Structure Reactivity And Thermochemistry Of Ions

Author : Pierre Ausloos,Sharon G. Lias
Publisher : Springer Science & Business Media
Page : 491 pages
File Size : 53,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400937871

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Structure/Reactivity and Thermochemistry of Ions by Pierre Ausloos,Sharon G. Lias Pdf

This volume presents the proceedings of a 1986 Advanced Study Institute entitled "Structure/Reactivity and Thermochemistry of Ions", held at Les Arcs, France, June 30 to July 11, 1986. The format of a NATO Institute is ideally suited to in-depth communications between scien tists of diverse backgrounds. Particularly in the field of ion physics and chemistry, where on-going research involves physicists, physical chemists, and organic chemists - who use a variety of experimental and theoretical techniques - it is found that in the relaxed but stimula ting atmosphere of a NATO ASI, each professional group provides unique insights, leading to a better definition and solution of problems relating to the properties of gas phase ions. This book presents chapters based on the lectures presented at the Les Arcs ASI. The participants took the initiative to organize a number of specialized workshops - informal discussion groups which considered questions or problem areas of particular interest. The accounts of these sessions, which are also included in this book, make stimulating reading, and include considerable useful information. This Advanced Study Institute is the fourth in a series of NATO-spon sored institutes devoted to the chemistry and physics of ions in the gas phase. The first, in 1974, in Biarritz, France, focussed on "Interactions between Ions and Molecules".

Author : M.A.V. Ribeiro Da Silva
Publisher : Springer Science & Business Media
Page : 840 pages
File Size : 54,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400963122

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Thermochemistry and Its Applications to Chemical and Biochemical Systems by M.A.V. Ribeiro Da Silva Pdf

Proceedings of the NATO Advanced Study Institute on Thermochemistry Today and Its Role in the Immediate Future, Viano do Castelo, Portugal, July 5-15, 1982

Author : James Keeler,Peter Wothers
Publisher : Oxford University Press
Page : 896 pages
File Size : 41,6 Mb
Release : 2013-11
Category : Science
ISBN : 9780199604135

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Chemical Structure and Reactivity by James Keeler,Peter Wothers Pdf

Chemical Structure and Reactivity: An Integrated Approach rises to the challenge of depicting the reality of chemistry. Offering a fresh approach, it depicts the subject as a seamless discipline, showing how organic, inorganic, and physical concepts can be blended together to achieve the common goal of understanding chemical systems.

Author : B.S. Freiser
Publisher : Springer Science & Business Media
Page : 341 pages
File Size : 47,9 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400901117

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Organometallic Ion Chemistry by B.S. Freiser Pdf

A study covering the gas-phase chemistry of organometallic ions. Topics covered include: periodic trends in gas-phase thermochemistry of transition metal-ligand systems; ab initio calculations to determine electronic structure, geometric structure, and thermochemistry of metal-containing systems; electronic state effects on metal ion reactivity; organometallic ion photochemistry; and applications of gas-phase electron transfer equilibria in organometallic redox thermochemistry. Also included are state-of-the-art mass spectrometric instrumentation used in such studies. It also features a comprehensive list (containing over 1500 entries) of metal ion-ligand bond energies, obtained from theory and experiment.

Author : Michael Baer,Cheuk-Yiu Ng
Publisher : John Wiley & Sons
Page : 584 pages
File Size : 40,7 Mb
Release : 1992-04-16
Category : Science
ISBN : 0471532630

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State Selected and State-to-State Ion-Molecule Reaction Dynamics, Volume 82, Part 2 by Michael Baer,Cheuk-Yiu Ng Pdf

The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.

Author : Anonim
Publisher : Unknown
Page : 294 pages
File Size : 45,5 Mb
Release : 1987
Category : Military research
ISBN : UIUC:30112101042049

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Research in Progress by Anonim Pdf

Author : National Library of Medicine (U.S.)
Publisher : Unknown
Page : 1060 pages
File Size : 44,5 Mb
Release : 2024-07-02
Category : Medicine
ISBN : UOM:39015014049426

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Current Catalog by National Library of Medicine (U.S.) Pdf

First multi-year cumulation covers six years: 1965-70.

Author : National Library of Medicine (U.S.)
Publisher : Unknown
Page : 1068 pages
File Size : 44,7 Mb
Release : 1988
Category : Medicine
ISBN : MINN:31951000310404Q

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National Library of Medicine Current Catalog by National Library of Medicine (U.S.) Pdf

Author : John L. Holmes,Christiane Aubry,Paul M. Mayer
Publisher : CRC Press
Page : 468 pages
File Size : 49,7 Mb
Release : 2006-12-26
Category : Science
ISBN : 9780203492475

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Assigning Structures to Ions in Mass Spectrometry by John L. Holmes,Christiane Aubry,Paul M. Mayer Pdf

Assigning Structures to Ions in Mass Spectrometry describes the tools currently available for determining gas-phase ion structures. It surveys current experimental methods for ion production and separation as well as those designed to reveal qualitative and quantitative aspects of gas-phase ions. It also examines how and when to apply computational chemistry and theoretical calculations. Selected case studies illustrate specific challenges associated with ion structure assignment and thermochemical problems. Bringing together key results collected over the past four decades, the book contains the data for describing or identifying ions containing C alone and C with H, O, N, S, P, halogens, and small organic cations.

Author : David H. Russell
Publisher : Springer Science & Business Media
Page : 422 pages
File Size : 55,7 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781468455298

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Gas Phase Inorganic Chemistry by David H. Russell Pdf

The field of gas phase inorganic ion chemistry is relatively new; the early studies date back approximately twenty years, but there has been intense interest and development in the field in the last ten years. As with much of modern chemistry, the growth in gas phase inorganic ion chemistry can be traced to the development of instrumentation and new experimental methods. Studies in this area require sophisticated instruments and sample introduc tion/ ionization methods, and often these processes are complicated by the need for state-selecting (or collisionally stabilizing) the reactive species in order to assign the chemistry unequivocally. At the present level of experimental development, a wide range of experiments on diverse ionic systems are possible and many detailed aspects of the chemistry can be studied. Gas Phase Inorganic Chemistry focuses on the reactions of metal ions and metal clusters, and on the study of these species using the available modern spectroscopic methods. Three of the twelve chapters cover the chemistry of ionic monometal transition metal ions and the chemistry of these species with small diatomics and model organics. Two of the chapters focus on the studies of the chemical and physical properties of (primarily) transition metal clusters, and these chapters review experimental methods and capabilities. Two chapters also deal with the chemistry of transition metal carbonyl clusters, and these chapters address issues important to cluster growth and activation as well as the characterization of such species.

Author : William L Hase
Publisher : Elsevier
Page : 329 pages
File Size : 51,9 Mb
Release : 2016-07-29
Category : Science
ISBN : 9781483283623

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Dynamics of Ion-Molecule Complexes by William L Hase Pdf

Advances in Classical Trajectory Methods, Volume 2: Dynamics of Ion-Molecule Complexes is a seven-chapter text that covers the considerable advances in the experimental and theoretical aspects of ion-molecular complexes, with particular emphasis on the dynamics and kinetics of their formation and ensuing unimolecular dissociation. This text also considers the development and testing of theoretical models for these formation and decomposition processes. The opening chapters discuss photoelectron photoion coincidence, ion cyclotron resonance, and crossed molecular beam studies of metastable ion-molecule complexes formed in ion-molecule collisions. These experimental studies involve comparisons with the predictions of statistical models, such as the Rice-Ramsperger-Kassel-Marcus and phase space theories, and comparisons with the reaction dynamics predicted by classical trajectory calculations. The succeeding chapter describes the double-well model for ion-molecular reactions taking place on a potential energy surface with a central barrier that separates two potential energy minima. These topics are followed by reviews of the quantum chemical calculation and reaction path Hamiltonian analysis of SN2 reactions, the transition state theory for ion-dipole and ion-quadrupole capture, and the capture and dynamical models for ion-molecule association to form a complex. The remaining chapters consider the temperature dependence of ion-molecule reactions, which proceed on a surface with many potential energy minima, specifically the ability to establish asymptotic limits for the reaction efficiency dependent upon the number of potential minima and the above relative probabilities. This book is of great value to experimental and theoretical chemists and physicists.

Author : Cheuk-Yiu Ng,Michael Baer
Publisher : John Wiley & Sons
Page : 702 pages
File Size : 52,6 Mb
Release : 2009-09-09
Category : Technology & Engineering
ISBN : 9780470141922

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State Selected and State-to-State Ion-Molecule Reaction Dynamics, Volume 82, Part 1 by Cheuk-Yiu Ng,Michael Baer Pdf

State-Selected and State-to-State Ion-Molecules Reaction Dynamics details the recent experimental and theoretical accomplishments in the field to date by some of its foremost researchers and theorists. Divided into two parts, each of which separately describe the experimental and theoretical aspects of the field, State-Selected and State-to-State Ion-Molecule Reaction Dynamics is an accessible, well organized look at a highly useful and emerging chemical specialty. Part 1, "Experiment," contains eight in-depth studies, which illustrate the key experimental work being done in the field today: Chapter 1 provide a comprehensive review of the theory and application of inhomogeneous rf fields for the study of the dynamics of low-energy ion-molecules processes Chapter 2 describes the application of multiphoton ionization (MPI) for the preparation of reactant ion states Chapter 3 reviews the application of MPI schemes for state specific cross-section measurements involving transition metal cations Chapter 4 describes the development of the threshold photoelectron secondary ion coincidence (TESICO) method Chapter 5 presents the conceptual and practical aspects of a multicoincidence technique Chapter 6 details the experimental results obtained using the photoionization and differential reactivity methods Chapter 7 reviews the several recent crossed beam studies of charge transfer and collision-induced dissociation systems involving atomic and molecular ions Chapter 8 is a survey of 15 years of high resolution crossed beam scattering of protons with atoms, diatoms, and poly-atomic molecules State-Selected and State-to-State Ion-Molecule Reaction Dynamics, Part 1: Experiment offers professionals a true state-of-the-science look at this fascinating and increasingly influential subject.

Author : C. Chatgilialoglu,Klaus-Dieter Asmus
Publisher : Springer Science & Business Media
Page : 448 pages
File Size : 40,9 Mb
Release : 2013-03-08
Category : Science
ISBN : 9781468458749

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Sulfur-Centered Reactive Intermediates in Chemistry and Biology by C. Chatgilialoglu,Klaus-Dieter Asmus Pdf

A wonderfully successful NATO Advanced Study Institute on "Sulfur-Centered Reactive Intermediates in Chemistry and Biology" was held 18-30 June, 1989, at the Hotel Villa del Mare in Maratea, Italy. Despite the beautiful setting with mountains behind us and over looking the clear blue Mediterranean Sea under a cloudless sky (and with a private beach available), the lectures were extremely well attended. While some credit can go to the seriousness of the students, more must go to the calibre of speakers and the high quality of C. Chatgilialoglu, and Co-Director, Professor K. -D. their presentations. The Director, Dr. Asmus, are to be congratulated for putting together such an outstanding scientific program. Dr. Chatgilialoglu is also to be commended for arranging an equally stimulating social pro gram which included bus, train and boat trips to many local sites of interest. It was particularly fitting that a meeting on the chemistry and biochemistry of sulfur should be held in Italy since Italian chemists have made major contributions to our under standing of the organic chemistry of sulfur, including the chemistry of its reactive inter mediates. The early Italian interest in sulfur chemistry arose from the fact that Italy, or more specifically, Sicily, was a major world producer of sulfur prior to the development and exploitation of the Frasch process in Texas and Louisiana.

Author : K.R. Jennings
Publisher : Springer Science & Business Media
Page : 520 pages
File Size : 40,9 Mb
Release : 1999
Category : Science
ISBN : 079235463X

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Fundamentals and Applications of Gas Phase Ion Chemistry by K.R. Jennings Pdf

This book draws together leading workers in the fields of mass spectrometry and gas phase ion chemistry, providing a forum for the exchange of ideas and information. It contains 14 lecture summaries and accounts of seven workshops with contributions from Europe and North America.

Author : Elliot R. Bernstein
Publisher : Oxford University Press
Page : 272 pages
File Size : 45,8 Mb
Release : 1996-06-06
Category : Science
ISBN : 9780195358216

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Chemical Reactions in Clusters by Elliot R. Bernstein Pdf

This book covers important new developments of the last five years in the area of cluster chemistry, presenting an excellent view of the successes and shortcomings of both current state-of-the-art theory and experiment. Each chapter, contributed by a leading expert, places heavy emphasis on theory without which the detailed analysis of the spectroscopic and kinetic results would be compromised. The cluster reactions reviewed in this work include electron and proton transfer reactions, hot atom reactions, vibrational predissociation, radical reactions, and ionic reactions. Some of the theories applied throughout the text are product state distribution determinations, state-to-state dynamical information, and access to the transition stage of the reaction. The discussions serve as a benchmark of how far the field has come since the mid 1980's and will be a good update for students and researchers interested in this area of physical chemistry.