The Chemical Physics Of Surfaces

Author : S.R. Morrison
Publisher : Springer Science & Business Media
Page : 448 pages
File Size : 53,6 Mb
Release : 2013-06-29
Category : Science
ISBN : 9781489924988

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The Chemical Physics of Surfaces by S.R. Morrison Pdf

of available information. Even more importantly, some authors who have contributed substantially to an area may have been overlooked. For this I apologize. I have, however, not attempted to trace techniques or observa tions historically, so there is no implication (unless specified) that the authors referred to were or were not the originators of a given method or observation. I would like to acknowledge discussions with co-workers at SFU for input relative to their specialties, to acknowledge the help of students who have pointed out errors and difficulties in the earlier presentation, and to acknowledge the infinite patience of my wife Phyllis while I spent my sabbatical and more in libraries and punching computers. S. Roy Morrison 0 1 Contents Notation XV 1. Introduction 1 1. 1. Surface States and Surface Sites . 1 1. 1. 1. The Chemical versus Electronic Representation of the Surface. 1 1. 1. 2. The Surface State on the Band Diagram 4 1. 1. 3. The Fermi Energy in the Surface State Model. 6 1. 1. 4. Need for Both Surface Site and Surface State Models 6 1. 2. Bonding of Foreign Species to the Solid Surface 7 1. 2. 1. Types of Interaction. 7 1. 2. 2. The Chemical Bond . 10 1. 2. 3. Acid and Basic Surface Sites on Solids . 13 1. 2. 4. Adsorbate Bonding on Various Solid Types. 16 1. 2. 5. Movement of Surface Atoms: Relaxation, Reconstruction, and Relocation .

Author : S. Morrison
Publisher : Springer Science & Business Media
Page : 428 pages
File Size : 51,9 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781461580072

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The Chemical Physics of Surfaces by S. Morrison Pdf

* At the present stage of development of surface science, there has seemed to be a need for a book-length review spanning the disciplines of surface physics and surface chemistry-a review to summarize and show the con nection between the observations from each discipline. The various results and theories, derived on the one hand from studies of the physical, electronic, and optical properties of surfaces and on the other hand from studies of the chemical activity of surfaces, supplement each other in the search for a realistic model of the surface. The improved understanding possible with such an interdisciplinary approach has been confirmed by recent develop ments which cannot be classified as either surface chemistry or surface physics. Specifically, recent new experimental techniques and quantum mechanical models have provided a much more accurate picture of the nature of the electronic energy levels (bonding orbitals) present at a solid surface. With this more accurate picture we are now able to reconcile the various chemical and physical models that appeared in the early literature on surfaces. The objective of this work has therefore been to describe the results and current models of surface science spanning a broad gray area between surface physics and surface chemistry with some overlap into each of these disciplines. Relevant aspects of surface chemistry are discussed; we cover chemical interactions where bonding and electronic properties dominate, but stop short of specialized topics such as surfactants or liquid/liquid interfaces.

Author : Stanley Roy Morrison
Publisher : Unknown
Page : 415 pages
File Size : 44,6 Mb
Release : 2000
Category : Surface chemistry
ISBN : OCLC:959793698

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The Chemical Physics of Surfaces by Stanley Roy Morrison Pdf

Author : Andrew Zangwill
Publisher : Cambridge University Press
Page : 128 pages
File Size : 53,9 Mb
Release : 1988-03-24
Category : Science
ISBN : 9781316583265

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Physics at Surfaces by Andrew Zangwill Pdf

Physics at Surfaces is a unique graduate-level introduction to the physics and chemical physics of solid surfaces, and atoms and molecules that interact with solid surfaces. A subject of keen scientific inquiry since the last century, surface physics emerged as an independent discipline only in the late 1960s as a result of the development of ultra-high vacuum technology and high speed digital computers. With these tools, reliable experimental measurements and theoretical calculations could at last be compared. Progress in the last decade has been truly striking. This volume provides a synthesis of the entire field of surface physics from the perspective of a modern condensed matter physicist with a healthy interest in chemical physics. The exposition intertwines experiment and theory whenever possible, although there is little detailed discussion of technique. This much-needed text will be invaluable to graduate students and researchers in condensed matter physics, physical chemistry and materials science working in, or taking graduate courses in, surface science.

Author : Friedhelm Bechstedt
Publisher : Springer Science & Business Media
Page : 342 pages
File Size : 53,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642554667

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Principles of Surface Physics by Friedhelm Bechstedt Pdf

An innovative, unified, and comprehensive treatment of the geometric and electronic structure of surfaces. The book emphasizes fundamental aspects, such as the principles of surface crystallography and thermodynamics, the forces driving the rearrangement of the atoms, and the relationship between bonding and electronic structure. It especially illuminates the relationship between surface orientation, chemistry, energetics, and the resulting properties. Principles of Surface Physics develops general physical arguments and methods that enable readers to analyse novel surfaces and interfaces of new materials. This makes the book an indispensable reference to all those studying growth, surface-molecule interactions, self-assembled structures, and materials engineering.

Author : Harald Ibach
Publisher : Springer Science & Business Media
Page : 646 pages
File Size : 48,7 Mb
Release : 2006-11-18
Category : Science
ISBN : 9783540347101

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Physics of Surfaces and Interfaces by Harald Ibach Pdf

This graduate-level textbook covers the major developments in surface sciences of recent decades, from experimental tricks and basic techniques to the latest experimental methods and theoretical understanding. It is unique in its attempt to treat the physics of surfaces, thin films and interfaces, surface chemistry, thermodynamics, statistical physics and the physics of the solid/electrolyte interface in an integral manner, rather than in separate compartments. It is designed as a handbook for the researcher as well as a study-text for graduate students. Written explanations are supported by 350 graphs and illustrations.

Author : M W Roberts,J M Thomas
Publisher : Royal Society of Chemistry
Page : 194 pages
File Size : 55,5 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847555809

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Chemical Physics of Solids and Their Surfaces by M W Roberts,J M Thomas Pdf

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.

Author : David Anthony King
Publisher : Unknown
Page : 650 pages
File Size : 50,8 Mb
Release : 1997
Category : Adsorption
ISBN : 0444419713

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The Chemical Physics of Solid Surfaces by David Anthony King Pdf

Author : Neil Kensington Adam
Publisher : Unknown
Page : 0 pages
File Size : 45,5 Mb
Release : 1941
Category : Capillarity
ISBN : LCCN:lc32000224

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The Physics and Chemistry of Surfaces by Neil Kensington Adam Pdf

Author : D.A. King
Publisher : Elsevier
Page : 362 pages
File Size : 40,7 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780444601551

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The Chemical Physics of Solid Surfaces by D.A. King Pdf

The Chemical Physics of Solid Surfaces, Volume 6: Coadsorption, Promoters, and Poisons focuses on the processes, reactions, and approaches involved in coadsorption and the functions of promoters and poisons in synthesis and reactions. The selection first offers information on adsorbate-adsorbate interactions on metal surfaces and interaction between alkali metal adsorbates and adsorbed molecules. Discussions focus on coadsorption of alkali metals and other molecules; model experiments of catalyst promotion; effective medium theory; direct and indirect hybridization effects; and elastic interaction between adsorbates. The publication then ponders on coadsorption of carbon monoxide and hydrogen on metal surfaces and adsorption on bimetallic surfaces. The manuscript examines the chemical properties of alloy single crystal surfaces and promotion in ammonia synthesis. Topics include substrate dependence of nitrogen adsorption and ammonia synthesis; effects of promotion on nitrogen dissociation and ammonia synthesis; and theoretical modeling. The text then elaborates on promotion in the Fischer-Tropsch hydrocarbon synthesis, promoters and poisons in the water-gas shift reaction, and strong metal-support interactions. The selection is a recommended reference for physicists and readers interested in coadsorption, promoters, and poisons.

Author : D.A. King
Publisher : Elsevier
Page : 488 pages
File Size : 43,9 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780444601308

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The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis by D.A. King Pdf

Surface Properties of Electronic Materials is the fifth volume of the series, The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis. This volume indicates the present state of some basic properties of semiconductor surfaces. Chapter one summarizes the general problems in electronic materials and the areas affected by the surface science methods. The next two chapters illustrate the existing perception of the electronic and structural properties of elemental and compound semiconductor surfaces. This volume also deals with the properties of adsorption of semiconductors relating to both relevant gas phase species and metals. Chapters four to six of this volume explore compound semiconductors and elemental semiconductors. The remaining chapters of this volume explore the adsorption of metals on elemental semiconductors; aspects of growth kinetics and dynamics involved in molecular beam epitaxy; molecular beam epitaxy of silicon; insulators; and metastable phases. The last chapter covers the surface chemistry of dry etching processes.

Author : Forest Ray Moulton
Publisher : Unknown
Page : 133 pages
File Size : 42,5 Mb
Release : 1986
Category : Electronic
ISBN : OCLC:605343832

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Recent Advances in Surface Chemistry and Chemical Physics by Forest Ray Moulton Pdf

Author : Hans-Jürgen Butt,Karlheinz Graf,Michael Kappl
Publisher : John Wiley & Sons
Page : 485 pages
File Size : 54,8 Mb
Release : 2023-02-07
Category : Science
ISBN : 9783527836161

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Physics and Chemistry of Interfaces by Hans-Jürgen Butt,Karlheinz Graf,Michael Kappl Pdf

Physics and Chemistry of Interfaces Comprehensive textbook on the interdisciplinary field of interface science, fully updated with new content on wetting, spectroscopy, and coatings Physics and Chemistry of Interfaces provides a comprehensive introduction to the field of surface and interface science, focusing on essential concepts rather than specific details, and on intuitive understanding rather than convoluted math. Numerous high-end applications from surface technology, biotechnology, and microelectronics are included to illustrate and help readers easily comprehend basic concepts. The new edition contains an increased number of problems with detailed, worked solutions, making it ideal as a self-study resource. In topic coverage, the highly qualified authors take a balanced approach, discussing advanced interface phenomena in detail while remaining comprehensible. Chapter summaries with the most important equations, facts, and phenomena are included to aid the reader in information retention. A few of the sample topics included in Physics and Chemistry of Interfaces are as follows: Liquid surfaces, covering microscopic picture of a liquid surface, surface tension, the equation of Young and Laplace, and curved liquid surfaces Thermodynamics of interfaces, covering surface excess, internal energy and Helmholtz energy, equilibrium conditions, and interfacial excess energies Charged interfaces and the electric double layer, covering planar surfaces, the Grahame equation, and limitations of the Poisson-Boltzmann theory Surface forces, covering Van der Waals forces between molecules, macroscopic calculations, the Derjaguin approximation, and disjoining pressure Physics and Chemistry of Interfaces is a complete reference on the subject, aimed at advanced students (and their instructors) in physics, material science, chemistry, and engineering. Researchers requiring background knowledge on surface and interface science will also benefit from the accessible yet in-depth coverage of the text.

Author : American Association for the Advancement of Science. Section on Chemistry
Publisher : Unknown
Page : 156 pages
File Size : 43,8 Mb
Release : 1939
Category : Science
ISBN : UOM:39015075977580

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Recent Advances in Surface Chemistry and Chemical Physics by American Association for the Advancement of Science. Section on Chemistry Pdf

Author : Hans-Jürgen Butt,Karlheinz Graf,Michael Kappl
Publisher : John Wiley & Sons
Page : 373 pages
File Size : 47,5 Mb
Release : 2006-03-06
Category : Science
ISBN : 9783527606405

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Physics and Chemistry of Interfaces by Hans-Jürgen Butt,Karlheinz Graf,Michael Kappl Pdf

Serving as a general introduction to surface and interface science, this book focuses on basic concepts rather than specific details, and on intuitive understanding rather than merely learning facts. The text reflects the fact that the physics and chemistry of surfaces is a diverse area of research that involves classical scientific and engineering disciplines. As such, it discusses fundamental subjects, such as thermodynamics of interfaces, as well as applied topics including wetting, friction, and lubrication. Following an introduction to the most important techniques and methods, readers will be able to apply simple models to their own scientific problems. Furthermore, manifold high end technological applications are shown together with the basic scientific treatment, for example AFM, surface technology, biotechnology, microelectronics, and biomaterials. The book is written with advanced students of chemistry, physics, materials science, chemical engineering and related subjects who have a basic knowledge of natural sciences and mathematics in mind. In addition, scientists and engineers who are not yet specialists in surface science but want to learn more about this important subject will equally benefit.