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Author : J. E. Fergusson
Publisher : Prentice Hall
Page : 330 pages
File Size : 46,5 Mb
Release : 1974
Category : Chemical bonds
ISBN : UCAL:B4477735
A chronicle of Jamestown, the first English colony to survive in the wilderness of the New World.
Author : Ronald James Gillespie
Publisher : Unknown
Page : 248 pages
File Size : 47,8 Mb
Release : 1972
Category : Science
ISBN : UOM:39076006403245
Author : Bozzano G Luisa
Publisher : Elsevier
Page : 395 pages
File Size : 52,6 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780444597328
The authors of this fourth volume in the series have reviewed the making and breaking of chemical bonds in a sophisticated manner. In particular, new pressures brought about by environmental concerns, larger demands for the medical and pharmaceutical sectors and economics of the market place are forcing us into demanding greater stereochemical control and better product yields for chemical reactions capable of producing useful products. The chapters are written by leading experts in this area and give excellent overviews of the strengths and weaknesses of the various methodologies.In Chapter 1 newer discoveries in such tried and true methods of C-C bond formation as alkylations and aldol reactions of metal enolates are reviewed. The author of Chapter 2 discusses the ability of ab-initio methods to justify the results of empirical observations in the field of transition metal derivatives of small molecules such as N2, CO2 and similar small molecules. Having established the strengths and weaknesses of the various approaches to such theoretical calculations, a more interesting approach to these methods is pursued, namely, their ability to predict, in those areas in which they are particularly strong and reliable, chemical and stereochemical events and/or results in advance of experiments, later carried out in the laboratory. Finally, Chapter 3 reviews the stereochemical results of electron transfer reactions in mononuclear copper compounds.
Author : D. L. Kepert
Publisher : Springer
Page : 250 pages
File Size : 51,7 Mb
Release : 1982
Category : Science
ISBN : UOM:39015016003454
Molecular stereochemistry is a fundamental aspect of all areas of chemistry. It is especially important in inorganic chemistry where the coordination numbers are variable and occasionally quite high. The present book evolved naturally from a series of articles written by Professor Kepert for Progre88 in Inorganic Ohemi8try, elucida ting aspects of the stereochemistry of inorganic compounds of co ordination numbers 4-12. In the present volume, Professor Kepert has added new sections and synthesized these individual chapters into a unified treatment, updating his references when necessary to the most recent contributions in the literature, and inter weaving the various themes as deemed appropriate. The result is a major contribution, describing the stereochemistry of coordi nation compounds having both unidentate and multidentate ligands. The viability of the repulsion approach to stereochemistry is tested to the limit in this treatise and shown to be an extremely good way of rationalizing a diverse body of data.
Author : Roman Boča
Publisher : Unknown
Page : 198 pages
File Size : 45,9 Mb
Release : 1989-01-01
Category : Chemical bonds
ISBN : 3540507752
Author : Alison Rodger,Mark Rodger
Publisher : Butterworth-Heinemann
Page : 203 pages
File Size : 50,8 Mb
Release : 2014-05-16
Category : Science
ISBN : 9781483106038
Molecular Geometry discusses topics relevant to the arrangement of atoms. The book is comprised of seven chapters that tackle several areas of molecular geometry. Chapter 1 reviews the definition and determination of molecular geometry, while Chapter 2 discusses the unified view of stereochemistry and stereochemical changes. Chapter 3 covers the geometry of molecules of second row atoms, and Chapter 4 deals with the main group elements beyond the second row. The book also talks about the complexes of transition metals and f-block elements, and then covers the organometallic compounds and transition metal clusters. The last chapter tackles the consequences of small, local variations in geometry. The text will be of great use to chemists who primarily deal with the properties of molecules and atoms.
Author : Mandeep Dalal
Publisher : Dalal Institute
Page : 480 pages
File Size : 45,9 Mb
Release : 2017-01-01
Category : Science
ISBN : 9788193872000
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author : Jeremy K. Burdett
Publisher : John Wiley & Sons
Page : 316 pages
File Size : 52,6 Mb
Release : 1980
Category : Science
ISBN : UOM:39015055711025
Author : Brian J Hathaway,Clair Murphy,Brian Murphy
Publisher : Royal Society of Chemistry
Page : 165 pages
File Size : 42,8 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847550217
General chemistry textbooks are usually lengthy and present chemistry to the student as an unconnected list of facts. In inorganic chemistry, emphasis should be placed on the connections between valence shell electron configuration and the physical and chemical properties of the element. Basic Principles of Inorganic Chemistry: Making the Connections is a short, concise book that emphasises these connections, in particular the chemistry of the Main Group compounds. With reference to chemical properties, Lewis Structures, stoichiometry and spider diagrams, students will be able to predict or calculate the chemistry of simple polyatomic compounds from the valence shell configuration and will no longer be required to memorise vast amounts of factual chemistry. This book is ideal for students taking chemistry as a subsidiary subject as well as honours degree students.
Author : Bodie Eugene Douglas,Darl Hamilton McDaniel
Publisher : Unknown
Page : 552 pages
File Size : 46,5 Mb
Release : 1965
Category : Chemistry
ISBN : UCAL:B3651955
Atomic structure and the periodic table; Covalent substances; Ionic substances; Thermodynamic considerations; The hydrogen bond; Acids and bases; The halogens; Electron deficient compounds; Metals; Coordination compounds-structure and bonding, stability and reaction mechanisms; Experimental methods for the elucidation of structure and bonding of chemical compounds.
Author : Ulrich Müller
Publisher : John Wiley & Sons
Page : 280 pages
File Size : 40,6 Mb
Release : 2007-09-27
Category : Science
ISBN : 9780470057261
The essential introduction to the understanding of the structure of inorganic solids and materials. This revised and updated 2nd Edition looks at new developments and research results within Structural Inorganic Chemistry in a number of ways, special attention is paid to crystalline solids, elucidation and description of the spatial order of atoms within a chemical compound. Structural principles of inorganic molecules and solids are described through traditional concepts, modern bond-theoretical theories, as well as taking symmetry as a leading principle.
Author : Bodie E. Douglas,Darl H. McDaniel,John J. Alexander
Publisher : Unknown
Page : 312 pages
File Size : 41,6 Mb
Release : 1983-08-31
Category : Science
ISBN : UOM:39015030292273
A clear introduction to modern inorganic chemistry. Covering both theory and descriptive chemistry, the text begins with atomic structure, bonding, and stereochemistry and then treats inorganic solids, acids and bases, and bioinorganic chemistry. This second edition includes optional sections on group theory, very thorough discussions of inorganic solids, and expanded material on subjects such as the mechanisms of reactions and bioinorganic chemistry. Presents numerous figures to encourage ``model-thinking'' and provides solved examples.
Author : D. P. Graddon
Publisher : Elsevier
Page : 173 pages
File Size : 46,9 Mb
Release : 2017-05-25
Category : Science
ISBN : 9781483184111
An Introduction to Co-Ordination Chemistry, Second Edition covers the fundamental aspects of co-ordination chemistry. The title is designed to introduce the readers to the basic principles and theories that govern co-ordination chemistry. The text first reviews the history of co-ordination chemistry, and then proceeds to discussing the modern theories of co-ordination chemistry. Next, the selection covers transition metal stereochemistry. Chapter IV talks about the stability of complex salts, while Chapter V deals with the stabilization of oxidation states. The text also covers carbonyls and II-complexes. In the last chapter, the title presents the practical applications of co-ordination chemistry. The book will be of great use to students, researchers, and practitioners of chemistry related disciplines.
Author : Nathaniel Warren Alcock
Publisher : Prentice Hall
Page : 332 pages
File Size : 45,6 Mb
Release : 1990
Category : Chemical bonds
ISBN : UOM:39076001450647
Author : Anonim
Publisher : Springer
Page : 198 pages
File Size : 53,9 Mb
Release : 2013-11-08
Category : Science
ISBN : 366215093X