Review And Evaluation Of Alternative Chemical Disposal Technologies

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Review and Evaluation of Alternative Chemical Disposal Technologies

Author : National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Panel on Review and Evaluation of Alternative Chemical Disposal Technologies
Publisher : National Academies Press
Page : 273 pages
File Size : 50,7 Mb
Release : 1996-12-15
Category : Political Science
ISBN : 9780309055253

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Review and Evaluation of Alternative Chemical Disposal Technologies by National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Panel on Review and Evaluation of Alternative Chemical Disposal Technologies Pdf

In 1994 the National Research Council published Recommendations for the Disposal of Chemical Agents and Munitions, which assessed the status of various alternative destruction technologies in comparison to the Army's baseline incineration system. The volume's main finding was that no alternative technology was preferable to incineration but that work should continue on the neutralization technologies under Army consideration. In light of the fact that alternative technologies have evolved since the 1994 study, this new volume evaluates five Army-chosen alternatives to the baseline incineration system for the disposal of the bulk nerve and mustard agent stored in ton containers at Army sites located in Newport, Indiana, and Aberdeen, Maryland, respectively. The committee assessed each technology by conducting site visits to the locations of the technology proponent companies and by meeting with state regulators and citizens of the affected areas. This volume makes recommendations to the Army on which, if any, of the five technologies has reached a level of maturity appropriate for consideration for pilot-scale testing at the two affected sites.

Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons

Author : National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons
Publisher : National Academies Press
Page : 267 pages
File Size : 55,6 Mb
Release : 1999-11-24
Category : Science
ISBN : 9780309184007

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Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons by National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons Pdf

This report examines seven disposal technologies being considered by the U.S. government as alternative methods to the process of incineration for destroying mortars, rockets, land mines, and other weapons that contain chemical warfare agents, such as mustard gas. These weapons are considered especially dangerous because they contain both chemical warfare agent and explosive materials in an assembled package that must be disassembled for destruction. The study identifies the strengths and weaknesses and advantages and disadvantages of each technology and assesses their potential for full-scale implementation.

Evaluation of Alternative Technologies for Disposal of Liquid Wastes from the Explosive Destruction System

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review and Evaluation of the Army Non-Stockpile Chemical Materiel Disposal Program
Publisher : National Academies Press
Page : 76 pages
File Size : 43,6 Mb
Release : 2002-01-20
Category : Science
ISBN : 9780309082693

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Evaluation of Alternative Technologies for Disposal of Liquid Wastes from the Explosive Destruction System by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review and Evaluation of the Army Non-Stockpile Chemical Materiel Disposal Program Pdf

Chemical warfare materiel (CWM) encompasses diverse items that were used during 60 years of efforts by the United States to develop a capability for conducting chemical warfare. Non-Stockpile CWM (NSCWM) is materiel not included in the current U.S. inventory of chemical munitions and includes buried materiel, recovered materiel, components of binary chemical weapons, former production facilities, and miscellaneous materiel. Because NSCWM is stored or buried at many locations, the Army is developing transportable treatment systems that can be moved from site to site as needed. Originally, the Army planned to develop three transportable treatment systems for nonstockpile chemical materiel: the rapid response system (RRS), the munitions management device (MMD), and the explosive destruction system (EDS). This report supplements an earlier report that evaluated eight alternative technologies for destruction of the liquid waste streams from two of the U.S. Army's transportable treatment systems for nonstockpile chemical materiel: the RRS and the MMD. This report evaluates the same technologies for the destruction of liquid waste streams produced by the EDS and discusses the regulatory approval issues and obstacles for the combined use of the EDS and the alternative technologies that treat the EDS secondary waste streams. Although it focuses on the destruction of EDS neutralent, it also takes into consideration the ability of posttreatment technologies to process the more dilute water rinses that are used in the EDS following treatment with a reagent.

Review and Evaluation of Alternative Chemical Disposal Technologies

Author : Panel on Review and Evaluation of Alternative Chemical Disposal Technologies,Commission on Engineering and Technical Systems,Division on Engineering and Physical Sciences,National Research Council
Publisher : National Academies Press
Page : 273 pages
File Size : 40,9 Mb
Release : 1996-11-29
Category : Science
ISBN : 9780309553094

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Review and Evaluation of Alternative Chemical Disposal Technologies by Panel on Review and Evaluation of Alternative Chemical Disposal Technologies,Commission on Engineering and Technical Systems,Division on Engineering and Physical Sciences,National Research Council Pdf

In 1994 the National Research Council published Recommendations for the Disposal of Chemical Agents and Munitions, which assessed the status of various alternative destruction technologies in comparison to the Army's baseline incineration system. The volume's main finding was that no alternative technology was preferable to incineration but that work should continue on the neutralization technologies under Army consideration. In light of the fact that alternative technologies have evolved since the 1994 study, this new volume evaluates five Army-chosen alternatives to the baseline incineration system for the disposal of the bulk nerve and mustard agent stored in ton containers at Army sites located in Newport, Indiana, and Aberdeen, Maryland, respectively. The committee assessed each technology by conducting site visits to the locations of the technology proponent companies and by meeting with state regulators and citizens of the affected areas. This volume makes recommendations to the Army on which, if any, of the five technologies has reached a level of maturity appropriate for consideration for pilot-scale testing at the two affected sites.

Disposal of Neutralent Wastes

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review and Evaluation of the Army Non-Stockpile Chemical Materiel Disposal Program
Publisher : National Academies Press
Page : 78 pages
File Size : 48,9 Mb
Release : 2001-04-29
Category : Science
ISBN : 9780309072878

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Disposal of Neutralent Wastes by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review and Evaluation of the Army Non-Stockpile Chemical Materiel Disposal Program Pdf

Chemical warfare materiel (CWM) is a collection of diverse items that were used during 60 years of efforts by the United States to develop a capability for conducting chemical warfare. Nonstockpile CWM, which is not included in the current U.S. inventory of chemical munitions, includes buried materiel, recovered materiel, binary chemical weapons, former production facilities, and miscellaneous materiel. CWM that was buried in pits on former military sites is now being dug up as the land is being developed for other purposes. Other CWM is on or near the surface at former test and firing ranges. According to the Chemical Weapons Convention (CWC), which was ratified by the United States in April 1997, nonstockpile CWM items in storage at the time of ratification must be destroyed by 2007. The U.S. Army is the designated executive agent for destroying CWM. Nonstockpile CWM is being handled by the Non-Stockpile Chemical Materiel Program (NSCMP); stockpile CWM is the responsibility of the Chemical Stockpile Disposal Program. Because nonstockpile CWM is stored or buried in many locations, the Army is developing transportable disposal systems that can be moved from site to site as needed. The Army has plans to test prototypes of three transportable systems-the rapid response system (RRS), the munitions management device (MMD), and the explosive destruction system (EDS)-for accessing and destroying a range of nonstockpile chemical agents and militarized industrial chemicals. The RRS is designed to treat recovered chemical agent identification sets (CAIS), which contain small amounts of chemical agents and a variety of highly toxic industrial chemicals. The MMD is designed to treat nonexplosively configured chemical munitions. The EDS is designed to treat munitions containing chemical agents with energetics equivalent to three pounds of TNT or less. These munitions are considered too unstable to be transported or stored. A prototype EDS system has recently been tested in England by non-stockpile program personnel. Although originally proposed for evaluation in this report, no test data were available to the committee on the composition of wastes from the EDS. Therefore, alternative technologies for the destruction of EDS wastes will be discussed in a supplemental report in fall 2001. Treatment of solid wastes, such as metal munition bodies, packing materials, and carbon air filters, were excluded from this report. Review and Evaluation of the Army Non-Stockpile Chemical Materiel Disposal Program: Disposal of Neutralent Wastes evaluates the near-term (1999-2005) application of advanced (nonincineration) technologies, such as from the Army's Assembled Chemical Weapons Assessment Program and the Alternative Technologies and Approaches Project, in a semi-fixed, skid-mounted mode to process Rapid Response System, Munitions Management Device, and Explosive Destruction System liquid neutralization wastes.

Integrated Design of Alternative Technologies for Bulk-Only Chemical Agent Disposal Facilities

Author : National Research Council,Commission on Engineering and Technical Systems,Board on Army Science and Technology,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program
Publisher : National Academies Press
Page : 58 pages
File Size : 53,5 Mb
Release : 2000-06-19
Category : Technology & Engineering
ISBN : 9780309069458

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Integrated Design of Alternative Technologies for Bulk-Only Chemical Agent Disposal Facilities by National Research Council,Commission on Engineering and Technical Systems,Board on Army Science and Technology,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program Pdf

The U.S. Army is pilot testing chemical hydrolysis as a method for destroying the chemical agents stockpiled at Aberdeen, Maryland (HD mustard agent), and Newport, Indiana (VX nerve agent). The chemical agents at both locations, which are stored only in bulk ton containers, will be hydrolyzed (using aqueous sodium hydroxide for VX and water for HD) at slightly below the boiling temperature of the solution. The resulting hydrolysate at Aberdeen, which will contain thiodiglycol as the primary reaction product, will be treated by activated sludge biodegradation in sequencing batch reactors to oxidize organic constituents prior to discharge to an on-site federally owned wastewater treatment facility. The hydrolysate at Newport, which will contain a thiol amine and methyl phosphonic acid as the major reaction products, is not readily amenable to treatment by biodegradation. Therefore, organic constituents will be treated using supercritical water oxidation (SCWO). Integrated Design of Alternative Technologies for Bulk-Only Chemical Agent Disposal Facilities focuses on the overarching issues in the process designs integrating individual processing steps, including potential alternative configurations and process safety and reliability. This report reviews the acquisition design packages (ADPs) for the ABCDF and NECDF prepared by Stone and Webster Engineering Company for the U.S. Army.

Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons

Author : National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons
Publisher : National Academies Press
Page : 267 pages
File Size : 44,9 Mb
Release : 1999-12-24
Category : Science
ISBN : 9780309066396

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Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons by National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons Pdf

This report examines seven disposal technologies being considered by the U.S. government as alternative methods to the process of incineration for destroying mortars, rockets, land mines, and other weapons that contain chemical warfare agents, such as mustard gas. These weapons are considered especially dangerous because they contain both chemical warfare agent and explosive materials in an assembled package that must be disassembled for destruction. The study identifies the strengths and weaknesses and advantages and disadvantages of each technology and assesses their potential for full-scale implementation.

Analysis of Engineering Design Studies for Demilitarization of Assembled Chemical Weapons at Pueblo Chemical Depot

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II
Publisher : National Academies Press
Page : 113 pages
File Size : 47,6 Mb
Release : 2001-10-27
Category : Science
ISBN : 9780309076074

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Analysis of Engineering Design Studies for Demilitarization of Assembled Chemical Weapons at Pueblo Chemical Depot by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II Pdf

The Program Manager for Assembled Chemical Weapons Assessment (PMACWA) of the Department of Defense (DOD) requested the National Research Council (NRC) to assess the engineering design studies (EDSs) developed by Parsons/Honeywell and General Atomics for a chemical demilitarization facility to completely dispose of the assembled chemical weapons at the Pueblo Chemical Depot in Pueblo, Colorado. To accomplish the task, the NRC formed the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (ACW II Committee). This report presents the results of the committee's scientific and technical assessment, which will assist the Office of the Secretary of Defense in selecting the technology package for destroying the chemical munitions at Pueblo. The committee evaluated the engineering design packages proposed by the technology providers and the associated experimental studies that were performed to validate unproven unit operations. A significant part of the testing program involved expanding the technology base for the hydrolysis of energetic materials associated with assembled weapons. This process was a concern expressed by the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (ACW I Committee) in its original report in 1999 (NRC, 1999). The present study took place as the experimental studies were in progress. In some cases, tests for some of the supporting unit operations were not completed in time for the committee to incorporate results into its evaluation. In those cases, the committee identified and discussed potential problem areas in these operations. Based on its expertise and its aggressive data-gathering activities, the committee was able to conduct a comprehensive review of the test data that had been completed for the overall system design. This report summarizes the study.

Evaluation of Demonstration Test Results of Alternative Technologies for Demilitarization of Assembled Chemical Weapons

Author : National Research Council,Commission on Engineering and Technical Systems,Board on Army Science and Technology,Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons
Publisher : National Academies Press
Page : 53 pages
File Size : 41,6 Mb
Release : 2000-03-14
Category : Science
ISBN : 9780309068970

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Evaluation of Demonstration Test Results of Alternative Technologies for Demilitarization of Assembled Chemical Weapons by National Research Council,Commission on Engineering and Technical Systems,Board on Army Science and Technology,Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons Pdf

In 1996, the U.S. Congress enacted two laws, Public Law 104-201 (authorization legislation) and Public Law 104-208 (appropriation legislation), mandating that the U.S. Department of Defense (DOD) conduct an assessment of alternative technologies to the baseline incineration process for the demilitarization of assembled chemical munitions. The PMACWA had previously requested that the National Research Council (NRC) perform and publish an independent evaluation of the seven technologies packages that had been selected during earlier phases of the Assembled Chemical Weapons Assessment (ACWA) program and deliver a report by September 1, 1999. However, to meet that deadline, the NRC Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (ACW Committee) had to terminate its data-gathering activities on March 15, 1999, prior to the completion of demonstration tests. In September 1999, the PMACWA requested that the ACW Committee examine the reports of the demonstration tests and determine if the results changed the committee's original findings, recommendations, and comments. Evaluation of Demonstration Test Results of Alternative Technologies for Demilitarization of Assembled Chemical Weapons documents the committee's reassessment of the findings and recommendations in the original report, Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons.

Review of the Army Non-Stockpile Chemical Materiel Disposal Program

Author : National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Board on Army Science and Technology,Committee on Review and Evaluation of the Army Non-Stockpile Chemical Materiel Disposal Program
Publisher : National Academies Press
Page : 149 pages
File Size : 49,8 Mb
Release : 2000-01-03
Category : Political Science
ISBN : 9780309068796

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Review of the Army Non-Stockpile Chemical Materiel Disposal Program by National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Board on Army Science and Technology,Committee on Review and Evaluation of the Army Non-Stockpile Chemical Materiel Disposal Program Pdf

This study is a review and evaluation of the U.S. Army's Report to Congress on Alternative Approaches for the Treatment and Disposal of Chemical Agent Identification Sets (CAIS). CAIS are test kits that were used to train soldiers from 1928 to 1969 in defensive responses to a chemical attack. They contain samples of chemicals that had been or might have been used by opponents as chemical warfare agents. The Army's baseline approach for treating and disposing of CAIS has been to develop a mobile treatment system, called the Rapid Response System (RRS), which can be carried by several large over-the-road trailers.

Effluents from Alternative Demilitarization Technologies

Author : F.W. Holm
Publisher : Springer Science & Business Media
Page : 225 pages
File Size : 47,9 Mb
Release : 2012-12-06
Category : Technology & Engineering
ISBN : 9789401153102

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Effluents from Alternative Demilitarization Technologies by F.W. Holm Pdf

FRANCIS W. HOLM 30 Agua Sarca Road, Placitas, New Mexico 1. Overview The North Atlantic Treaty Organization (NATO) sponsored an Advanced Research in Prague, Czech Republic, on October 13-15, 1997, to collect and Workshop (ARW) study information on effluents from alternative demilitarization technologies and to report on these fmdings. The effluents, orprocess residues, identified for assessment at the workshop are generated by systems that have been proposed as alternatives to incineration technology for destruction of munitions, chemical warfare agent, and associated materials and debris. The alternative technologies analyzed are grouped into three categories based on process bulk operating temperature: low (0-200 C), medium (200-600 C), and high (600-3,500 C). Reaction types considered include hydrolysis, biodegradation, electrochemical oxidation, gas-phase high-temperature reduction, steam reforming, gasification, sulfur reactions, solvated electron chemistry, sodium reactions, supercritical water oxidation, wet air oxidation, and plasma torch technology. These ofprocesses, some of which have been studied categories represent a broad spectrum only in the laboratory and some of which are in commercial use for destruction of hazardous and toxic wastes. Some technologies have been developed and used for specific commercial applications; however, in all cases, research, development, test, and evaluation (RDT&E) is necessary to assure that each technology application is effective for destroying chemical warfare materiel. Table 1 contains a list of more than 40 technologies from a recent report for the U.S. Army [1]. Many ofthe technologies in Table 1 are based on similar principles.

Recommendations for the Disposal of Chemical Agents and Munitions

Author : National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program
Publisher : National Academies Press
Page : 221 pages
File Size : 42,6 Mb
Release : 1994-02-01
Category : Science
ISBN : 9780309050463

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Recommendations for the Disposal of Chemical Agents and Munitions by National Research Council,Division on Engineering and Physical Sciences,Commission on Engineering and Technical Systems,Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program Pdf

The U.S. Army's chemical stockpile is aging and gradually deteriorating. Its elimination has public, political, and environmental ramifications. The U.S. Department of Defense has designated the Department of the Army as the executive agent responsible for the safe, timely, and effective elimination of the chemical stockpile. This book provides recommendations on the direction the Army should take in pursuing and completing its Chemical Stockpile Disposal Program.

Evaluation of Chemical Events at Army Chemical Agent Disposal Facilities

Author : National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Evaluation of Chemical Events at Army Chemical Agent Disposal Facilities
Publisher : National Academies Press
Page : 134 pages
File Size : 42,8 Mb
Release : 2002-12-25
Category : Science
ISBN : 9780309086295

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Evaluation of Chemical Events at Army Chemical Agent Disposal Facilities by National Research Council,Division on Engineering and Physical Sciences,Board on Army Science and Technology,Committee on Evaluation of Chemical Events at Army Chemical Agent Disposal Facilities Pdf

For over a decade the Army has been carrying out a program aimed at the destruction of accumulated chemical weapons stored at several sites. While destruction by incineration has been successful, several incidentsâ€"called chemical eventsâ€"occurred during the disposal process or decontamination activities that raised some public concerns about the safety of operations of three third generation incineration facilities. As a result, the Congress asked the NRC to investigate whether the incidents provide information useful to help ensure safe operation of the future sites. This book presents an analysis of causes of and responses to past chemical events, implications of such events for ongoing and future demilitarization activities, and recommendations for preparing for future events.

Department of Defense Appropriations for Fiscal Year 1997

Author : United States. Congress. Senate. Committee on Appropriations. Subcommittee on Defense
Publisher : Unknown
Page : 984 pages
File Size : 54,7 Mb
Release : 1997
Category : Business & Economics
ISBN : UCR:31210010687919

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Department of Defense Appropriations for Fiscal Year 1997 by United States. Congress. Senate. Committee on Appropriations. Subcommittee on Defense Pdf