Oxide Surfaces

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Defects at Oxide Surfaces

Author : Jacques Jupille,Geoff Thornton
Publisher : Springer
Page : 462 pages
File Size : 49,5 Mb
Release : 2015-02-09
Category : Science
ISBN : 9783319143675

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Defects at Oxide Surfaces by Jacques Jupille,Geoff Thornton Pdf

This book presents the basics and characterization of defects at oxide surfaces. It provides a state-of-the-art review of the field, containing information to the various types of surface defects, describes analytical methods to study defects, their chemical activity and the catalytic reactivity of oxides. Numerical simulations of defective structures complete the picture developed. Defects on planar surfaces form the focus of much of the book, although the investigation of powder samples also form an important part. The experimental study of planar surfaces opens the possibility of applying the large armoury of techniques that have been developed over the last half-century to study surfaces in ultra-high vacuum. This enables the acquisition of atomic level data under well-controlled conditions, providing a stringent test of theoretical methods. The latter can then be more reliably applied to systems such as nanoparticles for which accurate methods of characterization of structure and electronic properties have yet to be developed. The book gives guidance to tailor oxide surfaces by controlling the nature and concentration of defects. The importance of defects in the physics and chemistry of metal oxide surfaces is presented in this book together with the prominent role of oxides in common life. The book contains contributions from leaders in the field. It serves as a reference for experts and beginners in the field.

Oxide Surfaces

Author : Anonim
Publisher : Elsevier
Page : 676 pages
File Size : 40,5 Mb
Release : 2001-05-21
Category : Science
ISBN : 0080538312

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Oxide Surfaces by Anonim Pdf

The book is a multi-author survey (in 15 chapters) of the current state of knowledge and recent developments in our understanding of oxide surfaces. The author list includes most of the acknowledged world experts in this field. The material covered includes fundamental theory and experimental studies of the geometrical, vibrational and electronic structure of such surfaces, but with a special emphasis on the chemical properties and associated reactivity. The main focus is on metal oxides but coverage extends from 'simple' rocksalt materials such as MgO through to complex transition metal oxides with different valencies.

Chemistry on Modified Oxide and Phosphate Surfaces: Fundamentals and Applications

Author : Robson Fernandes de Farias
Publisher : Academic Press
Page : 214 pages
File Size : 44,9 Mb
Release : 2009-01-10
Category : Technology & Engineering
ISBN : 0080919847

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Chemistry on Modified Oxide and Phosphate Surfaces: Fundamentals and Applications by Robson Fernandes de Farias Pdf

Chemistry on Modified Oxide and Phosphate Surfaces: Fundamentals and Applications is in the authoritative Interface Science and Technology Series and presents the key features and applications of modified oxide and phosphate surfaces. Examines both basic and applied aspects Incorporates examples from recent publications

Molecular Spectroscopy of Oxide Catalyst Surfaces

Author : Anatoli Davydov
Publisher : John Wiley & Sons
Page : 706 pages
File Size : 41,7 Mb
Release : 2003-06-27
Category : Science
ISBN : UOM:39015051579996

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Molecular Spectroscopy of Oxide Catalyst Surfaces by Anatoli Davydov Pdf

As in the study of transition metal complexes in solution, molecular spectroscopic methods - principally the infrared, ultraviolet/visible and electron spin resonance spectroscopies - have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. This book describes the development of the principals of coordination chemistry of oxide surfaces using analyses of data obtained by these methods. The nature, properties, concentration of the surface adsorption centers and their influence on the character of interaction with different molecules are investigated. The book commences with an account of the basic theoretical principles and experimental techniques of the various spectroscopy methods, with special attention devoted to in situ measurements where the oxide or catalyst sample is in contact with the adsorbate or the reactant. A detailed account is presented of the methods for characterizing the oxidation state and degree of coordination of surface cations and oxygen anions by the adsorption of probe molecules. The complexation of many inorganic, organometallic and organic molecules with different oxide systems is critically examined, and a classification of formed surface compounds, based on the interaction with definite type of adsorption centers, is given. Possible mechanisms of numerous catalytic reactions, including the transformation of organic molecules over acidic catalysts via the carboionic mechanism, are discussed using the spectroscopic identifications of reaction intermediates. A comprehensive analysis of the literature on the interpretation of the spectra of surface compounds on oxides is presented. This highly illustrated and extensively referenced volume is intended for specialists working in the fields of surface physical chemistry, surface and materials sciences, and adsorption phenomena and is essential reading for those involved in the heterogeneous catalysis by transition metal-oxides.

Physics and Chemistry at Oxide Surfaces

Author : Claudine Noguera
Publisher : Cambridge University Press
Page : 243 pages
File Size : 41,7 Mb
Release : 1996-09-28
Category : Science
ISBN : 9780521472142

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Physics and Chemistry at Oxide Surfaces by Claudine Noguera Pdf

The first chapter of the book summarizes classical approaches, introduces the concept of ionicity, and describes the mixed iono-covalent character of the oxygen cation bond in bulk materials. The next three chapters focus on the characteristics of the atomic structure (relaxation, rumpling and reconstruction effects), the electronic structure (band width, gap width, etc.) and the excitations of clean surfaces.

Oxide Surfaces

Author : James A. Wingrave
Publisher : CRC Press
Page : 628 pages
File Size : 42,5 Mb
Release : 2019-10-16
Category : Science
ISBN : 1420030280

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Oxide Surfaces by James A. Wingrave Pdf

A detailed treatment of information relating to fluid-oxide interfaces. It outlines methods for quantifying adsorption and desorption of polymeric and non-polymeric solutes at the gas- and solution-oxide interfaces. It also analyzes novel properties of oxide membranes and the synthesis and dissolution of oxide solids.

Metal Oxide Nanomaterials for Chemical Sensors

Author : Michael A. Carpenter,Sanjay Mathur,Andrei Kolmakov
Publisher : Springer Science & Business Media
Page : 559 pages
File Size : 44,5 Mb
Release : 2012-11-09
Category : Science
ISBN : 9781461453956

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Metal Oxide Nanomaterials for Chemical Sensors by Michael A. Carpenter,Sanjay Mathur,Andrei Kolmakov Pdf

This book presents a state-of-the-art summary and critical analysis of work recently performed in leading research laboratories around the world on the implementation of metal oxide nanomaterial research methodologies for the discovery and optimization of new sensor materials and sensing systems. The book provides a detailed description and analysis of (i) metal oxide nanomaterial sensing principles, (ii) advances in metal oxide nanomaterial synthesis/deposition methods, including colloidal, emulsification, and vapor processing techniques, (iii) analysis of techniques utilized for the development of low temperature metal oxide nanomaterial sensors, thus enabling a broader impact into sensor applications, (iv) advances, challenges and insights gained from the in situ/ex situ analysis of reaction mechanisms, and (v) technical development and integration challenges in the fabrication of sensing arrays and devices.

Metal Oxide Catalysis, 2 Volume Set

Author : S. David Jackson,Justin S. J. Hargreaves
Publisher : John Wiley & Sons
Page : 887 pages
File Size : 44,5 Mb
Release : 2008-12-23
Category : Science
ISBN : 9783527626120

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Metal Oxide Catalysis, 2 Volume Set by S. David Jackson,Justin S. J. Hargreaves Pdf

With its two-volume structure, this handbook and ready reference allows for comprehensive coverage of both characterization and applications, while uniform editing throughout ensures that the structure remains consistent. The result is an up-to-date review of metal oxides in catalysis. The first volume covers a range of techniques that are used to characterize oxides, with each chapter written by an expert in the field. Volume 2 goes on to cover the use of metal oxides in catalytic reactions. For all chemists and engineers working in the field of heterogeneous catalysis.

Oxide Materials at the Two-Dimensional Limit

Author : Falko P. Netzer,Alessandro Fortunelli
Publisher : Springer
Page : 389 pages
File Size : 42,8 Mb
Release : 2016-04-01
Category : Technology & Engineering
ISBN : 9783319283326

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Oxide Materials at the Two-Dimensional Limit by Falko P. Netzer,Alessandro Fortunelli Pdf

This book summarizes the current knowledge of two-dimensional oxide materials. The fundamental properties of 2-D oxide systems are explored in terms of atomic structure, electronic behavior and surface chemistry. The concept of polarity in determining the stability of 2-D oxide layers is examined, charge transfer effects in ultrathin oxide films are reviewed as well as the role of defects in 2-D oxide films. The novel structure concepts that apply in oxide systems of low dimensionality are addressed, and a chapter giving an overview of state-of-the-art theoretical methods for electronic structure determination of nanostructured oxides is included. Special emphasis is given to a balanced view from the experimental and the theoretical side. Two-dimensional materials, and 2-D oxides in particular, have outstanding behavior due to dimensionality and proximity effects. Several chapters treat prototypical model systems as illustrative examples to discuss the peculiar physical and chemical properties of 2-D oxide systems. The chapters are written by renowned experts in the field.

The Surface Science of Metal Oxides

Author : Victor E. Henrich,P. A. Cox
Publisher : Cambridge University Press
Page : 484 pages
File Size : 49,8 Mb
Release : 1994
Category : Science
ISBN : 0521566878

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The Surface Science of Metal Oxides by Victor E. Henrich,P. A. Cox Pdf

Publisher Description

Defects at Oxide Surfaces

Author : Jacques Jupille,Geoff Thornton
Publisher : Unknown
Page : 128 pages
File Size : 50,6 Mb
Release : 2015
Category : Electronic
ISBN : 3319143689

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Defects at Oxide Surfaces by Jacques Jupille,Geoff Thornton Pdf

This book presents the basics and characterization of defects at oxide surfaces. It provides a state-of-the-art review of the field, containing information to the various types of surface defects, describes analytical methods to study defects, their chemical activity and the catalytic reactivity of oxides. Numerical simulations of defective structures complete the picture developed. Defects on planar surfaces form the focus of much of the book, although the investigation of powder samples also form an important part. The experimental study of planar surfaces opens the possibility of applying the large armoury of techniques that have been developed over the last half-century to study surfaces in ultra-high vacuum. This enables the acquisition of atomic level data under well-controlled conditions, providing a stringent test of theoretical methods. The latter can then be more reliably applied to systems such as nanoparticles for which accurate methods of characterization of structure and electronic properties have yet to be developed. The book gives guidance to tailor oxide surfaces by controlling the nature and concentration of defects. The importance of defects in the physics and chemistry of metal oxide surfaces is presented in this book together with the prominent role of oxides in common life. The book contains contributions from leaders in the field. It serves as a reference for experts and beginners in the field.

Proceedings of the Symposium on Surface Oxide Films

Author : Jennifer A. Bardwell
Publisher : The Electrochemical Society
Page : 338 pages
File Size : 49,8 Mb
Release : 1996
Category : Science
ISBN : 1566771684

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Proceedings of the Symposium on Surface Oxide Films by Jennifer A. Bardwell Pdf

Metal Oxide Nanoparticles, 2 Volume Set

Author : Oliver Diwald,Thomas Berger
Publisher : John Wiley & Sons
Page : 903 pages
File Size : 53,8 Mb
Release : 2021-09-14
Category : Technology & Engineering
ISBN : 9781119436744

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Metal Oxide Nanoparticles, 2 Volume Set by Oliver Diwald,Thomas Berger Pdf

Metal Oxide Nanoparticles A complete nanoparticle resource for chemists and industry professionals Metal oxide nanoparticles are integral to a wide range of natural and technological processes—from mineral transformation to electronics. Additionally, the fields of engineering, electronics, energy technology, and electronics all utilize metal oxide nanoparticle powders. Metal Oxide Nanoparticles: Formation, Functional Properties, and Interfaces presents readers with the most relevant synthesis and formulation approaches for using metal oxide nanoparticles as functional materials. It covers common processing routes and the assessment of physical and chemical particle properties through comprehensive and complementary characterization methods. This book will serve as an introduction to nanoparticle formulation, their interface chemistry and functional properties at the nanoscale. It will also act as an in-depth resource, sharing detailed information on advanced approaches to the physical, chemical, surface, and interface characterization of metal oxide nanoparticle powders and dispersions. Addresses the application of metal oxide nanoparticles and its economic impact Examines particle synthesis, including the principles of selected bottom-up strategies Explores nanoparticle formulation—a selection of processing and application routes Discusses the significance of particle surfaces and interfaces on structure formation, stability and functional materials properties Covers metal oxide nanoparticle characterization at different length scales With this valuable resource, academic researchers, industrial chemists, and PhD students can all gain insight into the synthesis, properties, and applications of metal oxide nanoparticles.

The emerging Sr2FeMoO6-based electrocatalysts for solid oxide electrochemical cell: synthesis, modulation and applications

Author : Yuanfeng Liao,Xiuan Xi,Hao Chen,Jianwen Liu,Xian-Zhu Fu,Jing-Li Luo
Publisher : OAE Publishing Inc.
Page : 30 pages
File Size : 45,7 Mb
Release : 2024-03-05
Category : Science
ISBN : 8210379456XXX

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The emerging Sr2FeMoO6-based electrocatalysts for solid oxide electrochemical cell: synthesis, modulation and applications by Yuanfeng Liao,Xiuan Xi,Hao Chen,Jianwen Liu,Xian-Zhu Fu,Jing-Li Luo Pdf

Solid oxide cells (SOCs) are regarded as a promising energy technology due to their large current density, diverse range of fuels, and high energy conversion efficiency. The double perovskite Sr2FeMoO6 (SFM) has attracted considerable attention for SOCs due to its tunable structure with superior performance of high conductivity, excellent thermal stability, and remarkable carbon deposition resistance in a reducing atmosphere. However, the electrocatalytic activity of SFM is considerably lower than that of commercial Ni-based SOC electrodes. A timely summary of the synthesis, modulation, and application of SFM perovskites is of great significance for its further development for SOCs. In this review, the methods employed in the preparation of SFM electrocatalysts are introduced first. Then, the advancements in the application of different SFM-based electrocatalysts in the field of SOCs are reviewed, and the research progress in the in-situ exsolution of SFM-based electrocatalysts through ion regulation is assessed. Finally, the future issues associated with SFM-based electrocatalysts are addressed in the realm of electrocatalysis, to advance their application.