Vibronic Interactions Jahn Teller Effect In Crystals And Molecules

Author : Michael D. Kaplan,George O. Zimmerman
Publisher : Springer Science & Business Media
Page : 378 pages
File Size : 43,8 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401009850

Get Book

Vibronic Interactions: Jahn-Teller Effect in Crystals and Molecules by Michael D. Kaplan,George O. Zimmerman Pdf

This book is based mostly on the reports presented at the XVth International lahn-Teller Symposium on Vibronic Interactions in Crystals and Molecules and NATO Advanced Research Workshop Colossal Magnetoresistance and Vibronic Interactions that took place at Boston on August 16-22 of the year 2000. This is the first time the Symposium took place in the USA where recently the giant splash of the attention to the 1 ahn-Teller effect occurred. This tremendous interest to the field all over the world is reflected not only in the numerous publications in many American and European 10urnals, but of the leading scientists from additionally in the Symposium's participation the well known Universities, National Laboratories and industrial companies, which was the largest in the history of the Symposium. The renaissance of the 1ahn-Teller physics is closely related to the three fundamental discoveries in science. The most significant among them is the discovery of high-Tc superconductivity by K. -A. Muller and G. Bednorz, for whom the "1ahn-Teller idea" was the motivation in their search. The result of this search is well known - a wide spectrum of the 1ahn-Teller ion based materials with Tc between 24K and 135K were found. The second discovery is the existence of a new polymorph of carbon - the C60. The microscopic analysis of all physical, chemical and biological properties of the buckyballs is based on 1ahn-Teller type of interactions. The third is colossal magnetoresistance.

Author : Michael D. Kaplan,George O. Zimmerman
Publisher : Springer
Page : 0 pages
File Size : 54,8 Mb
Release : 2001-10-31
Category : Science
ISBN : 1402000448

Get Book

Vibronic Interactions: Jahn-Teller Effect in Crystals and Molecules by Michael D. Kaplan,George O. Zimmerman Pdf

This book is based mostly on the reports presented at the XVth International lahn-Teller Symposium on Vibronic Interactions in Crystals and Molecules and NATO Advanced Research Workshop Colossal Magnetoresistance and Vibronic Interactions that took place at Boston on August 16-22 of the year 2000. This is the first time the Symposium took place in the USA where recently the giant splash of the attention to the 1 ahn-Teller effect occurred. This tremendous interest to the field all over the world is reflected not only in the numerous publications in many American and European 10urnals, but of the leading scientists from additionally in the Symposium's participation the well known Universities, National Laboratories and industrial companies, which was the largest in the history of the Symposium. The renaissance of the 1ahn-Teller physics is closely related to the three fundamental discoveries in science. The most significant among them is the discovery of high-Tc superconductivity by K. -A. Muller and G. Bednorz, for whom the "1ahn-Teller idea" was the motivation in their search. The result of this search is well known - a wide spectrum of the 1ahn-Teller ion based materials with Tc between 24K and 135K were found. The second discovery is the existence of a new polymorph of carbon - the C60. The microscopic analysis of all physical, chemical and biological properties of the buckyballs is based on 1ahn-Teller type of interactions. The third is colossal magnetoresistance.

Author : Isaac B. Bersuker,Victor Z. Polinger
Publisher : Springer Science & Business Media
Page : 434 pages
File Size : 45,9 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642834790

Get Book

Vibronic Interactions in Molecules and Crystals by Isaac B. Bersuker,Victor Z. Polinger Pdf

Vibronic interaction effects constitute a new field of investigation in the physics and chemistry of molecules and crystals that combines all the phenomena and laws originating from the mixing of different electronic states by nuclear displacements. This field is based on a new concept which goes beyond the separate descriptions of electronic and nuclear motions in the adiabatic approximation. Publications on this topic often appear under the title of the lahn-Thller effect, although the area of application of the new approach is much wider: the term vibronic interaction seems to be more appropriate to the field as a whole. The present understanding of the subject was reached only recently, during the last quarter of a century. As a result of intensive development of the theory and experiment, it was shown that the nonadiabatic mixing of close-in-energy elec tronic states under nuclear displacements and the back influence of the modified electronic structure on the nuclear dynamics result in a series of new effects in the properties of molecules and crystals. The applications of the theory of vibronic in of spectroscopy [including visible, ultraviolet, in teractions cover the full range frared, Raman, EPR, NMR, nuclear quadrupole resonance (NQR), nuclear gam ma resonance (NOR), photoelectron and x-ray spectroscopy], polarizability and magnetic susceptibility, scattering phenomena, ideal and impurity crystal physics and chemistry (including structural as well as ferroelectric phase transitions), stereochemistry and instability of molecular (including biological) systems, mechanisms of chemical reactions and catalysis.

Author : Isaac Bersuker
Publisher : Springer Science & Business Media
Page : 328 pages
File Size : 42,8 Mb
Release : 2013-06-29
Category : Science
ISBN : 9781461326533

Get Book

The Jahn-Teller Effect and Vibronic Interactions in Modern Chemistry by Isaac Bersuker Pdf

The first half of the title of this book may delude the uninitiated reader. The term '"Jahn-Teller effect," taken literally, refers to a special effect inherent in particular molecular systems. Actually, this term implies a new approach to the general problem of correlations between the structure and properties of any molecular polyatomic system, including solids. Just such a new approach, or concept (in some sense, a new outlook or even a new way of thinking), which leads not to one special effect but to a series of different effects and laws, is embodied in the many ( ~ 4000) studies devoted to the investigation and application of the Jahn-Teller effect. The term "vibronic interactions" seems to be most appropriate to the new concept, and this explains the origin of the second half of the title. The primary objective of this book is to present a systematic develop ment of the concept of vibronic interactions and its applications, and to illustrate its possibilities and significance in modern chemistry. In the first three chapters (covering about one-third of the book) the theoretical background of the vibronic concept and Jahn-Teller effect is given. The basic ideas are illustrated fully, although a comprehensive presentation of the theory with all related mathematical deductions is beyond the scope of this book. In the last three chapters the applications of theory to spectro scopy, stereochemistry and crystal chemistry, reactivity, and catalysis, are illustrated by a series of effects and laws.

Author : Mihail Atanasov,Claude Daul,Philip L.W. Tregenna-Piggott
Publisher : Springer Science & Business Media
Page : 451 pages
File Size : 41,8 Mb
Release : 2011-11-23
Category : Science
ISBN : 9789400723849

Get Book

Vibronic Interactions and the Jahn-Teller Effect by Mihail Atanasov,Claude Daul,Philip L.W. Tregenna-Piggott Pdf

The concepts of the Jahn-Teller effect and vibronic coupling are being applied to more and more systems in both chemistry and physics. Aspects of structural chemistry such as the distortion of the nuclear framework to a lower-symmetry conformation have received an increasing attention, as well as the dynamics on the coupled potential energy surfaces. The Jahn-Teller intersections are now recognized as prototype cases of conical intersections where the nuclear motion is known to be inherently nonadiabatic in nature and interchanges freely between the different potential energy surfaces. In the condensed phase especially, the significance of the Jahn-Teller effect has been increasingly appreciated, following the discovery of superconductivity in the fullerides and of very large ("colossal") magnetoresistance in the manganite perovskites. Indeed, these materials are particularly challenging since the Jahn-Teller interaction competes with electronic correlation effects. Vibronic Interactions and the Jahn-Teller Effect: Theory and Applications provides an in-depth discussion of the Jahn-Teller effect and vibronic interactions as reflected by the contributions presented at the XX International Conference on the Jahn-Teller effect, Fribourg, Switzerland, 2010. The following topics have been treated in a clear and concise way: • Complex topologies of Jahn-Teller effect and conical intersections • Multi-state vibronic interactions on strongly coupled potential energy surfaces • Interplay of vibronic and spin-orbit coupling • Strain in Jahn-Teller systems and cooperative Jahn-Teller effect • Orbital ordering and its relation to ferromagnetism, ferroelectricity and molecular magnets • The Jahn-Teller effect in icosahedral systems • The Jahn-Teller effect and high temperature superconductivity This book is of interest to a wide audience including academic and industrial theoretical and experimental physicists, chemists, spectroscopists, and crystallographers.

Author : Isaac B Bersuker,Victor Z Polinger
Publisher : Unknown
Page : 440 pages
File Size : 54,5 Mb
Release : 1989-08-10
Category : Electronic
ISBN : 3642834809

Get Book

Vibronic Interactions in Molecules and Crystals by Isaac B Bersuker,Victor Z Polinger Pdf

Author : R. Englman
Publisher : John Wiley & Sons
Page : 374 pages
File Size : 44,6 Mb
Release : 1972
Category : Science
ISBN : MINN:31951000522336N

Get Book

The Jahn-Teller Effect in Molecules and Crystals by R. Englman Pdf

Author : Michael D. Kaplan,Benjamin G. Vekhter
Publisher : Springer Science & Business Media
Page : 438 pages
File Size : 43,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781461518594

Get Book

Cooperative Phenomena in Jahn—Teller Crystals by Michael D. Kaplan,Benjamin G. Vekhter Pdf

This book by Kaplan and Vekhter brings together the molecular world of the chemist with the condensed matter world of the physicist. Prior to the collapse of the Soviet Union, chemists in the West devoted lit to relationships between molecular electronic structure and tle attention solid-state vibronic phenomena. Treating quantum mechanical problems wherein the adiabatic Born-Oppenheimer approximation fails was done by "brute force. " With bigger and better computers available in the West, molecular orbital calculations were done on observed and conceived static structures with little concern for any cooperativity of vibrational behavior that might connect these states. While it had long been understood in the West that situations do occur in which different static structures are found for molecules that have identical or nearly identical electronic structures, little attention had been paid to understanding the vibrational states that could connect such structures. It was easier to calculate the electronic structure observed with several possible distortions than to focus on ways to couple electronic and vibrational behavior. In the former Soviet Union, computational power was not as acces sible as in the West. Much greater attention, therefore, was devoted to conserving computational time by considering fundamental ways to han dle the vibrational connectivity between degenerate or nearly degenerate electronic states.

Author : Horst Köppel,David R. Yarkony,Heinz Barentzen
Publisher : Springer Science & Business Media
Page : 912 pages
File Size : 41,5 Mb
Release : 2009-12-08
Category : Science
ISBN : 9783642034329

Get Book

The Jahn-Teller Effect by Horst Köppel,David R. Yarkony,Heinz Barentzen Pdf

The Jahn-Teller effect continues to be a paradigm for structural instabilities and molecular dynamical processes. This volume provides a survey of the current Jahn-Teller interactions at the interface of quantum chemistry and condensed matter physics.

Author : Isaac Bersuker
Publisher : Springer
Page : 319 pages
File Size : 48,9 Mb
Release : 1984-01-01
Category : Science
ISBN : 0306652064

Get Book

The Jahn-Teller Effect:A Bibliographic Review by Isaac Bersuker Pdf

Author : Gad Fischer
Publisher : Unknown
Page : 234 pages
File Size : 44,5 Mb
Release : 1984
Category : Science
ISBN : MINN:31951000564073V

Get Book

Vibronic Coupling by Gad Fischer Pdf

Author : C. C. Chancey,M. C.M. O'Brien
Publisher : Princeton University Press
Page : 221 pages
File Size : 46,7 Mb
Release : 2021-02-09
Category : Science
ISBN : 9780691225340

Get Book

The Jahn-Teller Effect in C60 and Other Icosahedral Complexes by C. C. Chancey,M. C.M. O'Brien Pdf

Because of the high symmetry involved, the Jahn-Teller effect is the natural starting point for considering electron-phonon (or vibronic) interactions in icosahedral molecules. This work is the first comprehensive theoretical analysis of the Jahn-Teller interaction in C60 and other icosahedral complexes. The importance of this research derives in part from the increasing, widespread interest in C60 and other molecular clusters and their application in science and industry. The electrical and spectroscopic properties of fullerene and fulleride compounds depend intimately on the coupling between the electronic and vibrational modes of these systems, and this book addresses the fundamental theoretical questions. In particular, a chapter is devoted to the connection between the theory and experimental observations, such as ESR (electron spin resonance) effects and molecular spectra. Earlier books have discussed the theory of Jahn-Teller interactions in lower symmetry structures (cubic, tetrahedral, tetragonal, trigonal,...); this is the first that focuses on the new icosahedral systems, whose most famous example is Buckminsterfullerene, C60. The book's authors have over fifty years of combined research experience into the theoretical aspects of the Jahn-Teller effect.

Author : Magdolna Hargittai,Istvan Hargittai
Publisher : Springer Science & Business Media
Page : 528 pages
File Size : 51,8 Mb
Release : 2009-02-28
Category : Science
ISBN : 9781402056284

Get Book

Symmetry through the Eyes of a Chemist by Magdolna Hargittai,Istvan Hargittai Pdf

It is gratifying to launch the third edition of our book. Its coming to life testi?es about the task it has ful?lled in the service of the com- nity of chemical research and learning. As we noted in the Prefaces to the ?rst and second editions, our book surveys chemistry from the point of view of symmetry. We present many examples from ch- istry as well as from other ?elds to emphasize the unifying nature of the symmetry concept. Our aim has been to provide aesthetic pl- sure in addition to learning experience. In our ?rst Preface we paid tribute to two books in particular from which we learned a great deal; they have in?uenced signi?cantly our approach to the subject matter of our book. They are Weyl’s classic, Symmetry, and Shubnikov and Koptsik’s Symmetry in Science and Art. The structure of our book has not changed. Following the Int- duction (Chapter 1), Chapter 2 presents the simplest symmetries using chemical and non-chemical examples. Molecular geometry is discussed in Chapter 3. The next four chapters present gro- theoretical methods (Chapter 4) and, based on them, discussions of molecular vibrations (Chapter 5), electronic structures (Chapter 6), and chemical reactions (Chapter 7). For the last two chapters we return to a qualitative treatment and introduce space-group sym- tries (Chapter 8), concluding with crystal structures (Chapter 9). For the third edition we have further revised and streamlined our text and renewed the illustrative material.

Author : ConferenceSeries
Publisher : ConferenceSeries
Page : 212 pages
File Size : 42,5 Mb
Release : 2024-07-01
Category : Electronic
ISBN : 8210379456XXX

Get Book

Proceedings of 19th World Congress on Materials Science and Engineering 2018 by ConferenceSeries Pdf

June 11-13, 2018 Barcelona, Spain Key Topics : Materials Science and Engineering, Nanomaterials and Nanotechnology, Biomaterials and Medical Devices, Polymer Science and Technology, Ceramics and Composite Materials, Electronic, Optical and Magnetic Materials, Emerging Smart Materials, Materials for Energy and Environmental Sustainability, Physics and Chemistry of Materials, Metals, Mining, Metallurgy and Materials, Mechanics, Characterization Techniques and Equipments, Graphene and 2D Materials,

Author : Martin Quack,Frederic Merkt
Publisher : John Wiley & Sons
Page : 2236 pages
File Size : 47,6 Mb
Release : 2011-09-26
Category : Science
ISBN : 9780470066539

Get Book

Handbook of High-resolution Spectroscopy by Martin Quack,Frederic Merkt Pdf

The field of High-Resolution Spectroscopy has been considerably extended and even redefined in some areas. Combining the knowledge of spectroscopy, laser technology, chemical computation, and experiments, Handbook of High-Resolution Spectroscopy provides a comprehensive survey of the whole field as it presents itself today, with emphasis on the recent developments. This essential handbook for advanced research students, graduate students, and researchers takes a systematic approach through the range of wavelengths and includes the latest advances in experiment and theory that will help and guide future applications. The first comprehensive survey in high-resolution molecular spectroscopy for over 15 years Brings together the knowledge of spectroscopy, laser technology, chemical computation and experiments Brings the reader up-to-date with the many advances that have been made in recent times Takes the reader through the range of wavelengths, covering all possible techniques such as Microwave Spectroscopy, Infrared Spectroscopy, Raman Spectroscopy, VIS, UV and VUV Combines theoretical, computational and experimental aspects Has numerous applications in a wide range of scientific domains Edited by two leaders in this field Provides an overview of rotational, vibration, electronic and photoelectron spectroscopy Volume 1 - Introduction: Fundamentals of Molecular Spectroscopy Volume 2 - High-Resolution Molecular Spectroscopy: Methods and Results Volume 3 - Special Methods & Applications