The Chemistry Of Coordination Complexes And Transition Metals

Author : P.L. Soni,Vandna Soni
Publisher : CRC Press
Page : 403 pages
File Size : 46,8 Mb
Release : 2021-05-13
Category : Science
ISBN : 9781000404135

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The Chemistry of Coordination Complexes and Transition Metals by P.L. Soni,Vandna Soni Pdf

This book covers all important nomenclature, theories of bonding and stereochemistry of coordination complexes. The authors have made an effort to inscribe the ideas knowledge, clearly and in an interesting way to benefit the readers. The complexities of Molecular Orbital theory have been explained in a very simple and easy manner. It also deals with transition and inner transition metals. Conceptually, all transition and inner transition elements form complexes which have definite geometry and show interesting properties. General and specific methods of preparation, physical and chemical properties of each element has been discussed at length. Group wise study of elements in d-block series have been explained. Important compounds, complexes and organometallic compounds of metals in different oxidation states have been given explicitly. Note: T&F does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka.

Author : P.L. Soni,Vandna Soni
Publisher : CRC Press
Page : 332 pages
File Size : 44,8 Mb
Release : 2021-05-14
Category : Science
ISBN : 9781000404142

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The Chemistry of Coordination Complexes and Transition Metals by P.L. Soni,Vandna Soni Pdf

This book covers all important nomenclature, theories of bonding and stereochemistry of coordination complexes. The authors have made an effort to inscribe the ideas knowledge, clearly and in an interesting way to benefit the readers. The complexities of Molecular Orbital theory have been explained in a very simple and easy manner. It also deals with transition and inner transition metals. Conceptually, all transition and inner transition elements form complexes which have definite geometry and show interesting properties. General and specific methods of preparation, physical and chemical properties of each element has been discussed at length. Group wise study of elements in d-block series have been explained. Important compounds, complexes and organometallic compounds of metals in different oxidation states have been given explicitly. Note: T&F does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka.

Author : P. L. Soni,Vandna Soni
Publisher : Unknown
Page : 0 pages
File Size : 52,6 Mb
Release : 2021
Category : Science
ISBN : 1003183425

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The Chemistry of Coordination Complexes and Transition Metals by P. L. Soni,Vandna Soni Pdf

This book covers all important nomenclature, theories of bonding and stereochemistry of coordination complexes. The authors have made an effort to inscribe the ideas knowledge, clearly and in an interesting way to benefit the readers. The complexities of Molecular Orbital theory have been explained in a very simple and easy manner. It also deals with transition and inner transition metals. Conceptually, all transition and inner transition elements form complexes which have definite geometry and show interesting properties. General and specific methods of preparation, physical and chemical properties of each element has been discussed at length. Group wise study of elements in d-block series have been explained. Important compounds, complexes and organometallic compounds of metals in different oxidation states have been given explicitly. Note: T&F does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka.

Author : Fred Basolo,Ronald C. Johnson
Publisher : Unknown
Page : 166 pages
File Size : 52,8 Mb
Release : 1986
Category : Science
ISBN : UCSD:31822002898385

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Coordination Chemistry by Fred Basolo,Ronald C. Johnson Pdf

Author : A. Veillard
Publisher : Springer Science & Business Media
Page : 518 pages
File Size : 45,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400946569

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Quantum Chemistry: The Challenge of Transition Metals and Coordination Chemistry by A. Veillard Pdf

Over the last twenty years, developments of the ab initio metho dologies and of the computing capacities have progressively turned quantum chemistry into a predictive tool for molecular systems involving only light elements. The situation appears less advanced for systems containing transition metal elements where specific difficulties arise, like those 1inked to the quasi-degeneracy of the lowest atomic states. Correlation effects, which are important only for quantitative accuracy in the treatment of molecules made of light elements, need sometimes to be considered even for a qualitative des cription of transition metals systems (like the multiple metal-metal bond). The treatment of atoms of a high atomic number has necessited the development of model potential methods. These difficulties ex acerbate for systems containing several trans ition atoms a correct description of the dichromium molecule Crz still represents a challenge to quantum chemists. Yet many advances have been made recently in the theoretical treatment of these systems, despite the fact that our understanding still remains disparate with a variety of models and methodologies used more or less successfully (one-electron models, explicitly correlated ab initio methods, density functional formalisms). For these reasons, a NATO Advanced Research Workshop was organized to review in detail the state-of-the-art techniques and at the same time the most common applications. These encompass many fields including the spectroscopy of diatomics and small aggregates, structure and reactivity problems in organometallic chemistry, the cluster surface analogy with its implications for heterogeneous catalysis and the description of extended structures.

Author : Fred Basolo,John L Burmeister
Publisher : World Scientific
Page : 656 pages
File Size : 55,9 Mb
Release : 2003-10-14
Category : Science
ISBN : 9789814488006

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On Being Well-Coordinated by Fred Basolo,John L Burmeister Pdf

This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry. Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance. Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature. Contents: Ligand Substitution Reactions of Transition Metal ComplexesApplication of Reaction Mechanisms to the Synthesis of Metal ComplexesCarbon Monoxide Substitution Reactions of Metal CarbonylsMetal Nitrosyl CarbonylsCatalysis of CO Substitution in Metal CarbonylsMigratory Insertion ReactionsOxygen Atom Transfer to Metal CarbonylsSynthetic Oxygen Carries of Biological Interestand other papers Readership: Researchers in the solution of metals, as well as bioinorganic, organometallic and solid state chemistry. Keywords:Coordination Chemistry;Metal Complexes;Transition Metals;Inorganic Chemistry;Biochemistry

Author : P. L. Soni,Vandna Soni
Publisher : CRC Press
Page : 300 pages
File Size : 45,7 Mb
Release : 2013-04-09
Category : Science
ISBN : 1466500506

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Coordination Chemistry by P. L. Soni,Vandna Soni Pdf

This book has been written in a simple and lucid language to help students understand the intricate theories of co-ordination chemistry. Divided into two parts, the first part reviews all the recent developments in the fields of organometallics and co-ordination chemistry. The second part deals with transition and inner transition metals including the study of f-block elements. It was developed with a focus on the need to demystify coordination complexes and transition metals.

Author : D.M. Roundhill
Publisher : Springer Science & Business Media
Page : 364 pages
File Size : 43,9 Mb
Release : 2013-06-29
Category : Science
ISBN : 9781489914958

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Photochemistry and Photophysics of Metal Complexes by D.M. Roundhill Pdf

Focusing on practical applications, the author provides a balanced introduction to the many possible technological uses of metal complexes. Coverage includes the transition metals, lanthanide and actinide complexes, metal porphyrins, and many other complexes. This volume meets the needs of students and scientists in inorganic chemistry, chemical physics, and solid-state physics.

Author : M. Satake & Y. Mido
Publisher : Discovery Publishing House
Page : 230 pages
File Size : 55,7 Mb
Release : 2010
Category : Electronic
ISBN : 8171412432

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Chemistry Of Transition Elements by M. Satake & Y. Mido Pdf

Contents: The Properties of Transition Elements, Titanium, Zirconium and Hafnium Group IV A, Vanadium, Niobium and Tantalum Group V A, Chromium, Molybdenum and Tungsten Group VI A, Manganese, Technetium and Rhenium Group VII A, Iron, Cobalt and Nickel, The Platinum Metals, Copper, Silver and Gold Group IB, Analytical and Biological Aspects of Transition Metals, Coordination Compounds, Lanthanides & Actinides.

Author : S. F. A. Kettle
Publisher : Springer
Page : 503 pages
File Size : 53,9 Mb
Release : 2013-11-11
Category : Science
ISBN : 9783662251911

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Physical Inorganic Chemistry by S. F. A. Kettle Pdf

GEORGE CHRISTOU Indiana University, Bloomington I am no doubt representative of a large number of current inorganic chemists in having obtained my undergraduate and postgraduate degrees in the 1970s. It was during this period that I began my continuing love affair with this subject, and the fact that it happened while I was a student in an organic laboratory is beside the point. I was always enchanted by the more physical aspects of inorganic chemistry; while being captivated from an early stage by the synthetic side, and the measure of creation with a small c that it entails, I nevertheless found the application of various theoretical, spectroscopic and physicochemical techniques to inorganic compounds to be fascinating, stimulating, educational and downright exciting. The various bonding theories, for example, and their use to explain or interpret spectroscopic observations were more or less universally accepted as belonging within the realm of inorganic chemistry, and textbooks of the day had whole sections on bonding theories, magnetism, kinetics, electron-transfer mechanisms and so on. However, things changed, and subsequent inorganic chemistry teaching texts tended to emphasize the more synthetic and descriptive side of the field. There are a number of reasons for this, and they no doubt include the rise of diamagnetic organometallic chemistry as the dominant subdiscipline within inorganic chemistry and its relative narrowness vis-d-vis physical methods required for its prosecution.

Author : Yves Jean
Publisher : Oxford University Press on Demand
Page : 288 pages
File Size : 48,8 Mb
Release : 2005-03-24
Category : Science
ISBN : 9780198530930

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Molecular Orbitals of Transition Metal Complexes by Yves Jean Pdf

This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions such as symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter and the structure of the "d block" is used to trace the relationships between the electronic structure and the geometry of the complexes. The third chapter studies the change in analysis when the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (e.g. structure and reactivity). The fifth chapter deals with the "isolobal analogy" which points out the resemblance between the molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some of the complexes studied in the earlier chapters.

Author : Purshottam L. Soni,Vandna Soni
Publisher : Unknown
Page : 346 pages
File Size : 52,9 Mb
Release : 2013
Category : Chemistry
ISBN : 9382127143

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Coordination Chemistry by Purshottam L. Soni,Vandna Soni Pdf

This book has been written in a simple and lucid language to help students understand the intricate theories of co-ordination chemistry. Divided into two parts, the first part reviews all the recent developments in the fields of organometallics and co-ordination chemistry. The second part deals with transition and inner transition metals including the study of f-block elements. It was developed with a focus on the need to demystify coordination complexes and transition metals.

Author : A. B. P. Lever
Publisher : Elsevier
Page : 206 pages
File Size : 44,8 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781483284729

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Coordination Chemistry—XIV by A. B. P. Lever Pdf

Coordination Chemistry–XIV provides information pertinent to the fundamental characteristics and synthesis of coordination compounds. This book discusses the importance of undertaking accurate X-ray analysis of a wide-ranging series of complexes in order to derive more secure theoretical correlations. Organized into 13 chapters, this book begins with an overview of the properties of alkyl and aryl derivatives of transition elements. This text then describes the two methods that lead to transition metal complexes of carborane ligands, namely, polyhedral expansion and polyhedral contraction. Other chapters consider the argument that organo-transition metal complexes also consisting phosphines and similar ligands are often too kinetically inert to act as good models for catalytic processes. This book discusses as well the developments in the mechanisms of substitution in transition metal complexes. The final chapter deals with the calibration of low resolution spectrometers. This book is a valuable resource for chemists, organometallic chemists, and inorganic chemists.

Author : Sandeep Kaur-Ghumaan
Publisher : Nova Science Publishers
Page : 438 pages
File Size : 55,8 Mb
Release : 2021
Category : Science
ISBN : 1685071996

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A Closer Look at Coordination Complexes by Sandeep Kaur-Ghumaan Pdf

"Coordination chemistry plays an important role in the designing of inorganic metal complexes, materials, organo-synthesis, biological systems and catalysis. In A Closer Look at Coordination Complexes, novel and evolving developments in the field have been described. The book includes chapters on the synthesis of coordination compounds using different ligand combinations (Schiff base ligands, phosphines, thiolates, ligands with N- and S-donors and so on), biological relevance and catalytic applications of the reported metal complexes. Different aspects of metal complexes, viz. structural and coordination properties of the ligands and complexes and applications viz., asymmetric organic transformations, potential anticancer agents, antibacterial-antioxidant-antifungal properties, alkenes epoxidation, olefins polymerization, nitrogen reduction, hydrogen evolution and oxidation and mercury poisoning treatment reviewed by the authors have been delineated in the eight chapters of the book"--

Author : Kenneth Kam-Wing Lo
Publisher : Academic Press
Page : 406 pages
File Size : 54,8 Mb
Release : 2016-12-30
Category : Science
ISBN : 9780128038871

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Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells by Kenneth Kam-Wing Lo Pdf

Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells provides a complete overview of this important research area that is perfect for both newcomers and expert researchers in the field. Through concise chapters written and edited by esteemed experts, this book brings together a comprehensive treatment of the area previously only available through scattered, lengthy review articles in the literature. Advanced topics of research are covered, with particular focus on recent advances in the biological applications of transition metal complexes, including inorganic medicine, enzyme inhibitors, antiparasital agents, and biological imaging reagents. Geared toward researchers and students who seek an introductory overview of the field, as well as researchers working in advanced areas Focuses on the interactions of inorganic and organometallic transition metal complexes with biological molecules and live cells Foscuses on the fundamentals and their potential therapeutic and diagnostic applications Covers recent biological applications of transition metal complexes, such as anticancer drugs, enzyme inhibitors, bioconjugation agents, chemical biology tools, and bioimaging reagents