Reaction Kinetics And The Development And Operation Of Catalytic Processes

Author : G.F. Froment,K.C. Waugh
Publisher : Elsevier
Page : 664 pages
File Size : 54,9 Mb
Release : 2001-04-03
Category : Science
ISBN : 0080540295

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Reaction Kinetics and the Development and Operation of Catalytic Processes by G.F. Froment,K.C. Waugh Pdf

Reaction Kinetics and the Development and Operation of Catalytic Processes is a trendsetter. The Keynote Lectures have been authored by top scientists and cover a broad range of topics like fundamental aspects of surface chemistry, in particular dynamics and spillover, the modeling of reaction mechanisms, with special focus on the importance of transient experimentation and the application of kinetics in reactor design. Fundamental and applied kinetic studies are well represented. More than half of these deal with transient kinetics, a new trend made possible by recent sophisticated experimental equipment and the awareness that transient experimentation provides more information and insight into the microphenomena occurring on the catalyst surface than steady state techniques. The trend is not limited to purely kinetic studies since the great majority of the papers dealing with reactors also focus on transients and even deliberate transient operation. It is to be expected that this trend will continue and amplify as the community becomes more aware of the predictive potential of fundamental kinetics when combined with detailed realistic modeling of the reactor operation.

Author : Anonim
Publisher : Unknown
Page : 477 pages
File Size : 51,9 Mb
Release : 1999
Category : Electronic
ISBN : OCLC:1132009007

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Reaction kinetics and the development of catalytic processes : proceedings of the international symposium, Brugge, Belgium, April 19-21, 1999 by Anonim Pdf

Author : Gilbert F. Froment,K. C. Waugh
Publisher : Elsevier Science Limited
Page : 477 pages
File Size : 49,9 Mb
Release : 1999
Category : Science
ISBN : 0444500731

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Reaction Kinetics and the Development of Catalytic Processes by Gilbert F. Froment,K. C. Waugh Pdf

The symposium "Reaction Kinetics and the Development of Catalytic Processes" is the continuation of the very successful International Symposium "Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis", held in September 1997 in Antwerp, Belgium. These proceedings contain a unique series of top level plenary lectures mainly focused on . the dynamics of catalytic surfaces . the interaction of the reacting molecules with the solid catalyst . the elementary steps of reaction pathways and molecular kinetics. Surface science techniques, molecular modeling, transient kinetic studies, sophisticated and specific reactors are included to a growing extent in the kinetic modeling and the development of catalytic processes. How this is practiced today and how it will evolve in the coming years, and what benefit can be expected for a more fundamentally based approach is the aim of the symposium.

Author : Ruud I. Wijngaarden,K. Roel Westerterp,Alexander Kronberg,A. N. R. Bos
Publisher : John Wiley & Sons
Page : 285 pages
File Size : 48,9 Mb
Release : 2008-07-11
Category : Science
ISBN : 9783527611959

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Industrial Catalysis by Ruud I. Wijngaarden,K. Roel Westerterp,Alexander Kronberg,A. N. R. Bos Pdf

This is a book for developers of catalysts, and for practitioners working in the field of design, operation, and optimization of chemical reactors in which heterogeneous catalysis is performed. It is designed to give a better understanding of the phenomena which can influence catalyst performance. Since two disciplines, chemistry and chemical engineering, meet in catalyst research and development, this book covers the chemical point of view for engineers, and the engineering point of view for chemists. It starts with an introduction explaining selectivity, activity and effectiveness providing the fundamentals for the newcomer. Catalyst preparation and catalyst testing are also described. A method is introduced that can be used to calculate the effectiveness of catalyst pellets as a function of shape, size, pore size, type of kinetics and diffusion, and temperature and pressure conditions. Optimization of catalysts and troubleshooting are also covered. This is a book without any rilvals because of its practical relevance.

Author : C.H. Bamford,R.G. Compton,C.F.H. Tipper†
Publisher : Elsevier
Page : 412 pages
File Size : 44,9 Mb
Release : 1978-01-01
Category : Science
ISBN : 0080868142

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Complex Catalytic Processes by C.H. Bamford,R.G. Compton,C.F.H. Tipper† Pdf

Complex Catalytic Processes

Author : Friedrich G. Helfferich
Publisher : Elsevier
Page : 508 pages
File Size : 48,8 Mb
Release : 2004-09-15
Category : Science
ISBN : 9780080473185

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Kinetics of Multistep Reactions by Friedrich G. Helfferich Pdf

This book addresses primarily the engineer in industrial process development, the research chemist in academia and industry, and the graduate student intending to become a reaction engineer. In industry, competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such development should be based on "fundamental" kinetics that reflect the elementary steps of which the reaction consists. The book forges fundamental kinetics into a practical tool by presenting new, effective methods for elucidation of mechanisms and reduction of complexity without unacceptable sacrifice in accuracy: fewer equations (lesser computational load), fewer coefficients (fewer experiment to determine them). For network elucidation, new rules relating network configurations to observable kinetic behaviour allow incorrect networks to be ruled out by whole classes instead of one by one. For modelling, general equations and algorithms are given from which equations for specific networks can be recovered by simple substitutions. The procedures are illustrated with examples of industrial reactions including, among others, paraffin oxidation, ethoxylation, hydroformylation, hydrocyanation, shape-selective catalysis, ethane pyrolysis, styrene polymerization, and ethene oligomerization. Many of the rate equations have not been published before. The expanded edition of the 2001 title, Kinetics of Homogeneous Multistep Reactions includes new chapters on heterogeneous catalysis and periodic and chaotic re-actions; new sections on adsorption, statistical methods, and lumping; and other new detail. Contains new chapters on heterogeneous catalysis, oscillations and chaos Includes new sections on statistical methods, lumping adsorption and software and databases Provides a better understanding of complex reaction mechanisms

Author : Dmitry Yu Murzin,Tapio Salmi
Publisher : Elsevier
Page : 752 pages
File Size : 55,8 Mb
Release : 2016-06-04
Category : Technology & Engineering
ISBN : 9780444634634

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Catalytic Kinetics by Dmitry Yu Murzin,Tapio Salmi Pdf

Catalytic Kinetics: Chemistry and Engineering, Second Edition offers a unified view that homogeneous, heterogeneous, and enzymatic catalysis form the cornerstone of practical catalysis. The book has an integrated, cross-disciplinary approach to kinetics and transport phenomena in catalysis, but still recognizes the fundamental differences between different types of catalysis. In addition, the book focuses on a quantitative chemical understanding and links the mathematical approach to kinetics with chemistry. A diverse group of catalysts is covered, including catalysis by acids, organometallic complexes, solid inorganic materials, and enzymes, and this fully updated second edition contains a new chapter on the concepts of cascade catalysis. Finally, expanded content in this edition provides more in-depth discussion, including topics such as organocatalysis, enzymatic kinetics, nonlinear dynamics, solvent effects, nanokinetics, and kinetic isotope effects. Fully revised and expanded, providing the latest developments in catalytic kinetics Bridges the gaps that exist between hetero-, homo- and enzymatic-catalysis Provides necessary tools and new concepts for researchers already working in the field of catalytic kinetics Written by internationally-renowned experts in the field Examples and exercises following each chapter make it suitable as an advanced course book

Author : Michel Boudart
Publisher : Elsevier
Page : 262 pages
File Size : 52,5 Mb
Release : 2014-05-16
Category : Science
ISBN : 9781483183978

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Kinetics of Chemical Processes by Michel Boudart Pdf

Kinetics of Chemical Processes details the concepts associated with the kinetic study of the chemical processes. The book is comprised of 10 chapters that present information relevant to applied research. The text first covers the elementary chemical kinetics of elementary steps, and then proceeds to discussing catalysis. The next chapter tackles simplified kinetics of sequences at the steady state. Chapter 5 deals with coupled sequences in reaction networks, while Chapter 6 talks about autocatalysis and inhibition. The seventh chapter describes the irreducible transport phenomena in chemical kinetics. The next two chapters discuss the correlations in homogenous kinetics and heterogeneous catalysis, respectively. The last chapter covers the analysis of reaction networks. The book will be of great use to students, researchers, and practitioners of scientific disciplines that deal with chemical reaction, particularly chemistry and chemical engineering.

Author : I. Chorkendorff,J. W. Niemantsverdriet
Publisher : John Wiley & Sons
Page : 50 pages
File Size : 53,6 Mb
Release : 2017-05-30
Category : Technology & Engineering
ISBN : 9783527691289

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Concepts of Modern Catalysis and Kinetics by I. Chorkendorff,J. W. Niemantsverdriet Pdf

In the past 12 years since its publication, Concepts of Modern Catalysis and Kinetics has become a standard textbook for graduate students at universities worldwide. Emphasizing fundamentals from thermodynamics, physical chemistry, spectroscopy, solid state chemistry and quantum chemistry, it introduces catalysis from a molecular perspective, and stresses how it is interwoven with the field of reaction kinetics. The authors go on to explain how the world of reacting molecules is connected to the real world of industry, by discussing the various scales (nano - micro - macro) that play a role in catalysis. Reflecting the modern-day focus on energy supplies, this third edition devotes attention to such processes as gas-to-liquids, coal-to-liquids, biomass conversion and hydrogen production. From reviews of the prior editions: 'Overall, this is a valuable book that I will use in teaching undergraduates and postgraduates.' (Angewandte Chemie - I. E.) '...this excellent book is highly recommended to students at technical universities, but also entrants in chemical industry. Furthermore, this informative handbook is also a must for all professionals in the community.' (AFS) 'I am impressed by the coverage of the book and it is a valuable addition to the catalysis literature and I highly recommend purchase' (Energy Sources)

Author : Guy B. Marin,Gregory S. Yablonsky,Denis Constales
Publisher : John Wiley & Sons
Page : 446 pages
File Size : 47,7 Mb
Release : 2018-12-14
Category : Science
ISBN : 9783527808366

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Kinetics of Chemical Reactions by Guy B. Marin,Gregory S. Yablonsky,Denis Constales Pdf

This second, extended and updated edition presents the current state of kinetics of chemical reactions, combining basic knowledge with results recently obtained at the frontier of science. Special attention is paid to the problem of the chemical reaction complexity with theoretical and methodological concepts illustrated throughout by numerous examples taken from heterogeneous catalysis combustion and enzyme processes. Of great interest to graduate students in both chemistry and chemical engineering.

Author : Santosh K. Upadhyay
Publisher : Springer Science & Business Media
Page : 256 pages
File Size : 47,9 Mb
Release : 2007-04-29
Category : Science
ISBN : 9781402045479

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Chemical Kinetics and Reaction Dynamics by Santosh K. Upadhyay Pdf

Chemical Kinetics and Reaction Dynamics brings together the major facts and theories relating to the rates with which chemical reactions occur from both the macroscopic and microscopic point of view. This book helps the reader achieve a thorough understanding of the principles of chemical kinetics and includes: Detailed stereochemical discussions of reaction steps Classical theory based calculations of state-to-state rate constants A collection of matters on kinetics of various special reactions such as micellar catalysis, phase transfer catalysis, inhibition processes, oscillatory reactions, solid-state reactions, and polymerization reactions at a single source. The growth of the chemical industry greatly depends on the application of chemical kinetics, catalysts and catalytic processes. This volume is therefore an invaluable resource for all academics, industrial researchers and students interested in kinetics, molecular reaction dynamics, and the mechanisms of chemical reactions.

Author : G.F. Froment,K.C. Waugh
Publisher : Elsevier
Page : 475 pages
File Size : 55,5 Mb
Release : 1999-03-18
Category : Technology & Engineering
ISBN : 0080540279

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Reaction Kinetics and the Development of Catalytic Processes by G.F. Froment,K.C. Waugh Pdf

The symposium "Reaction Kinetics and the Development of Catalytic Processes" is the continuation of the very successful International Symposium "Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis", held in September 1997 in Antwerp, Belgium. These proceedings contain a unique series of top level plenary lectures mainly focused on • the dynamics of catalytic surfaces • the interaction of the reacting molecules with the solid catalyst • the elementary steps of reaction pathways and molecular kinetics. Surface science techniques, molecular modeling, transient kinetic studies, sophisticated and specific reactors are included to a growing extent in the kinetic modeling and the development of catalytic processes. How this is practiced today and how it will evolve in the coming years, and what benefit can be expected for a more fundamentally based approach is the aim of the symposium.

Author : C. H. Bartholomew,Robert J. Farrauto
Publisher : John Wiley & Sons
Page : 1224 pages
File Size : 46,7 Mb
Release : 2011-11-30
Category : Technology & Engineering
ISBN : 9781118209738

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Fundamentals of Industrial Catalytic Processes by C. H. Bartholomew,Robert J. Farrauto Pdf

Catalysis is central to the chemical industry, as it is directly or involved in the production of almost all useful chemical products. In this book the authors, present the definitive account of industrial catalytic processes. Throughout Fundamentals of Industrial Catalytic Processes the information is illustrated with many case studies and problems. This book is valuable to anyone wanting a clear account of industrial catalytic processes, but is particularly useful to industrial and academic chemists and engineers and graduate working on catalysis. This book also: Covers fundamentals of catalytic processes, including chemistry, catalyst preparation, properties and reaction engineering. Addresses heterogeneous catalytic processes employed by industry. Provides detailed data on existing catalysts and catalytic reactions, process design and chemical engineering. Covers catalysts used in fuel cells.

Author : Robert J. Farrauto,Lucas Dorazio,C. H. Bartholomew
Publisher : John Wiley & Sons
Page : 340 pages
File Size : 54,7 Mb
Release : 2016-04-11
Category : Technology & Engineering
ISBN : 9781118454602

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Introduction to Catalysis and Industrial Catalytic Processes by Robert J. Farrauto,Lucas Dorazio,C. H. Bartholomew Pdf

Introduces major catalytic processes including products from the petroleum, chemical, environmental and alternative energy industries Provides an easy to read description of the fundamentals of catalysis and some of the major catalytic industrial processes used today Offers a rationale for process designs based on kinetics and thermodynamics Alternative energy topics include the hydrogen economy, fuels cells, bio catalytic (enzymes) production of ethanol fuel from corn and biodiesel from vegetable oils Problem sets of included with answers available to faculty who use the book Review: "In less than 300 pages, it serves as an excellent introduction to these subjects whether for advanced students or those seeking to learn more about these subjects on their own time...Particularly useful are the succinct summaries throughout the book...excellent detail in the table of contents, a detailed index, key references at the end of each chapter, and challenging classroom questions..." (GlobalCatalysis.com, May 2016)

Author : S. Sundaramoorthy
Publisher : CRC Press
Page : 392 pages
File Size : 48,6 Mb
Release : 2018-08-10
Category : Green chemistry
ISBN : 1138893579

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Green Chemical Engineering by S. Sundaramoorthy Pdf

"This book deals with energy and material balance applied to chemical reactors with catalysis to achieve a given purpose, including fundamentals of chemical reaction engineering. The authors explain reactor design fundamentals, from simple kinetic models to complex reactor systems involving heat/material transfer or multiple reaction contents. The book spans the full range from fundamentals of kinetics and heterogeneous catalysis via modern experimental and theoretical results of model studies to their equivalent large-scale industrial production processes. It also includes significant developments, with recent research case studies and literature. With a focus on practical application, rather than theory, the result is key knowledge for students at technical universities and professionals already working in industry. "--