Room Temperature Organic Synthesis

Author : Goutam Brahmachari
Publisher : Elsevier
Page : 386 pages
File Size : 43,8 Mb
Release : 2015-03-19
Category : Science
ISBN : 9780128011386

Get Book

Room Temperature Organic Synthesis by Goutam Brahmachari Pdf

Filling a gap in the scientific literature, Room Temperature Organic Synthesis is unique in its authoritative, thorough, and applied coverage of a wide variety of "green" organic synthetic methodologies. The book describes practical, feasible protocols for room temperature reactions to produce carbon-carbon and carbon-heteroatom bond formations including aliphatic, aromatic, alicyclic, heterocycles, and more. Consistently organized for easy access, each selected reaction is discussed in a very compact and structured manner including: reaction type, reaction condition, reaction strategy, catalyst, keywords, general reaction scheme, mechanism (in selected cases), representative entries, experimental procedure, characterization data of representative entries, and references. This book will be a valuable resource for synthetic organic, natural products, medicinal, and biochemists as well as those working in the pharmaceutical and agrochemical industry. Includes more than 300 protocols for a green approach to organic synthesis Provides specific detail about experimental conditions Increases efficiency in the laboratory by eliminating time-consuming literature searches

Author : P.A. Grieco
Publisher : Springer Science & Business Media
Page : 321 pages
File Size : 44,7 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401149501

Get Book

Organic Synthesis in Water by P.A. Grieco Pdf

The use of water as a medium for promoting organic reactions has been rather neglected in the development of organic synthesis, despite the fact that it is the solvent in which almost all biochemical processes take place. Chemists have only recently started to appreciate the enormous potential water has to offer in the development of new synthetic reactions and strategies, where it can offer benefits in both unique chemistry and reduced environmental impact. In this new book, the editor, well known for his contribution to the development of water as a useful medium in synthetic organic chemistry, has assembled an international team of authors, themselves at the forefront of research into the use of the unique properties of water carrying out organic transformations, to provide a timely and concise overview of current research. By focusing on the practical use of water in synthetic organic chemistry, and with the concern for the use of solvents in organic chemistry, professional chemists, particularly those involved in industrial research and development, will find this book an essential guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate and advanced undergraduate students, will find this book an invaluable guide to this exciting and important area of chemistry.

Author : Goutam Brahmachari
Publisher : Royal Society of Chemistry
Page : 392 pages
File Size : 42,5 Mb
Release : 2017-11-06
Category : Electronic
ISBN : 9781782624127

Get Book

Catalyst-free Organic Synthesis by Goutam Brahmachari Pdf

Author : Koichi Tanaka
Publisher : John Wiley & Sons
Page : 442 pages
File Size : 41,5 Mb
Release : 2006-03-06
Category : Science
ISBN : 9783527605361

Get Book

Solvent-free Organic Synthesis by Koichi Tanaka Pdf

The demand for increasingly clean and efficient chemical syntheses is continuously becoming more urgent from both an economic and an environmental standpoint. So-called green technologies are looking for alternatives, yet they focus on large quantities of hazardous even toxic solvents. One could even say that the best solvent is no solvent. It is against this background that chemical synthesis without the use of solvents has increasingly developed into a powerful methodology. Once the chemical reactivity is increased, the amount of initial substances needed is reduced; in particular it removes the need for the complex recycling and disposal of solvents. In this book, the third in our open "Green Chemistry" series, Koichi Tanaka describes the latest developments in this exciting field. Packed with advice on applications, this will be equally useful to practitioners in research as well as process chemists in industry, such that it is sure to become an invaluable reference source.

Author : Jie Jack Li,Chris Limberakis,Derek A. Pflum
Publisher : Oxford University Press
Page : 224 pages
File Size : 54,9 Mb
Release : 2007-09-10
Category : Science
ISBN : 9780199884896

Get Book

Modern Organic Synthesis in the Laboratory by Jie Jack Li,Chris Limberakis,Derek A. Pflum Pdf

Searching for reaction in organic synthesis has been made much easier in the current age of computer databases. However, the dilemma now is which procedure one selects among the ocean of choices. Especially for novices in the laboratory, it becomes a daunting task to decide what reaction conditions to experiment with first in order to have the best chance of success. This collection intends to serve as an "older and wiser lab-mate" one could have by compiling many of the most commonly used experimental procedures in organic synthesis. With chapters that cover such topics as functional group manipulations, oxidation, reduction, and carbon-carbon bond formation, Modern Organic Synthesis in the Laboratory will be useful for both graduate students and professors in organic chemistry and medicinal chemists in the pharmaceutical and agrochemical industries.

Author : Nicola Petragnani,Hélio A. Stefani
Publisher : Elsevier
Page : 398 pages
File Size : 52,7 Mb
Release : 2010-07-07
Category : Science
ISBN : 0080474926

Get Book

Tellurium in Organic Synthesis by Nicola Petragnani,Hélio A. Stefani Pdf

The increasing number of publications that use tellurium clearly demonstrates the important role of tellurium compounds as unique and powerful tools in a broad range of organic chemical manipulations, often characterized by their selective behavior. Tellurium in Organic Synthesis provides an overview of the principal aspects of organic tellurium chemistry. Many chapters have been enriched and updated in this second edition. New chapters include overviews of toxicology and pharmacology and a review on the preparation and reactivity of several tellurium heterocycles. The first part of the book focuses on the preparation of selected inorganic tellurium compounds and on the main classes of organotellurium compounds. The second part, and main interest of the book, details the use of these inorganic and organic compounds as reagents to perform specific organic manipulations and synthesis. Reactions covered include reduction, formation and reaction of anionic species, deprotection, tellurium cyclizations, formation of alkenes, use of vinyllic tellurides, free radical chemistry, transmetallations, and removal of tellurium. Overview of inorganic and organic tellurium chemistry Synthetic applications of tellurium compounds All topics accompanied by detailed experimental procedures

Author : Davor Margetic
Publisher : Walter de Gruyter GmbH & Co KG
Page : 326 pages
File Size : 53,6 Mb
Release : 2019-07-08
Category : Science
ISBN : 9783110556025

Get Book

High Pressure Organic Synthesis by Davor Margetic Pdf

High pressure chemistry is a widely used methodology in organic synthesis which helps to increase the rate and to improve the efficiency of chemical processes. The current publication outlines the impact of pressure on many types of chemical reactions important from synthetic point of view and gives practical considerations how to plan and perform synthetic experiments under high pressure in the lab.

Author : David J. Procter,Robert A. Flowers,Troels Skrydstrup
Publisher : Royal Society of Chemistry
Page : 221 pages
File Size : 42,5 Mb
Release : 2010
Category : Science
ISBN : 9781847551108

Get Book

Organic Synthesis Using Samarium Diiodide by David J. Procter,Robert A. Flowers,Troels Skrydstrup Pdf

Samarium diiodide is one of the most important reducing agents available to synthetic organic chemists. The lanthanide(II) reagent acts by single-electron transfer to organic substrates leading to the formation of both radical and/or anionic intermediates. The power of the reagent arises from its versatility - samarium diiodide can be used in processes ranging from functional group conversions to elaborate carbon-carbon bond-forming cyclization sequences that result in a dramatic increase in molecular complexity. In addition, reactions involving samarium diiodide often show high stereoselectivity as samarium ions can coordinate to Lewis basic sites on substrates and can direct the stereochemical course of reactions. The ability to fine-tune the reactivity of the reagent by the use of additives and co-solvents is an additional, attractive feature. Although samarium diiodide is used extensively by organic chemists, there is still a widely held view that the reagent can be difficult to prepare and use. In addition, samarium diiodide can mediate such a wide variety of organic chemistry that potential new users are often overawed by the extensive primary literature on the reagent. The objective of this book is to provide a concise, practical guide to the reagent. Rather than being a comprehensive review of the chemistry of samarium diiodide, this user-friendly book adopts an "an all you need to know" approach to the topic. The international authors are well-known for their work with the reagent and their expertise covers current developments in new reactivity and selectivity, applications in target synthesis, co-solvent and additive effects, coordination chemistry and mechanism. The book includes the best methods for preparing and handling the reagent, how solvents, co-solvents and additives alter reactivity, the basic mechanisms of reactions, common transformations using the reagent, and emerging areas in samarium diiodide chemistry. The authors have distilled the extensive primary literature to allow the reader to quickly grasp an understanding of the reagent and its utility. The illustrative practical procedures help the reader to prepare and use the reagent in the laboratory while references from the recent literature allow readers to pursue their interest in the popular reagent. The book also contains many illustrations and chemical schemes.

Author : Dmitry V. Liskin,Penny Chaloner
Publisher : CRC Press
Page : 131 pages
File Size : 48,5 Mb
Release : 2015-11-04
Category : Medical
ISBN : 9781482244977

Get Book

Advanced Organic Synthesis by Dmitry V. Liskin,Penny Chaloner Pdf

Laboratory experience equips students with techniques that are necessary for professional practice. Advanced Organic Synthesis: A Laboratory Manual focuses on a mechanistic background of key reactions in organic chemistry, gives insight into well-established trends, and introduces new developments in the field.The book features experiments performe

Author : Kiyoshi Matsumoto,R. Morrin Acheson
Publisher : Wiley-Interscience
Page : 480 pages
File Size : 46,9 Mb
Release : 1991-04-12
Category : Science
ISBN : UOM:39015019816605

Get Book

Organic Synthesis at High Pressures by Kiyoshi Matsumoto,R. Morrin Acheson Pdf

Presented here is a state-of-the-art examination of organic syntheses at high pressures designed to help synthetic organic chemists decide whether high pressure technology, with its advantages and limitations, might or might not be useful in solving their current problems. Following the introduction, chapters cover the basic principles, mechanisms, apparatus and operation of using high pressure technology. Further explores specific reactions and how they relate to various chemical compounds under high pressure.

Author : Davor Margetic,Vjekoslav Štrukil
Publisher : Elsevier
Page : 386 pages
File Size : 41,9 Mb
Release : 2016-04-23
Category : Science
ISBN : 9780128025253

Get Book

Mechanochemical Organic Synthesis by Davor Margetic,Vjekoslav Štrukil Pdf

Mechanochemical Organic Synthesis is a comprehensive reference that not only synthesizes the current literature but also offers practical protocols that industrial and academic scientists can immediately put to use in their daily work. Increasing interest in green chemistry has led to the development of numerous environmentally-friendly methodologies for the synthesis of organic molecules of interest. Amongst the green methodologies drawing attention, mechanochemistry is emerging as a promising method to circumvent the use of toxic solvents and reagents as well as to increase energy efficiency. The development of synthetic strategies that require less, or the minimal, amount of energy to carry out a specific reaction with optimum productivity is of vital importance for large-scale industrial production. Experimental procedures at room temperature are the mildest reaction conditions (essentially required for many temperature-sensitive organic substrates as a key step in multi-step sequence reactions) and are the core of mechanochemical organic synthesis. This green synthetic method is now emerging in a very progressive manner and until now, there is no book that reviews the recent developments in this area. Features cutting-edge research in the field of mechanochemical organic synthesis for more sustainable reactions Integrates advances in green chemistry research into industrial applications and process development Focuses on designing techniques in organic synthesis directed toward mild reaction conditions Includes global coverage of mechanochemical synthetic protocols for the generation of organic compounds

Author : Okram Mukherjee Singh,Thokchom Prasanta Singh
Publisher : Cambridge Scholars Publishing
Page : 387 pages
File Size : 52,5 Mb
Release : 2022-09-23
Category : Science
ISBN : 9781527588677

Get Book

Versatile Precursors in Organic Synthesis by Okram Mukherjee Singh,Thokchom Prasanta Singh Pdf

This book elaborates on the synthesis of versatile precursors and their applications in organic synthesis through a systematic approach. It shows that understanding the chemical properties of different types of versatile building blocks is essential for the successful execution of organic synthesis. The text also discusses how a particular type of precursor is used in the preparation of different types of simple and complex organic compounds, depending on reaction conditions and other substrates.

Author : Tse-Lok Ho
Publisher : World Scientific
Page : 400 pages
File Size : 47,8 Mb
Release : 1998-06-23
Category : Science
ISBN : 9789814497008

Get Book

Distinctive Techniques for Organic Synthesis by Tse-Lok Ho Pdf

This important book is intended to familiarize the practitioner of synthetic chemistry with somewhat extraordinary techniques which should prove very helpful to his or her work. It covers some reactions or techniques for organic synthesis which are not found in most introductory texts. They include reactions under high pressure, mediated by ultrasonic, flash vacuum pyrolysis, photochemical processes, phase transfer reactions, electrochemical reactions, and reactions on solid supports. The emphasis of the book is on applications. Examples are often drawn from significant contributions, such as natural product syntheses. Contents:Phase Transfer ReactionsReactions with Solid-Supported Reagents and CatalystsSonochemistryHigh Pressure ReactionsFlash Vacuum Pyrolysis and Some Other Thermal ProcessesElectroorganic TransformationsOrganic Photochemistry Readership: Organic chemists. keywords:

Author : Charles K. Zercher
Publisher : John Wiley & Sons
Page : 1606 pages
File Size : 50,6 Mb
Release : 2015-10-19
Category : Science
ISBN : 9781118117828

Get Book

Organic Syntheses, Collective Volume 12 by Charles K. Zercher Pdf

Continuing the tradition of providing significant and interesting procedures, Organic Syntheses, Collective Volume XII is a compilation of revised editions of Annual Volumes 85 through 89. The contents of this volume are organized by primarily by reaction type, with the precise classification made according to the bias of the editor, who attempted to ascertain the primary purpose or utility of the procedure.

Author : Shoubhik Das
Publisher : John Wiley & Sons
Page : 623 pages
File Size : 43,8 Mb
Release : 2020-09-16
Category : Science
ISBN : 9783527821969

Get Book

CO2 as a Building Block in Organic Synthesis by Shoubhik Das Pdf

A guide to the fascinating application of CO2 as a building block in organic synthesis This important book explores modern organic synthesis’ use of the cheap, non-toxic and abundant chemical CO2as an attractive C1 building block. With contributions from an international panel of experts, CO2 as a Building Block in Organic Synthesis offers a review of the most important reactions which use CO2 as a building block in organic synthesis. The contributors examine a wide-range of CO2 reactions including methylation reactions, CH bond functionalization, carboxylation, cyclic carbonate synthesis, multicomponent reactions, and many more. The book reviews the most recent developments in the field and also: Presents the most important reactions like CH-bond functionalization, carboxylation, carbonate synthesis and many more Contains contributions from an international panel of experts Offers a comprehensive resource for academics and professionals in the field Written for organic chemists, chemists working with or on organometallics, catalytic chemists, pharmaceutical chemists, and chemists in industry, CO2 as Building Block in Organic Synthesis contains an analysis of the most important reactions which use CO2 as an effective building block in organic synthesis.