Plasma Polymerization And Plasma Treatment Of Polymers
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Plasma Surface Modification and Plasma Polymerization by Norihiro Inagaki Pdf
In current materials R&D, high priority is given to surface modification techniques to achieve improved surface properties for specific applications requirements. Plasma treatment and polymerization are important technologies for this purpose. This book provides a basic and thorough presentation of this subject. This is probably the first book to cover plasma treatment and polymerization for the purpose of surface modification. Chemistry, processes and applications are detailed. More than 150 figures include numerous schematics which illustrate the chemistry and processes. More than 100 tables and graphics provide useful reference data in convenient form.
Atmospheric Pressure Plasma Treatment of Polymers by Michael Thomas,K. L. Mittal Pdf
An indispensable volume detailing the current and potential applications of atmospheric pressure plasma treatment by experts practicing in fields around the world Polymers are used in a wide variety of industries to fabricate legions of products because of their many desirable traits. However, polymers in general (and polyolefins, in particular) are innately not very adhesionable because of the absence of polar or reactive groups on their surfaces and concomitant low surface energy. Surface treatment of polymers, however, is essential to impart reactive chemical groups on their surfaces to enhance their adhesion characteristic. Proper surface treatment can endow polymers with improved adhesion without affecting the bulk properties. A plethora of techniques (ranging from wet to dry, simple to sophisticated, vacuum to non-vacuum) for polymer surface modification have been documented in the literature but the Atmospheric Pressure Plasma (APP) treatment has attracted much attention because it offers many advantages vis-a-vis other techniques, namely uniform treatment, continuous operation, no need for vacuum, simplicity, low cost, no environmental or disposal concern, and applicability to large area samples. Although the emphasis in this book is on the utility of APP treatment for enhancement of polymer adhesion, APP is also applicable and effective to modulate many other surface properties of polymers: superhydrophilicity, superhydrophobicity, anti-fouling, anti-fogging, anti-icing, cell adhesion, biocompatibility, tribological behavior, etc. The key features of Atmospheric Pressure Plasma Treatment of Polymers: Address design and functions of various types of reactors Bring out current and potential applications of APP treatment Represent the cumulative wisdom of many key academic and industry researchers actively engaged in this key and enabling technology
Plasma Modification of Polyolefins by N. S. Baneesh,P. S. Sari,Tatana Vackova,Sabu Thomas Pdf
This book addresses plasma modification of polyolefin surfaces. It comprises 21 chapters divided into three major sections. The first section covers the different techniques used for plasma modification of polyolefin surfaces and the effects of various gases as a surrounding medium, while the second provides a detailed analysis of the physics and chemistry of plasma modification and discusses various innovative characterization techniques, as well as ageing of the modified surface. It focuses on the analysis of changes in polymers’ surface chemistry using various spectroscopic techniques, and of changes in their surface morphology after plasma treatment using optical microscopy, electron microscopy and atomic force microscopy. In addition, it provides detailed information on the characterization of modified polymer surfaces. The book’s third and last section covers a range of applications of plasma-modified polyolefin surfaces varying from the packaging industry to the biomedical field, and shares valuable insights on the lifecycle analysis of plasma modification and modified surfaces.
Plasma Polymerization aims to bridge the conceptual gap between the academic and practical approaches to plasma polymerization and highlights the significance of plasma polymerization in materials science and technology. The major topics covered are gas-phase kinetics, ionization of gases, fundamentals of polymerization, mechanism of polymer formation in plasma, competitive aspects of polymer formation and ablation, mechanism of polymer deposition, operational factors of plasma polymerization, and electrical properties of plasma polymers. This book is comprised of 11 chapters and begins with a brief overview of plasma polymerization and its growing importance for the formation of entirely new kinds of materials. The discussion then shifts to a comparison between plasma-state polymerization and plasma-induced polymerization, between plasma polymerization and graft polymerization, and between plasma polymerization and radiation polymerization. The reader is also introduced to fundamental aspects of gas-phase reactions, paying particular attention to the classical kinetic theory of gas, as well as the mechanisms of formation of polymeric materials in plasma, competitive ablation and polymer formation in plasma, and polymer deposition in plasma polymerization. The operational parameters of plasma polymerization are described and a chapter devoted to the electrical properties of plasma-polymerized thin organic films concludes the book. This book will be of interest to students and researchers of material science.
Plasma Deposition, Treatment, and Etching of Polymers by Riccardo d'Agostino Pdf
Plasma Deposition, Treatment, and Etching of Polymers takes a broad look at the basic principles, the chemical processes, and the diagnostic procedures in the interaction of plasmas with polymer surfaces. This recent technology has yielded a large class of new materials offering many applications, including their use as coatings for chemical fibers and films. Additional applications include uses for the passivation of metals, the surface hardening of tools, increased biocompatibility of biomedical materials, chemical and physical sensors, and a variety of micro- and optoelectronic devices. Appeals to a broad range of industries from microelectronics to space technology Discusses a wide array of new uses for plasma polymers Provides a tutorial introduction to the field Surveys various classes of plasma polymers, their chemical and morphological properties, effects of plasma process parameters on the growth and structure of these synthetic materials, and techniques for characterization Interests scientists, engineers, and students alike
Plasma Surface Modification of Polymers: Relevance to Adhesion by Kash L. Mittal,M.,Lyons Pdf
This book is a collection of invited papers (previously published in special issues of the Journal of Adhesion Science and Technology) written by internationally recognized researchers actively working in the field of plasma surface modification. It provides a current, comprehensive overview of the plasma treatment of polymers. In contrast to plasm
Plasma Polymerization Processes by Hynek Biederman,Yoshihito Osada Pdf
The aim of this book is to show how to make useful plasma polymerization processes resulting in polymeric (organic) materials - usually thin films of the desirable properties. The main emphasis is on the detailed discussion of the deposition apparatus, deposition parameters and properties of the obtained films. The historical background and the processes related to plasma polymerization are discussed. Fundamentals of plasma physics and plasma chemistry are concisely reviewed and used as a base for the explanation of plasma polymerization principles and its models. Special attention is devoted to the real plasma polymerization reactors and various polymer film deposition arrangements. Many technical details are examined including the influence of process parameters on the properties of the resulting plasma polymers. New systems based on a microwave discharge are also described. The properties of the most important plasma polymers - plasma polymerized organosilicons, halocarbons and composite metal/plasma polymers are reviewed. Finally, the applications of plasma polymers are presented, e.g. for passivation and protective coatings, lithography and optical beam recording, electrophotography, microelectronics, modifications of conventional polymer surfaces - biomedical uses, membranes, etc. Future prospects and developments in plasma polymerization e.g. for molecular electronics and other areas are also outlined.
Polymer Surfaces and Interfaces by Manfred Stamm Pdf
In what is an extremely practical and applicable new work, experts provide concise explanations, with examples and illustrations, of the key techniques in this important field. In each case, after basic principles have been reviewed, applications of the experimental techniques are discussed and illustrated with specific examples. Scientists and engineers in research and development will benefit from an application-oriented book that helps them to find solutions to both fundamental and applied problems. They will know that the surfaces and interfaces of polymers play an important role in most of the application areas of polymers, from moulds, foils, and composites, to biomaterials and applications in micro- and nanotechnology.
Plasma Processes and Polymers by Riccardo d'Agostino,Pietro Favia,Christian Oehr,Michael R. Wertheimer Pdf
This volume compiles essential contributions to the most innovative fields of Plasma Processes and Polymers. High-quality contributions cover the fields of plasma deposition, plasma treatment of polymers and other organic compounds, plasma processes under partial vacuum and at atmospheric pressure, biomedical, textile, automotive, and optical applications as well as surface treatment of bulk materials, clusters, particles and powders. This unique collection of refereed papers is based on the best contributions presented at the 16th International Symposium on Plasma Chemistry in Taormina, Italy (ISPC-16, June 2003). A high class reference of relevance to a large audience in plasma community as well as in the area of its industrial applications.
The topic of polymer surface modification is of tremendous contemporary interest because of its critical importance in many and varied technological applications where polymers are used. Currently there is brisk research activity in unraveling the mechanisms of surface modification and finding ways to prolong the life of surface treatment. Also there is acute interest and need to devise new, improved and economical means to modify polymer surfaces. This book is divided into three parts as follows: Part 1: Surface Modification Techniques; Part 2: Interfacial Aspects and Adhesion; Part 3: General Papers. The topics covered include: various techniques for surface modification including plasma (both vacuum and atmospheric pressure), ozone, photografting, UV photo-oxidation, laser, use of charged particles and others for a variety of polymers; longevity of surface treatment; hydrophobic recovery; fabrication of high-density polymer nano-dots; immobilization of organometallic catalysts on textile carrier materials; polymer membrane antifouling properties; electroless metallization of polymers; effects of surface modification on interfacial shear strength of composites, cord/rubber adhesion, adhesion of UV-curable coatings and attachment of hyperbranched polymers; plasma polymerization; block copolymers; application of plasma technology in decontamination of heat-sensitive polymer surfaces. In essence this book reflects the current state-of-the-knowledge in the arena and represents the work of many renowned scientists and technologists. It should be of interest to anyone with a desire or need to learn the latest R&D activity in this domain and the information contained here should be very valuable in deciding the optimum surface modification technique for his/her particular requirements.
Plasma Science and Technology by Herman Boenig Pdf
In a systematic and comprehensive manner, this book describes the science of low-temperature plasma—a new field that is emerging at a fast pace. An expert well known in this field gives a coherent overview of the applications of low-temperature plasmas to chemical reactions, and in greater detail, to polymers formed or treated in plasma. After laying the groundwork with chapters on the nature of plasma and the variety of typical reactions that occur in discharges, the author deals with specific applications in the production of polymers. He then devotes a chapter each to the deposition of films, the nature of polymers produced in plasmas, and the specific properties of polymers, with a concluding chapter on additional applications of plasma technology. Herman Boenig emphasizes thin-film depositions—their high quality and integrity, as well as their applications in a variety of industrially important uses, including microcircuitry, integrated optics, and metal and other material coatings. He also discusses extensively the applications of plasma deposition in other areas such as high adhesion to metals, polymers, and glasses; high temperature resistance; special friction characteristics; and use in reverse osmosis, permselectivity, and other membrane applications. In a special chapter he covers the use of plasma in ion implantations, plasma cleaning of materials surfaces, and the technique now being considered for use in devices to clean polluted air and convert waste products in submarines and space capsules. Plasma Science and Technology should prove invaluable as a text for graduate students and advanced undergraduates, and as a reference for chemists, material scientists, metallurgists, environmental scientists, engineers, and physicists. It will be of particular interest to those involved in microcircuitry, microcomputers, integrated optics, optical equipment, desalination, biomedicine, thin films, adhesion, ion implantation, textile treatment, advanced composites, and chemical synthesis.
Plasma Polymer Films examines the current status of the deposition and characterization of fluorocarbon-, hydrocarbon- and silicon-containing plasma polymer films and nanocomposites, with plasma polymer matrix. It introduces plasma polymerization process diagnostics such as optical emission spectroscopy (OES, AOES), and describes special deposition techniques such as atmospheric pressure glow discharge. Important issues for applications such as degradation and stability are treated in detail, and structural characterization, basic electrical and optical properties and biomedical applications are discussed.
