Interim Design Assessment For The Blue Grass Chemical Agent Destruction Pilot Plant

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Assess Designs for Pueblo and Blue Grass Chemical Agent Destruction Pilot Plants
Publisher : National Academies Press
Page : 94 pages
File Size : 43,8 Mb
Release : 2005-10-25
Category : Science
ISBN : 9780309181693

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Interim Design Assessment for the Blue Grass Chemical Agent Destruction Pilot Plant by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Assess Designs for Pueblo and Blue Grass Chemical Agent Destruction Pilot Plants Pdf

Because of concerns about incineration, the Department of Defense plans to use alternative means to destroy the chemical agent stockpiles at the Pueblo and Blue Grass facilities. The DOD contracted with Bechtel Parsons to design and operate pilot plants for this purpose. As part of the NRC efforts to assist the DOD with its chemical demilitarization efforts, the Department requested a review and assessment of the Bechtel designs for both plants. An earlier report presented an assessment of the Pueblo design. This report provides a review of the Blue Grass Chemical Agent Destruction Pilot Plant based on review of data and information about the initial design and some intermediate design data. Among other topics, the report presents technical risk assessment issues, an analysis of delivery and disassembly operations and of agent destruction core processes, and an examination of waste treatment.

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Assess Designs for Pueblo and Blue Grass Chemical Agent Destruction Pilot Plants
Publisher : National Academies Press
Page : 92 pages
File Size : 53,9 Mb
Release : 2005-01-18
Category : Technology & Engineering
ISBN : 9780309165303

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Interim Design Assessment for the Pueblo Chemical Agent Destruction Pilot Plant by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Assess Designs for Pueblo and Blue Grass Chemical Agent Destruction Pilot Plants Pdf

In 1996, Congress enacted directing the Department of Defense to assess and demonstrate technology alternatives to incineration for destruction of the chemical weapons stored at Pueblo Chemical and Blue Grass Army Depots. Since then, the National Research Council (NRC) has been carrying out evaluations of candidate technologies including reviews of engineering design studies and demonstration testing. Most recently, the NRC was asked by the Army to evaluate designs for pilot plants at Pueblo and Blue Grass. These pilot plants would use chemical neutralization for destroying the chemical agent and the energetics in the munitions stockpiles of these two depots. This report provides the interim assessment of the Pueblo Chemical Agent Destruction Pilot Plant (PCAPP) to permit adjustment of any significant problems as soon as possible. The report presents an analysis of the issues about the current PCAPP design and a series of findings and recommendations about ways to reduce concerns with involve the public more heavily in the process.

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Assess Supercritical Water Oxidation System Testing for the Blue Grass Chemical Agent Destruction Pilot Plant
Publisher : National Academies Press
Page : 58 pages
File Size : 54,6 Mb
Release : 2013-10-10
Category : Technology & Engineering
ISBN : 9780309287326

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Assessment of Supercritical Water Oxidation System Testing for the Blue Grass Chemical Agent Destruction Pilot Plant by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Assess Supercritical Water Oxidation System Testing for the Blue Grass Chemical Agent Destruction Pilot Plant Pdf

Assessment of Supercritical Water Oxidation System Testing for the Blue Grass Chemical Agent Destruction Pilot Plant reviews and evaluates the results of the tests conducted on one of the SCWO units to be provided to Blue Grass Chemical Agent Destruction Pilot Plant. The Army Element, Assembled Chemical Weapons Alternatives (ACWA) is responsible for managing the conduct of destruction operations for the remaining 10 percent of the nation's chemical agent stockpile, stored at the Blue Grass Army Depot (Kentucky) and the Pueblo Chemical Depot (Colorado). Facilities to destroy the agents and their associated munitions are currently being constructed at these sites. The Blue Grass Chemical Agent Destruction Pilot Plant (BGCAPP) will destroy chemical agent and some associated energetic materials by a process of chemical neutralization known as hydrolysis. The resulting chemical waste stream is known as hydrolysate. Among the first-of-a-kind equipment to be installed at BGCAPP are three supercritical water oxidation (SCWO) reactor systems. These particular hydrolysate feeds present unique non-agent-related challenges to subsequent processing via SCWO due to their caustic nature and issues of salt management.This report provides recommendations on SCWO systemization testing inclusive of durability testing and discusses systemization testing objectives and concepts.

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Assess Process Safety Metrics for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants
Publisher : National Academies Press
Page : 60 pages
File Size : 40,5 Mb
Release : 2011-04-19
Category : Political Science
ISBN : 9780309215077

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Assessment of Approaches for Using Process Safety Metrics at the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Assess Process Safety Metrics for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants Pdf

The Department of Defense, through the Assembled Chemical Weapons Alternatives program, is currently in the process of constructing two full-scale pilot plants at the Pueblo Chemical Depot in Colorado and the Blue Grass Army Depot in Kentucky to destroy the last two remaining inventories of chemical weapons in the U.S. stockpile. These two storage sites together account for about 10 percent of the original U.S. chemical agent stockpile that is in the process of being destroyed in accordance with the international Chemical Weapons Convention treaty. Unlike their predecessors, these facilities will use neutralization technologies to destroy agents contained within rockets, projectiles, and mortar rounds, requiring the use of specially designed equipment. As part of its focus on safe operation of the planned facilities, the Program Manager for Assembled Chemical Weapons Alternatives asked the National Research Council (NRC) to conduct a study to offer guidance on the application of process safety metrics at the Pueblo Chemical Depot and Blue Grass Army Depot. Process safety is a disciplined framework for managing the integrity of operating systems, processes and personnel handling hazardous substances, and operations by applying good design principles, engineering, and operating practices. Process Safety Metrics at the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants discusses the use of leading and lagging process safety metrics that could provide feedback on the effectiveness of controls to mitigate risks and minimize consequences of potential incidents. The book makes several recommendations that will facilitate the development and application of process safety metrics at both sites.

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Review Secondary Waste Disposal and Regulatory Requirements for the Assembled Chemical Weapons Alternatives Program
Publisher : National Academies Press
Page : 84 pages
File Size : 51,6 Mb
Release : 2008-11-14
Category : Political Science
ISBN : 9780309178532

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Review of Secondary Waste Disposal Planning for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Review Secondary Waste Disposal and Regulatory Requirements for the Assembled Chemical Weapons Alternatives Program Pdf

The U.S. Army Program Manager for Assembled Chemical Weapons Alternatives (PMACWA) is charged with disposing of chemical weapons as stored at two sites: Pueblo, Colorado, and Blue Grass, Kentucky. In accordance with congressional mandates, technologies other than incineration are to be used if they are as safe and as cost effective. The weapons are to be disposed of in compliance with the Chemical Weapons Convention. Although an element of the U.S. Army, the PMACWA is responsible to the Assistant Secretary of Defense for Acquisitions, Technology, and Logistics for completing this mission. This book deals with the expected significant quantities of secondary wastes that will be generated during operations of the facilities and their closure. While there are only estimates for the waste quantities that will be generated, they provide a good basis for planning and developing alternatives for waste disposal while the plants are still in the design phase. Establishing efficient disposal options for the secondary wastes can enable more timely and cost-effective operation and closure of the facilities.

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants
Publisher : National Academies Press
Page : 192 pages
File Size : 51,8 Mb
Release : 2012-09-21
Category : Science
ISBN : 9780309259880

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Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants Pdf

January 2012 saw the completion of the U.S. Army's Chemical Materials Agency's (CMA's) task to destroy 90 percent of the nation's stockpile of chemical weapons. CMA completed destruction of the chemical agents and associated weapons deployed overseas, which were transported to Johnston Atoll, southwest of Hawaii, and demilitarized there. The remaining 10 percent of the nation's chemical weapons stockpile is stored at two continental U.S. depots, in Lexington, Kentucky, and Pueblo, Colorado. Their destruction has been assigned to a separate U.S. Army organization, the Assembled Chemical Weapons Alternatives (ACWA) Element. ACWA is currently constructing the last two chemical weapons disposal facilities, the Pueblo and Blue Grass Chemical Agent Destruction Pilot Plants (denoted PCAPP and BGCAPP), with weapons destruction activities scheduled to start in 2015 and 2020, respectively. ACWA is charged with destroying the mustard agent stockpile at Pueblo and the nerve and mustard agent stockpile at Blue Grass without using the multiple incinerators and furnaces used at the five CMA demilitarization plants that dealt with assembled chemical weapons - munitions containing both chemical agents and explosive/propulsive components. The two ACWA demilitarization facilities are congressionally mandated to employ noncombustion-based chemical neutralization processes to destroy chemical agents. In order to safely operate its disposal plants, CMA developed methods and procedures to monitor chemical agent contamination of both secondary waste materials and plant structural components. ACWA currently plans to adopt these methods and procedures for use at these facilities. The Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants report also develops and describes a half-dozen scenarios involving prospective ACWA secondary waste characterization, process equipment maintenance and changeover activities, and closure agent decontamination challenges, where direct, real-time agent contamination measurements on surfaces or in porous bulk materials might allow more efficient and possibly safer operations if suitable analytical technology is available and affordable.

Author : Anonim
Publisher : Unknown
Page : 13 pages
File Size : 46,6 Mb
Release : 2006
Category : Chemical weapons disposal
ISBN : OCLC:817653830

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Letter Report of Review and Assessment of the Proposals for Design and Operation of Designated Chemical Agent Destruction Pilot Plants (DCAPP-Blue Grass) by Anonim Pdf

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review and Evaluation of International Technologies for the Destruction of Non-Stockpile Chemical Materiel
Publisher : National Academies Press
Page : 128 pages
File Size : 48,7 Mb
Release : 2006-11-02
Category : Technology & Engineering
ISBN : 9780309180511

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Review of International Technologies for Destruction of Recovered Chemical Warfare Materiel by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review and Evaluation of International Technologies for the Destruction of Non-Stockpile Chemical Materiel Pdf

The Chemical Weapons Convention requires, among other things, that the signatories to the conventionâ€"which includes the United Statesâ€"destroy by April 29, 2007, or as soon possible thereafter, any chemical warfare materiel that has been recovered from sites where it has been buried once discovered. For several years the United States and several other countries have been developing and using technologies to dispose of this non-stockpile materiel. To determine whether international efforts have resulted in technologies that would benefit the U.S. program, the U.S. Army asked the NRC to evaluate and compare such technologies to those now used by the United States. This book presents a discussion of factors used in the evaluations, summaries of evaluations of several promising international technologies for processing munitions and for agent-only processing, and summaries of other technologies that are less likely to be of benefit to the U.S. program at this time.

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Review Secondary Waste Disposal and Regulatory Requirements for the Assembled Chemical Weapons Alternatives Program
Publisher : National Academies Press
Page : 84 pages
File Size : 43,6 Mb
Release : 2008-12-14
Category : Political Science
ISBN : 9780309120500

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Review of Secondary Waste Disposal Planning for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee to Review Secondary Waste Disposal and Regulatory Requirements for the Assembled Chemical Weapons Alternatives Program Pdf

The U.S. Army Program Manager for Assembled Chemical Weapons Alternatives (PMACWA) is charged with disposing of chemical weapons as stored at two sites: Pueblo, Colorado, and Blue Grass, Kentucky. In accordance with congressional mandates, technologies other than incineration are to be used if they are as safe and as cost effective. The weapons are to be disposed of in compliance with the Chemical Weapons Convention. Although an element of the U.S. Army, the PMACWA is responsible to the Assistant Secretary of Defense for Acquisitions, Technology, and Logistics for completing this mission. This book deals with the expected significant quantities of secondary wastes that will be generated during operations of the facilities and their closure. While there are only estimates for the waste quantities that will be generated, they provide a good basis for planning and developing alternatives for waste disposal while the plants are still in the design phase. Establishing efficient disposal options for the secondary wastes can enable more timely and cost-effective operation and closure of the facilities.

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review Criteria for Successful Treatment of Hydrolysate at the Pueblo and Blue Grass Chemical Agent Destruction Pilot Plants
Publisher : National Academies Press
Page : 86 pages
File Size : 47,9 Mb
Release : 2015-03-26
Category : Technology & Engineering
ISBN : 9780309317917

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Review Criteria for Successful Treatment of Hydrolysate at the Pueblo Chemical Agent Destruction Pilot Plant by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review Criteria for Successful Treatment of Hydrolysate at the Pueblo and Blue Grass Chemical Agent Destruction Pilot Plants Pdf

One of the last two sites with chemical munitions and chemical materiel is the Pueblo Chemical Depot in Pueblo, Colorado. The stockpile at this location consists of about 800,000 projectiles and mortars, all of which are filled with the chemical agent mustard. Under the direction of the Assembled Chemical Weapons Alternative Program (ACWA), the Army has constructed the Pueblo Chemical Agent Destruction Pilot Plant (PCAPP) to destroy these munitions. The primary technology to be used to destroy the mustard agent at PCAPP is hydrolysis, resulting in a secondary waste stream referred to as hydrolysate. PCAPP features a process that will be used to treat the hydrolysate and the thiodiglycol - a breakdown product of mustard - contained within. The process is a biotreatment technology that uses what are known as immobilized cell bioreactors. After biodegradation, the effluent flows to a brine reduction system, producing a solidified filter cake that is intended to be sent offsite to a permitted hazardous waste disposal facility. Water recovered from the brine reduction system is intended to be recycled back through the plant, thereby reducing the amount of water that is withdrawn from groundwater. Although biotreatment of toxic chemicals, brine reduction, and water recovery are established technologies, never before have these technologies been combined to treat mustard hydrolysate. At the request of the U.S. Army, Review Criteria for Successful Treatment of Hydrolysate at the Pueblo Chemical Agent Destruction Pilot Plant reviews the criteria for successfully treating the hydrolysate. This report provides information on the composition of the hydrolysate and describes the PCAPP processes for treating it; discusses stakeholder concerns; reviews regulatory considerations at the federal, state, and local levels; discusses Department of Transportation regulations and identifies risks associated with the offsite shipment of hydrolysate; establishes criteria for successfully treating the hydrolysate and identifies systemization data that should factor into the criteria and decision process for offsite transport and disposal of the hydrolysate; and discusses failure risks and contingency options as well as the downstream impacts of a decision to ship hydrolysate offsite.

Author : Anonim
Publisher : Unknown
Page : 52 pages
File Size : 55,6 Mb
Release : 2012
Category : Chemical weapons disposal
ISBN : OCLC:830033683

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Letter Report on the Blue Grass Chemical Agent Destruction Pilot Plant's Water Recovery System by Anonim Pdf

Author : National Research Council (U.S.). Committee On Review Criteria for Successful Treatment of Hydrolysate at the Pueblo and Blue Grass Chemical Agent Destruction Pilot Plant
Publisher : Unknown
Page : 85 pages
File Size : 40,9 Mb
Release : 2015
Category : TECHNOLOGY & ENGINEERING
ISBN : 0309367646

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Review Criteria for Successful Treatment of Hydrolysate at the Pueblo Chemical Agent Destruction Pilot Plant by National Research Council (U.S.). Committee On Review Criteria for Successful Treatment of Hydrolysate at the Pueblo and Blue Grass Chemical Agent Destruction Pilot Plant Pdf

"One of the last two sites with chemical munitions and chemical materiel is the Pueblo Chemical Depot in Pueblo, Colorado. The stockpile at this location consists of about 800,000 projectiles and mortars, all of which are filled with the chemical agent mustard. Under the direction of the Assembled Chemical Weapons Alternative Program (ACWA), the Army has constructed the Pueblo Chemical Agent Destruction Pilot Plant (PCAPP) to destroy these munitions. The primary technology to be used to destroy the mustard agent at PCAPP is hydrolysis, resulting in a secondary waste stream referred to as hydrolysate. PCAPP features a process that will be used to treat the hydrolysate and the thiodiglycol - a breakdown product of mustard - contained within. The process is a biotreatment technology that uses what are known as immobilized cell bioreactors. After biodegradation, the effluent flows to a brine reduction system, producing a solidified filter cake that is intended to be sent offsite to a permitted hazardous waste disposal facility. Water recovered from the brine reduction system is intended to be recycled back through the plant, thereby reducing the amount of water that is withdrawn from groundwater. Although biotreatment of toxic chemicals, brine reduction, and water recovery are established technologies, never before have these technologies been combined to treat mustard hydrolysate. At the request of the U.S. Army, Review Criteria for Successful Treatment of Hydrolysate at the Pueblo Chemical Agent Destruction Pilot Plant reviews the criteria for successfully treating the hydrolysate. This report provides information on the composition of the hydrolysate and describes the PCAPP processes for treating it; discusses stakeholder concerns; reviews regulatory considerations at the federal, state, and local levels; discusses Department of Transportation regulations and identifies risks associated with the offsite shipment of hydrolysate; establishes criteria for successfully treating the hydrolysate and identifies systemization data that should factor into the criteria and decision process for offsite transport and disposal of the hydrolysate; and discusses failure risks and contingency options as well as the downstream impacts of a decision to ship hydrolysate offsite."--Publisher's description.

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Continuing Operability of Chemical Agent Disposal Facilities and Equipment
Publisher : National Academies Press
Page : 78 pages
File Size : 55,6 Mb
Release : 2007-03-08
Category : Political Science
ISBN : 9780309103510

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Assessment of the Continuing Operability of Chemical Agent Disposal Facilities and Equipment by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Continuing Operability of Chemical Agent Disposal Facilities and Equipment Pdf

The U.S. Army's Chemical Materials Agency (CMA) currently oversees contracts for the operation of chemical agent stockpile incineration facilities at four disposal sites. Because the period of time required to dispose of these chemical agents has grown beyond that originally planned, the Army is becoming concerned about the possibility of growing operational problems as the processing equipment ages. To help address these concerns, the CMA requested the NRC to assess whether current policies and practices will be able to adequately anticipate and address facility obsolescence issues. This report presents a review of potential infrastructure and equipment weaknesses given that the facilities are being operated well beyond their original design lifetime; an assessment of the Army's current and evolving obsolescence management programs; and offers recommendations about how the programs may be improved and strengthened to permit safe and expeditious completion of agent stockpile destruction and facility closure.

Author : Engineering National Academies of Sciences (and Medicine)
Publisher : Unknown
Page : 30 pages
File Size : 55,6 Mb
Release : 2019
Category : Electronic
ISBN : 0309490251

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Metrics for Successful Supercritical Water Oxidation System Operation at the Blue Grass Chemical Agent Destruction Pilot Plant by Engineering National Academies of Sciences (and Medicine) Pdf

Author : Department of the Army
Publisher : Createspace Independent Pub
Page : 582 pages
File Size : 53,5 Mb
Release : 2013-03-09
Category : History
ISBN : 1482732939

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Destruction of Chemical Munitions at Blue Grass Army Depot, Kentucky - Final Environmental Impact Statement, Volume I (Main Report, Appendicies A-J) by Department of the Army Pdf

“Destruction of Chemical Munitions at Blue Grass Army Depot, Kentucky – Final Environmental Impact Statement – Volume I (Main Report and Appendices A-J)” (see also “Volume II – Appendix K”) - Public Law 99-145 and subsequent related legislation requires destruction of the U.S. stockpile of lethal unitary chemical agents and munitions. Furthermore, in 1993 an international treaty, the Chemical Weapons Convention (CWC), was signed by 65 nations, including the United States. The CWC, which set the deadline for completing destruction of chemical weapons as 10 years following ratification by the required number of nations, received the necessary ratifications on April 29,1997. Thus, the international deadline for destruction of chemical weapons is April 29, 2007. The Army Chemical Stockpile Disposal Program has prepared this Final Environmental Impact Statement (FEIS) to assess the potential health and environmental impacts of the construction, operation, and closure of a facility to destroy the chemical agent and munitions stored at Blue Grass Army Depot (BGAD), Kentucky. Four alternatives are addressed in this FEIS for possible use in destruction of the BGAD stockpile: (1) baseline incineration, which is currently in use by the Army at Deseret Chemical Depot (DCD), Utah and was used by the Johnston Atoll Chemical Agent Disposal System (JACADS) to destroy the entire stockpile on Johnston Atoll; (2) chemical neutralization followed by supercritical water oxidation, a developing technology that would be initially operated as a pilot test facility; (3) chemical neutralization followed by supercritical water oxidation and gas phase chemical reduction, a developing technology that would be initially operated as a pilot test facility; and (4) electrochemical oxidation, which is also under development and would be initially operated as a pilot test facility. The latter three alternatives have also been evaluated in a separate EIS prepared by the Army Assembled Chemical Weapons Assessment Program (ACWA) as part of four chemical neutralization technologies being considered for pilot testing at BGAD and three other chemical munitions storage locations. The data and information obtained from testing and full-scale operation of the incineration technology, and available data and information from on-going studies of the technologies provided by ACWA are analyzed and compared to the extent possible in this FEIS.