Mxene Based Hybrid Nano Architectures For Environmental Remediation And Sensor Applications

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MXene-Based Hybrid Nano-Architectures for Environmental Remediation and Sensor Applications

Author : Ram Gupta,Muhammad Bilal,Tuan Anh Nguyen,Hafiz M. N. Iqbal,Ghulam Yasin
Publisher : Elsevier
Page : 555 pages
File Size : 47,6 Mb
Release : 2024-01-19
Category : Science
ISBN : 9780323955164

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MXene-Based Hybrid Nano-Architectures for Environmental Remediation and Sensor Applications by Ram Gupta,Muhammad Bilal,Tuan Anh Nguyen,Hafiz M. N. Iqbal,Ghulam Yasin Pdf

Approx.630 pages Covers fundamentals of MXene-based hybrid nanostructures, including synthesis and characterization methods Explores innovative and emerging applications, with a focus on environmental remediation and sensors Addresses challenges, such as environmental impact and lifecycle, as well as future possibilities

MXenes as Emerging Modalities for Environmental and Sensing Applications

Author : Tahir Rasheed,Chandrabhan Verma
Publisher : Elsevier
Page : 0 pages
File Size : 53,6 Mb
Release : 2024-11-01
Category : Science
ISBN : 9780443218521

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MXenes as Emerging Modalities for Environmental and Sensing Applications by Tahir Rasheed,Chandrabhan Verma Pdf

MXenes as Emerging Modalities for Environmental and Sensing Applications: Theories, Design and Approach explores how MXene-based hybrid nanostructures are used to remedy environmental pollutants. The book also explains how they assist in sensing and degradation/removal applications to protect the ecological system, both environmental and aquatic life, from various types of toxic pollutants released from industrial sectors. This book focuses on the design, fabrication, and application of MXene-based nanostructures and their integration with the biotechnological processes for monitoring and treatment of pollutants in environmental matrices and sensing applications. It aims to increase scientific and technological awareness of the urgency required to tackle life-threatening pollutants arising from various industrial and biotechnological sectors of the modern world. Provides advanced materials for mitigating environmental pollutants that collectively describe the entire aspects of environmental and material chemistry Explains the use of MXenes and MXenes-based hybrid materials as advanced environmental remediation tools Focuses on the most advanced industrial-scale materials for industry, including current challenges during manufacturing and applications Offers up-to-date reference materials, including websites of interest and information about the latest research

Environmental Applications of Nanomaterials

Author : Glen E. Fryxell,Guozhong Cao
Publisher : World Scientific
Page : 751 pages
File Size : 52,5 Mb
Release : 2012
Category : Science
ISBN : 9781848168039

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Environmental Applications of Nanomaterials by Glen E. Fryxell,Guozhong Cao Pdf

This book is concerned with functional nanomaterials, materials containing specific, predictable nanostructures whose chemical composition, or interfacial structure enables them to perform a specific job: to destroy, sequester, or detect some material that constitutes an environmental threat. Nanomaterials have a number of features that make them ideally suited for this job: they have a high surface area, high reactivity, easy dispersability, and rapid diffusion,to name a few. The purpose of this book is to showcase how these features can be tailored to address some of the environmental remediation and sensing/detection problems faced by mankind today. A number of leading researchers have contributed to this volume, painting a picture of diverse synthetic strategies, structures, materials, and methods. The intent of this book is to showcase the current state of environmental nanomaterials in such a way as to be useful either as a research resource, or as a graduate level textbook. We have organized this book into sections on nanoparticle-based remediation strategies, nanostructured inorganic materials (e.g. layered materials like the apatites), nanostructured organic/inorganic hybrid materials, and the use of nanomaterials to enhance the performance of sensors.

Functional Hybrid Nanomaterials for Environmental Remediation

Author : Ahmad Fauzi Ismail,Pei Sean Goh
Publisher : Royal Society of Chemistry
Page : 323 pages
File Size : 49,8 Mb
Release : 2021-09-24
Category : Science
ISBN : 9781839165290

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Functional Hybrid Nanomaterials for Environmental Remediation by Ahmad Fauzi Ismail,Pei Sean Goh Pdf

Functional and structural nanomaterials are emerging materials that display interesting physical and chemical properties because of their size and surface area to volume ratio. Applications for these materials include uses in removing pollutants from the environment. Looking at the current state-of-the-art as well as future trends in the use of nanomaterials for tackling environmental issues this book covers everything from the synthesis and characterisation of these materials to their use in the removal of specific contaminants. Functional Hybrid Nanomaterials for Environmental Remediation is a useful resource both for nanomaterial scientists interested in the real world application of hybrid nanomaterials and for environmental chemists and environmental engineers interested in novel materials for environmental remediation.

Environmental Applications of Nanomaterials

Author : Glen E Fryxell,Guozhong Cao
Publisher : World Scientific
Page : 752 pages
File Size : 41,5 Mb
Release : 2012-07-24
Category : Science
ISBN : 9781908977069

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Environmental Applications of Nanomaterials by Glen E Fryxell,Guozhong Cao Pdf

This book is concerned with functional nanomaterials, materials containing specific, predictable nanostructures whose chemical composition, or interfacial structure enables them to perform a specific job: to destroy, sequester, or detect some material that constitutes an environmental threat. Nanomaterials have a number of features that make them ideally suited for this job: they have a high surface area, high reactivity, easy dispersability, and rapid diffusion, to name a few. The purpose of this book is to showcase how these features can be tailored to address some of the environmental remediation and sensing/detection problems faced by mankind today. A number of leading researchers have contributed to this volume, painting a picture of diverse synthetic strategies, structures, materials, and methods. The intent of this book is to showcase the current state of environmental nanomaterials in such a way as to be useful both as a research resource and as a graduate level textbook. We have organized this book into sections on nanoparticle-based remediation strategies, nanostructured inorganic materials (e.g. layered materials like the apatites), nanostructured organic/inorganic hybrid materials, and the use of nanomaterials to enhance the performance of sensors. Contents:Nanoparticle-based Approaches:Nanoparticle Metal Oxides for Chlorocarbon and Organophosphonate Remediation (Olga B Koper, Shyamala Rajagopalan, Slawomir Winecki and Kenneth J Klabunde)Nanoscale Zero-Valent Iron (nZVI) for Site Remediation (Daniel W Elliott, Hsing-Lung Lien and Wei-xian Zhang)Synthesis, Characterization, and Properties of Zero-Valent Iron Nanoparticles (Donald R Baer, Paul G Tratnyek, You Qiang, James E Amonette, John Linehan, Vaishnavi Sarathy, James T Nurmi, Chongmin Wang and J Antony)Nanostructured Inorganic Materials:Formation of Nanosized Apatite Crystals in Sediment for Containment and Stabilization of Contaminants (Robert C Moore, Jim Szecsody, Michael J Truex, Katheryn B Helean, Ranko Bontchev and Calvin Ainsworth)Functionalized Nanoporous Sorbents for Adsorption of Radioiodine from Groundwater and Waste Glass Leachates (Shas V Mattigod, Glen E Fryxell and Kent E Parker)Nanoporous Organic/Inorganic Hybrid Materials:Nature's Nanoparticles: Group IV Phosphonates (Abraham Clearfield)Twenty-five Years of Nuclear Waste Remediation Studies (Abraham Clearfield)Synthesis of Nanostructured Hybrid Sorbent Materials Using Organosilane Self-assembly on Mesoporous Ceramic Oxides (Glen E Fryxell)Chemically Modified Mesoporous Silicas and Organosilicas for Adsorption and Detection of Heavy Metal Ions (Oksana Olkhovyk and Mietek Jaroniec)Hierarchically Imprinted Adsorbents (Hyunjung Kim, Chengdu Liang and Sheng Dai)Functionalization of Periodic Mesoporous Silica and Its Application to the Adsorption of Toxic Anions (Hideaki Yoshitake)Layered Semi-crystalline Polysilsesquioxane: A Mesostructured and Stoichiometric Organic-Inorganic Hybrid Solid for the Removal of Environmentally Hazardous Ions (Hideaki Yoshitake)A Thiol-functionalized Nanoporous Silica Sorbent for Removal of Mercury from Actual Industrial Waste (Shas V Mattigod, Glen E Fryxell and Kent E Parker)Functionalized Nanoporous Silica for Oral Chelation Therapy of a Broad Range of Radionuclides (Wassana Yantasee, Wilaiwan Chouyyok, Robert J Wiacek, Jeffrey A Creim, R Shane Addleman, Glen E Fryxell and Charles Timchalk)Amine-functionalized Nanoporous Materials for Carbon Dioxide (CO2) Capture (Feng Zheng, R Shane Addleman, Christopher L Aardahl, Glen E Fryxell, Daryl R Brown and Thomas S Zemanian)Carbon Dioxide Capture from Post-combustion Streams Using Amine-functionalized Nanoporous Materials (Rodrigo Serna-Guerrero and Abdelhamid Sayari)Nanomaterials that Enhance Sensing/Detection of Environmental Contaminants:Nanostructured ZnO Gas Sensors (Huamei Shang and Guozhong Cao)Synthesis and Properties of Mesoporous-based Materials for Environmental Applications (Jianlin Shi, Hangrong Chen, Zile Hua and Lingxia Zhang)Electrochemical Sensors Based on Nanomaterials for Environmental Monitoring (Wassana Yantasee, Yuehe Lin and Glen E Fryxell)Nanomaterial-based Environmental Sensors (Dosi Dosev, Mikaela Nichkova and Ian M Kennedy)Carbon Nanotube- and Graphene-based Sensors for Environmental Applications (Dan Du)One-dimensional Hollow Oxide Nanostructures: A Highly Sensitive Gas-sensing Platform (Jong-Heun Lee)Preparation and Electrochemical Application of Titania Nanotube Arrays (Peng Xiao, Guozhong Cao and Yunhuai Zhang) Readership: Graduate students and researchers in nanomaterials and nanostructures. Keywords:Nanomaterials;Nanoporous Sorbents;Chemical Separations;Environmental Clean-Up;Heavy Metals;Radionuclides;Nanoparticles;SensorsKey Features:The materials and methods described herein offer exciting new possibilities in the remediation and/or detection of a wide variety of environmental concerns, including chemical warfare agents, dense non-aqueous phase liquids (DNAPLs), heavy metals, radionuclides, biological threats, carbon dioxide, carbon monoxide and more. The approaches described run the gamut from laboratory design and synthesis of the nanomaterial, to final application/deployment of the technology to clean up hazardous wasteThe contributing authors are leading experts in the field of environmental nanomaterialsStrategies cover a wide variety of chemistries and structural morphologies, including nanoparticles, nanotubes and nanoporous materials, thereby providing a valuable overview of the state-of-the-art

Nanomaterials for Sustainable Energy and Environmental Remediation

Author : Mu. Naushad,R. Saravanan,Raju Kumar
Publisher : Elsevier
Page : 404 pages
File Size : 49,7 Mb
Release : 2020-03-14
Category : Technology & Engineering
ISBN : 9780128193563

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Nanomaterials for Sustainable Energy and Environmental Remediation by Mu. Naushad,R. Saravanan,Raju Kumar Pdf

Nanostructured materials, especially, 1D, 2D and 3D nanostructures, and their engineered architectures are being increasingly used due to their potential to achieve sustainable development in energy and environmental sectors, providing a solution to a range of global challenges. A huge amount of research has been devoted in the recent past on the fine-tuning of nano-architecutres to accomplish innovations in energy storage and conversions, i.e., batteries, supercapacitors, fuel cells, solar cells, and electrochromic devices, bifunctional catalysts for ORR and OER, gas to fuels, liquid to fuels, and photocatalysts, corrosion, electrochemical sensors, and pollution and contaminants removal. Nanomaterials for Sustainable Energy and Environmental Remediation describes the fundamental aspects of a diverse range of nanomaterials for the sustainable development in energy and environmental remediation in a comprehensive manner. Experimental studies of varies nanomaterials will be discussed along with their design and applications, with specific attention to various chemical reactions involving and their challenges for catalysis, energy storage and conversion systems, and removal of pollutants are addressed. This book will also emphasise the challenges with past developments and direction for further research, details pertaining to the current ground - breaking technology and future perspective with multidisciplinary approach on energy, nanobiotechnology and environmental science Summarizes the latest advances in how nanotechnology is being used in energy and environmental science Outlines the major challenges to using nanomaterials for creating new products and devices in the sustainable energy and environmental sectors Helps materials scientists and engineers make selection and design decisions regarding which nanomaterial to use when creating new produts and evices for energy and environmental applications

Sustainable Nanotechnology for Environmental Remediation

Author : Rama Rao Karri,Janardhan Reddy Koduru,Nabisab Mujawar Mubarak,Erick R. Bandala
Publisher : Elsevier
Page : 832 pages
File Size : 54,6 Mb
Release : 2022-01-13
Category : Technology & Engineering
ISBN : 9780323852920

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Sustainable Nanotechnology for Environmental Remediation by Rama Rao Karri,Janardhan Reddy Koduru,Nabisab Mujawar Mubarak,Erick R. Bandala Pdf

Sustainable Nanotechnology for Environmental Remediation provides a single-source solution to researchers working in environmental, wastewater management, biological and composite nanomaterials applications. It addresses the potential environmental risks and uncertainties surrounding the use of nanomaterials for environmental remediation, giving an understanding of their impact on ecological receptors in addition to their potential benefits. Users will find comprehensive information on the application of state-of-the-art processes currently available to synthesize advanced green nanocomposite materials and biogenic nanomaterials. Other sections explore a wide range of promising approaches for green nanotechnologies and nanocomposites preparations. Case study chapters connect materials engineering and technology to the social context for a sustainable environment. Applications and different case studies provide solutions to the challenges faced by industry, thus minimizing negative social impacts. Provides information on the use of biologically mediated synthetic protocols to generate nanomaterials Discusses a wide range of promising?approaches?for?green nanotechnologies and nanocomposites preparations Presents novel fabrication techniques for bionanocomposites, paving the way for the development of a new generation of advanced materials that can cope with spatiotemporal multi-variant environments

MXene Nanocomposites

Author : Poushali Das,Andreas Rosenkranz,Sayan Ganguly
Publisher : CRC Press
Page : 294 pages
File Size : 48,9 Mb
Release : 2023-05-30
Category : Technology & Engineering
ISBN : 9781000868357

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MXene Nanocomposites by Poushali Das,Andreas Rosenkranz,Sayan Ganguly Pdf

MXenes offer single step processing, excellent electrical conductivity, easy heat dissipation behavior, and capacitor-like properties and are used in photodetectors, lithium-ion batteries, solar cells, photocatalysis, electrochemiluminescence sensors, and supercapacitors. Because of their superior electrical and thermal conductivities, these composites are an ideal choice in electromagnetic interference (EMI) shielding. MXene Nanocomposites: Design, Fabrication, and Shielding Applications presents a comprehensive overview of these emerging materials, including their underlying chemistry, fabrication strategies, and cutting-edge applications in EMI shielding. Covers modern fabrication technologies, processing, properties, nanostructure formation, and mechanisms of reinforcement Discuss biocompatibility, suitability, and toxic effects Details innovations, applications, opportunities, and future directions in EMI shielding applications This book is aimed at researchers and advanced students in materials science and engineering and is unique in its detailed coverage of MXene-based polymer composites for EMI shielding.

Environmental Applications of Carbon Nanomaterials-Based Devices

Author : Shadpour Mallakpour,Chaudery M. Hussain
Publisher : John Wiley & Sons
Page : 468 pages
File Size : 55,5 Mb
Release : 2021-12-20
Category : Technology & Engineering
ISBN : 9783527348657

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Environmental Applications of Carbon Nanomaterials-Based Devices by Shadpour Mallakpour,Chaudery M. Hussain Pdf

Environmental Applications of Carbon Nanomaterials-Based Devices Explore this insightful treatment of the function and fabrication of high-performance devices for environmental applications Environmental Applications of Carbon Nanomaterials-Based Devices delivers an overview of state-of-the-art technology in functionalized carbon nanomaterials-based devices for environmental applications. The book provides a powerful foundation, based in materials science, on functionalized carbon nanomaterials in general, and environmental science and device fabrication in particular. The book focuses on the chemical and physical methods of functionalization of carbon nanomaterials and the technology of device fabrication, including lab-on-a-chip approaches and applications such as wastewater purification and gas sensing. It provides readers with a thorough understanding of effective environmental remediation techniques performed with carbon nanomaterials-based devices. In addition to topics such as cross-linked graphene oxide membranes assembled with graphene oxide nanosheets, free-standing graphene oxide-chitin nanocrystal composite membranes for dye adsorption and oil/water separation, and in-situ grown covalent organic framework nanosheets on graphene for membrane-based dye/salt separation, readers will also benefit from the inclusion of: A thorough introduction to charge-gated ion transport through polyelectrolyte intercalated amine reduced graphene oxide membranes An exploration of hydrotalcite/graphene oxide hybrid nanosheets functionalized nanofiltration membrane for desalination A discussion of the incorporation of attapulgite nanorods into graphene oxide nanofiltration membranes for efficient dyes wastewater treatment An examination of attapulgite nanofibers and graphene oxide composite membranes for high-performance molecular separation Perfect for materials scientists, analytical chemists, and environmental chemists, Environmental Applications of Carbon Nanomaterials-Based Devices will also earn a place in the libraries of sensor developers seeking a one-stop resource for high-performance devices and sensors useful for environmental applications.

Emerging Nanomaterials for Recovery of Toxic and Radioactive Metal Ions from Environmental Media

Author : Xiangke Wang
Publisher : Elsevier
Page : 398 pages
File Size : 45,5 Mb
Release : 2021-11-26
Category : Science
ISBN : 9780323854856

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Emerging Nanomaterials for Recovery of Toxic and Radioactive Metal Ions from Environmental Media by Xiangke Wang Pdf

Emerging Nanomaterials for Recovery of Toxic and Radioactive Metal Ions from Environmental Media covers nanomaterials used in the environmental remediation of sites contaminated by toxic or radioactive heavy metals. The book comprehensively covers the use of MOF-based nanomaterials, COF-based nanomaterials, MXene-based nanomaterials, nZVI-based nanomaterials and carbon-based nanomaterials in remediation techniques and details the main interaction mechanisms between toxic/radioactive metal ions and the described novel nanomaterials through kinetic analysis, thermodynamic analysis, spectroscopic techniques and theoretical calculations. It provides a thorough reference on the use of the described novel nanomaterials for academics, researchers and advanced postgraduates in the environmental sciences and environmental chemistry. Provides a comprehensive and systematic reference on various novel nanomaterials that are available for use in the treatment of heavy metal ions and radioactive wastes Presents the latest knowledge on the interaction of toxic and radioactive metal ions with novel nanomaterials, including how to choose different materials for specific uses Covers the principles and functionalization of nanomaterials in environmental remediation, enabling an understanding of methodologies and best choice in nanomaterials

Metal-Organic Frameworks-Based Hybrid Materials for Environmental Sensing and Monitoring

Author : Ram K. Gupta,Tahir Rasheed,Tuan Anh Nguyen,Muhammad Bilal
Publisher : CRC Press
Page : 349 pages
File Size : 52,5 Mb
Release : 2022-06-22
Category : Technology & Engineering
ISBN : 9781000569124

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Metal-Organic Frameworks-Based Hybrid Materials for Environmental Sensing and Monitoring by Ram K. Gupta,Tahir Rasheed,Tuan Anh Nguyen,Muhammad Bilal Pdf

With an unprecedented population boom and rapid industrial development, environmental pollution has become a severe problem for the ecosystem and public health. Classical techniques for sensing and determining environmental contaminants often require complex pretreatments, expensive equipment, and longer testing times. Therefore, new, and state-of-the-art sensing technologies possessing the advantages of excellent sensitivity, rapid detection, ease of use, and suitability for in situ, real-time, and continuous monitoring of environmental pollutants, are highly desirable. Metal-Organic Frameworks-based Hybrid Materials for Environmental Sensing and Monitoring covers the current-state-of-the-art hybrid nanomaterials based on metal-organic frameworks for electrochemical monitoring purposes. Accomplished authors cover various synthetic routes, methods, and theories behind enhancing the electrochemical properties and applications of metal-organic frameworks-based hybrid nanomaterials for electrochemical sensing of environmental pollutants under one roof. This book is essential reading for all academic and industrial researchers working in the fields of materials science and nanotechnology.

Hybrid Nanomaterials for Sustainable Applications

Author : Janardhan Reddy Koduru,Rama Rao Karri,Mubarak Nabisab Mujawar
Publisher : Elsevier
Page : 454 pages
File Size : 51,9 Mb
Release : 2023-01-15
Category : Science
ISBN : 9780323983716

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Hybrid Nanomaterials for Sustainable Applications by Janardhan Reddy Koduru,Rama Rao Karri,Mubarak Nabisab Mujawar Pdf

Hybrid Nanomaterials for Sustainable Applications: Case Studies and Applications brings together the latest advances in hybrid nanocomposites and their diverse applications for improved sustainability. The book begins by introducing hybrid nanomaterials, synthesis strategies, and approaches to production for engineering applications. Subsequent sections provide chapters on key application areas, including water purification, nanobiotechnologies, energy storage, and biomedicine, presenting approaches for sustainable application for each usage. Throughout the book, key challenges are addressed, with case studies used to support implementation and improve end applications. This is a valuable resource for researchers and advanced students in nanotechnology, polymer science, sustainable materials, chemistry, chemical engineering, environmental science, and materials engineering, as well as industrial scientists, engineers, and R&D professionals with an interest in hybrid nanomaterials for a range of applications. Offers the latest techniques in the synthesis and preparation of hybrid nanomaterials Addresses challenges and uses case studies to support further development and implementation Opens the door to key sustainable applications across water purification, nanobiotechnologies, energy storage and biomedicine

Nanotechnologies for Environmental Remediation

Author : Giusy Lofrano,Giovanni Libralato,Jeanette Brown
Publisher : Springer
Page : 325 pages
File Size : 44,7 Mb
Release : 2017-03-02
Category : Technology & Engineering
ISBN : 9783319531625

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Nanotechnologies for Environmental Remediation by Giusy Lofrano,Giovanni Libralato,Jeanette Brown Pdf

In this book discussing the principles of green chemistry and green engineering an international team of investigators present significant recent developments in applying nanoscience, nanoengineering, and nanotechnology to the area of environmental remediation. The opening chapters introduce candidate nanomaterials, properties, mechanisms that enable the applications, the advantages and limitations compared to existing processes and commercial research requirements. It then explores the detection and application of nanomaterials in photocatalytic processes and as adsorbents, and also covers the effect of nanoparticles in the activated sludge process. Later chapters focus on the effects of nanoparticles on crops, the risks associated with the presence of nanoparticles in the environment, and lastly the environmental effects of nanoscale zero-valent iron (nZVI) on land remediation. This timely, multi-author contributed volume is aimed at students, technicians, and academics interested in the role, risks and benefits of nanotechnology in modern environmental contexts.

Nanomaterials and Nanocomposites for Environmental Remediation

Author : Swatantra P. Singh,Karthik Rathinam,Tarun Gupta,Avinash Kumar Agarwal
Publisher : Springer Nature
Page : 341 pages
File Size : 47,8 Mb
Release : 2021-08-10
Category : Technology & Engineering
ISBN : 9789811632563

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Nanomaterials and Nanocomposites for Environmental Remediation by Swatantra P. Singh,Karthik Rathinam,Tarun Gupta,Avinash Kumar Agarwal Pdf

p="" This monograph focuses on recent development of nanomaterials and nanocomposites for pollution measurement and their control in water, air, and soil. The contents incorporate carbon-based, metal-based, and metal-organic framework based nanomaterials and nanocomposites for emerging contaminants (pharmaceuticals and personal care products) degradation, disinfection, and other traditional pollutants degradation and removal. The book also offers updated literature for researchers and academicians working in the field of environmental remediation by nanomaterials. Readers will learn about different metal and non-metal based nanoparticles for environmental remediation. It will be a useful guide for professionals, and post-graduate students involved in material science & engineering, chemical engineering and environmental nanotechnology research. ^

Environmental Remediation Through Carbon Based Nano Composites

Author : Mohammad Jawaid,Akil Ahmad,Norli Ismail,Mohd Rafatullah
Publisher : Springer Nature
Page : 444 pages
File Size : 50,6 Mb
Release : 2020-09-25
Category : Technology & Engineering
ISBN : 9789811566998

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Environmental Remediation Through Carbon Based Nano Composites by Mohammad Jawaid,Akil Ahmad,Norli Ismail,Mohd Rafatullah Pdf

This book examines carbon-based nanocomposite materials and their application in various environmental fields, such as wastewater treatment, and air and soil remediation. Featuring illustrations, and tables summarizing the latest research, it gathers up-to-date information on the application of carbon nanocomposites in the removal of environmental pollutants from different sources. Given its scope, the book is a valuable textbook for research students, and a useful handbook and reference resource for researchers, academics and industrial scientists working in the field of environmental pollutants and their safe removal.