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When we use science to describe and understand the world around us, we are in essence grasping nature through symmetry. Emphasizing the concepts, this book leads the reader coherently and comprehensively into the fertile field of symmetry and its applications. Among the most important applications considered are the fundamental forces of nature and the Universe. Written by a renowned expert, this book will convince all interested readers of the importance of symmetry in science.
Symmetry and group theory provide us with a formal method for the description of the geometry of objects by describing the patterns in their structure. In chemistry it is a powerful method that underlies many apparently disparate phenomena. Symmetry allows us to accurately describe the types of bonding that can occur between atoms or groups of atoms in molecules. It also governs the transitions that may occur between energy levels in molecular systems, which in turn allows us to predict the absorption properties of molecules and hence their spectra. Molecular Symmetry lays out the formal language used in the area using illustrative examples of particular molecules throughout. It then applies the ideas of symmetry to describe molecular structure, bonding in molecules and consider the implications in spectroscopy. Topics covered include: Symmetry elements Symmetry operations and products of operations Point groups used with molecules Point group representations, matrices and basis sets Reducible and irreducible representations Applications in vibrational spectroscopy Symmetry in chemical bonding Molecular Symmetry is designed to introduce the subject by combining symmetry with spectroscopy in a clear and accessible manner. Each chapter ends with a summary of learning points, a selection of self-test questions, and suggestions for further reading. A set of appendices includes templates for paper models which will help students understand symmetry groups. Molecular Symmetry is a must-have introduction to this fundamental topic for students of chemistry, and will also find a place on the bookshelves of postgraduates and researchers looking for a broad and modern introduction to the subject.
Symmetry through the Eyes of a Chemist by Istvan Hargittai,Magdolna Hargittai Pdf
We have been gratified by the warm reception of our book, by reviewers, colleagues, and students alike. Our interest in the subject matter of this book has not decreased since its first appearance; on the contrary. The first and second editions envelop eight other symmetry-related books in the creation of which we have participated: I. Hargittai (ed.), Symmetry: Unifying Human Understanding, Pergamon Press, New York, 1986. I. Hargittai and B. K. Vainshtein (eds.), Crystal Symmetries. Shubnikov Centennial Papers, Pergamon Press, Oxford, 1988. M. Hargittai and I. Hargittai, Fedezziikf6l a szimmetri6t! (Discover Sym- try, in Hungarian), Tank6nyvkiad6, Budapest, 1989. I. Hargittai (ed.), Symmetry 2: Unifying Human Understanding, Pergamon Press, Oxford, 1989. I. Hargittai (ed.), Quasicrystals, Networks, and Molecules of Fivefold Sym- try, VCH, New York, 1990. I. Hargittai (ed.), Fivefold Symmetry, World Scientific, Singapore, 1992. I. Hargittai and C. A. Pickover (eds.), Spiral Symmetry, World Scientific, Singapore, 1992. I. Hargittai and M. Hargittai, Symmetry: A Unifying Concept, Shelter Publi- tions, Bolinas, California, 1994. We have also pursued our molecular structure research, and some books have appeared related to these activities: vi Preface to the Second Edition I. Hargittai and M. Hargittai (eds.), Stereochemical Applications of Gas-Phase Electron Diffraction, Parts A and B, VCH, New York, 1988. R. Gillespie and I. Hargittai, VSEPR Model of Molecular Geometry, Allyn and Bacon, Boston, 1991. A. Domenicano and I. Hargittai (eds.), Accurate Molecular Structures, Oxford University Press, Oxford, 1992.
Organic Reactions and Orbital Symmetry by T. L. Gilchrist,R. C. Storr Pdf
First published in 1979 as the second edition of a 1972 original, this textbook provides a systematic account of an important area of organic chemistry - that of cycloadditions and molecular rearrangements. The necessary theoretical background for understanding these reactions is presented in non-mathematical form and various alternative approaches to the theory are compared. The core of the book is a descriptive account of various types of cycloaddition and rearrangement reactions. The synthetic importance of these reactions is emphasised and, by providing the mechanistic background, the book demonstrates to the reader the relationship between the different types of reactions. This book will be of value to anyone with an interest in organic chemistry.
International Series in Modern Applied Mathematics and Computer Science, Volume 10: Symmetry: Unifying Human Understanding provides a tremendous scope of “symmetry , covering subjects from fractals through court dances to crystallography and literature. This book discusses the limits of perfection, symmetry as an aesthetic factor, extension of the Neumann-Minnigerode-Curie principle, and symmetry of point imperfections in solids. The symmetry rules for chemical reactions, matching and symmetry of graphs, mosaic patterns of H. J. Woods, and bilateral symmetry in insects are also elaborated. This text likewise covers the crystallographic patterns, Milton's mathematical symbol of theodicy, symmetries of soap films, and gapon formalism. This volume is a good source for researchers and specialists concerned with symmetry.
Symmetry in Bonding and Spectra by Bodie E. Douglas,Charles A. Hollingsworth Pdf
Many courses dealing with the material in this text are called "Applications of Group Theory." Emphasizing the central role and primary importance of symmetry in the applications, Symmetry in Bonding and Spectra enables students to handle applications, particularly applications to chemical bonding and spectroscopy. It contains the essential background in vectors and matrices for the applications, along with concise reviews of simple molecular orbital theory, ligand field theory, and treatments of molecular shapes, as well as some quantum mechanics. Solved examples in the text illustrate theory and applications or introduce special points. Extensive problem sets cover the important methods and applications, with the answers in the appendix.
Symmetry and Spectroscopy by Daniel C. Harris,Michael D. Bertolucci Pdf
Informal, effective undergraduate-level text introduces vibrational and electronic spectroscopy, presenting applications of group theory to the interpretation of UV, visible, and infrared spectra without assuming a high level of background knowledge. 200 problems with solutions. Numerous illustrations. "A uniform and consistent treatment of the subject matter." — Journal of Chemical Education.
Symmetry through the Eyes of a Chemist by Magdolna Hargittai,Istvan Hargittai Pdf
It is gratifying to launch the third edition of our book. Its coming to life testi?es about the task it has ful?lled in the service of the com- nity of chemical research and learning. As we noted in the Prefaces to the ?rst and second editions, our book surveys chemistry from the point of view of symmetry. We present many examples from ch- istry as well as from other ?elds to emphasize the unifying nature of the symmetry concept. Our aim has been to provide aesthetic pl- sure in addition to learning experience. In our ?rst Preface we paid tribute to two books in particular from which we learned a great deal; they have in?uenced signi?cantly our approach to the subject matter of our book. They are Weyl’s classic, Symmetry, and Shubnikov and Koptsik’s Symmetry in Science and Art. The structure of our book has not changed. Following the Int- duction (Chapter 1), Chapter 2 presents the simplest symmetries using chemical and non-chemical examples. Molecular geometry is discussed in Chapter 3. The next four chapters present gro- theoretical methods (Chapter 4) and, based on them, discussions of molecular vibrations (Chapter 5), electronic structures (Chapter 6), and chemical reactions (Chapter 7). For the last two chapters we return to a qualitative treatment and introduce space-group sym- tries (Chapter 8), concluding with crystal structures (Chapter 9). For the third edition we have further revised and streamlined our text and renewed the illustrative material.
Local Activity Principle: The Cause Of Complexity And Symmetry Breaking by Mainzer Klaus,Chua Leon O Pdf
The principle of local activity explains the emergence of complex patterns in a homogeneous medium. At first defined in the theory of nonlinear electronic circuits in a mathematically rigorous way, it can be generalized and proven at least for the class of nonlinear reaction-diffusion systems in physics, chemistry, biology, and brain research. Recently, it was realized by memristors for nanoelectronic device applications. In general, the emergence of complex patterns and structures is explained by symmetry breaking in homogeneous media, which is caused by local activity. This book argues that the principle of local activity is really fundamental in science, and can even be identified in quantum cosmology as symmetry breaking of local gauge symmetries generating the complexity of matter and forces in our universe. Applications are considered in economic, financial, and social systems with the emergence of equilibrium states, symmetry breaking at critical points of phase transitions and risky acting at the edge of chaos./a
This book highlights the symmetrical characteristics of organic molecules. It demonstrates how to use principles of symmetry to synthesize and prepare both symmetrical and asymmetrical molecules.
Unitary Symmetry and Elementary Particles by D. B. Lichtenberg Pdf
Unitary Symmetry and Elementary Particles discusses the role of symmetry in elementary particle physics. The book reviews the theory of abstract groups and group representations including Eigenstates, cosets, conjugate classes, unitary vector spaces, unitary representations, multiplets, and conservation laws. The text also explains the concept of Young Diagrams or Young Tableaux to prove the basis functions of the unitary irreducible representations of the unitary group SU(n). The book defines Lie groups, Lie algebras, and gives some examples of these groups. The basis vectors of irreducible unitary representations of Lie groups constitute a multiplet, which according to Racah (1965) and Behrends et al. (1962) can have properties of weights. The text also explains the properties of Clebsch-Gordan coefficients and the Wigner-Eckart theorem. SU(3) multiplets have members classified as hadrons (strongly interacting particles), of which one characteristic show that the mass differences of these members have some regular properties. The Gell-Mann and Ne-eman postulate also explains another characteristic peculiar to known multiplets. The book describes the quark model, as well as, the uses of the variants of the quark model. This collection is suitable for researchers and scientists in the field of applied mathematics, nuclear physics, and quantum mechanics.
Unitary Symmetry and Elementary Particles by D Lichtenberg Pdf
Unitary Symmetry and Elementary Particles, Second Edition presents the role of symmetry in the study of the physics of the elementary particles. This book discusses the nature and scope of unitary symmetry in physics. Comprised of 12 chapters, this edition starts with an overview of the theories of electromagnetism and gravitation to describe the behavior of certain physical systems. This text then examines the two main categories of the mathematical properties of groups, namely, the properties of abstract groups and the properties of representations of groups. Other chapters consider the use of group theory, which is a significant tool in studying symmetry. This book discusses as well the states that are the basis vectors of irreducible unitary representations of Lie group. The final chapter deals with the quark model, which provides a useful way to understand many properties of hadrons in terms of simpler entities. This book is a valuable resource for physicists.
Fundamentals of Molecular Symmetry by P.R. Bunker,P. Jensen Pdf
Winner of a 2005 CHOICE Outstanding Academic Book Award Molecular symmetry is an easily applied tool for understanding and predicting many of the properties of molecules. Traditionally, students are taught this subject using point groups derived from the equilibrium geometry of the molecule. Fundamentals of Molecular Symmetry shows how to set up symmetry groups for molecules using the more general idea of energy invariance. It is no more difficult than using molecular geometry and one obtains molecular symmetry groups. The book provides an introductory description of molecular spectroscopy and quantum mechanics as the foundation for understanding how molecular symmetry is defined and used. The approach taken gives a balanced account of using both point groups and molecular symmetry groups. Usually the point group is only useful for isolated, nonrotating molecules, executing small amplitude vibrations, with no tunneling, in isolated electronic states. However, for the chemical physicist or physical chemist who wishes to go beyond these limitations, the molecular symmetry group is almost always required.
Atomic & Molecular Symmetry Groups and Chemistry by S.C. Rakshit Pdf
Atomic Symmetry Groups, being continuous groups, are just a fallout of the Lie Groups and Lie Algebras. Atoms are structurally simpler than molecules but atomic symmetry is more complex than molecular symmetry. In quantum mechanics we study atoms first and then the molecules. In symmetry studies, we do just the reverse. In this book, apart from theories, the description of both the symmetry groups – atomic and molecular, are attended with adequate applications. Please note: Taylor & Francis does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka.
Shattered Symmetry by Pieter Thyssen,Arnout Ceulemans Pdf
Symmetry is at the heart of our understanding of matter. This book tells the fascinating story of the constituents of matter from a common symmetry perspective. The standard model of elementary particles and the periodic table of chemical elements have the common goal to bring order in the bewildering chaos of the constituents of matter. Their success relies on the presence of fundamental symmetries in their core. The purpose of Shattered Symmetry is to share the admiration for the power and the beauty of these symmetries. The reader is taken on a journey from the basic geometric symmetry group of a circle to the sublime dynamic symmetries that govern the motions of the particles. Along the way the theory of symmetry groups is gradually introduced with special emphasis on its use as a classification tool and its graphical representations. This is applied to the unitary symmetry of the eightfold way of quarks, and to the four-dimensional symmetry of the hydrogen atom. The final challenge is to open up the structure of Mendeleev's table which goes beyond the symmetry of the hydrogen atom. Breaking this symmetry to accommodate the multi-electron atoms requires us to leave the common ground of linear algebras and explore the potential of non-linearity.