Mössbauer Spectroscopy And Transition Metal Chemistry

Author : P. Gütlich,R. Link,A. Trautwein
Publisher : Springer Science & Business Media
Page : 292 pages
File Size : 41,8 Mb
Release : 2013-11-11
Category : Science
ISBN : 9783662125458

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Mössbauer Spectroscopy and Transition Metal Chemistry by P. Gütlich,R. Link,A. Trautwein Pdf

Two decades have passed since the original discovery of recoilless nuclear gamma resonance by Rudolf Mossbauer; the spectroscopic method based on this resonance effect - referred to as Mossbauer spectroscopy - has developed into a powerful tool in solid-state research. The users are chemists, physicists, biologists, geologists, and scientists from other disciplines, and the spectrum of problems amenable to this method has become extraordinarily broad. In the present volume we have confined ourselves to applications of Mossbauer spectroscopy to the area of transition elements. We hope that the book will be useful not only to non-Mossbauer special ists with problem-Oriented activities in the chemistry and physics of transition elements, but also to those actively working in the field of Mossbauer spectroscopy on systems (compounds as well as alloys) of transition elements. The first five chapters are directed to introducing the reader who is not familiar with the technique to the principles of the recoilless nuclear resonance effect, the hyperfme interactions between nuclei and electronic properties such as electric and magnetic fields, some essential aspects about measurements, and the evaluation of Moss bauer spectra. Chapter 6 deals with the interpretation of Mossbauer parameters of iron compounds. Here we have placed emphasis on the information about the electronic structure, in correlation with quantum chemical methods, because of its importance for chemical bonding and magnetic properties.

Author : Philipp Gütlich,Eckhard Bill,Alfred X. Trautwein
Publisher : Springer
Page : 569 pages
File Size : 43,6 Mb
Release : 2011-01-17
Category : Science
ISBN : 3540884270

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Mössbauer Spectroscopy and Transition Metal Chemistry by Philipp Gütlich,Eckhard Bill,Alfred X. Trautwein Pdf

concentrates on teaching techniques using as much theory as needed. application of the techniques to many problems of materials characterization. Mössbauer spectroscopy is a profound analytical method which has nevertheless continued to develop. The authors now present a state-of-the art book which consists of two parts. The first part details the fundamentals of Mössbauer spectroscopy and is based on a book published in 1978 in the Springer series 'Inorganic Chemistry Concepts' by P. Gütlich, R. Link and A.X. Trautwein. The second part covers useful practical aspects of measurements, and the application of the techniques to many problems of materials characterization. The update includes the use of synchroton radiation and many instructive and illustrative examples in fields such as solid state chemistry, biology and physics, materials and the geosciences, as well as industrial applications. Special chapters on magnetic relaxation phenomena (S. Morup) and computation of hyperfine interaction parameters (F. Neese) are also included. The book concentrates on teaching the technique using theory as much as needed and as little as possible. The reader will learn the fundamentals of the technique and how to apply it to many problems of materials characterization. Transition metal chemistry, studied on the basis of the most widely used Mössbauer isotopes, will be in the foreground.

Author : G.J Long,F. Grandjean
Publisher : Springer Science & Business Media
Page : 652 pages
File Size : 55,9 Mb
Release : 2013-11-11
Category : Science
ISBN : 9781489922892

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Mössbauer Spectroscopy Applied to Inorganic Chemistry by G.J Long,F. Grandjean Pdf

In 1988 the Mossbauer effect community completed 30 years of continual contribution to the fields of nuclear physics, solid state science, and a variety of related disciplines. To celebrate this anniversary, Professor Gonser of the Universitat des Saarlandes has contributed a chapter to this volume on the history of the effect. Although Mossbauer spectroscopy has reached its mature years, the chapters in this volume illustrate that it is still a dynamic field of science with applications to topics ranging from permanent magnets to biologi cal mineralization. During the discussion of a possible chapter for this volume, a potential author asked, "Do we really need another Mossbauer book?" The editors responded in the affirmative because they believe that a volume of this type offers several advantages. First, it provides the author with an opportunity to write a personal view of the subject, either with or without extensive pedagogic content. Second, there is no artificially imposed restriction on length. In response to the question, "How long should my chapter be?," we have responded that it should be as long as is necessary to clearly present, explain, and evaluate the topic. In this type of book, it is not necessary to condense the topic into two, four, or eight pages as is now so often a requirement for publication in the research literature.

Author : G.J Long,F. Grandjean
Publisher : Springer Science & Business Media
Page : 370 pages
File Size : 49,6 Mb
Release : 2013-06-29
Category : Science
ISBN : 9781489917638

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Mössbauer Spectroscopy Applied to Magnetism and Materials Science by G.J Long,F. Grandjean Pdf

This book represents Volume 2 in a series on the use of Mossbauer spectroscopy in the study of magnetism and materials. However, the perceptive reader will notice some differences from Volume 1. Specifically, in order to market the book at a more affordable price for most universities and research laboratories, the book has been prepared in camera ready format The editors and the authors agreed to do this because there is a demand for such a book in the Mossbauer community. This format has placed an extra burden on the editors and the authors and we hope we have overcome all the difficulties generated by the transfer of files between different computers. In order to make the book more attractive to materials scientists who are not experts in Mossbauer spectroscopy, this volume is particularly oriented towards the study of materials by Mossbauer spectroscopy and related complementary techniques, such as neutron scattering and a variety of surface scattering techniques. The authors of this volume can be proud of the high quality professional effort they have devoted to clearly presenting their specific topics. As a result we very much enjoyed working with the authors on this volume. We hope that their effort will help to educate the next generation of Mossbauer effect spectroscopists, a generation which will face the challenge of maintaining equally high scientific and professional standards in their research work.

Author : Virender K. Sharma,Gostar Klingelhofer,Tetsuaki Nishida
Publisher : John Wiley & Sons
Page : 1018 pages
File Size : 55,7 Mb
Release : 2013-08-13
Category : Science
ISBN : 9781118771976

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Mössbauer Spectroscopy by Virender K. Sharma,Gostar Klingelhofer,Tetsuaki Nishida Pdf

Providing a modern update of the field, Mossbauer Spectroscopy focuses on applications across a broad range of fields, including analysis of inorganic elements, nanoparticles, metalloenzymyes, biomolecules (including proteins), glass, coal, and iron. Ideal for a broad range of scientists, this one-stop reference presents advances gained in the field over past two decades, including a detailed theoretical description of Mossbauer spectroscopy, an extensive treatment of Mossbauer spectroscopy in applied areas, and challenges and future opportunities for the further development of this technique.

Author : John Gehret Stevens
Publisher : Unknown
Page : 664 pages
File Size : 52,8 Mb
Release : 1981
Category : Science
ISBN : UOM:39015016086715

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Mössbauer Spectroscopy and Its Chemical Applications by John Gehret Stevens Pdf

Author : S. Cohen
Publisher : Springer Science & Business Media
Page : 258 pages
File Size : 50,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781461586876

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Perspectives in Mössbauer Spectroscopy by S. Cohen Pdf

This book is for the most part made up of the invited papers presented at the International Conference on Applica tions of the Kdssbauer effect, held at Aye1eth Hashahar, Israel, in August 1972. The purpose of the conference was to review perspec tives in MHssbauer spectroscopy from the point of view of applications in various fields of science - mainly physics, chemistry, and biology. It was hoped that the bringing together of scientists who work in different disciplines but use a common tool would encourage interdisciplinary re search and widen the horizon of the individual researcher. Both these features have been an important and unique characteristic of Kdssbauer research in the past decade. Accordingly, the main papers were presented in the following areas: magnetic properties of solids, applications to in organic chemistry, biochemical studies, amorphous systems, metal alloys, advances in high-resolution studies, and the new techniques for studying recoil-free spectra from isolated atoms in inert materials. A special panel discussion was devoted to the subject of phase transitions. Recent years have witnessed a rapid growth in the use of X-ray photoelec tron spectroscopy for the study of the physics and chemistry of solids. A report on this area of research and its rela tion to Kdssbauer studies has been included.

Author : C.N.R. Rao
Publisher : Elsevier
Page : 425 pages
File Size : 47,9 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323150903

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Spectroscopy in Inorganic Chemistry V1 by C.N.R. Rao Pdf

Spectroscopy in Inorganic Chemistry, Volume I describes the innovations in various spectroscopic methods that are particularly effective in inorganic chemistry studies. This volume contains nine chapters; each chapter discusses a specific spectroscopic method, their fundamental principles, methods, instrumentation, advantages disadvantages, and application. Chapter 1 covers some of the general principles and experiments that have been used in the recording and interpretation of crystal spectra of molecules that contain transition-metal ions. Chapter 2 illustrates the application of spectroscopic techniques to the photochemistry of small inorganic molecules, non-transition-metal compounds, and transition-metal complexes. The remaining chapters examine several spectroscopic methods, such as matrix isolation, mass, soft X-ray, and Mössbauer spectroscopies, high-resolution NMR, and nuclear quadrupole resonance, with a particular emphasis on their effective application in inorganic chemistry studies. This book will be of great benefit to inorganic chemists, spectroscopists, and inorganic chemistry teachers and students.

Author : Rolfe Herber
Publisher : Springer
Page : 400 pages
File Size : 40,8 Mb
Release : 1984
Category : Gardening
ISBN : UCAL:B4456377

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Chemical Mössbauer Spectroscopy by Rolfe Herber Pdf

The past twenty five years - roughly the period from 1960 to 1985 - have been by all measures among the most exciting and challenging times of our science. The increasing sensitivity of chemical instrumentation, the introduction of the routine use of computers for data reduction and of microprocessors for instrumental control, the wide-spread utilization of lasers, and the disappearance of traditional disciplinary boundaries between scientific fields are but a few of the examples one could cite to support the introductory contention. Almost all of these developments have had their impact on the development of Mossbauer Effect Spectroscopy into a technique par excellence for the elucidation of problems in all areas of chemistry and its associated sister sciences. Indeed, because this spectroscopy is based on fundamental phenomena in nuclear physics, is described in terms of the theory of the solid state and structural chemistry, is useful in the understanding of chemical reactivity and biological phenomena, and can serve to supplement information developed by many other experimental techniques, it has provided an unparalleled opportunity for the exchange of ideas among practitioners of a very wide variety of subfields of the physical and biological sciences. The present collection of contributions is the direct result of such an interaction.

Author : Yann Garcia,Junhu Wang,Tao Zhang
Publisher : John Wiley & Sons
Page : 342 pages
File Size : 40,5 Mb
Release : 2023-10-30
Category : Science
ISBN : 9783527346912

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Mossbauer Spectroscopy by Yann Garcia,Junhu Wang,Tao Zhang Pdf

Mössbauer Spectroscopy Unique and comprehensive overview of versatile applications of Mössbauer spectroscopy in chemistry and material sciences Mössbauer Spectroscopy provides a comprehensive overview of relevant applications of this physical analysis method in chemistry and material sciences. The book shows the versatility of Mössbauer spectroscopy in finding useful information on electronic structure, structural insights, and solid-state effects of chemical systems. A wide range of chemical applications and applied concepts are covered as well as numerous examples, selected from recent literature. To aid in reader comprehension and accessibility, contents are well-structured and divided in different sections covering energy, catalysis, coordination chemistry, spin crossover, sensing, photomagnetism. Edited by prominent scientists in the field and authored by a group of international experts, Mössbauer Spectroscopy covers sample topics such as: Li-ion batteries, catalysts, fuel cells, Fe based silicides and iron phosphates containing minerals Gold clusters and gold mixed valence complexes Molecule based magnets, photoswitchable spin crossover coordination polymers and molecular sensors for meat freshness control With comprehensive coverage of the developments in the technique, Mössbauer Spectroscopy is a beneficial resource for researchers, professionals, and academics in chemistry related fields, such as material science, sustainable environment, and molecular electronics. It can be used by newcomers as well as for educational purposes at the master and PhD levels.

Author : G.J Long
Publisher : Springer Science & Business Media
Page : 677 pages
File Size : 53,5 Mb
Release : 2013-11-11
Category : Science
ISBN : 9781489904621

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Mössbauer Spectroscopy Applied to Inorganic Chemistry by G.J Long Pdf

When presented with a new compound or material, the inorganic chemist will usually have several questions in mind about its composition and structure. Although a simple elemental analysis may answer many questions about its composition, the chemist will still have questions about its structure, and, ifthe material contains a metal atom, he will often want to know its oxidation state, coordination number and geometry. Further, at an increasingly frequent rate, the chemist may need details of the spin state, magnetic and perhaps dynamic properties of the material. If the investigator is fortunate, the material or compound may contain an ele ment such as iron, tin, antimony, iodine, gold, or one of several of the rare earth metals which are amenable to study by the Mossbauer effect. Often the Mossbauer effect can, sometimes with quite simple experiments, provide the answers to all of these questions. The goal of this book is to illustrate the effectiveness of the Mossbauer effect in providing the answers to the many questions that arise in char acterizing new materials and, indeed, in studying known materials in more detail. Several chapters introduce the effect to the novice and provide details about the various hyperfine interactions that are the "bread and butter" of the Mossbauer spectroscopist. Three chapters deal specifically with the experimental aspects of the technique and the increasing impor tance of sophisticated computer analysis of the resulting data.

Author : Yutaka Yoshida,Guido Langouche
Publisher : Springer Nature
Page : 533 pages
File Size : 44,6 Mb
Release : 2021-01-19
Category : Science
ISBN : 9789811594229

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Modern Mössbauer Spectroscopy by Yutaka Yoshida,Guido Langouche Pdf

This book presents an overview of the latest Mössbauer spectroscopy research. It sheds light on various cutting-edge research subjects: (i) nuclear resonance scattering experiments implemented at synchrotron radiation facilities, e.g., ESRF, DESY and Spring-8; (ii) multidisciplinary materials research related to chemistry, biology, geoscience, molecular magnetism of metal complexes, batteries, and magnetism; (iii) novel imaging techniques based on probing diffusion in solids using Mössbauer spectroscopy. The first three chapters introduce recent research on modern Mössbauer spectroscopy, including nuclear resonant scattering experiments and development of related techniques at synchrotron accelerator facilities. Chapters 4 and 5 then demonstrate the applications of such pioneering techniques to chemistry, biology and geoscience. Chapters 6 and 7 describe the applications to new functional materials, i.e., metal complexes and Li- and Na-ion batteries, while the final two chapters are devoted to two important measuring techniques: Mössbauer spectroscopy under external magnetic fields, and microscopic Mössbauer techniques on diffusion in solids, which are expected to play an essential role in the investigation and characterization of magnetic structures and microstructures in materials. The cutting-edge content provides readers with quick updates on the latest research topics in the field, while the tutorial-style descriptions allow readers unfamiliar with Mössbauer spectroscopy to learn and implement the techniques. As such, the book is especially useful for advanced undergraduate and early graduate students who have recently been assigned to a laboratory.

Author : Miroslav Mashlan,Marcel Miglierini,Peter Schaaf
Publisher : Springer Science & Business Media
Page : 369 pages
File Size : 44,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401001519

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Material Research in Atomic Scale by Mössbauer Spectroscopy by Miroslav Mashlan,Marcel Miglierini,Peter Schaaf Pdf

Mössbauer spectroscopy is uniquely able to probe hyperfine interactions by looking at the short-range order of resonant atoms. Materials containing an appropriate isotope as one of their constituent atoms, such as iron or tin, are readily investigated. But even materials that do not contain Mössbauer-active atoms can be investigated if the probe atoms are incorporated in minor quantities (ca. 0.1 at.-%) to act as molecular-level indicators. These 35 papers collected here represent a state-of-the-art description of Mössbauer spectroscopy techniques applied to advanced materials. The topics covered comprise investigations of nanomaterials, nanoparticles, and quasicrystals, artificially structured materials as well as applications of Mössbauer spectroscopy in chemistry, mineralogy and metallurgy. The main aim of is the dissemination of information on research and recent developments of the method in materials science as obtained in leading Mössbauer laboratories.

Author : Richard Vernon Parish
Publisher : Ellis Horwood
Page : 232 pages
File Size : 40,9 Mb
Release : 1990
Category : Science
ISBN : UOM:39015019867491

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NMR, NQR, EPR, and Mössbauer Spectroscopy in Inorganic Chemistry by Richard Vernon Parish Pdf

Author : Leopold May
Publisher : Springer Science & Business Media
Page : 213 pages
File Size : 53,8 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781468489118

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An Introduction to Mössbauer Spectroscopy by Leopold May Pdf

The initial impetus for this text occurred when we were searching for a single book that could be recommended to the attendees at the Mossbauer Spectroscopy Institute at The Catholic University of America. This Institute is an introductory course on the theory and interpretation of Mossbauer spectroscopy for workers in industrial, academic, and government labora tories. None of the books available adequately covered the breadth and scope of the lectures in the Institute. A list of these books and review articles is included in Appendix C. To meet our needs, we undertook the creation of this text. The chapters are based upon the lectures given at the various Institutes from 1967 to 1969. Most of the lectures were recorded and transcripts sent to the lecturers, who then prepared the manuscripts, using the transcripts as a guide so as to retain the style developed during the lecture. Each chapter is written in the style of the authors. As the editor, my main task was to main tain uniformity of format and nomenclature. A list of nomenclature used in this volume is reproduced in Appendix A. We hope that this list will be used particularly by new investigators and teachers of Mossbauer spectroscopy so that future literature will employ a uniform system.