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Providing a thorough overview of leading research from internationally-recognized contributing authors, this book describes methods for the preparation and application of redox systems for organic electronic materials like transistors, photovoltaics, and batteries. • Covers bond formation and cleavage, supramolecular systems, molecular design, and synthesis and properties • Addresses preparative methods, unique structural features, physical properties, and material applications of redox active p-conjugated systems • Offers a useful guide for both academic and industrial chemists involved with organic electronic materials • Focuses on the transition-metal-free redox systems composed of organic and organo main group compounds
Providing a thorough overview of leading research from internationally-recognized contributing authors, this book describes methods for the preparation and application of redox systems for organic electronic materials like transistors, photovoltaics, and batteries. • Covers bond formation and cleavage, supramolecular systems, molecular design, and synthesis and properties • Addresses preparative methods, unique structural features, physical properties, and material applications of redox active p-conjugated systems • Offers a useful guide for both academic and industrial chemists involved with organic electronic materials • Focuses on the transition-metal-free redox systems composed of organic and organo main group compounds
Redox Systems Under Nano-Space Control by Toshikazu Hirao Pdf
The generation of novel redox systems under nano-space control is one of the most exciting fields in present organic, inorganic, and supramolecular chemistry. The authors have drawn together the newest information on the construction of such novel redox systems using nano-space control of complexation or molecular chain-induced spaces and metal- or self-assembled spaces through combining techniques in coordination, supramolecular, and bio-inspired chemistry. Such design on the nano level produces hybrid conjugated systems composed of transition and synthetic metals, metallohosts, redox-active self-assembled monolayers of helical peptides, DNA-directed metal arrays, photoactive antibody systems, chiral rotaxanes, and redox-active imprinted polymers. In the future, these systems will be the basis for novel selective electron-transfer reactions as well as new functional materials and catalysts.
Functionalized Redox Systems by Toshikazu Hirao Pdf
In this book the authors describe how they reproduced the redox functions of biocatalysts artificially. It includes the introduction and discussion of synthetic reactions via electron transfer, hybrid π-conjugated systems, and biorganometallic conjugates as novel redox systems. The work was conducted in pioneering fields based on redox systems, in synthetic organic chemistry, synthetic materials chemistry, and bioorganometallic chemistry. The step-by-step process is illustrated by the three major parts of the book: redox reactions (selective synthetic methods using metal-induced redox reactions), redox systems (design and redox function of conjugated complexes with polyanilines or quinonediimines and molecular bowl sumanene), and design of bioorganometallic conjugates to induce chirality-organized structures (bio-related structurally controlled systems). This systematic and up-to-date description will be of special interest to graduate students who are meeting the new challenges of chemistry, as well as to post-doctoral researchers and other practicing chemists in both academic and industrial settings.
Color Atlas of Biochemistry by Jan Koolman,K H Rhm Pdf
Totally revised and expanded, Color Atlas of Biochemistry presents the fundamentals of human and mammalian biochemistry on 215 stunning color plates. Alongside a short introduction to chemistry and the classical topics of biochemistry, the second edition covers new approaches and aspects in biochemistry, such as links between chemical structure and biological function or pathways for information transfer, as well as recent developments and discoveries, such as the structures of many new important molecules. Key features include: The unique combination of highly effective color graphics and comprehensive figure legends Unified color-coding of atoms, coenzymes, chemical classes, and cell organelles that allows quick recognition of all involved systems Computer graphics provide simulated 3D representation of many important molecules This Flexibook is ideal for students of medicine and biochemistry and a valuable source of reference for practitioners.
Sustainable and Functional Redox Chemistry by Shinsuke Inagi Pdf
Mimicking nature's efficiency and sustainability in organic chemistry is a major goal for future chemists; redox reactions are a key element in a variety of fields ranging from synthesis and catalysis to materials chemistry and analytical applications. Sustainability is increasingly becoming a consideration in synthesis and functional chemistry and an essential element for the next generation of chemistry in academia and industry. This book represents a compilation of the latest advancements in functional redox chemistry and demonstrates its importance in achieving a more sustainable future. This book is an ideal companion for any postgraduate students or researchers interested in sustainability in academia and industry.
Fuel Cells Using Organic Redox Compounds by Jun Mizuguchi Pdf
In living systems, hydrogen supplied from the TCA cycle is transferred to molecular oxygen and oxidized by the electron carrier system, thereby generating energy. It appears that the reversible redox system such as the electron carrier system has not yet been studied in vitro. It was considered that the system of cystine-cysteine containing ferric ion or that of quinone-hydroquinone containing an enzyme might act like the electron carrier system. The authors attempted to use the electron carrier system at the cathode of a fuel cell to obtain a greater amount of electric current. As a result, it has been demonstrated that a fuel cell, based on the model of carrier systems, shows the properties of larger current density and capacity than the ordinary fuel cell and following the model of the carrier system, oxidation and reduction can be repeated alternately without consumption of reactants.
Oxidases and Related Redox Systems by Tsso E. King,Howard S. Mason,Martin Morrison Pdf
Oxidases and Related Redox Systems is a collection of papers from the Third International Symposium on Oxidases and Related Reduction Systems held in Albany, New York on July 3-7, 1979. This book deals with the oxygen and peroxide activating enzymes field. The book addresses electron transfer related to oxygen biochemistry by comparing quantum, semiclassical, and classical methods of electron transfer reactions. Several papers then discuss the active and toxic states of oxygen and superoxide as the discovery of superoxide dismutase activity of erythrocuprein can provide a means to studying oxygen reaction in biological systems. One paper then compares the active sites of molluskan and arthropodan hemocyanins, which are known as reversible oxygen-carriers. The result of this study is presented in a table. Other papers discuss the flavin catalyzed reactions of molecular oxygen and the implications of the physiological function of D-amino acid oxidase from inhibition studies. The book then explains the role of carbon monoxide in the reaction mechanism of oxygen with cytochrome oxidase. This collection will prove beneficial for research students and professors in the field of biochemistry and chemical physics.
Handbook of Electrochemistry by Cynthia G. Zoski Pdf
Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)
Soil Components: Organic components by John Eldon Gieseking Pdf
Volume 1: Organic components; Chemical composition and Physical properties of humic substances; Saccharides; Nitrogenous substances; Other organic phosphorus compounds; Sulfur in soil organic substances; Fats, waxes, and resins in soil; Micromorphology of soil organic matter; Humus of virgin and cultivated soils. Volume 2: Inorganic components - The classification of soil silicates and oxides; Micas in macroscopoic forms; Fine-grained micas in soils; Smectites; the crystallography of minerals of the kaolin group; Vermiculites; Chlorites; Interstratified clay minerals; Fibrous minerals; Allophane; Oxides and hydrous oxides of silicon; Feldspar minerals; Heavy minerals; Bioliths; Water in soil; The thermal characteristics of soil minerals and the use of these characteristics in the qualitative and quantitative determination of clay minerals in soils; The charatcterization of soil minerals by infrared spectroscopy.
