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Author : N. M. Emanuel',K. Dobson
Publisher : Pergamon
Page : 425 pages
File Size : 43,5 Mb
Release : 1965
Category : Electronic books
ISBN : 0080104916
Author : EMANUEL N. M.
Publisher : Springer
Page : 350 pages
File Size : 49,8 Mb
Release : 1995-12-31
Category : Science
ISBN : 0306302926
Author : Nikolaĭ Markovich Ėmanuėlʹ,Evgeniĭ Timofeevich Denisov,Zinaida Kushelevna Maĭzus
Publisher : Unknown
Page : 374 pages
File Size : 51,5 Mb
Release : 1967
Category : Science
ISBN : UOM:39015009823389
Author : Institut khimicheskoĭ fiziki (Akademii︠a︡ nauk SSSR)
Publisher : Unknown
Page : 434 pages
File Size : 54,6 Mb
Release : 1965
Category : Hydrocarbons
ISBN : STANFORD:36105032082336
Author : N. M. Emanuel'
Publisher : Elsevier
Page : 424 pages
File Size : 55,5 Mb
Release : 2013-11-19
Category : Science
ISBN : 9781483149257
The Oxidation of Hydrocarbons in the Liquid Phase investigates the kinetics and mechanism of the oxidation of hydrocarbons in the liquid phase. Topics covered include the chain reactions taking place in the liquid-phase oxidation of hydrocarbons; the action of inhibitors on degenerately branched chain reactions; and the mechanism of inhibitor action during oxidations with molecular oxygen. The liquid-phase oxidation of some aryl-aliphatic hydrocarbons is also discussed. This book is comprised of 35 chapters and begins with an analysis of the chain processes taking place during the oxidation of hydrocarbons and how to stimulate slow chain branching reactions. The role of peroxides in the kinetics of liquid-phase oxidation processes is then considered, along with several elementary stages of the liquid-phase oxidation of hydrocarbons. Subsequent chapters explore the relationship between the length of unbranched chains and the concentration of oxidation products accumulating in the reaction mixture on the basis of the theory of degenerate chain branching; the effect of various inhibitors on the autocatalytic oxidation of cycloparaffins; the role of metals during the liquid-phase oxidation of fuels; and the oxidation of aromatic hydrocarbons with oxygen. The final chapter examines the behavior of lubricating oils in internal combustion engines, paying particular attention to the influence of temperature and oxygen on the oxidation of the oil both in bulk and in thin films. This monograph will appeal to chemists and engineers and those concerned with the establishment of a detailed mechanism of liquid-phase oxidation reactions.
Author : V. Ya. Shtern
Publisher : Elsevier
Page : 721 pages
File Size : 44,6 Mb
Release : 2016-07-29
Category : Science
ISBN : 9781483185071
The Gas-Phase Oxidation of Hydrocarbons reviews research on the mechanism of oxidation of paraffins, naphthenes, olefines, and aromatic hydrocarbons and explains in detail the phenomena and theories with significant kinetic equations and graphs. This book first presents a study of the development of research on the gaseous-phase oxidation of hydrocarbons. The non-chain schemes for the oxidation of hydrocarbons, such as hydroxylation, peroxidation, and aldehyde and dehydrogenation schemes, are then discussed. This book also presents experimental investigations and important topics such as oxidation of methane and olefinic hydrocarbons. This selection will be invaluable to students and experts in the field of chemistry and related disciplines.
Author : C.H. Bamford,R.G. Compton,C.F.H. Tipper†
Publisher : Elsevier
Page : 263 pages
File Size : 52,7 Mb
Release : 1980-08-01
Category : Science
ISBN : 008086810X
Liquid Phase Oxidation
Author : Evgeniĭ Timofeevich Denisov,Nikolaĭ Ivanovich Mit︠s︡kevich,Vladimir Enokovich Agabekov
Publisher : Unknown
Page : 380 pages
File Size : 54,7 Mb
Release : 1977
Category : Science
ISBN : UOM:39015016096573
Author : Shannon S. Stahl,Paul L. Alsters
Publisher : John Wiley & Sons
Page : 454 pages
File Size : 46,8 Mb
Release : 2016-10-10
Category : Technology & Engineering
ISBN : 9783527337811
The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.
Author : A.E. Shilov
Publisher : Springer Science & Business Media
Page : 226 pages
File Size : 52,5 Mb
Release : 1984-06-30
Category : Science
ISBN : 9027716285
Author : David Azbel
Publisher : Cambridge University Press
Page : 372 pages
File Size : 54,5 Mb
Release : 1981-08-31
Category : Science
ISBN : 0521237726
The behaviour of bubbles is a unifying theme of this book. From an explanation of the fundamentals of bubbles formation at a single orifice, Dr Azbel goes on to set up equations for bubble motion, bubble size, bubble-size distribution and pressure drop across a perforated plate.
Author : Vladimir Arutyunov
Publisher : Elsevier
Page : 320 pages
File Size : 55,9 Mb
Release : 2014-01-30
Category : Technology & Engineering
ISBN : 9780444632517
Direct Methane to Methanol: Foundations and Prospects of the Process offers a state-of-the-art account of one of the most interesting and potentially commercial technologies for direct conversion of natural gas into valuable chemicals. The book thoroughly explains the complex and unusual chemistry of the process, as well as possible applications for direct methane to methanol (DMTM). It covers topics involving thermokinetics, pressure, direct oxidation of heavier alkanes, and more, and provides detailed appendices with experimental data and product yields. This book provides all those who work in the field of gas processing and gas chemistry with the theory and experimental data to develop and apply new processes based on direct oxidation of natural gas. All those who deal with oil and natural gas production and processing will learn about this promising technology for the conversion of gas into more valuable chemicals. Reviews more than 350 publications on high-pressure, low-temperature oxidation of methane and other gas phase hydrocarbons Contains rare material available for the first time in English Explains the reasons of previous failure and outlines the way forward for commercial development of the conversion technology Presents a deep theoretical knowledge of this complex conversion process
Author : Arno de Klerk
Publisher : John Wiley & Sons
Page : 661 pages
File Size : 42,7 Mb
Release : 2011-08-29
Category : Science
ISBN : 9783527326051
The Fischer-Tropsch process is gaining recognition again due to the world-wide increase in energy needs and decrease in oil availability. The increasing interest in utilizing biomass as a potential renewable feedstock in energy generation is further supporting this development. The book covers the production and refining of Fischer-Tropsch syncrude to fuels and chemicals systematically and comprehensively, presenting a wealth of new knowledge and material. As such, it deals extensively with aspects of engineering, chemistry and catalysis. This handbook and ready reference adopts a fundamental approach, looking at the molecules and their transformation from feed to product. Numerous examples illustrate the possibilities and limitations of Fischer-Tropsch syncrude as feesdstock. Of great interest to everyone interested in refining - not just Fischer-Tropsch specialists. From the Contents: Fischer-Tropsch Facilities and Refineries at a Glance Production of Fischer-Tropsch Syncrude Industrial Fischer-Tropsch Facilities Synthetic Transportation Fuels Refining Technology Refinery Design
Author : F. Asinger
Publisher : Elsevier
Page : 920 pages
File Size : 42,7 Mb
Release : 2016-03-05
Category : Technology & Engineering
ISBN : 9781483146621
Paraffins: Chemistry and Technology deals primarily with fundamentals of those methods and processes for the manufacture and chemical treatment of the paraffinic hydrocarbons. The present book, the first edition of which was published by the Akademie-Verlag GmbH, Berlin, in 1956, and an unchanged reprint of which of the first edition was necessary in 1959, has been revised, in 1962, for translation into English. The book begins with a discussion of the production and manufacture of the paraffinic hydrocarbons. Separate chapters then cover the catalytic hydrogenation of carbon monoxide by means of the Fischer-Tropsch synthesis; the chlorination, sulfochlorination, and oxidation the paraffins along with the corresponding products; and the direct nitration of the paraffinic hydrocarbons. Subsequent chapters deal with the sulfoxidation and other substitution reactions of the paraffinic hydrocarbons and isomerization of the paraffinic hydrocarbons. The book is directed primarily to the chemist involved in research and development. It will also give the advanced student a picture of the many-sided possibilities of the use of the paraffinic hydrocarbons, which were long regarded as extraordinarily unreactive.
Author : Evgeny T. Denisov,Taissa Denisova
Publisher : CRC Press
Page : 318 pages
File Size : 40,8 Mb
Release : 1999-11-11
Category : Science
ISBN : 0849390044
Designed for scientists and engineers involved in the chemistry and technology of antioxidants, the Second Edition of this popular handbook continues to provide comprehensive data on the thermodynamics and reactivity of antioxidants. Fully revised and updated, the Second Edition provides the latest data on antioxidants and polymer stabilizers, new data for biological antioxidants, a corrected list of bond dissociation energies, and a full bibliography. Additions and changes in the New Edition: The latest data on O-H bond dissociation energies of phenols and the new scale these values Thermodynamic functions of antioxidants and their intermediate presented in tables A table with current data on dissociation energies of C-H bonds of hydrocarbons and oxygen-containing compounds Rate constants and activation energies of reactions of antioxidants with ozone, nitrogen dioxide, and hydroperoxide Kinetic characteristics of benzoquinine reactions with antioxidants Rate constants of free radical generation through biomolecular reactions with ozone, nitrogen dioxide, and hydroperoxide All calculated data from the first edition has been recalculated in accordance with new data on dissociation energies and parameters of reactivity Data on thermodynamics of hydrogen bond formation of antioxidants All data on cyclic mechanisms of chain termination by antioxidants collected into a special chapter Special chapters on bioantioxidants and stabilization of polymers The Handbook of Antioxidants puts essential data at your fingertips. Its comprehensive nature and ease-of-use make it the resource for scientific researchers and engineers working in the field of physical chemistry of antioxidants.
