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Reaction Mechanisms in Sulphuric Acid and other Strong Acid Solutions by M Liler Pdf
Reaction Mechanisms in Sulfuric Acid and other Strong Acid Solutions covers the reactivity in sulfuric acid and other strongly acid solutions. This book is composed of five chapters that emphasize the measure of acidity of sulfuric acid and other acid solutions. Chapters 1 and 2 discuss the physical, thermodynamic, spectroscopic properties, and acidity functions of sulfuric acid/water mixtures. Chapters 3 and 4 examine the protonation and more complex modes of ionization of compounds in these acidic media. Chapter 5 outlines first the possible mechanisms of reactions in acid solutions followed by a discussion of mechanistic criteria that have been developed in order to distinguish between kinetically indistinguishable alternatives. This chapter also presents some methods of kinetic investigation, which are specific to concentrated sulfuric acid solutions. Inorganic chemists and researchers, teachers, and students will find this book invaluable.
Sulfuric Acid Manufacture by Matt King,Michael Moats,William G. Davenport Pdf
By some measure the most widely produced chemical in the world today, sulfuric acid has an extraordinary range of modern uses, including phosphate fertilizer production, explosives, glue, wood preservative and lead-acid batteries. An exceptionally corrosive and dangerous acid, production of sulfuric acid requires stringent adherence to environmental regulatory guidance within cost-efficient standards of production. This work provides an experience-based review of how sulfuric acid plants work, how they should be designed and how they should be operated for maximum sulfur capture and minimum environmental impact. Using a combination of practical experience and deep physical analysis, Davenport and King review sulfur manufacturing in the contemporary world where regulatory guidance is becoming ever tighter (and where new processes are being required to meet them), and where water consumption and energy considerations are being brought to bear on sulfuric acid plant operations. This 2e will examine in particular newly developed acid-making processes and new methods of minimizing unwanted sulfur emissions. The target readers are recently graduated science and engineering students who are entering the chemical industry and experienced professionals within chemical plant design companies, chemical plant production companies, sulfuric acid recycling companies and sulfuric acid users. They will use the book to design, control, optimize and operate sulfuric acid plants around the world. Unique mathematical analysis of sulfuric acid manufacturing processes, providing a sound basis for optimizing sulfuric acid manufacturing processes Analysis of recently developed sulfuric acid manufacturing techniques suggests advantages and disadvantages of the new processes from the energy and environmental points of view Analysis of tail gas sulfur capture processes indicates the best way to combine sulfuric acid making and tailgas sulfur-capture processes from the energy and environmental points of view Draws on industrial connections of the authors through years of hands-on experience in sulfuric acid manufacture
A Practical Guide to the Manufacture of Sulfuric Acid, Oleums, and Sulfonating Agents by Navin G. Ashar,Kiran R. Golwalkar Pdf
This critical volume provides practical insights on sulfuric acid and related plant design and on techniques to improve and enhance substantially the efficiency of an existing plant by means of small modifications. The book provides readers with a better understanding of the state-of-art in sulfuric acid manufacture as well as, importantly, in the manufacture of value-added products based on sulfur that are also associated with the manufacture of sulfuric acid. Overall, engineers and plant managers will be introduced to technologies for making their sulfuric acid enterprises more productive, remunerative, and environmentally friendly. A Practical Guide to the Manufacture of Sulfuric Acid, Oleums, and Sulfonating Agents covers sulfuric acid and derivative chemical plant details from the nuts-and-bolts level to a holistic perspective based on actual field experience. The book is indispensable to anyone involved in implementing a sulfuric acid or related chemical plant.
Sulphuric Utopias by Lukas Engelmann,Christos Lynteris Pdf
How early twentieth century fumigation technologies transformed maritime quarantine practices and inspired utopian visions of disease-free global trade. In the late nineteenth and early twentieth centuries, fumigation technologies transformed global practices of maritime quarantine through chemical and engineering innovation. One of these technologies, the widely used Clayton machine, blasted sulphuric acid gas through a docked ship in an effort to eliminate pathogens, insects, and rats while leaving the cargo and the structure of the vessel unharmed, shortening its time in quarantine and minimizing the risk of importing infectious diseases. In Sulphuric Utopias, Lukas Engelmann and Christos Lynteris examine this overlooked but historically crucial practice at the intersection of epidemiology, hygiene, applied chemistry, and engineering. They show how maritime fumigation inspired utopian visions of disease-free trade to improve global shipping and to encourage universally applicable standards of sanitation and hygiene. Engelmann and Lynteris chart the history of ideas about fumigation, disinfection, and quarantine, and chronicle the development of the Clayton machine in 1880s New Orleans. Built by the Louisiana Board of Health and adapted and patented by Thomas Clayton, the machine offered a barrier against bacteria and pests and enabled a highway to global trade. Engelmann and Lynteris chronicle the Clayton machine's success and examine its competitors, including carbon-based fumigation methods in Germany and the Ottoman Empire as well as the “Sulfurozador” in Argentina. They follow the international standardization of maritime fumigation and explore the Clayton machine's decline after World War I, when visions of “sulphuric utopia” were replaced by a pragmatic acknowledgment of epidemiological complexity.
Sulphur Trioxide, Oleum and Sulphuric Acid Mist by Richard Griffiths Pdf
Sulphur trioxide has a great affinity for water. It produces sulphuric acid with violence and liberation of great heat. If it escapes accidently it creates a sulphuric acid mist. This monograph explains what is known about the effects of sulphuric acid mist when it comes into contact with humans. It covers the properties, manufacture, storage and handling of sulphur trioxide and oleum and includes modelling of mist formation and dispersion. Five appendices detail exposure, animal studies and past incidents, with particular reference to the data required for computer modelling.
Author : Henry Arthur Smith Publisher : BoD – Books on Demand Page : 102 pages File Size : 45,7 Mb Release : 2023-07-13 Category : Fiction ISBN : 9783368175115