Progress In Layered Double Hydroxides From Synthesis To New Applications
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Progress In Layered Double Hydroxides: From Synthesis To New Applications by Umberto Costantino,Morena Nocchetti Pdf
Layered Double Hydroxides (LDH) are two-dimensional materials with unique physiochemical properties, which enable their use in a wide range of applications such as catalysis, biomaterials, energy, filler of polymeric composites, and water remediation.This book addresses basic aspects of LDH as the implementations in the methodologies based on density functional theory (DFT) to understand the properties and applications of LDHs, the synthetic methods to prepare LDHs and LDH based core-shell structures, and the swelling and exfoliation behaviors of LDH compounds. A relevant part of the book is devoted to consolidated and emerging applications of LDHs as catalysts in photocatalysis, electrocatalysis and water oxidation processes, as biomaterials and as functional fillers in food packaging. New advances on LDH are described with a keen eye on the past research.
Recent Advances in Layered Double Hydroxide-based Composites by Mohamed Reda Berber Pdf
Layered double hydroxides (LDHs) or hydrotalcites are inorganic clay materials with many promising properties. LDHs are a family of natural and synthetic compounds having the general formula [M(II) 1-x M(III)x (OH)2 ](Yn-))x/n yH2O, where M(II) and M(III) represent divalent and trivalent metal ions, respectively, and Yn- is the anion between the layers. They consist structurally of brucite-like [Mg(OH)2] layers, with a net positive charge due to partial substitution of M(II) by M(III). This positive charge is balanced by the anionic interlayer anion. Over the past few years, an increasing interest has been directed to the use of these clays as host materials, anion exchangers, delivery carriers and additives for polymers in order to create potential products with desirable physical and chemical properties. From the many significant research achievements and the many potential practical applications, it is assumed that the prospects for LDHs and their composites with the different organic and bioactive materials are very bright indeed and still more remains to be done in order to exploit completely their potential applications. In this book, we focus on the progress of the development of LDHs and their derivatives, including the synthetic techniques, the nanocomposite preparation routes, the factors affecting the physicochemical properties and how these properties affect the nanoparticle structure and the host-guest process. Furthermore, we summarise the current LDH potential applications and the possible future trends in agricultural, biological and medical researches (eg: the role of LDHs as reinforcements, as catalysts and catalyst supports) in the field of catalysis, as a carrier in drug delivery and as host for a safe preservation of the bioactive material.
Layered Double Hydroxide Polymer Nanocomposites by Sabu Thomas,Saju Daniel Pdf
Nanocomposites based on layered double hydroxides (LDHs) have recently become a formidable research area due to their amendable properties and potential applications. The distinct properties of LDH polymer nanocomposites include a wide range of chemical compositions, structural homogeneity, unique anion exchanging ability, easy synthesis, high bound water content, memory effect, non-toxicity and biocompatibility. This means that LDH polymer nanocomposites have the potential for new and innovative applications. Layered Double Hydroxide Polymer Nanocomposites presents a comprehensive overview of the recent innovative advances in the fabrication, characterization and applications of LDH polymer nanocomposites. As well as covering fundamental structural and chemical knowledge, this book also explores various properties and characterization techniques including microscopic, spectroscopic and mechanical behaviors. There is also a strong focus on the potential applications of LDH polymer nanocomposites, such as energy, electrical and electronic, electromagnetic shielding, biomedical, agricultural, food packaging and water purification functions. This book provides comprehensive coverage of cutting-edge research in the field of LDH polymer nanocomposites and their future applications. This book will be an essential read for all academics, researchers, engineers and students working in this area. Fundamental knowledge of LDH polymer nanocomposites, including chemical composition, structural features and fabrication techniques Provides an analytical overview of the different types of characterization techniques and technologies Extensive review on cutting-edge research for potential future applications, in a variety of industries
Layered Double Hydroxides (LDHs) by Roberto Pizzoferrato,Maria Richetta Pdf
Layered Double Hydroxides (LDHs) certainly do not represent a newcomer to the scientific community, yet they continue to attract a strong and general interest among a vast and multifaceted range of researchers. This persistent modernity is definitely due to some peculiar characteristics of these materials, which allow researchers and engineers to play with different aspects of two worlds: organic and inorganic, crystalline and molecular, solid and liquid, cationic and anionic. A virtually infinite number of possible chemical combinations takes advantage of their layered structure to express an unrivaled collection of remarkable properties. The capture and/or release of organic and inorganic species, versatile low-cost catalytic activity, and blending with other compounds to build up a variety of hybrid composites, are just some of the many effects investigated to date. As a result, the applications encompass almost all aspects of our life, ranging from renewable energy production to water purification, including biomedical applications, gas sensing, drug delivery, and food packaging and safety. This Special Issue highlights some of the recent research lines, and shows that remarkable progress has been and is still being made in all these aspects, to allow the consideration of LDHs as one of the most interesting and versatile inorganic materials.
Layered Double Hydroxides (LDHs) by Ian T. Sherman Pdf
Layered double hydroxides (LDHs) are clay-type materials with extraordinary properties, whose structure is composed of stacked inorganic metal oxide layers built by connected sheets. The crystal structure of layered double hydroxides is based on positive charged brucite-like mainlayers and balanced by reversible exchangeable interlayer anions, additional cations and water molecules. Due to their negligible toxicity and buffering properties, LDHs are commercially employed as antacids and they are increasingly studied as vehicles in drug and gene delivery systems. This book discusses the synthesis, characterization and applications of layered double hydroxides.
Biodegradable and Biocompatible Polymer Composites by Navinchandra Gopal Shimpi Pdf
Biodegradable and Biocompatible Polymer Composites: Processing, Properties and Applications begins by discussing the current state-of-the-art, new challenges and opportunities for various biodegradable and biocompatible polymer composite systems. Interfacial characterization of composites and the structure-property relationships in various composite systems are explained in detail via a theoretical model. Processing techniques for various macro and nanocomposite systems and the influence of processing parameters on properties of the composite are also reviewed in detail. The characterization of microstructure, elastic, visco-elastic, static and dynamic mechanical, thermal, rheological, optical, and electrical properties are highlighted, as are a broad range of applications. The book is a useful reference resource for both researchers and engineers working in composites materials science, biotechnology and nanotechnology, and is also useful for students attending chemistry, physics, and materials science and engineering courses. Presents recent outcomes and highlights the going importance of biodegradable and biocompatible polymer composites and their impact on the environment Analyzes all the main processing techniques, characterization and applications of biodegradable composites Written by leading international experts working in the field of biodegradable and biocompatible polymer composites Covers a broad range of application fields, including medical and pharmaceutical, agricultural, packaging and transport
Applications of Layered Double Hydroxides by Rajib Lochan Goswamee,Pinky Saikia Pdf
"Currently, Layered Double Hydroxides (LDH) is a hot area of research on inorganic layered materials. The present book, Applications of Layered Double Hydroxides, edited by Dr. Rjib Lochan Goswamee and Dr. Pinky Saikia, is a collection of articles from various researchers from different parts of the world mainly on structure and property relationships of various types of LDH and their related application prospects. How these application prospects can be related to the most pressing problems of humanity like drug delivery, global warming, green catalysis, electrochemical energy storage and generation etc. are clearly discussed in the articles inside. The book provides a thorough up-to-date review of recent literature on applications of LDH available in the global scientific and technical media. For example, the book lucidly describes the behaviour of LDH nanocarriers in biological fluids, their low cytotoxicity and high levels of cellular internalization, and high drug loading capacity. Similarly, the book examines why hybrid nanocomposites of LDH-MOF are considered promising materials due to their diverse functionality, flexible properties and tailored end-use properties. Likewise, application of LDH in secondary batteries and electro-chemical supercapacitors with a thorough up-to-date review is included in the book. Also, basic research articles on structural properties and measurements of a special class of unique LDH Li-Al-LDHs are included. Editors also have written their own articles on their findings on the prospective application of dispersions of LDH nanocomposites on structured catalysts for green-house gas emission. Overall, the book gives a short glimpse of wonderful opportunities that LDH can provide in solving many global socio-economic problems of today"--
Clay Minerals and Synthetic Analogous as Emulsifiers of Pickering Emulsions by Fernando Wypych,Rilton Alves de Freitas Pdf
Clay Minerals and Synthetic Analogous as Emulsifiers of Pickering Emulsions begins with basic concepts of Pickering emulsions, describes the thermodynamic, kinetic and gravitational stability, the methods of preparation, and the most common characterization techniques. Next, the book presents detailed structure, properties, and physical-chemical modifications of natural and synthetic layered minerals to optimize its properties. Figures and schemes are prepared for experts in the area as well as the undergraduate and graduate students from many different research areas where clay minerals, synthetic layered materials and Pickering emulsion have potential applications. Clay Minerals and Synthetic Analogous as Emulsifiers of Pickering Emulsions fills a gap in the literature, stimulates the aggregation of value of clay minerals, and shows the readers the methods of preparation, characterization, and applications of Pickering emulsions stabilized with layered materials, giving special attention to clay minerals. Fills a gap in the literature with multidisciplinary coverage of Pickering Emulsions Presents methods of preparation, characterization, and applications of Pickering emulsions for clay minerals Includes contributions from top experts in the relevant fields
Engineering of Thermoplastic Elastomer with Graphene and Other Anisotropic Nanofillers by Abhijit Bandyopadhyay,Poulomi Dasgupta,Sayan Basak Pdf
This book is an effort to tether all the exuberant observations on adding nanomaterial in the TPE matrix. With an enhanced processing property along with amplified recyclability and reprocessing feature, thermoplastic elastomers (TPE) proves to be one of the most significant polymeric materials till date. As the scientific world evolves, these advanced materials have attuned themselves with various anisotropic nanomaterials to induce an enhanced property effect on the final product. On an additional note, authors have done extensive research on graphene, the most multifaceted element in the filler family keeping TPE and its derivate as the matrix martial. Cogitating the idea of a multidimensional readership, authors have analyzed the synthesis, derivatization, and properties of graphene and its derivatives separately. Apart from reviewing the future prospects and the potential application of these nano-filled advanced materials, they have kept the structure–property relationship of graphene-based composites at the cynosure to provide firm understanding on the blossoming of these elastomeric composites. The authors believe this book is a potential content for both professionals and academicians.
Annual Reports on NMR Spectroscopy by Graham A. Webb Pdf
Annual Reports on NMR Spectroscopy, Volume 104 has established itself as a premier resource for both specialists and non-specialists who are looking to become familiar with new techniques and applications pertaining to NMR spectroscopy. Serves as the premier resource for learning new techniques and applications in NMR spectroscopy Provides a key reference for chemists and physicists using NMR spectroscopy to study the structure and dynamics of molecules Covers all aspects of molecular science, including MRI (Magnetic Resonance Imaging)
Recent Developments in Atomic Force Microscopy and Raman Spectroscopy for Materials Characterization by Chandra Shakher Pathak,Samir Kumar Pdf
This book contains chapters that describe advanced atomic force microscopy (AFM) modes and Raman spectroscopy. It also provides an in-depth understanding of advanced AFM modes and Raman spectroscopy for characterizing various materials. This volume is a useful resource for a wide range of readers, including scientists, engineers, graduate students, postdoctoral fellows, and scientific professionals working in specialized fields such as AFM, photovoltaics, 2D materials, carbon nanotubes, nanomaterials, and Raman spectroscopy.
Layered 2D Materials and Their Allied Applications by Inamuddin,Rajender Boddula,Mohd Imran Ahamed,Abdullah M. Asiri Pdf
Ever since the discovery of graphene, two-dimensional layered materials (2DLMs) have been the central tool of the materials research community. The reason behind their importance is their superlative and unique electronic, optical, physical, chemical and mechanical properties in layered form rather than in bulk form. The 2DLMs have been applied to electronics, catalysis, energy, environment, and biomedical applications. The following topics are discussed in the book’s fifteen chapters: • The research status of the 2D metal-organic frameworks and the different techniques used to synthesize them. • 2D black phosphorus (BP) and its practical application in various fields. • Reviews the synthesis methods of MXenes and provides a detailed discussion of their structural characterization and physical, electrochemical and optical properties, as well as applications in catalysis, energy storage, environmental management, biomedicine, and gas sensing. • The carbon-based materials and their potential applications via the photocatalytic process using visible light irradiation. • 2D materials like graphene, TMDCs, few-layer phosphorene, MXene in layered form and their heterostructures. • The structure and applications of 2D perovskites. • The physical parameters of pristine layered materials, ZnO, transition metal dichalcogenides, and heterostructures of layered materials are discussed. • The coupling of graphitic carbon nitride with various metal sulfides and oxides to form efficient heterojunction for water purification. • The structural features, synthetic methods, properties, and different applications and properties of 2D zeolites. • The methods for synthesizing 2D hollow nanostructures are featured and their structural aspects and potential in medical and non-medical applications. • The characteristics and structural aspects of 2D layered double hydroxides (LDHs) and the various synthesis methods and role of LDH in non-medical applications as adsorbent, sensor, catalyst, etc. • The synthesis of graphene-based 2D layered materials synthesized by using top-down and bottom-up approaches where the main emphasis is on the hot-filament thermal chemical vapor deposition (HFTCVD) method. • The different properties of 2D h-BN and borophene and the various methods being used for the synthesis of 2D h-BN, along with their growth mechanism and transfer techniques. • The physical properties and current progress of various transition metal dichalcogenides (TMDC) based on photoactive materials for photoelectrochemical (PEC) hydrogen evolution reaction. • The state-of-the-art of 2D layered materials and associated devices, such as electronic, biosensing, optoelectronic, and energy storage applications.
Layered Double Hydroxides by Xue Duan,David G. Evans Pdf
D.G. Evans, R.C.T. Slade: Structural Aspects of Layered Double Hydroxides.- J. He, M. Wei, B. Li, Y. Kang, D.G. Evans, X. Duan: Preparation of Layered Double Hydroxides.- C. Taviot-Gueho, F. Leroux: In Situ Polymerization and Intercalation of Polymers in Layered Double Hydroxides.- G.R. Williams, A.I. Khan, D. O'Hare: Mechanistic and Kinetic Studies of Guest Ion Intercalation into Layered Double Hydroxides Using Time-Resolved, In-Situ X-Ray Powder Diffraction.- F. Li, X. Duan: Applications of Layered Double Hydroxides
