Silicon Based Polymers

Author : François Ganachaud,Sylvie Boileau,Bruno Boury
Publisher : Springer Science & Business Media
Page : 285 pages
File Size : 51,7 Mb
Release : 2008-08-09
Category : Technology & Engineering
ISBN : 9781402085284

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Silicon Based Polymers by François Ganachaud,Sylvie Boileau,Bruno Boury Pdf

Silicon Based Polymers presents highlights in advanced research and technological innovations using macromolecular organosilicon compounds and systems, as presented in the 2007 ISPO congress. Silicon-containing materials and polymers are used all over the world and in a variety of industries, domestic products and high technology applications. Among them, silicones are certainly the most well–known, however there are still new properties discovered and preparative processes developed all the time, therefore adding to their potential. Less known, but in preparation for the future, are other silicon containing-polymers which are now close to maturity and in fact some are already available like polysilsesquioxanes and polysilanes. All these silicon based materials can adopt very different structures like chains, dendrimers, hyperbranched and networks, physical and chemical gels. The result is a vast array of materials with applications in various areas such as optics, electronics, ionic electrolytes, liquid crystals, biomaterials, ceramics and concrete, paints and coatings ... all needed to face the environmental, energetical and technological issues of today. Some industrial aspects of the applications of these materials will also be presented.

Author : Jerzy J. Chruściel
Publisher : Walter de Gruyter GmbH & Co KG
Page : 428 pages
File Size : 40,8 Mb
Release : 2022-03-07
Category : Technology & Engineering
ISBN : 9783110643671

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Silicon-Based Polymers and Materials by Jerzy J. Chruściel Pdf

Silicon based materials and polymers are made of silicon containing polymers, mainly macromolecular siloxanes (silicones). This book covers the different kinds of siliconbased polymers: silicones, silsesquioxanes (POSS), and silicon-based copolymers. Other silicon containig polymers: polycarbosilanes, polysilazanes, siloxane-organic copolymers, silicon derived high-tech ceramics: silicon carbide and oxycarbide, silicon nitride, etc. have also a very important practical meaning and a hudge number of practical applications. These materials make up products in a variety of industries and products, including technical and medical applicatons. Polycrystalline silicon is the basic material for large scale photovoltaic (PV) applications as solar cells. Technical applications of crystalline (c-Si) and amorphous (a-Si) silicon (fully inorganic materials), silicon nanowires are still quickly growing, especially in the fi eld of microelectronics, optoelectronics, photonics. and photovoltaics, catalysts, and different electronic devices (e.g. sensors, thermoelectric devices). This book is ideal for researchers and as such covers the industrial perspective of using each class of silicon based materials. Discusses silanes, silane coupling agents (SCA), silica, silicates, silane modified fillers, silsesquioxanes, silicones, and other silicon polymers and copolymers for practical applications as polymeric materials and very useful ingredients in materials science.

Author : R.G. Jones,W. Ando,Julian Chojnowski
Publisher : Springer Science & Business Media
Page : 766 pages
File Size : 48,9 Mb
Release : 2013-11-11
Category : Science
ISBN : 9789401139397

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Silicon-Containing Polymers by R.G. Jones,W. Ando,Julian Chojnowski Pdf

BACKGROUND Polysiloxanes have chains constructed of alternately arranged silicon and oxygen atoms with organic groups attached to the silicon atoms. This structure gives them a unique combination of properties that hold great interest for a host of practical applications. Although they have been known and manufactured for many years, their applications continue to expand rapidly and this boosts progress in the generation of new and modified polysiloxanes. Polysiloxanes constitute the oldf'"' known class of silicon-based polymers and the broadest one when viewed in terms of the variety of structures differing in topology and the constitution of organic substituents. There are also many and various types of siloxane copolymers, some of purely siloxane structure and others of siloxane-organic composition. There is no doubt that polysiloxanes are the most technologically important silicon-based polymers. The broad class of model materials known as silicones is based on polysiloxanes. They are also the best known, as most research in the area of silicon polymers has for many years been directed towards the synthesis of new polysiloxanes, to understanding their properties and to extending their applications.

Author : John Martin Zeigler,F. W. Gordon Fearon
Publisher : Unknown
Page : 840 pages
File Size : 40,6 Mb
Release : 1990
Category : Language Arts & Disciplines
ISBN : UOM:39015017921803

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Silicon-based Polymer Science by John Martin Zeigler,F. W. Gordon Fearon Pdf

This book provides the first unified reference work for silicon-based polymers. It brings together in one volume research on the synthesis, properties, chemistry, electronic structure, applications, and technology of these materials. The volume is built around a series of critical overviews of these rapidly advancing fields and is supplemented by a substantial number of shorter papers that focus on current findings. It also provides insight into possible directions for future scientific and technological advances in the field.

Author : Aziz M. Muzafarov
Publisher : Springer Science & Business Media
Page : 242 pages
File Size : 47,8 Mb
Release : 2010-09-22
Category : Technology & Engineering
ISBN : 9783642160479

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Silicon Polymers by Aziz M. Muzafarov Pdf

Modern Synthetic and Application Aspects of Polysilanes: An Underestimated Class of Materials?, by A. Feigl, A. Bockholt, J. Weis, and B. Rieger; * Conjugated Organosilicon Materials for Organic Electronics and Photonics, by Sergei A. Ponomarenko and Stephan Kirchmeyer; * Polycarbosilanes Based on Silicon-Carbon Cyclic Monomers, by E.Sh. Finkelshtein, N.V. Ushakov, and M.L. Gringolts; * New Synthetic Strategies for Structured Silicones Using B(C6F5)3, by Michael A. Brook, John B. Grande, and François Ganachaud; * Polyhedral Oligomeric Silsesquioxanes with Controlled Structure: Formation and Application in New Si-Based Polymer Systems, by Yusuke Kawakami, Yuriko Kakihana, Akio Miyazato, Seiji Tateyama, and Md. Asadul Hoque;

Author : Roger De Jaeger
Publisher : Unknown
Page : 522 pages
File Size : 45,5 Mb
Release : 2008
Category : Science
ISBN : STANFORD:36105131682762

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Silicon-based Inorganic Polymers by Roger De Jaeger Pdf

Inorganic polymers are large molecules, usually linear or branched chains with atoms other than carbon in their backbone. In this new advanced research book, silicon-based inorganic polymers are treated by J Cypryk (Poland), G. Kickelbick (Austria), X. Coqueret (France), A. Colas (Belgium), J. Koe (Japan), W. Uhlig (Switzerland), and by M. Rehahn and M. Weinmann (Germany). Different aspects of phosphorus-containing macromolecules are described by F.F. Stewart (USA), R. De Jaeger and L. Montagne (France), and by M. Carenza, S. Lora, and M.Gleria (Italy). Tin- and germanium-based polymers are illustrated by M. Okano (Japan), while inorganic dendrimers are presented by A.M. Caminade and J.P. Majoral (France) and by V. Balzani (Italy). Miscellaneous topics covering the flame-retardant and the intumescent behavior of the inorganic macromolecules (S. Bourbigot, France), ionically-conductive inorganic macromolecules (E. Montoneri, Italy) and chiral inorganic polymers (G.A. Carriedo and J.F. Garcia-Alonso, Spain) are also addressed.

Author : Ignazio Blanco
Publisher : MDPI
Page : 188 pages
File Size : 49,7 Mb
Release : 2019-07-11
Category : Technology & Engineering
ISBN : 9783038971252

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Siloxane-Based Polymers by Ignazio Blanco Pdf

This book, a collection of 12 original contributions and 4 reviews, provides a selection of the most recent advances in the preparation, characterization, and applications of polymeric nanocomposites comprising nanoparticles. The concept of nanoparticle-reinforced polymers came about three decades ago, following the outstanding discovery of fullerenes and carbon nanotubes. One of the main ideas behind this approach is to improve the matrix mechanical performance. The nanoparticles exhibit higher specific surface area, surface energy, and density compared to microparticles and, hence, lower nanofiller concentrations are needed to attain properties comparable to, or even better than, those obtained by conventional microfiller loadings, which facilitates processing and minimizes the increase in composite weight. The addition of nanoparticles into different polymer matrices opens up an important research area in the field of composite materials. Moreover, many different types of inorganic nanoparticles, such as quantum dots, metal oxides, and ceramic and metallic nanoparticles, have been incorporated into polymers for their application in a wide range of fields, ranging from medicine to photovoltaics, packaging, and structural applications.

Author : Paul M. Zelisko
Publisher : Wiley
Page : 480 pages
File Size : 53,7 Mb
Release : 2015-06-15
Category : Technology & Engineering
ISBN : 0470942363

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Synthesis, Properties, and Applications of Silicon-Based Polymers by Paul M. Zelisko Pdf

With their flexible Si-O-Si linkages, silicone polymers have unique physical properties that cannot be matched by purely organic polymer systems. Presenting comprehensive overviews of the successes and shortcomings of existing technologies and methodologies, Synthesis, Properties, and Applications of Silicon-Based Polymers provides insights into future directions for silicon-based polymer systems. By gathering the vast information available into a single resource, the author provides academics with a comprehensive understanding of the field, the history behind the discoveries, and the opportunities for future development, as well as a framework to create new silicon-based polymers and subsequent applications for these systems.

Author : Walter Noll
Publisher : Elsevier
Page : 716 pages
File Size : 48,6 Mb
Release : 2012-12-02
Category : Technology & Engineering
ISBN : 9780323141406

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Chemistry and Technology of Silicones by Walter Noll Pdf

Chemistry and Technology of Silicones retains the nature of a monograph despite its expanded scope, giving the reader in condensed form not only a wide-ranging but also a thorough review of this rapidly growing field. In contrast to some other monographs on organosilicon compounds that have appeared in the interim, the silicones occupy in this edition the central position, and the technological part of the work is entirely devoted to them. This book comprises 12 chapters, and begins with a general discussion of the chemistry and molecular structure of the silicones. The following chapters then discuss preparation of silanes with nonfunctional organic substituents; monomeric organosilicon compounds RnSiX4-n; and organosilanes with organofunctional groups. Other chapters cover preparation of polyorganosiloxanes; the polymeric organosiloxanes; other organosilicon polymers; production of technical silicone products from polyorganosiloxanes; properties of technical products; applications of technical silicone products in various branches of industry; esters of silicic acid; and analytical methods. This book will be of interest to practitioners in the fields of molecular chemistry.

Author : Michael A. Brook
Publisher : Wiley-Interscience
Page : 704 pages
File Size : 51,9 Mb
Release : 1999-12-28
Category : Science
ISBN : 0471196584

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Silicon in Organic, Organometallic, and Polymer Chemistry by Michael A. Brook Pdf

A comprehensive, up-to-date reference to synthetic applications of organosilicon chemistry Organic, organometallic, and polymer chemistry as well as materials science all utilize silicon in various forms, yet there is little cross-fertilization of ideas and applications among the disciplines. This book presents a much-needed overview of silicon chemistry, allowing fundamental and applied scientists to take full advantage of progress made within and outside their primary fields of expertise. With an emphasis on the preparation and reactivity of silicon compounds in organic, organometallic, and polymer chemistry, the author examines a broad range of useful topics-from mechanisms to syntheses of and syntheses using different organofunctional silanes. Numerous schemes as well as up-to-date examples from academia and industry will help readers to solve current synthetic problems and explore ideas for future research. Clear, concise coverage includes: * The mechanistic basis for the development of new silicon-based reactions * Formation and cleavage of silane reagents and functional siliconheteroatom compounds * Silicones, silica, polysilanes, and other silicon-containing polymers * Properties of molecules containing silicon, including bioactivity * Methods for the preparation of Si-C compounds * Silicon in organic synthesis * An extensive functional group index for easy access to functional group transformations

Author : Michael Potter,Noel Rose
Publisher : Springer Science & Business Media
Page : 423 pages
File Size : 40,5 Mb
Release : 2012-12-06
Category : Medical
ISBN : 9783642852268

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Immunology of Silicones by Michael Potter,Noel Rose Pdf

This issue of Current Topics in Microbiology and Immunology records the proceedings of a Workshop on the Immunology of Sili cones held at the Natcher Conference Center, National Institutes of Health, Bethesda, Maryland, March 13 and 14, 1995. A large num ber of investigators from North America and Europe met to discuss available data on how the immune system responds to silicones and related materials. Some aspects of this field are controversial. Nonetheless, the meeting was marked by a civil and open ex change of scientific information and divergent interpretations, re flecting the traditions of scientific communication. Each invited participant was asked to submit an article sum marizing his/her presentation. Most of the papers are published as submitted, with only editorial changes to conform with the guide lines given to each contributor or revisions to clarify aspects of the paper. The papers should not be regarded as peer-reviewed publi cations. This preface will attempt to outline some of the immu nological areas of investigation relating to silicones.

Author : Aziz M. Muzafarov
Publisher : Springer
Page : 234 pages
File Size : 41,6 Mb
Release : 2010-12-02
Category : Technology & Engineering
ISBN : 3642160492

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Silicon Polymers by Aziz M. Muzafarov Pdf

Modern Synthetic and Application Aspects of Polysilanes: An Underestimated Class of Materials?, by A. Feigl, A. Bockholt, J. Weis, and B. Rieger; * Conjugated Organosilicon Materials for Organic Electronics and Photonics, by Sergei A. Ponomarenko and Stephan Kirchmeyer; * Polycarbosilanes Based on Silicon-Carbon Cyclic Monomers, by E.Sh. Finkelshtein, N.V. Ushakov, and M.L. Gringolts; * New Synthetic Strategies for Structured Silicones Using B(C6F5)3, by Michael A. Brook, John B. Grande, and François Ganachaud; * Polyhedral Oligomeric Silsesquioxanes with Controlled Structure: Formation and Application in New Si-Based Polymer Systems, by Yusuke Kawakami, Yuriko Kakihana, Akio Miyazato, Seiji Tateyama, and Md. Asadul Hoque;

Author : Paul M. Zelisko
Publisher : Springer
Page : 132 pages
File Size : 54,9 Mb
Release : 2014-11-14
Category : Science
ISBN : 9789401794398

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Bio-Inspired Silicon-Based Materials by Paul M. Zelisko Pdf

The contributed volume addresses a wide range of topics including, but not limited to, biotechnology, synthetic chemistry, polymer chemistry and materials chemistry. The book will serve as a specialized review of the field of biologically inspired silicon-based structures. Researchers studying biologically inspired silicon materials chemistry will find this volume invaluable.

Author : Roger De Jaeger
Publisher : Nova Science Publishers
Page : 516 pages
File Size : 50,5 Mb
Release : 2014-05-14
Category : Inorganic polymers
ISBN : 1608762564

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Silicon-based Inorganic Polymers by Roger De Jaeger Pdf

Author : Sahar Amiri,Mohammad Ali Semsarzadeh,Sanam Amiri
Publisher : Springer
Page : 60 pages
File Size : 44,5 Mb
Release : 2014-08-11
Category : Technology & Engineering
ISBN : 9783319092256

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Silicon Containing Copolymers by Sahar Amiri,Mohammad Ali Semsarzadeh,Sanam Amiri Pdf

Silicones have unique properties including thermal oxidative stability, low temperature flow, high compressibility, low surface tension, hydrophobicity and electric properties. These special properties have encouraged the exploration of alternative synthetic routes of well defined controlled microstructures of silicone copolymers, the subject of this Springer Brief. The authors explore the synthesis and characterization of notable block copolymers. Recent advances in controlled radical polymerization techniques leading to the facile synthesis of well-defined silicon based thermo reversible block copolymers are described along with atom transfer radical polymerization (ATRP), a technique utilized to develop well-defined functional thermo reversible block copolymers. The brief also focuses on Polyrotaxanes and their great potential as stimulus-responsive materials which produce poly (dimethyl siloxane) (PDMS) based thermo reversible block copolymers.