Phosphorus Ylides

Author : Oleg I. Kolodiazhnyi
Publisher : John Wiley & Sons
Page : 568 pages
File Size : 44,5 Mb
Release : 2008-09-26
Category : Science
ISBN : 9783527613915

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Phosphorus Ylides by Oleg I. Kolodiazhnyi Pdf

When Wittig first developed and described phosphorus ylides, nobody could have imagined how useful and versatile this class of compounds could be. This book provides a comprehensive and up-to-date compilation of the chemistry and applications of phosphorus ylides in organic synthesis. The ylides are discussed as reagents in the synthesis of a broad range of substances, amongst them olefins, acetylenes, cyclic and heterocyclic compounds, in such naturally occurring compounds as pheromones, steroids and carotenoids, and pharmaceutically and biologically active compounds such as antibiotics and prostaglandins. A particularly beneficial feature of this book is the 150 key experimental procedures with all the necessary data, allowing the preparation to start immediately without the need for an extremely time-consuming literature search. But should a search prove inevitable, around 2,500 references provide easy access to the primary literature. Every chemist in academia and industry working in organic, bioorganic, inorganic, and medicinal chemistry will welcome this book as an inspiration of concepts, ideas and practical syntheses.

Author : A. William Johnson
Publisher : Wiley-Interscience
Page : 626 pages
File Size : 55,8 Mb
Release : 1993-08-05
Category : Science
ISBN : MINN:31951D00872792W

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Ylides and Imines of Phosphorus by A. William Johnson Pdf

Provides overview of ylide and imine chemistry of phosphorous. Contains over 3,150 references. Focuses on their application, particularly in organic synthesis. Presents up-to-date understanding of structure, bonding and behavior of each type of ylide. Covers ylide preparations, handling and decomposition. Features theoretical descriptions of the bonding in ylides and the reactions of phosphorous ylides with transition metal compounds.

Author : Viktor Iaroshenko
Publisher : John Wiley & Sons
Page : 586 pages
File Size : 49,9 Mb
Release : 2019-04-22
Category : Science
ISBN : 9783527335725

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Organophosphorus Chemistry by Viktor Iaroshenko Pdf

Filling the gap for an up-to-date reference that presents the field of organophosphorus chemistry in a comprehensive and clearly structured way, this one-stop source covers the chemistry, properties, and applications from life science and medicine. Divided into two parts, the first presents the chemistry of various phosphorus-containing compounds and their synthesis, including ylides, acids, and heterocycles. The second part then goes on to look at applications in life science and bioorganic chemistry. Last but not least, such important practical aspects as 31P-NMR and protecting strategies for these compounds are presented. For organic, bioinorganic, and medicinal chemists, as well as those working on organometallics, and for materials scientists. The book, a contributed work, features a team of renowned scientists from around the world whose expertise spans the many aspects of modern organophosphorus chemistry.

Author : Francis A. Carey,Richard J. Sundberg
Publisher : Springer
Page : 958 pages
File Size : 46,8 Mb
Release : 2006-05-02
Category : Science
ISBN : 9780306473807

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Advanced Organic Chemistry by Francis A. Carey,Richard J. Sundberg Pdf

The control of reactivity to achieve specific syntheses is one of the overarching goals of organic chemistry. In the decade since the publication of the third edition, major advances have been made in the development of efficient new methods, particularly catalytic processes, and in means for control of reaction stereochemistry. This volume assumes a level of familiarity with structural and mechanistic concepts comparable to that in the companion volume, Part A, Structures and Mechanisms. Together, the two volumes are intended to provide the advanced undergraduate or beginning graduate student in chemistry with a sufficient foundation to comprehend and use the research literature in organic chemistry. The New Revised 5th Edition will be available shortly. For details, click on the link in the right-hand column.

Author : Viktor Iaroshenko
Publisher : John Wiley & Sons
Page : 224 pages
File Size : 40,8 Mb
Release : 2019-01-07
Category : Science
ISBN : 9783527672257

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Organophosphorus Chemistry by Viktor Iaroshenko Pdf

Filling the gap for an up-to-date reference that presents the field of organophosphorus chemistry in a comprehensive and clearly structured way, this one-stop source covers the chemistry, properties, and applications from life science and medicine. Divided into two parts, the first presents the chemistry of various phosphorus-containing compounds and their synthesis, including ylides, acids, and heterocycles. The second part then goes on to look at applications in life science and bioorganic chemistry. Last but not least, such important practical aspects as 31P-NMR and protecting strategies for these compounds are presented. For organic, bioinorganic, and medicinal chemists, as well as those working on organometallics, and for materials scientists. The book, a contributed work, features a team of renowned scientists from around the world whose expertise spans the many aspects of modern organophosphorus chemistry.

Author : Anonim
Publisher : Newnes
Page : 9815 pages
File Size : 48,6 Mb
Release : 2014-02-14
Category : Science
ISBN : 9780080977430

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Comprehensive Organic Synthesis by Anonim Pdf

The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition, Nine Volume Set an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively

Author : George Britton,Hanspeter Pfander,Synnove Liaaen-Jensen
Publisher : Springer Science & Business Media
Page : 392 pages
File Size : 42,9 Mb
Release : 1996-05
Category : Medical
ISBN : 3764352973

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Carotenoids, Volume 2: Synthesis by George Britton,Hanspeter Pfander,Synnove Liaaen-Jensen Pdf

"Carotenoids, Volume 2" is the first book to be devoted entirely to the chemical synthesis of carotenoids. The essential in-depth appreciation of the perspectives, principles and strategies of carotenoid synthesis is provided in the first chapter. Preparation of polyene synthons and carotenoid end groups, and the coupling reactions commonly used for carbon-carbon double bond formation, as well as the application of these methods and synthons for the synthesis of carotenoids, are then described in detail. The commercially important technical syntheses used for the large scale industrial production of carotenoids, and methods for the preparation of isotopically labelled carotenoids, in particular for biological and medical applications, are also covered. Following the practice established in Volume 1A, Worked Examples are presented. These describe in detail reliable and efficient procedures for key reactions and can be used to form the basis of practical exercises for students of organic chemistry. Tables of useful synthons and a list of natural carotenoids that have been prepared by total synthesis are included as appendices.

Author : Hanspeter Pfander,George Britton,Synnove Liaaen-Jensen
Publisher : Birkhäuser
Page : 377 pages
File Size : 44,5 Mb
Release : 2013-12-01
Category : Science
ISBN : 9783034893237

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Carotenoids by Hanspeter Pfander,George Britton,Synnove Liaaen-Jensen Pdf

George Britton, Synnl/Jve Liaaen-Jensen and Hanspeter Pfander This book, Volume 2 in the series Carotenoids, is the first book to be published that is devoted entirely to the total synthesis of carotenoids, but it is timely in view of the rapid development and the growing diversification of the carotenoid field. The 1971 Carotenoids book contained a major chapter of 250 pages on total synthesis by H. Mayer and O. Isler. That comprehensive and authoritative review described systematically the construction of many synthons and the synthesis of many natural and unnatural carotenoids and related compounds. Twenty five years on, that chapter remains an essential reference work and source of information, with its extensive collection of tabulated data and lists of references to the original literature. Surveys of progress since 1971 have been presented at the IUPAC International Symposia on Carotenoids and are included in the published proceedings of these symposia. The history of major publications in the carotenoid field, leading to the development of this series, was outlined in the preface to the series published in Vol. IA. The general philo sophy outlined in that preface, with emphasis on practical guidance and the inclusion of worked examples of some of the most useful procedures, is maintained in Vol. 2. In kceping with this philosophy, Vol. 2 is not intended to be an exhaustive review of the literature, but is planned as a practical book, as well as a source of information.

Author : Jean-Pierre Majoral
Publisher : Springer Science & Business Media
Page : 238 pages
File Size : 51,5 Mb
Release : 2003
Category : Biochemistry
ISBN : 3540007148

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New Aspects in Phosphorus Chemistry III by Jean-Pierre Majoral Pdf

Author : Anonim
Publisher : Elsevier
Page : 10504 pages
File Size : 46,9 Mb
Release : 2004-12-16
Category : Science
ISBN : 9780080523477

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Comprehensive Organic Functional Group Transformations II by Anonim Pdf

Comprehensive Organic Functional Group Transformations II (COFGT-II) will provide the first point of entry to the literature for all scientists interested in chemical transformations. Presenting the vast subject of organic synthesis in terms of the introduction and interconversion of all known functional groups, COFGT-II provides a unique information source documenting all methods of efficiently performing a particular transformation. Organised by the functional group formed, COFGT-II consists of 144 specialist reviews, written by leading scientists who evaluate and summarise the methods available for each functional group transformation. Also available online via ScienceDirect – featuring extensive browsing, searching, and internal cross-referencing between articles in the work, plus dynamic linking to journal articles and abstract databases, making navigation flexible and easy. For more information, pricing options and availability visit www.info.sciencedirect.com. By systematically treating each functional group in turn the work also identifies what is not known, thus pointing the way to new research areas Follows the systematic layout of the successful 1995 COFGT reference work, based on the arrangement and bonding of hetero-atoms around a central carbon atom The work will save researchers valuable time in their research as each chapter is written by experts who have critically read and reviewed the literature and presented the best methods of forming every known functional group

Author : Nouria A. Al-Awadi
Publisher : John Wiley & Sons
Page : 304 pages
File Size : 51,9 Mb
Release : 2019-12-05
Category : Science
ISBN : 9781118057476

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Gas-Phase Pyrolytic Reactions by Nouria A. Al-Awadi Pdf

Offers a physical organic chemistry and mechanistic perspective of the chemistry of thermal processes in the gas phase The book looks at all aspects of the chemical processing technique called gas-phase pyrolysis, including its methodology and reactors, synthesis, reaction mechanisms, structure, kinetics, and applications. It discusses combinations of pyrolytic reactors with physiochemical techniques, routes for and reactions for the synthesis of organic compounds, and the control of reaction rates. Gas-Phase Pyrolytic Reactions: Synthesis, Mechanisms, and Kinetics starts with in-depth chapter coverage of static pyrolysis, dynamic flow pyrolysis, and analytical pyrolysis. It then examines synthesis and applications, including flash vacuum pyrolysis in organic synthesis, elimination of HX, elimination of CO and CO2, pyrolysis of Meldrum’s acid derivatives, and elimination of N2. A chapter on reaction mechanism comes next and includes coverage of retero-ene reaction and reactive intermediates. Following that are sections covering: structure/reactivity correlation, functional group & structural frame interconversions; gas-phase pyrolysis of hydrazones and phosphorus Ylides; and more. Deals with a growing area of chemistry and engineering interest that fits under the practices of green and sustainable chemistry Addresses several important aspects: methodology and reactors, synthesis, reaction mechanisms, structure, kinetics, and applications Reviews general methods of pyrolysis techniques Sets out the fundamentals and advantages of gas-phase pyrolysis in a way that illustrates its wide potential applications Gas-Phase Pyrolytic Reactions: Synthesis, Mechanisms, and Kinetics will appeal to organic chemists, physical organic chemists, chemical engineers and anyone interested in green/sustainable chemistry, chemical synthesis, or process chemistry.

Author : Derek Barton,J. E. Baldwin,W. D. Ollis
Publisher : Elsevier
Page : 234 pages
File Size : 41,9 Mb
Release : 2016-10-13
Category : Science
ISBN : 9781483147628

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Tetrahedron Reports on Organic Chemistry by Derek Barton,J. E. Baldwin,W. D. Ollis Pdf

Tetrahedron Reports on Organic Chemistry, Volume 3 contains 10 tetrahedron reports on organic chemistry with report numbers 21-30. Some reports focus on synthetic uses of anodic substitution reactions; an empirical analysis of the circular dichroism of chiral olefins; structure and reactivity of cycloimmonium ylides; the mechanism of epoxidation of olefins by peracids; regiospecific preparation and synthetic uses of ketone enolates. Other tetrahedron reports center on aspects of the formation and use of stenhouse salts and related compounds; synthesis of macrolides; interesting aspects of marine natural products chemistry; participation of isomeric tRNA's in the partial reactions of protein biosynthesis; biosynthesis of ß-lactam antibiotics.

Author : Raj K. Bansal
Publisher : Jones & Bartlett Learning
Page : 436 pages
File Size : 48,7 Mb
Release : 1996
Category : Science
ISBN : 0763706655

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Synthetic Approaches in Organic Chemistry by Raj K. Bansal Pdf

Designed for undergraduate and beginning graduate courses in organic synthesis.

Author : Metin Balcı
Publisher : John Wiley & Sons
Page : 644 pages
File Size : 50,9 Mb
Release : 2021-12-01
Category : Science
ISBN : 9783527349647

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Reaction Mechanisms in Organic Chemistry by Metin Balcı Pdf

An accessible and step-by-step exploration of organic reaction mechanisms In Reaction Mechanisms in Organic Chemistry, eminent researcher Dr. Metin Balci delivers an excellent textbook for understanding organic reaction mechanisms. The book offers a way for undergraduate and graduate students to understand???rather than memorize???the principles of reaction mechanisms. It includes the most important reaction types, including substitution, elimination, addition, pericyclic, and C-C coupling reactions. Each chapter contains problems and accompanying solutions that cover central concepts in organic chemistry. Students will learn to understand the foundational nature of ideas like Lewis acids and bases, electron density, the mesomeric effect, and the inductive effect via the use of detailed examples and an expansive discussion of the concept of hybridization. Along with sections covering aromaticity and the chemistry of intermediates, the book includes: A thorough introduction to basic concepts in organic reactions, including covalent bonding, hybridization, electrophiles and nucleophiles, and inductive and mesomeric effects Comprehensive explorations of nucleophilic substitution reactions, including optical activity and stereochemistry of SN2 reactions Practical discussions of elimination reactions, including halogene elimination and Hofmann elimination In-depth examinations of addition reactions, including the addition of water to alkenes and the epoxidation of alkenes Perfect for students of chemistry, biochemistry, and pharmacy, Reaction Mechanisms in Organic Chemistry will also earn a place in the libraries of researchers and lecturers in these fields seeking a one-stop resource on organic reaction mechanisms.

Author : Alan R. Katritzky,Stanley M. Roberts,Otto Meth-Cohn,Charles Wayne Rees
Publisher : Elsevier
Page : 1452 pages
File Size : 43,6 Mb
Release : 1995
Category : Mathematics
ISBN : 0080423221

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Comprehensive Organic Functional Group Transformations by Alan R. Katritzky,Stanley M. Roberts,Otto Meth-Cohn,Charles Wayne Rees Pdf

This Volume covers the formation of carbon-carbon single-, double- and triple bonds by substitution and addition reactions as well as by various rearrangements. The formation of carbon-carbon multiple bonds by elimination and condensation procedures is fully documented. In addition the synthesis of carbon-hydrogen bonds principally by substitution and addition reactions is featured as is the preparation of a wide variety of carbon-centred anions, cations and radicals.