compilation of recent achievements in organometallic chemistry The prestigious International Conference on Organometallic Chemistry (ICOMC) was launched in 1963, providing a forum for researchers from around the world to share their findings and explore new paths to advance our knowledge and application of organometallic chemistry. The 25th ICOMC, held in Lisbon in 2012, gathered more than 1,200 participants from 54 countries. This volume celebrates the 25th Silver Edition and the 50th Gold Year of the ICOMC. Featuring contributions from invited 25th ICOMC speakers, Advances in Organometallic Chemistry and Catalysis highlights recent achievements and new and emerging areas of research in the field. Its seven sections cover: Activation and Functionalization of Carbon Single Bonds and Small Molecules Organometallic Synthesis and Catalysis Organometallic Polymerization Catalysis Organometallic Polymers and Materials Organometallic Chemistry and Sustainable Energy Bioorganometallic Chemistry Organometallic Electrochemistry Chapters discuss fundamental underlying concepts, offer illustrative examples and cases, and explore future avenues for continued research. Readers will discover basic principles and properties of organometallic compounds, reaction mechanisms, and detailed descriptions of current applications. Collectively, these chapters underscore the versatility, richness, and potential of modern organometallic chemistry, including its interrelationships with other scientific disciplines. All the contributions are extensively referenced, providing a gateway to the most important original research papers and reviews in organometallic chemistry. Presenting a contemporary understanding of organometallic chemistry and its many applications, Advances in Organometallic Chemistry and Catalysis is recommended for all researchers in the field, from students to advanced investigators.

Cross-Coupling Reactions

Norio Miyaura
Cross Coupling Reactions Book PDF

Author : Norio Miyaura
Publisher : Springer
Page : 248 pages
File Size : 41,5 Mb
Release : 2003-07-01
Category : Science
ISBN : 9783540453130

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Cross-Coupling Reactions by Norio Miyaura Pdf

In 1972, a very powerful catalytic cycle for carbon-carbon bond formation was 2 first discovered by the coupling reaction of Grignard reagents at the sp -carbon. Over the past 30 years, the protocol has been substantially improved and expanded to other coupling reactions of Li,B,N,O,Al,Si,P,S,Cu,Mn,Zn,In,Sn, and Hg compounds. These reactions provided an indispensable and simple methodology for preparative organic chemists. Due to the simplicity and rel- bility in the carbon-carbon, carbon-heteroatom, and carbon-metalloid bo- formations,as well as high efficiency of the catalytic process,the reactions have been widely employed by organic chemists in various fields. Application of the protocol ranges from various syntheses of complex natural products to the preparation of biologically relevant molecules including drugs, and of sup- molecules, and to functional materials. The reactions on solid surfaces allow robot synthesis and combinatorial synthesis. Now, many organic chemists do not hesitate to use transition metal complexes for the transformation of org- ic molecules. Indeed, innumerable organic syntheses have been realized by the catalyzed reactions of transition metal complexes that are not achievable by t- ditional synthetic methods. Among these, the metal-catalyzed cross-coupling reactions have undoubtedly contributed greatly to the development of such a new area of “metal-catalyzed organic syntheses”. An excellent monograph for the cross-coupling reactions and other met- catalyzed C-C bond-forming reactions recently appeared in Metal-catalyzed Cross-coupling Reactions (Wiley-VCH,1998).

Solvent-free Organic Synthesis

Koichi Tanaka
Solvent free Organic Synthesis Book PDF

Author : Koichi Tanaka
Publisher : John Wiley & Sons
Page : 476 pages
File Size : 44,7 Mb
Release : 2009-03-02
Category : Science
ISBN : 3527322647

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Solvent-free Organic Synthesis by Koichi Tanaka Pdf

In this second edition of a best-selling handbook all the chapters have been completely revised and updated, while four completely new chapters have been added. In order to meet the needs of the practitioner, emphasis is placed on describing precisely the technology and know-how involved. Adopting a didactic and comprehensible approach, the book guides the reader through theory and applications, thus ensuring its warm welcome among the scientific community. An excellent, essential and exhaustive overview.

Catalytic Application of Nano-Gold Catalysts

Neeraj Kumar Mishra
Catalytic Application of Nano Gold Catalysts Book PDF

Author : Neeraj Kumar Mishra
Publisher : BoD – Books on Demand
Page : 142 pages
File Size : 52,5 Mb
Release : 2016-08-31
Category : Science
ISBN : 9789535126409

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Catalytic Application of Nano-Gold Catalysts by Neeraj Kumar Mishra Pdf

Gold, considered catalytically inactive for a long time, is now a fascinating partner of modern chemistry, as scientists such as Bond, Teles, Haruta, Hutchings, Ito and Hayashi opened new perspectives for the whole synthetic chemist community. Recently gold has attracted significant attention due to its advantageous characteristics as a catalytic material and since it allows easy functionalization with biologically active molecules. In this context, when gold is prepared as very small particles, it turns out to be a highly active catalyst. However, such a phenomenon completely disappears when the gold particle size grows into the micrometer range. Therefore, the preparation for obtaining an active gold catalyst is so important. The primary objective of this book is to provide a comprehensive overview of gold metal nanoparticles and their application as promising catalysts.

Modern Acetylene Chemistry

Peter J. Stang,François Diederich
Modern Acetylene Chemistry Book PDF

Author : Peter J. Stang,François Diederich
Publisher : John Wiley & Sons
Page : 527 pages
File Size : 53,7 Mb
Release : 2008-09-26
Category : Science
ISBN : 9783527615261

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Modern Acetylene Chemistry by Peter J. Stang,François Diederich Pdf

This comprehensive handbook presents the full potential of modern acetylene chemistry, from organic synthesis through materials science to bioorganic chemistry. K. Houk, H. Hopf, P. Stang, K. M. Nicholas, N. Schore, M. Regitz, K. C. Nicolaou, R. Gleiter, L. Scott, R. Grubbs, H. Iwamura, J. Moore, and F. Diederich - internationally renowned authors introduce the reader, in a didactically skilful manner, to the state-of-the-art in alkyne chemistry. Emphasis is placed on presenting carefully selected and instructive examples as well as essential references to the original literature. Special benefits: Each chapter is rounded off by useful experimental procedures.