Water In Crystalline Hydrates Aqueous Solutions Of Simple Nonelectrolytes

Author : Felix Franks
Publisher : Springer Science & Business Media
Page : 697 pages
File Size : 54,9 Mb
Release : 2013-04-18
Category : Science
ISBN : 9781475769586

Get Book

Water in Crystalline Hydrates Aqueous Solutions of Simple Nonelectrolytes by Felix Franks Pdf

vi the information collected and discussed in this volume may help toward the achievement of such an objective. I should like to express my debt of gratitude to the authors who have contributed to this volume. Editing a work of this nature can strain long established personal relationships and I thank my various colleagues for bearing with me and responding (sooner or later) to one or several letters or telephone calls. My special thanks once again go to Mrs. Joyce Johnson, who bore the main brunt of this seemingly endless correspondence and without whose help the editorial and referencing work would have taken several years. F. FRANKS Biophysics Division Unilever Research Laboratory Colworth/ Welwyn Colworth House, Sharnbrook, Bedford January, 1973 Contents Contents of Volume 1 ............................. . . . . . .. . . .. xv Contents of Volume 3 ........................ '. . . . . . . . . . . . xvi . . . . Contents of Volume 4 . . . . . . . . . . . . . . . . . . . . . . . . .. . . . xvii . . . . . . . . . . . Chapter 1 The Solvent Properties of Water F. Franks 1. Water, the Universal Solvent-the Study of Aqueous Solutions 2. Aqueous Solutions of Nonelectrolytes ................. . 5 2.1. Apolar Solutes ................................. . 6 2.2. Polar Solutes .................................. . 19 2.3. Ionic Solutes Containing Alkyl Residues-"Apolar Electrolytes" ................................... . 38 3. Aqueous Solutions of Electrolytes .................... . 42 3.1. Single Ion Properties ............................ . 42 3.2. Ion-Water Interactions ......................... . 43 3.3. Interionic Effects ............................... . 47 4. Complex Aqueous Mixtures 48 Chapter 2 Water in Stoichiometric Hydrates M. Falk and O. Knop 1. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 . . . . . . . . . . . . . 2. Symmetry and Types of Environment of the H0 Molecule 2 in Crystals .......................................... 57 vii Contents viii 2.1. Site Symmetry. . . . . . . . . . . . . . . . . . . . . . . . . 57 . . . . . . . . . .

Author : Felix Franks
Publisher : Springer Science & Business Media
Page : 482 pages
File Size : 48,8 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781468429558

Get Book

Aqueous Solutions of Simple Electrolytes by Felix Franks Pdf

The chapters making up this volume had originally been planned to form part of a single volume covering solid hydrates and aqueous solutions of simple molecules and ions. However, during the preparation of the manu scripts it became apparent that such a volume would turn out to be very unwieldy and I reluctantly decided to recommend the publication of sepa rate volumes. The most sensible way of dividing the subject matter seemed to lie in the separation of simple ionic solutions. The emphasis in the present volume is placed on ion-solvent effects, since a number of excellent texts cover the more general aspects of electrolyte solutions, based on the classical theories of Debye, Huckel, On sager, and Fuoss. It is interesting to speculate as to when a theory becomes "classical." Perhaps this occurs when it has become well known, well liked, and much adapted. The above-mentioned theories of ionic equilibria and transport certainly fulfill these criteria. There comes a time when the refinements and modifications can no longer be related to physical significance and can no longer hide the fact that certain fundamental assumptions made in the development of the theory are untenable, especially in the light of information obtained from the application of sophisticated molecular and thermodynamic techniques.

Author : Felix Franks
Publisher : Springer Science & Business Media
Page : 495 pages
File Size : 50,9 Mb
Release : 2013-11-11
Category : Science
ISBN : 9781475769524

Get Book

Water and Aqueous Solutions at Subzero Temperatures by Felix Franks Pdf

This Volume, the last of the series, is devoted to water in its metastable forms, especially at sub-zero temperatures. The past few years have wit nessed an increasing interest in supercooled water and amorphous ice. If the properties of liquid water in the normal temperature range are already eccentric, then they become exceedingly so below the normal freezing point, in the metastable temperature range. Water can be supercooled to -39°C without too much effort, and most of its physical properties show a re markable temperature dependence under these conditions. Although ade quate explanations are still lacking, the time has come to review available knowledge. The study of amorphous ice, that is, the solid formed when water vapor is condensed on a very cold surface, is of longer standing. It has achieved renewed interest because it may serve as a model for the liquid state. There is currently a debate whether or not a close structural relation ship exists between amorphous ice and supercooled water. The nucleation and growth of ice in supercooled water and aqueous solutions is also still one of those grey areas of research, although these topics have received considerable attention from chemists and physicists over the past two decades. Even now, the relationships between degree of supercooling, nucleation kinetics, crystal growth kinetics, cooling rate and solute concentration are somewhat obscure. Nevertheless, at the empirical level much progress has been made, because these topics are of considerable importance to biologists, technologists, atmospheric physicists and gla ciologists.

Author : Anonim
Publisher : Unknown
Page : 874 pages
File Size : 53,7 Mb
Release : 1974
Category : Water
ISBN : STANFORD:36105007166320

Get Book

Selected Water Resources Abstracts by Anonim Pdf

Author : H. R. Thirsk
Publisher : Royal Society of Chemistry
Page : 123 pages
File Size : 51,5 Mb
Release : 1970
Category : Electronic
ISBN : 9780851860473

Get Book

Electrochemistry Vol 5 by H. R. Thirsk Pdf

Annotation. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.

Author : H R Thirsk
Publisher : Royal Society of Chemistry
Page : 322 pages
File Size : 50,6 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847557186

Get Book

Electrochemistry by H R Thirsk Pdf

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.

Author : Felix Franks
Publisher : Springer Science & Business Media
Page : 848 pages
File Size : 52,6 Mb
Release : 2013-04-17
Category : Science
ISBN : 9781468429589

Get Book

Water A Comprehensive Treatise by Felix Franks Pdf

Author : Felix Franks
Publisher : Springer Science & Business Media
Page : 610 pages
File Size : 40,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781468483345

Get Book

The Physics and Physical Chemistry of Water by Felix Franks Pdf

to arrive at some temporary consensus model or models; and to present reliable physical data pertaining to water under a range of conditions, i.e., "Dorsey revisited," albeit on a less ambitious scale. I should like to acknowledge a debt of gratitude to several of my col leagues, to Prof. D. J. G. Ives and Prof. Robert L. Kay for valuable guidance and active encouragement, to the contributors to this volume for their willing cooperation, and to my wife and daughters for the understanding shown to a husband and father who hid in his study for many an evening. My very special thanks go to Mrs. Joyce Johnson, who did all the cor respondence and much of the arduous editorial work with her usual cheerful efficiency. F. FRANKS Biophysics Division Unilever Research Laboratory ColworthjWelwyn Colworth House, Sharnbrook, Bedford March 1972 Contents Chapter 1 Introduction-Water, the Unique Chemical F. Franks I. lntroduction ........................................ . 2. The Occurrence and Distribution of Water on the Earth 2 3. Water and Life ...................................... 4 4. The Scientific Study of Water-A Short History ........ 8 5. The Place of Water among Liquids . . . . . . . . . . . . . . . 13 . . . . . Chapter 2 The Water Moleeule C. W. Kern and M. Karplus 1. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 . . . . . . . . . . 2. Principles of Structure and Spectra: The Born-Oppenheimer Separation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 . . . . . . . . . . . . 3. The Electronic Motion ............................... 26 3.1. The Ground Electronic State of Water ............ 31 3.2. The Excited Electronic States of Water ........... 50 4. The Nuclear Motion ................................. 52 5. External-Field Effects ................................. 70 5.1. Perturbed Hartree-Fock Method . . . . . . . . . . . . . . . 74 . . .

Author : Gustavo V. Barbosa-Cánovas,Anthony J. Fontana, Jr.,Shelly J. Schmidt,Theodore P. Labuza
Publisher : John Wiley & Sons
Page : 456 pages
File Size : 52,9 Mb
Release : 2008-04-15
Category : Technology & Engineering
ISBN : 9780470376362

Get Book

Water Activity in Foods by Gustavo V. Barbosa-Cánovas,Anthony J. Fontana, Jr.,Shelly J. Schmidt,Theodore P. Labuza Pdf

Water Activity in Foods: Fundamentals and Applications is a one-of-a-kind reference text that brings together an international group of food scientists, chemists, and engineers to present a broad but thorough coverage of an important factor known to influence the attributes of foods – water activity. A team of experienced editors designed this book for lasting value as a sound introduction to the concept of water activity for neophytes and seasoned professionals in both academe and industry. Topics have been carefully selected to provide a comprehensive understanding of the mechanisms by which water activity influences the quality, shelf life, and safety of food products. Water Activity in Foods belongs on the shelves of all food science professionals for use in product development, quality control, and food safety. Students and newcomers to these areas will appreciate the instructional approach adopted by the experienced teachers and industry specialists who have contributed chapters to this comprehensive overview.

Author : R F Barrow,Derek A Long,J Sheridan
Publisher : Royal Society of Chemistry
Page : 338 pages
File Size : 55,6 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847556738

Get Book

Molecular Spectroscopy by R F Barrow,Derek A Long,J Sheridan Pdf

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Author : Anonim
Publisher : Royal Society of Chemistry
Page : 338 pages
File Size : 53,7 Mb
Release : 1973
Category : Molecular spectra
ISBN : 9780851865560

Get Book

Molecular Spectroscopy Volume 6 by Anonim Pdf

This product is not available separately, it is only sold as part of a set. There are 750 products in the set and these are all sold as one entity. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Author : Willem Norde
Publisher : CRC Press
Page : 498 pages
File Size : 50,8 Mb
Release : 2011-06-06
Category : Medical
ISBN : 9781439817186

Get Book

Colloids and Interfaces in Life Sciences and Bionanotechnology, Second Edition by Willem Norde Pdf

Colloidal systems occur everywhere—in soils, seawater, foodstuff, pharmaceuticals, paints, blood, biological cells, and microorganisms. Colloids and Interfaces in Life Sciences and Bionanotechnology, Second Edition, gives a concise treatment of physicochemical principles determining interrelated colloidal and interfacial phenomena. New in the Second Edition: New topics, including phase separations in polymer systems, electrokinetics of charged permeable surface coatings, and polymer brush coatings to control adsorption and adhesion of particles Emphasis on inter-particle interactions and surface phenomena in (bio)nanotechnology Full solutions to over 100 updated and additional exercises are presented in the Appendix Focusing on physicochemical concepts that form the basis of understanding colloidal and interfacial phenomena—rather than on experimental methods and techniques—this book is an excellent primer for students and scientists interested in colloidal and interfacial phenomena, their mutual relations and connections, and the fascinating role they play in natural and man-made systems.

Author : Urs von Stockar,Luuk A. M. van der Wielen
Publisher : CRC Press
Page : 632 pages
File Size : 53,9 Mb
Release : 2013-05-30
Category : Science
ISBN : 9781466582163

Get Book

Biothermodynamics by Urs von Stockar,Luuk A. M. van der Wielen Pdf

This book covers the fundamentals of the rapidly growing field of biothermodynamics, showing how thermodynamics can best be applied to applications and processes in biochemical engineering. It describes the rigorous application of thermodynamics in biochemical engineering to rationalize bioprocess development and obviate a substantial fraction of this need for tedious experimental work. As such, this book will appeal to a diverse group of readers, ranging from students and professors in biochemical engineering, to scientists and engineers, for whom it will be a valuable reference.

Author : Tatsuko Hatakeyama,Hyoe Hatakeyama
Publisher : Springer Science & Business Media
Page : 336 pages
File Size : 55,6 Mb
Release : 2006-01-27
Category : Technology & Engineering
ISBN : 9781402023545

Get Book

Thermal Properties of Green Polymers and Biocomposites by Tatsuko Hatakeyama,Hyoe Hatakeyama Pdf

From the reviews: "...This very well written new book is recommended to academic and industrial researchers and specialists interested in green polymers and mainly in their thermal properties...This new and opportune book covers some important properties of green polymers and bio-composites." (D. Feldman, Concordia University, Montreal, Canada)

Author : A.L. Horvath
Publisher : CRC Press
Page : 920 pages
File Size : 43,9 Mb
Release : 2020-11-25
Category : Science
ISBN : 9781000110227

Get Book

Halogenated Hydrocarbons by A.L. Horvath Pdf

This book promotes a basic understanding of the concept of solubility and miscibility between halogenated hydrocarbons and water. It points out the regularities existing between solubility and physical properties of solute and solvent. The book is valuable to chemists and chemical engineers.