Organometallics And Related Molecules For Energy Conversion

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Organometallics and Related Molecules for Energy Conversion

Wai-Yeung Wong
Organometallics and Related Molecules for Energy Conversion Book PDF

Author : Wai-Yeung Wong
Publisher : Unknown
Page : 128 pages
File Size : 44,6 Mb
Release : 2015
Category : Electronic
ISBN : 3662460556

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Organometallics and Related Molecules for Energy Conversion by Wai-Yeung Wong Pdf

This book presents a critical perspective of the applications of organometallic compounds (including those with metal or metalloid elements) and other related metal complexes as versatile functional materials in the transformation of light into electricity (solar energy conversion) and electricity into light (light generation in light emitting diode), in the reduction of carbon dioxide to useful chemicals, as well as in the safe and efficient production and utilization of hydrogen, which serves as an energy storage medium (i.e. energy carrier). This book focuses on recent research developments in these emerging areas, with an emphasis on fundamental concepts and current applications of functional organometallic complexes and related metal-based molecules for energy research. With contributions from front-line researchers in the field from academia and industry, this timely book provides a valuable contribution to the scientific community in the field of energy science related to metal-based molecular materials. Wai-Yeung Wong, PhD, is Chair Professor and Head of the Department of Chemistry at Hong Kong Baptist University, Hong Kong, P. R. China.

Organometallics and Related Molecules for Energy Conversion

Wai-Yeung Wong
Organometallics and Related Molecules for Energy Conversion Book PDF

Author : Wai-Yeung Wong
Publisher : Springer
Page : 541 pages
File Size : 49,9 Mb
Release : 2015-03-30
Category : Technology & Engineering
ISBN : 9783662460542

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Organometallics and Related Molecules for Energy Conversion by Wai-Yeung Wong Pdf

This book presents a critical perspective of the applications of organometallic compounds (including those with metal or metalloid elements) and other related metal complexes as versatile functional materials in the transformation of light into electricity (solar energy conversion) and electricity into light (light generation in light emitting diode), in the reduction of carbon dioxide to useful chemicals, as well as in the safe and efficient production and utilization of hydrogen, which serves as an energy storage medium (i.e. energy carrier). This book focuses on recent research developments in these emerging areas, with an emphasis on fundamental concepts and current applications of functional organometallic complexes and related metal-based molecules for energy research. With contributions from front-line researchers in the field from academia and industry, this timely book provides a valuable contribution to the scientific community in the field of energy science related to metal-based molecular materials. Wai-Yeung Wong, PhD, is Chair Professor and Head of the Department of Chemistry at Hong Kong Baptist University, Hong Kong, P. R. China.

The Organometallic Chemistry of the Transition Metals

Robert H. Crabtree
The Organometallic Chemistry of the Transition Metals Book PDF

Author : Robert H. Crabtree
Publisher : John Wiley & Sons
Page : 466 pages
File Size : 42,8 Mb
Release : 2019-07-18
Category : Science
ISBN : 9781119465881

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The Organometallic Chemistry of the Transition Metals by Robert H. Crabtree Pdf

Provides vital information on organometallic compounds, their preparation, and use in synthesis, and explores the fundamentals of the field and its modern applications Fully updated and expanded to reflect recent advances, the new, seventh edition of this bestselling text presents students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry. This edition features up-to-date examples of fundamental reaction steps and greater emphasis on key topics like oxidation catalysis, CH functionalization, nanoclusters and nanoparticles, and green chemistry. New coverage is added for computational chemistry, energy production, and biochemical aspects of organometallic chemistry. The Organometallic Chemistry of the Transition Metals, Seventh Edition provides new/enhanced chapter coverage of ligand-assisted additions and eliminations; proton-coupled electron transfer; surface, supported, and cooperative catalysis; green, energy, and materials applications; and photoredox catalysis. It covers coordination chemistry; alkyls and hydrides; Pi-complexes; and oxidative addition and reductive elimination. The book also features sections on insertion and elimination; spectroscopy; metathesis polymerization and bond activation; and more. Provides an excellent foundation of the fundamentals of organometallic chemistry Includes end-of-chapter problems and their solutions Expands and includes up-to-date examples of fundamental reaction steps and focuses on important topics such as oxidation catalysis, CH functionalization, nanoparticles, and green chemistry Features all new coverage for computational chemistry, energy production, and biochemical aspects of organometallic chemistry The Organometallic Chemistry of the Transition Metals, Seventh Edition is an insightful book that will appeal to all advanced undergraduate and graduate students in organic chemistry, organometallic chemistry, inorganic chemistry, and bioinorganic chemistry, as well as any practicing chemist in those fields.

Computational Materials Discovery

Artem Oganov,Gabriele Saleh,Alexander Kvashnin
Computational Materials Discovery Book PDF

Author : Artem Oganov,Gabriele Saleh,Alexander Kvashnin
Publisher : Royal Society of Chemistry
Page : 456 pages
File Size : 41,8 Mb
Release : 2018-10-30
Category : Science
ISBN : 9781782629610

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Computational Materials Discovery by Artem Oganov,Gabriele Saleh,Alexander Kvashnin Pdf

New technologies are made possible by new materials, and until recently new materials could only be discovered experimentally. Recent advances in solving the crystal structure prediction problem means that the computational design of materials is now a reality. Computational Materials Discovery provides a comprehensive review of this field covering different computational methodologies as well as specific applications of materials design. The book starts by illustrating how and why first-principle calculations have gained importance in the process of materials discovery. The book is then split into three sections, the first exploring different approaches and ideas including crystal structure prediction from evolutionary approaches, data mining methods and applications of machine learning. Section two then looks at examples of designing specific functional materials with special technological relevance for example photovoltaic materials, superconducting materials, topological insulators and thermoelectric materials. The final section considers recent developments in creating low-dimensional materials. With contributions from pioneers and leaders in the field, this unique and timely book provides a convenient entry point for graduate students, researchers and industrial scientists on both the methodologies and applications of the computational design of materials.

Activation of Small Molecules

William B. Tolman
Activation of Small Molecules Book PDF

Author : William B. Tolman
Publisher : John Wiley & Sons
Page : 382 pages
File Size : 45,8 Mb
Release : 2006-12-13
Category : Science
ISBN : 9783527609376

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Activation of Small Molecules by William B. Tolman Pdf

The first to combine both the bioinorganic and the organometallic view, this handbook provides all the necessary knowledge in one convenient volume. Alongside a look at CO2 and N2 reduction, the authors discuss O2, NO and N2O binding and reduction, activation of H2 and the oxidation catalysis of O2. Edited by the highly renowned William Tolman, who has won several awards for his research in the field.

Advances in Organometallic Chemistry

Anonim
Advances in Organometallic Chemistry Book PDF

Author : Anonim
Publisher : Academic Press
Page : 407 pages
File Size : 52,7 Mb
Release : 1992-01-13
Category : Science
ISBN : 0080580343

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Advances in Organometallic Chemistry by Anonim Pdf

Advances in Organometallic Chemistry

Organometallic Compounds

Dakeshwar Kumar Verma,Jeenat Aslam
Organometallic Compounds Book PDF

Author : Dakeshwar Kumar Verma,Jeenat Aslam
Publisher : John Wiley & Sons
Page : 453 pages
File Size : 52,6 Mb
Release : 2023-03-08
Category : Science
ISBN : 9783527351787

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Organometallic Compounds by Dakeshwar Kumar Verma,Jeenat Aslam Pdf

Organometallic Compounds An up-to-date overview of the fundamentals, synthesis, and applications of organometallic compounds Organometallic Compounds: Synthesis, Reactions, and Applications delivers an accessible and robust introduction to the fundamentals of organometallic compounds, including their reactions, catalytic mechanisms, and modern applications, including carbon-dioxide fixation, reduction, gas adsorption and purification, drug delivery, renewable energy, and wastewater treatment. The book also covers toxicological and computational studies. The authors address the current challenges confronting researchers seeking to sustainably synthesize and process organometallic compounds and offer complete coverage on the most recent advancements in applications relating to the fields of environmental science, electronics, fossil fuels, and more. Readers will also find: Introduces to fundamentals, nomenclature, properties, and classification of organometallic compounds Discusses methods of synthesis of organometallic compounds Practical discussions of organometallic complexes of the lanthanoids and actinoids, as well as bio-organometallic chemistry Includes characterization techniques of organometallic compounds Perfect for organic, environmental, inorganic, water, and catalytic chemists, Organometallic Compounds: Synthesis, Reactions, and Applications will also benefit chemical engineers and industrial chemists.

Transformation of Carbon Dioxide to Formic Acid and Methanol

Wan-Hui Wang,Xiujuan Feng,Ming Bao
Transformation of Carbon Dioxide to Formic Acid and Methanol Book PDF

Author : Wan-Hui Wang,Xiujuan Feng,Ming Bao
Publisher : Springer
Page : 123 pages
File Size : 55,6 Mb
Release : 2017-10-26
Category : Science
ISBN : 9789811032509

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Transformation of Carbon Dioxide to Formic Acid and Methanol by Wan-Hui Wang,Xiujuan Feng,Ming Bao Pdf

This brief explains the principles and fundamentals of carbon dioxide utilization and highlights the transformation to fuels and value-added chemicals such as formic acid and methanol. It is divided into six chapters, including an introduction to the basics of CO2 utilization and transformation of CO2 to formic acid and methanol with homogeneous and heterogeneous catalysts, respectively. The brief will appeal to a wide readership of academic and industrial researchers focusing on homogeneous and heterogeneous catalysis, organometallic chemistry, green chemistry, energy conversion and storage.

Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds

A.J.L. Pombeiro,J.A. McCleverty
Molecular Electrochemistry of Inorganic Bioinorganic and Organometallic Compounds Book PDF

Author : A.J.L. Pombeiro,J.A. McCleverty
Publisher : Springer Science & Business Media
Page : 652 pages
File Size : 41,7 Mb
Release : 2012-02-02
Category : Science
ISBN : 9789401116282

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Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds by A.J.L. Pombeiro,J.A. McCleverty Pdf

The use of electrochemical techniques by chemists, particularly those who regard themselves as "inorganic" coordination chemists, has undergone a very rapid growth in the last 15-20 years. The techniques, as dassically applied to inorganic species, had their origins in analytical chemistry, and the methodology had assumed, until the mid 60s, more importance than the chemiStry. However, the growth of interest in coordination compounds (including organometallic complexes) having unusually rich of electron-transfer in bio-inorganic redox properties, and in the understanding species, has propelfed electro-chemistry into the foreground of potentially readily available techniques for application to a very wide range of problems of interest to those chemists. This growth has been fuelled additionally by the availability of relatively cheap equipment of growing sophistication and by an increase in the "inorganic" chemists' general knowledge of physical electrochemistry. In particular, with increasing availability and sophistication of eqUipment, kinetic problems are now being addressed, and the range of electrode types and configuration and solvents has been greatly expanded. Furthermore, the rapid expansion of interest in biological problems has opened new avenues in functionalisation of electrodes, in the development of sensory devices and, in a sense, a return to the analytical base of the science, using novel and multi-disciplinary techniques drawing on synthesis chemistry of and electronic micro-engeneering. The drive towards increasing use microcomputer-controlled data analysis and the development of microeledrodes has opened exciting new avenues for the exploration of chemical reactions involving electron-transfer processes.

Molecular Organometallic Materials for Optics

Zuqiang Bian
Molecular Organometallic Materials for Optics Book PDF

Author : Zuqiang Bian
Publisher : Springer Science & Business Media
Page : 236 pages
File Size : 55,7 Mb
Release : 2009-11-10
Category : Science
ISBN : 9783642018657

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Molecular Organometallic Materials for Optics by Zuqiang Bian Pdf

Aimed at a multidisciplinary scientific readership, this publication covers a number of specific topics in what is now a rapidly developing field, including coordination and organometallic complexes as second-order nonlinear optical molecular materials.

Energetics of Organometallic Species

José A. Martinho Simões
Energetics of Organometallic Species Book PDF

Author : José A. Martinho Simões
Publisher : Springer Science & Business Media
Page : 445 pages
File Size : 45,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401124669

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Energetics of Organometallic Species by José A. Martinho Simões Pdf

An overview of modern organometallic thermochemistry, made by some of the most active scientists in the area, is offered in this book. The contents correspond to the seventeen lectures delivered at the NATO ASI Energetics of Organometallic Species (Curia, Portugal, September 1991), plus three other invited contributions from participants of that summer school. These papers reflect a variety of research interests, and discuss results obtained with several techniques. It is therefore considered appropriate to add a few preliminary words, attempting to bring some unity out of that diversity. In the first three chapters, results obtained by classical calorimetric methods are described. Modern organometallic thermochemistry started in Manchester, with Henry Skinner, and his pioneering work is briefly surveyed in the first chapter. The historical perspective is followed by a discussion of a very actual issue: the trends of stepwise bond dissociation enthalpies. Geoff Pilcher, another Manchester thermochemist, makes, in chapter 2, a comprehensive and authoritative survey of problems found in the most classical of thermochemical techniques - combustion calorimetr- applied to organometallic compounds. Finally, results from another classical technique, reaction-solution calorimetry, are reviewed in the third chapter, by Tobin Marks and coworkers. More than anybody else, Tobin Marks has used thermochemical values to define synthetic strategies for organometallic compounds, thus indicating an application of thermochemical data of which too little use has been made so far.

Mechanisms of Inorganic and Organometallic Reactions Volume 7

M.V. Twigg
Mechanisms of Inorganic and Organometallic Reactions Volume 7 Book PDF

Author : M.V. Twigg
Publisher : Springer Science & Business Media
Page : 468 pages
File Size : 42,9 Mb
Release : 2013-11-11
Category : Science
ISBN : 9781461537106

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Mechanisms of Inorganic and Organometallic Reactions Volume 7 by M.V. Twigg Pdf

The objective of Mechanisms of Inorganic and Organometallic Reactions is to provide an ongoing critical review of the literature concerned with the mechanisms of reactions of inorganic and organometallic compounds. The main focus is on reactions in solution, although solid state and gas phase studies are included where they provide relevant mechanistic insight. Each volume covers an eighteen month literature period, and this, the seventh volume in the series, deals with papers published during July 1988 through December 1989. Where appropriate, there are references to earlier work, and also to specific sections in previous volumes. Coverage continues to span the whole area as comprehensively as possible in each volume, and although it is impossible be absolutely complete, every effort is made to include all the important for it to published work that is relevant to the elucidation of reaction mechanisms. Numerical data are reported in the units used by the original authors, and they are only converted to common units when making comparisons. The basic format of earlier volumes is retained to facilitate tracing progress over several years in a particular topic; this can now be done for more than a decade worth of research. In the last volume, ligand reactivity of both coordination and organometallic compounds were brought together in Chapter 12, and, in response to numerous positive comments from readers, this arrangement has been maintained. There have been some similar suggestions about oscillating reactions, and this topic may have a separate section in the next volume.

Organometallics for Green Catalysis

Pierre H. Dixneuf,Jean-François Soulé
Organometallics for Green Catalysis Book PDF

Author : Pierre H. Dixneuf,Jean-François Soulé
Publisher : Springer
Page : 301 pages
File Size : 47,9 Mb
Release : 2019-02-25
Category : Science
ISBN : 9783030109554

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Organometallics for Green Catalysis by Pierre H. Dixneuf,Jean-François Soulé Pdf

This volume presents the latest developments in the use of organometallic catalysis for the formation of bulk chemicals and the production of energy, via green processes including efficient utilization of waste feedstocks from industry. The chemistry of carbon dioxide relating to its hydrogenation into methanol –an eco-friendly energy storage strategy– and its uses as C1 synthon for the formation of important building-blocks for fine chemicals industry are covered. Catalytic hydrogenations of various functional groups and hydrogen transfer reactions including the use of first row metal catalysts are presented as well as the conversion of alcohols to carboxylates via hydrogen transfer with a zero-waste strategy using water. Transformation of renewable or bio-based raw materials is surveyed through alkene metathesis and C–O bond activations and functionalizations. A green aspect for selective formation of C-C, C-O and C-N bonds involves direct regioselective C–H bond activations and functionalizations. These transformations can now be promoted under mild reaction conditions due to the use photoredox catalyts. C–H bond oxidation using visible light leads mainly to the formation of C–O and C–N bonds, whereas cross-coupled C–C bonds can be formed through the radical additions on (hetero) arenes using photoredox assisted mechanism.

Organometallic Mechanisms and Catalysis

Jay Kochi
Organometallic Mechanisms and Catalysis Book PDF

Author : Jay Kochi
Publisher : Elsevier
Page : 642 pages
File Size : 49,7 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323144100

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Organometallic Mechanisms and Catalysis by Jay Kochi Pdf

Organometallic Mechanisms and Catalysis: The Role of Reactive Intermediates in Organic Processes covers the mechanistic delineation of organometallic chemistry and catalysis. This book is organized into three parts encompassing 18 chapters. The first part describes first the oxidation-reduction process of organometals, followed by discussions on the catalytic reactions of peroxides, metal-catalyzed addition to olefins, and reduction of organic halides. This part also explores other reactions involving transition metal carbonyls and metal-catalyzed reactions of aromatic diazonium salts. The second part deals with some chemical aspects of organometals, such as their stability, thermochemistry, decomposition, hemolytic pathways, and the formation of carbon-carbon bonds. The third part examines the charge transfer processes and interactions of organometals with electron acceptors. This part further looks into the cleavage and insertion reactions of organometals with electrophiles, as well as the electrophilic and electron transfer mechanisms of organometals. Organic and inorganic chemists, teachers, and students will greatly benefit from this book.

Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds

K. Kalyanasundaram,M. Grätzel
Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds Book PDF

Author : K. Kalyanasundaram,M. Grätzel
Publisher : Springer Science & Business Media
Page : 475 pages
File Size : 47,8 Mb
Release : 2013-06-29
Category : Science
ISBN : 9789401726269

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Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds by K. Kalyanasundaram,M. Grätzel Pdf

Photosensitization and photocatalysis refer to processes by which permanent chemical transformations are induced on substrates (organic/inorganic) by radiation to which the substrates themselves are transparent. Such transformations can be highly specific, very efficient, and occur under mild conditions. Herein lies the power of photochemical methods for possible applications in the field of conversion and storage of solar energy. This book provides a recent survey of the progress in this important area in catalysis, with an emphasis on inorganic complexes and organometallic compounds as the key light aborbers. The book is organized in three parts: fundamentals, followed by applications. Discussions cover a wide variety of photosensitized or photocatalyzed reactions: decomposition of water, reduction of CO2 and CO; spectral sensitization in photoelectrochemical cells; transformations (oxidation, reduction, isomerization, hydrogenation, dehydrogenation, carbonylation, etc.) of organics such as alkanes, alkenes, alcohols, etc. In view of the variety of systems (sensitizers, substrates) and the topics covered, the volume is unique in the field of photochemistry and will appeal to academic and industrial researchers in various subdisciplines of chemistry, material science and catalysis.