Unusual Structures And Physical Properties In Organometallic Chemistry

Author : Marcel Gielen,Rudolph Willem,Bernd Wrackmeyer
Publisher : John Wiley & Sons
Page : 446 pages
File Size : 48,7 Mb
Release : 2003-08-01
Category : Science
ISBN : 9780470855614

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Unusual Structures and Physical Properties in Organometallic Chemistry by Marcel Gielen,Rudolph Willem,Bernd Wrackmeyer Pdf

The principal idea of this volume is to offer a Capita Selecta of unconventional and thought-provoking topics in organometallic chemistry, presented by experts in each field. As intended, this approach leads either to reviews covering a specific uncommon class of organometallic compounds or to overviews which relate uncommon physical properties with various classes of organometallic compounds. The contributions are streamlined thus onto two main axes - unusual properties reflecting structures and bonding situations, on the one hand, and uncommon structural features or structure-reactivity relationships, on the other. Extensive cross-referencing of useful information is provided, making this volume accessible for people working in rather different areas of organometallic chemistry. The synthesis of molecules with 'extreme' properties is a challenge for all those working in organometallic chemistry, irrelevant of theoretical/computational, synthetic or application interests. This book presents case studies at the interface of these overlapping interests. Unusual Structures and Physical Properties in Organometallic Chemistry: * Provides test cases for computational and theoretical models * Presents a challenge for synthetic chemists * Provides ideal show cases for analytical techniques This volume will be an invaluable reference for researchers in organometallic chemistry, computational and theoretical chemistry, NMR and other spectroscopic methods.

Author : Thomas CW Mak,Yu San Cheung,Yingxia Wang,Gong Du Zhou
Publisher : Oxford University Press
Page : 593 pages
File Size : 53,6 Mb
Release : 2023-10-12
Category : Science
ISBN : 9780198872962

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Structural Chemistry across the Periodic Table by Thomas CW Mak,Yu San Cheung,Yingxia Wang,Gong Du Zhou Pdf

This book is an expanded and updated version of Part III of the authors' previous work, Advanced Structural Inorganic Chemistry (OUP 2008). The original part deals with main-group elements, the rare-earth elements, transition-metal clusters, and supramolecular systems. In this new book, selected material from significant advances in the past decade has been added, with particular emphasis on compounds that exemplify new types of bonds such as sigma-hole, triel bond, tetrel bond, pnictogen bond, chalcogen bond, halogen bond, halogen-halogen interaction, aerogen bond, as well as quintuple and sextuple metal-metal bonds. Other new topics include actinide compounds, metallophilicity, heterometallic macrocycles and cages, com- and dis-proportionation reactions, hydrogen-bonded organic frameworks (HOFs), halogen-bonded organic frameworks, halogen-halogen interactions in supramolecular frameworks, covalent organic frameworks (COFs), and metal-organic frameworks (MOFs).

Author : Wai-Kee Li,Gong-Du Zhou,Thomas C. W. Mak,Thomas Mak
Publisher : Oxford University Press
Page : 842 pages
File Size : 45,9 Mb
Release : 2008-03-27
Category : Science
ISBN : 9780199216949

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Advanced Structural Inorganic Chemistry by Wai-Kee Li,Gong-Du Zhou,Thomas C. W. Mak,Thomas Mak Pdf

A revised and updated English edition of a textbook based on teaching at the final year undergraduate and graduate level. It presents structure and bonding, generalizations of structural trends, crystallographic data, as well as highlights from the recent literature.

Author : Marcel Gielen,Rudolph Willem,Bernd Wrackmeyer
Publisher : John Wiley & Sons
Page : 340 pages
File Size : 50,9 Mb
Release : 2005-01-28
Category : Science
ISBN : 9780470858448

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Fluxional Organometallic and Coordination Compounds by Marcel Gielen,Rudolph Willem,Bernd Wrackmeyer Pdf

This series offers leading contributions by well-known chemists reviewing the state of the art of this wide research area. Physical organometallic chemistry aims to develop new insights and to promote novel interest and investigations applicable to organometallic chemistry. This volume focuses on several important topics on fluxionality in organometallic and coordination chemistry, reviewed by experts in each of the respective fields. It is intended to provide both authoritative concepts and stimulating ideas in order to tackle dynamics from different angles, aiming at an interdisciplinary approach. The fascinating fluxionality of metal-ligand interactions has been in the centre of interest ever since modern coordination and organometallic chemistry started, and has expanded towards bioinorganic chemistry, catalysis and materials sciences. Provides information on some of the most relevant physical methods for studying dynamic processes Presents numerous examples of dynamic behavior, demonstrating the efficiency of the respective method and stimulating further applications Connects main group, transition metal and solid state chemistry in the question for dynamics

Author : Toshikazu Hirao
Publisher : Springer Science & Business Media
Page : 302 pages
File Size : 49,5 Mb
Release : 2006-08-02
Category : Technology & Engineering
ISBN : 9783540295808

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Redox Systems Under Nano-Space Control by Toshikazu Hirao Pdf

The generation of novel redox systems under nano-space control is one of the most exciting fields in present organic, inorganic, and supramolecular chemistry. The authors have drawn together the newest information on the construction of such novel redox systems using nano-space control of complexation or molecular chain-induced spaces and metal- or self-assembled spaces through combining techniques in coordination, supramolecular, and bio-inspired chemistry. Such design on the nano level produces hybrid conjugated systems composed of transition and synthetic metals, metallohosts, redox-active self-assembled monolayers of helical peptides, DNA-directed metal arrays, photoactive antibody systems, chiral rotaxanes, and redox-active imprinted polymers. In the future, these systems will be the basis for novel selective electron-transfer reactions as well as new functional materials and catalysts.

Author : Anonim
Publisher : Unknown
Page : 764 pages
File Size : 44,9 Mb
Release : 1975
Category : Nuclear energy
ISBN : UOM:39015023546412

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Nuclear Science Abstracts by Anonim Pdf

Author : Yuichiro Himeda
Publisher : John Wiley & Sons
Page : 320 pages
File Size : 42,7 Mb
Release : 2021-03-30
Category : Technology & Engineering
ISBN : 9783527824090

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CO2 Hydrogenation Catalysis by Yuichiro Himeda Pdf

A guide to the effective catalysts and latest advances in CO2 conversion in chemicals and fuels Carbon dioxide hydrogenation is one of the most promising and economic techniques to utilize CO2 emissions to produce value-added chemicals. With contributions from an international team of experts on the topic, CO2 Hydrogenation Catalysis offers a comprehensive review of the most recent developments in the catalytic hydrogenation of carbon dioxide to formic acid/formate, methanol, methane, and C2+ products. The book explores the electroreduction of carbon dioxide and contains an overview on hydrogen production from formic acid and methanol. With a practical review of the advances and challenges in future CO2 hydrogenation research, the book provides an important guide for researchers in academia and industry working in the field of catalysis, organometallic chemistry, green and sustainable chemistry, as well as energy conversion and storage. This important book: Offers a unique review of effective catalysts and the latest advances in CO2 conversion Explores how to utilize CO2 emissions to produce value-added chemicals and fuels such as methanol, olefins, gasoline, aromatics Includes the latest research in homogeneous and heterogeneous catalysis as well as electrocatalysis Highlights advances and challenges for future investigation Written for chemists, catalytic chemists, electrochemists, chemists in industry, and chemical engineers, CO2 Hydrogenation Catalysis offers a comprehensive resource to understanding how CO2 emissions can create value-added chemicals.

Author : Vladimir I. Bakhmutov
Publisher : John Wiley & Sons
Page : 224 pages
File Size : 52,7 Mb
Release : 2005-04-08
Category : Science
ISBN : 9780470094471

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Practical Nuclear Magnetic Resonance Relaxation for Chemists by Vladimir I. Bakhmutov Pdf

This book demonstrates how NMR relaxation can be applied for structural diagnostics of chemical compounds, recognition of weak intermolecular interactions, determinations of internuclear distances and lengths of chemical bonds when compounds under investigation can exist only in solutions. Written as a textbook for chemists, demanding little background in physics and NMR Its practical approach helps the reader to apply the techniques in the lab First book to teach NMR Relaxation techniques to chemists

Author : Piero Zanello,Carlo Nervi,Fabrizia Fabrizi de Biani
Publisher : Royal Society of Chemistry
Page : 737 pages
File Size : 50,6 Mb
Release : 2019-05-16
Category : Science
ISBN : 9781788018197

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Inorganic Electrochemistry by Piero Zanello,Carlo Nervi,Fabrizia Fabrizi de Biani Pdf

In order to understand the basic aspects of an electrochemical investigation on inorganic molecules (in its widest meaning, of any molecule which contains at least one metal centre) it must be taken into account that in these molecules the metal-ligand bonds are of the prevailingly covalent type. Since electrochemical techniques allow you to add or remove electrons in a controlled manner, it is conceivable that the addition or removal of electrons inside these molecules can lead to the formation of new bonds or to the breakage of existing bonds. The main aim of this book is to study the effects of such electron addition and removal processes on the molecular frames. The second edition of this classic book has been fully revised and updated and is a straightforward, logical introduction to electrochemical investigations for inorganic chemists. All chapters have been rewritten with new material including: - the addition of reactivity with nitric oxide to the chapter on the reactivity of metal complexes with small molecules - thiolate-protected gold nanoclusters has been added to the chapter on metal-sulfur and metal-carbonyl clusters - a new chapter on the digital simulation of electrochemical responses - a new chapter on the theoretical calculations to explain the nature of the electrochemical activity of metal complexes - new chapters on spectroelectrochemistry and electrochemiluminescence. The book covers every aspect of inorganic electrochemistry - the introduction is followed by chapters on the basic aspects of electrochemistry followed by practical and applicative aspects and ends with full appendices. It is probably the only publication with a simple approach to electrochemical aspects of the topics in inorganic chemistry. Bridging the gap between undergraduate and research-level electrochemistry books, this publication will be a welcome addition to the literature of inorganic chemists. It will also be particularly useful to final year students in chemistry and as background reading for graduates and researchers without adequate electrochemical knowledge to become active in the discipline or who want to collaborate with electrochemists.

Author : R. Bruce King
Publisher : Elsevier
Page : 640 pages
File Size : 51,8 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781483290027

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Organometallic Syntheses by R. Bruce King Pdf

Over 160 detailed and tested procedures for the preparation of specific organometallic compounds are given in Volume 4. Part I contains procedures for the synthesis of 76 types of transition metal organometallic compounds, and Part II procedures for the synthesis of 85 nontransition metal organometallic compounds. In both parts, the editors have sought to include procedures that give the safe, reliable synthesis of organometallic compounds that can lay some claim to significance in current chemical research. This significance may be based on various factors such as: (a) the synthesis describes the formation of an unusual or less common structural type; (b) the compound prepared is a useful intermediate in other syntheses; (c) the compound is a model reagent for investigating the mechanisms of various fundamental or industrial processes, such as the Fischer-Tropsch reaction; (d) the compound is a useful reagent in organic synthesis; and (e) the techniques employed in the synthesis of the compound are unusual and worthy of further application, such as metal-atom and electrochemical procedures. Each specific or generalized procedure is organized into the following sections: an Introduction which discusses the available procedures and the reasons guiding the choice of the one selected; a Procedure section which strives to describe the modus operandi, the safety concerns and pitfalls in the preparation; a Properties section that offers further physical and chemical data on the product and, where appropriate, indications of how the compounds can be employed in research; and a Reference section which gives both leading literature citations and supplemental comments on the procedure. Research laboratories in organometallic chemistry, organic chemistry, inorganic chemistry and molecular catalysis have in this book a rich source of information on the preparation of organometallic compounds.

Author : Geoffrey C. Bond
Publisher : Springer Science & Business Media
Page : 677 pages
File Size : 41,8 Mb
Release : 2006-10-03
Category : Science
ISBN : 9780387261119

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Metal-Catalysed Reactions of Hydrocarbons by Geoffrey C. Bond Pdf

This unique book, drawing on the author’s lifetime experience, critically evaluates the extensive literature on the field of Metal-Catalysed Reactions of Hydrocarbons. Emphasis is placed on reaction mechanisms involving hydrogenation, hydrogenolysis, skeletal and positional isomerisation, and exchange reactions. The motivation for fundamental research in heterogeneous catalysis is to identify the physicochemical characteristics of active centres for the reaction being studied, to learn how these may be modified or manipulated to improve the desired behavior of the catalyst, and to recognize and control those aspects of the catalyst's structure that limit its overall performance. By restricting the subject of the book to hydrocarbons, Bond has progressively developed the subject matter to include areas of importance both to researchers and to those working in the industry.

Author : Marcel Gielen
Publisher : Wiley
Page : 288 pages
File Size : 52,5 Mb
Release : 2008-06-24
Category : Science
ISBN : 0470779519

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Organometallic Chemistry by Marcel Gielen Pdf

Organometallic Chemistry comprises of seven essential references. Click on the individual titles for further information about the volumes included in the set. Metallotherapeutic Drugs and Metal-Based Diagnostic Agents: The Use of Metals in Medicine Marcel Gielen (Editor), Edward R.T. Tiekink (Editor) ISBN: 978-0-470-86403-6 Hardcover | 638 pages Publication Date: March 2005 Handbook of Metalloproteins, 3-Volume Set Albrecht Messerschmidt (Editor) ISBN: 978-0-470-86981-9 Hardcover | 2308 pages Publication Date: March 2004 Fluxional Organometallic and Coordination Compounds Marcel Gielen (Editor), Rudolph Willem (Editor), Bernd Wrackmeyer (Editor) ISBN: 978-0-470-85839-4 Hardcover | 340 pages Publication Date: August 2004 Unusual Structures and Physical Properties in Organometallic Chemistry Marcel Gielen (Editor), Rudolph Willem (Editor), Bernd Wrackmeyer (Editor) ISBN: 978-0-471-49635-9 Hardcover | 446 pages Publication Date: September 2002 Solid State Organometallic Chemistry: Methods and Applications Marcel Gielen (Editor), Rudolph Willem (Editor), Bernd Wrackmeyer (Editor) ISBN: 978-0-471-97920-3 Hardcover | 548 pages Publication Date: October 1999

Author : Vladimir I. Bakhmutov
Publisher : CRC Press
Page : 360 pages
File Size : 54,8 Mb
Release : 2015-04-10
Category : Medical
ISBN : 9781482262728

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NMR Spectroscopy in Liquids and Solids by Vladimir I. Bakhmutov Pdf

NMR Spectroscopy in Liquids and Solids provides an introduction of the general concepts behind Nuclear Magnetic Resonance (NMR) and its applications, including how to perform adequate NMR experiments and interpret data collected in liquids and solids to characterize molecule systems in terms of their structure and dynamics. The book is composed of ten chapters. The first three chapters consider the theoretical basis of NMR spectroscopy, the theory of NMR relaxation, and the practice of relaxation measurements. The middle chapters discuss the general aspects of molecular dynamics and their relationships to NMR, NMR spectroscopy and relaxation studies in solutions, and special issues related to NMR in solutions. The remaining chapters introduce general principles and strategies involved in solid-state NMR studies, provide examples of applications of relaxation for the determination of molecular dynamics in diamagnetic solids, and discuss special issues related to solid state NMR— including NMR relaxation in paramagnetic solids. All chapters are accompanied by references and recommended literature for further reading. Many practical examples of multinuclear NMR and relaxation experiments and their interpretations are also presented. The book is ideal for scientists new to NMR, students, and investigators working in the areas of chemistry, biochemistry, biology, pharmaceutical sciences, or materials science.

Author : A. K. Holliday,G. Hughes,S. M. Walker
Publisher : Elsevier
Page : 167 pages
File Size : 43,5 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781483151946

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The Chemistry of Carbon by A. K. Holliday,G. Hughes,S. M. Walker Pdf

The Chemistry of Carbon: Organometallic Chemistry is a specialist's selection of certain chapters in Comprehensive Inorganic Chemistry comprising five volumes. This book contains corrections and added prefatory material and individual indices. This volume deals with carbon (Chapter 13) and describes organic chemistry of the metallic elements (Chapter 14). Carbon is unique in its ability to form strong chemical bonds with itself or other elements. Graphite and diamonds are some elementary forms of carbon. Chapter 14 discusses the basis for a qualitative, comparative description of the organic chemistry of metals and any inorganic chemistry found common in them. The book uses the covalent model in describing both bondings made in most organometallic compounds and inorganic derivatives. The text also discusses the atoms in molecules, particularly in a molecular ion, as having both ligands X and a central atom M. A table then shows the classification of some common ligands, grouping them according to the number of valence electrons that make up their bonding. The text then explains the general trends in the chemistry of the main group elements of the Periodic Table that contain ns and np orbitals in their valence shells. The book also discusses some atomic properties, their consequences, and the occurrence of unpaired electrons in organo transition metal complexes. This book will be valuable for students and professors dealing with general chemistry, gemologists, molecular scientists, and researchers.

Author : Vladimir I. Bakhmutov
Publisher : John Wiley & Sons
Page : 256 pages
File Size : 45,9 Mb
Release : 2008-03-03
Category : Science
ISBN : 0470226749

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Dihydrogen Bond by Vladimir I. Bakhmutov Pdf

This definitive reference consolidates current knowledge on dihydrogen bonding, emphasizing its role in organizing interactions in different chemical reactions and molecular aggregations. After an overview, it analyzes the differences between dihydrogen bonds, classical hydrogen bonds, and covalent bonds. It describes dihydrogen bonds as intermediates in intramolecular and intermolecular proton transfer reactions. It describes dihydrogen bonding in the solid-state, the gas phase, and in solution. This is the premier reference for physical chemists, biochemists, biophysicists, and chemical engineers.