The Importance Of Pi Interactions In Crystal Engineering

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The Importance of Pi-Interactions in Crystal Engineering

Author : Edward R. T. Tiekink,Julio Zukerman-Schpector
Publisher : John Wiley & Sons
Page : 413 pages
File Size : 40,5 Mb
Release : 2012-03-22
Category : Science
ISBN : 9781119940920

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The Importance of Pi-Interactions in Crystal Engineering by Edward R. T. Tiekink,Julio Zukerman-Schpector Pdf

Crystal engineers aim to control the way molecules aggregate in the crystalline phase and are therefore concerned with crystal structure prediction, polymorphism, and discovering the relative importance of different types of intermolecular forces and their influence on molecular structure. In order to design crystal structures, knowledge of the types, strengths, and nature of possible intermolecular interactions is essential. Non-covalent interactions involving p-systems is a theme that is under extensive investigation as these interactions can be inductors for the assembly of a vast array of supramolecular architectures. The Importance of Pi-Interactions in Crystal Engineeringcovers topics ranging from the identification of interactions involving p-systems, their impact on molecular and crystal structure in both organic and metallorganic systems, and how these interactions might be exploited in the design of new materials. Specialist reviews are written by internationally recognized researchers drawn from both academia and industry. The Importance of Pi-Interactions in Crystal Engineeringprovides an essential overview of this important aspect of crystal engineering for both entrants to the field as well as established practitioners, and for those working in crystallography, medicinal and pharmaceutical sciences, solid-state chemistry, physical chemistry, materials and nanotechnology

The Importance of Pi-Interactions in Crystal Engineering

Author : Edward R. T. Tiekink,Julio Zukerman-Schpector
Publisher : John Wiley & Sons
Page : 0 pages
File Size : 48,9 Mb
Release : 2012-04-09
Category : Science
ISBN : 0470688270

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The Importance of Pi-Interactions in Crystal Engineering by Edward R. T. Tiekink,Julio Zukerman-Schpector Pdf

Crystal engineers aim to control the way molecules aggregate in the crystalline phase and are therefore concerned with crystal structure prediction, polymorphism, and discovering the relative importance of different types of intermolecular forces and their influence on molecular structure. In order to design crystal structures, knowledge of the types, strengths, and nature of possible intermolecular interactions is essential. Non-covalent interactions involving p-systems is a theme that is under extensive investigation as these interactions can be inductors for the assembly of a vast array of supramolecular architectures. The Importance of Pi-Interactions in Crystal Engineeringcovers topics ranging from the identification of interactions involving p-systems, their impact on molecular and crystal structure in both organic and metallorganic systems, and how these interactions might be exploited in the design of new materials. Specialist reviews are written by internationally recognized researchers drawn from both academia and industry. The Importance of Pi-Interactions in Crystal Engineeringprovides an essential overview of this important aspect of crystal engineering for both entrants to the field as well as established practitioners, and for those working in crystallography, medicinal and pharmaceutical sciences, solid-state chemistry, physical chemistry, materials and nanotechnology

Intermolecular Interactions in Crystals

Author : Juan Novoa
Publisher : Royal Society of Chemistry
Page : 782 pages
File Size : 43,9 Mb
Release : 2017-10-27
Category : Science
ISBN : 9781782621737

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Intermolecular Interactions in Crystals by Juan Novoa Pdf

This new book brings together the latest information on intermolecular bonding within molecular crystals, providing a very useful introductory text for graduates.

Advances in Organometallic Chemistry

Author : Anthony F. Hill,Mark J. Fink
Publisher : Academic Press
Page : 192 pages
File Size : 47,7 Mb
Release : 2012-12-31
Category : Science
ISBN : 9780123972774

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Advances in Organometallic Chemistry by Anthony F. Hill,Mark J. Fink Pdf

Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field that has expanded enormously since the publication of Volume 1 in 1964. Contributions from leading authorities Informs and updates on all the latest developments in the field

Frontiers in Crystal Engineering

Author : Edward R. T. Tiekink,Jagadese Vittal
Publisher : John Wiley & Sons
Page : 346 pages
File Size : 41,5 Mb
Release : 2006-05-01
Category : Science
ISBN : 9780470022597

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Frontiers in Crystal Engineering by Edward R. T. Tiekink,Jagadese Vittal Pdf

Crystal engineering - where the myriad of intermolecular forces operating in the solid-state are employed to design new nano- and functional materials - is a key new technology with implications for catalysis, pharmaceuticals, synthesis and materials science. Frontiers in Crystal Engineering gathers personal perspectives, from international specialists working in molecular aspects of crystal engineering, on the practical and theoretical challenges of the discipline, and future prospects. These demonstrate the approaches that are being used to tackle the problems associated with the complexity, design and functionality of crystalline molecular solids. Topics include * how intermolecular forces direct and sustain crystal structures * functional engineering and design elements * coordination polymers and network structures * applications in green and pharmaceutical chemistry Frontiers in Crystal Engineering is a useful guide to this exciting new discipline for both entrants to the field as well as established practitioners, and for those working in crystallography, medicinal and pharmaceutical sciences, solid-state chemistry, and materials and nanotechnology.

Aromatic Interactions

Author : Darren W Johnson,Fraser Hof
Publisher : Royal Society of Chemistry
Page : 282 pages
File Size : 42,6 Mb
Release : 2016-11-15
Category : Science
ISBN : 9781782626626

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Aromatic Interactions by Darren W Johnson,Fraser Hof Pdf

The field of aromatic interactions, the fundamental nature of substituent effects and the identification of contacts between anions and aromatic systems have generated stimulating arguments in recent years. New theoretical frameworks have been developed and tested and aromatic interactions have emerged as potential solutions for varied problems in biology and materials science. This book provides a wide ranging survey of the latest findings and advances surrounding aromatic interactions, stretching from the fundamentals to modern applications in synthesis, biology and materials chemistry. It also discusses computational, experimental and analytical approaches to understanding these interactions, including pi-pi, anion-pi, and cation-pi interactions. Aromatic Interactions: Frontiers in Knowledge and Application is a useful text for advanced students and researchers, and appeals to those working within the fields of supramolecular chemistry, computational chemistry and thermodynamics.

Advances in Organic Crystal Chemistry

Author : Rui Tamura,Mikiji Miyata
Publisher : Springer
Page : 706 pages
File Size : 46,6 Mb
Release : 2015-08-06
Category : Science
ISBN : 9784431555551

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Advances in Organic Crystal Chemistry by Rui Tamura,Mikiji Miyata Pdf

For the last decade, the topics of organic crystal chemistry have become diversified, and each topic has been substantially advanced in concert with the rapid development of various analytical and measurement techniques for solid-state organic materials. The aim of this book is to systematically summarize and record the recent notable advances in various topics of organic crystal chemistry involving liquid crystals and organic–inorganic hybrid materials that have been achieved mainly in the last 5 years or so. The authors are invited members of the Division of Organic Crystals, The Chemical Society of Japan (CSJ), and prominent invited experts from abroad. This edited volume is planned to be published periodically, at least every 5 years, with contributions by prominent authors in Japan and from abroad.

Structural Chemistry across the Periodic Table

Author : Thomas CW Mak,Yu San Cheung,Yingxia Wang,Gong Du Zhou
Publisher : Oxford University Press
Page : 593 pages
File Size : 45,9 Mb
Release : 2023-10-12
Category : Science
ISBN : 9780198872962

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Structural Chemistry across the Periodic Table by Thomas CW Mak,Yu San Cheung,Yingxia Wang,Gong Du Zhou Pdf

This book is an expanded and updated version of Part III of the authors' previous work, Advanced Structural Inorganic Chemistry (OUP 2008). The original part deals with main-group elements, the rare-earth elements, transition-metal clusters, and supramolecular systems. In this new book, selected material from significant advances in the past decade has been added, with particular emphasis on compounds that exemplify new types of bonds such as sigma-hole, triel bond, tetrel bond, pnictogen bond, chalcogen bond, halogen bond, halogen-halogen interaction, aerogen bond, as well as quintuple and sextuple metal-metal bonds. Other new topics include actinide compounds, metallophilicity, heterometallic macrocycles and cages, com- and dis-proportionation reactions, hydrogen-bonded organic frameworks (HOFs), halogen-bonded organic frameworks, halogen-halogen interactions in supramolecular frameworks, covalent organic frameworks (COFs), and metal-organic frameworks (MOFs).

Coordination Polymers

Author : Stuart R Batten,Suzanne M Neville,David R Turner
Publisher : Royal Society of Chemistry
Page : 440 pages
File Size : 48,6 Mb
Release : 2008-11-06
Category : Science
ISBN : 9781847558862

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Coordination Polymers by Stuart R Batten,Suzanne M Neville,David R Turner Pdf

The field of coordination polymer research has undergone rapid expansion in recent years. No longer are these materials the vaguely defined 'insoluble material' at the bottom of your vessel that spell death for your reaction. They have gone from 'polymeric rubbish' to 'materials of the future'. Great leaps in the deliberate design of coordination polymers were made in the 1990s. These were allied with similar advances in related areas such as organic crystal engineering, metallosupramolecular chemistry and X-ray diffraction. No longer did we assemble things atom by atom. Whole molecules were used as building blocks and new materials were made. This is the first book to provide a broad overview of all the major facets of coordination polymer research in one place. It combines chapters on nets and interpenetration with wide-ranging surveys of transition metal and lanthanoid coordination polymers and their properties. The aim is to provide a flavour of each aspect whilst introducing the important concepts and developments using carefully selected examples. After an introduction, the text is split into three sections: -Design (nets, interpenetration, malleability) -Analysis (transition metal coordination polymers, lanthanoid coordination polymers, organometallic networks, organic-inorganic hybrids) -Application (magnetic properties, porosity, acentric and chiral networks, reactive coordination polymers, other properties). Written in the style of a tutorial review, the book is suitable for both senior specialists and new postgraduate students taking their first steps in the field. It also provides an authoritative and detailed reference source.

Problems in Structural Inorganic Chemistry

Author : Wai-Kee Li,Hung Kay Lee,Dennis Kee Pui Ng,Yu-San Cheung,Kendrew Kin Wah Mak,Thomas Chung Wai Mak
Publisher : Oxford University Press
Page : 464 pages
File Size : 53,6 Mb
Release : 2018-11-30
Category : Science
ISBN : 9780192557186

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Problems in Structural Inorganic Chemistry by Wai-Kee Li,Hung Kay Lee,Dennis Kee Pui Ng,Yu-San Cheung,Kendrew Kin Wah Mak,Thomas Chung Wai Mak Pdf

This book consists of over 422 problems and their acceptable answers on structural inorganic chemistry at the senior undergraduate and beginning graduate level. The central theme running through these questions is symmetry, bonding and structure: molecular or crystalline. A wide variety of topics are covered, including Electronic States and Configurations of Atoms and Molecules, Introductory Quantum Chemistry, Atomic Orbitals, Hybrid Orbitals, Molecular Symmetry, Molecular Geometry and Bonding, Crystal Field Theory, Molecular Orbital Theory, Vibrational Spectroscopy, Crystal Structure, Transition Metal Chemistry, Metal Clusters: Bonding and Reactivity, and Bioinorganic Chemistry. The questions collected here originate from the examination papers and take-home assignments arising from the teaching of courses in Chemical Bonding, Elementary Quantum Chemistry, Advanced Inorganic Chemistry, and X-Ray Crystallography by the book's two senior authors over the past five decades. The questions have been tested by generations of students taking these courses. The questions in this volume cover essentially all the topics in a typical course in structural inorganic chemistry. The text may be used as a supplement for a variety of inorganic chemistry courses at the senior undergraduate level. It also serves as a problem text to accompany the book Advanced Structural Inorganic Chemistry, co-authored by W.-K. Li, G.-D. Zhou, and T. C. W. Mak (Oxford University Press, 2008).

Hot Topics in Crystal Engineering

Author : Kari Rissanen
Publisher : Elsevier
Page : 300 pages
File Size : 41,8 Mb
Release : 2021-08-24
Category : Science
ISBN : 9780128181935

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Hot Topics in Crystal Engineering by Kari Rissanen Pdf

Hot Topics in Crystal Engineering covers the design and synthesis of single crystalline solid-state materials, their properties and applications, focusing on the understanding and use of intermolecular interactions that constitute single crystalline materials. Many of the most modern materials, such as metal-organic frameworks (MOFs) capable of gas storage and separation, and selective entrapment of harmful substances, are the result of the rational use of crystal engineering. Topics covered in this work highlight breakthroughs in this rapidly developing field. This work offers a carefully chosen cross-section of the latest developments, some in their early infancy and some covered for the first time. Provides comprehensive and authoritative articles, giving readers access to a wealth of information to fully support their research and activities Covers the latest developments in crystal engineering, including topics which are in their early infancy Written by leading international experts

Organic Crystal Engineering

Author : Edward R. T. Tiekink,Jagadese Vittal,Michael Zaworotko
Publisher : John Wiley & Sons
Page : 336 pages
File Size : 44,8 Mb
Release : 2010-01-15
Category : Science
ISBN : 9780470681800

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Organic Crystal Engineering by Edward R. T. Tiekink,Jagadese Vittal,Michael Zaworotko Pdf

Organic Crystal Engineering provides reviews of topics in organic crystal engineering that will be of interest to all researchers in molecular solid-state chemistry. Specialist reviews written by internationally recognized researchers, drawn from both academia and industry, cover topics including crystal structure prediction features, polymorphism, reactions in the solid-state, designing new arrays and delineating prominent intermolecular forces for important organic molecules.

Advances in Organic Synthesis

Author : Atta-ur-Rahman
Publisher : Bentham Science Publishers
Page : 317 pages
File Size : 48,8 Mb
Release : 2018-10-18
Category : Science
ISBN : 9781681087474

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Advances in Organic Synthesis by Atta-ur-Rahman Pdf

Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challenging structures. The series presents comprehensive reviews written by eminent authorities on different synthetic approaches to selected target molecules and new methods developed to achieve specific synthetic transformations or optimal product yields. Advances in Organic Synthesis is essential for all organic chemists in academia and the industry who wish to keep abreast of rapid and important developments in the field. This volume presents the following reviews: o Recent Progress on Asymmetric Synthesis of Chiral Flavanones, Chromanones, and Chromenes o Supramolecular Chemistry of Modified Amino Acids and Short Peptides o The Use of Nanocatalysts in the Synthesis of Heterocycles: A Contemporary Approach o Synthesis and Applications of 1,2,3-Triazoles o Ring C–H Functionalization of Aromatic N-Oxides.

Creative Complex Systems

Author : Kazuo Nishimura,Masatoshi Murase,Kazuyoshi Yoshimura
Publisher : Springer Nature
Page : 427 pages
File Size : 49,6 Mb
Release : 2021-10-26
Category : Business & Economics
ISBN : 9789811644573

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Creative Complex Systems by Kazuo Nishimura,Masatoshi Murase,Kazuyoshi Yoshimura Pdf

In recent years, problems such as environmental and economic crises and pandemics caused by new viruses have been occurring on a global scale. Globalization brings about benefits, but it can increase the potential risks of “systemic problems”, leading to system-wide disruptions. The coronavirus pandemic, declared on March 11, 2020, by the World Health Organization, has revealed social disparities in the form of a higher risk of death for people of low-socioeconomic status and has caused massive destruction of the economy and of globalization itself. Extensive efforts to cope with these challenges have often led to the emergence of additional problems due to the chain of hidden causation. What can be done to protect against such emerging challenges? Despite the resulting complexity, once these individual problems are considered as different aspects of a single whole, seemingly contradictory issues can become totally understandable, as they can be integrated into a single coherent framework. This is the integrationist approach in contrast to the reductionist approach. Situations of this kind are truly relevant to understanding the question, “What are creative complex systems?” This book features contributions by members and colleagues of the Kyoto University International Research Unit of Integrated Complex System Science. It broadens our outlook from the traditional view of stability, in which global situations are eventually stabilized after the impact of destruction, to “creative” complex systems.

Crystal Engineering: A Textbook

Author : Gautam R Desiraju,Jagadese J Vittal,Arunachalam Ramanan
Publisher : World Scientific Publishing Company
Page : 232 pages
File Size : 42,7 Mb
Release : 2011-06-20
Category : Science
ISBN : 9789813100695

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Crystal Engineering: A Textbook by Gautam R Desiraju,Jagadese J Vittal,Arunachalam Ramanan Pdf

This book is important because it is the first textbook in an area that has become very popular in recent times. There are around 250 research groups in crystal engineering worldwide today. The subject has been researched for around 40 years but there is still no textbook at the level of senior undergraduates and beginning PhD students. This book is expected to fill this gap.The writing style is simple, with an adequate number of exercises and problems, and the diagrams are easy to understand. This book consists major areas of the subject, including organic crystals and co-ordination polymers, and can easily form the basis of a 30 to 40 lecture course for senior undergraduates.