Advanced Applications Of Nmr To Organometallic Chemistry

Author : Marcel Gielen,Rudolph Willem,Bernd Wrackmeyer
Publisher : John Wiley & Sons
Page : 408 pages
File Size : 45,6 Mb
Release : 1996-12-23
Category : Science
ISBN : UCAL:B4378645

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Advanced Applications of NMR to Organometallic Chemistry by Marcel Gielen,Rudolph Willem,Bernd Wrackmeyer Pdf

This new series offers leading contributions by well known chemists reviewing the state-of-the-art of this wide research area. Physical Organometallic Chemistry aims to develop new insights and to promote novel interest and investigations applicable to organometallic chemistry. NMR spectroscopy has had a considerable impact on many fields of chemistry, although it has served organometallic chemistry mainly on a routine level. In a collection of reviews, leading chemists provide an insight into the scope of applications and uncover the potential of this technique for organometallic chemists. Advanced Applications of NMR to Organometallic Chemistry; Illustrates how recent 1D and 2D and specialized multinuclear applications can solve specific problems encountered by organometallic chemists Surveys modern NMR techniques in organometallic chemistry Includes metal NMR related techniques Focuses on the advent of solid state NMR in organometallic chemistry This book will prove invaluable to the NMR spectroscopist and organometallic chemists and will also be of interest to all organic, inorganic and physical chemists Contents: Selective Excitation and Selective Detection in 29Si NMR; Two-dimensional 13C, Metal Nuclei Correlation; Two-dimensional 1H-119Sn Proton Detected Correlation Spectroscopy in Coordination Chemistry of Hypervalent Organotin Compounds; Indirect Nuclear 119Sn-X Spin-Spin Coupling; Solid State NMR Applications in Organotin and Organolead Chemistry; Solid State NMR Investigations of Metal Carbonyl Complexes; High Pressure NMR in Organometallic Chemistry; Multinuclear NMR Spectroscopy in Supercritical Fluids; High Resolution 6,7Li NMR of Organolithium Compounds; Metal NMR of Organovanadium, -Niobium and -Tantalum Compounds; NMR of Metallic Nuclei in Clusters; 171Yb NMR Spectroscopy.

Author : J.F. Harrod,R.M. Laine
Publisher : Springer Science & Business Media
Page : 352 pages
File Size : 54,6 Mb
Release : 2012-12-06
Category : Technology & Engineering
ISBN : 9789401103374

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Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials by J.F. Harrod,R.M. Laine Pdf

In the ten years since the scientific rationale for the design, synthesis and application of inorganic and organometallic polymers (IOPs) was first conceptualised, we have witnessed the first tentative exploration of IOPs as precursors to new materials, with efforts focusing on the design and synthesis of novel ceramic precursors. Developing expertise led to precursor studies combined with the characterisation of the transformation processes that occur when IOPs are converted to ceramic materials. Now at maturity, the science presented in this volume reveals the polymer precursor approach to materials synthesis together with examples of processing ceramic shapes for a range of mechanical properties, the development of sophisticated, noninvasive analytical techniques, and IOP design rationales relying on well-defined processing-property relationships. The production of multifunctional IOPs is described, providing ion conductivity, gas sensing, bioactivity, magnetic properties, etc., combined with processability. The existence of well-defined IOPs and the exquisite control that can be exerted on sol-gel systems now provide access to such a variety of mixed organic-organometallic and/or inorganic hybrid systems that their exploitation is likely to develop into an entirely new field of materials chemistry. Future exciting avenues of research are also being opened up with the advent of buckyballs, Met-Cars, dopable preceramics, rigid-rod organometallics, and molecular tinkertoys.

Author : L. M. Jackman,S. Sternhell
Publisher : Elsevier
Page : 474 pages
File Size : 48,9 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781483280943

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Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry by L. M. Jackman,S. Sternhell Pdf

Application of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry, Second Edition covers the theoretical background necessary for the intelligent application of NMR spectroscopy to common problems encountered in organic chemistry. This book is composed of five parts, and begins with introduction to the theory and practice of nuclear magnetic resonance. The succeeding chapter deals with the theory of chemical effects in NMR spectroscopy. These topics are followed by a discussion on the application of chemical shift to organic compound analysis and the principles of the spin-spin coupling .The final chapter considers the applications of time- dependent phenomena in NMR spectroscopy. This book will prove useful to analytical chemists and researchers in the allied fields.

Author : Norman S. Bhacca,Dudley H. Williams
Publisher : Unknown
Page : 216 pages
File Size : 50,6 Mb
Release : 1964
Category : Science
ISBN : UOM:39015000311822

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Applications of NMR Spectroscopy in Organic Chemistry by Norman S. Bhacca,Dudley H. Williams Pdf

Author : Marcel Gielen,Rudolph Willem,Bernd Wrackmeyer
Publisher : John Wiley & Sons
Page : 340 pages
File Size : 47,5 Mb
Release : 2005-01-28
Category : Science
ISBN : 9780470858448

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Fluxional Organometallic and Coordination Compounds by Marcel Gielen,Rudolph Willem,Bernd Wrackmeyer Pdf

This series offers leading contributions by well-known chemists reviewing the state of the art of this wide research area. Physical organometallic chemistry aims to develop new insights and to promote novel interest and investigations applicable to organometallic chemistry. This volume focuses on several important topics on fluxionality in organometallic and coordination chemistry, reviewed by experts in each of the respective fields. It is intended to provide both authoritative concepts and stimulating ideas in order to tackle dynamics from different angles, aiming at an interdisciplinary approach. The fascinating fluxionality of metal-ligand interactions has been in the centre of interest ever since modern coordination and organometallic chemistry started, and has expanded towards bioinorganic chemistry, catalysis and materials sciences. Provides information on some of the most relevant physical methods for studying dynamic processes Presents numerous examples of dynamic behavior, demonstrating the efficiency of the respective method and stimulating further applications Connects main group, transition metal and solid state chemistry in the question for dynamics

Author : Harald Günther
Publisher : Unknown
Page : 612 pages
File Size : 43,6 Mb
Release : 1995-03-15
Category : Science
ISBN : UOM:39015059080021

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NMR Spectroscopy by Harald Günther Pdf

As with its predecessor, this edition uses a practical non-mathematical approach. Features a number of recent developments in the field including two-dimensional methods, solid state NMR and an enlarged treatment of Fourier Transform methods. Contains numerous two-color diagrams.

Author : B. I. Ionin
Publisher : Springer Science & Business Media
Page : 396 pages
File Size : 55,9 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781468417852

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NMR Spectroscopy in Organic Chemistry by B. I. Ionin Pdf

In recent years high-resolution nuclear magnetic resonance spec troscopy has found very wide application in organie chemistry in structural and physicochemical investigations and. also in the study of the characteristics of organic compounds which are re lated to the distribution of the electron cloud in the molecules. The vigorous development of this method, which may really be re garded as an independent branch of science, is the result of ex tensive progress in NMR technology, the refinement of its theory, and the accumulation of large amounts of experimental material, which has been correlated by empiricallaws and principles. The literature directly concerned with the NMR method and its applica tion has now grown to such an extent that a complete review of it is practically impossible. Therefore the authors have limited themselves to an examination of only the most important, funda mental, and general investigations. The book consists of six chapters. In the first chapter we have attempted to present the fundamentals of the NMR method in such a way that the reader with little knowledge of the subject will be able to use the method in practical work for investigating simple compounds and solving simple problems. The three subsequent chapters give a deeper analysis of the method, while the last two chapters and the appendix illustrate the various applications of NMR spectroscopy in organic chemistry.

Author : J.W. Akitt,B. E. Mann
Publisher : CRC Press
Page : 400 pages
File Size : 50,8 Mb
Release : 2017-12-21
Category : Science
ISBN : 9781482268379

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NMR and Chemistry by J.W. Akitt,B. E. Mann Pdf

Keeping mathematics to a minimum, this book introduces nuclear properties, nuclear screening, chemical shift, spin-spin coupling, and relaxation. It is one of the few books that provides the student with the physical background to NMR spectroscopy from the point of view of the whole of the periodic table rather than concentrating on the narrow applications of 1H and 13C NMR spectroscopy. Aids to structure determination, such as decoupling, the nuclear Overhauser effect, INEPT, DEPT, and special editing, and two dimensional NMR spectroscopy are discussed in detail with examples, including the complete assignment of the 1H and 13C NMR spectra of D-amygdain. The authors examine the requirements of a modern spectrometer and the effects of pulses and discuss the effects of dynamic processes as a function of temperature or pressure on NMR spectra. The book concludes with chapters on some of the applications of NMR spectroscopy to medical and non-medical imaging techniques and solid state chemistry of both I = F1/2 and I > F1/2 nuclei. Examples and problems, mainly from the recent inorganic/organometallic chemistry literature support the text throughout. Brief answers to all the problems are provided in the text with full answers at the end of the book.

Author : Paul S. Pregosin
Publisher : John Wiley & Sons
Page : 416 pages
File Size : 50,7 Mb
Release : 2013-07-26
Category : Science
ISBN : 9783527680313

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NMR in Organometallic Chemistry by Paul S. Pregosin Pdf

The first and ultimate guide for anyone working in transition organometallic chemistry and related fields, providing the background and practical guidance on how to efficiently work with routine research problems in NMR. The book adopts a problem-solving approach with many examples taken from recent literature to show readers how to interpret the data. Perfect for PhD students, postdocs and other newcomers in organometallic and inorganic chemistry, as well as for organic chemists involved in transition metal catalysis.

Author : L. M. Jackman,S. Sternhell
Publisher : Elsevier
Page : 473 pages
File Size : 41,7 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781483138596

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Application of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry by L. M. Jackman,S. Sternhell Pdf

Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry, Second Edition focuses on the applications of nuclear magnetic resonance spectroscopy to problems in organic chemistry and the theories involved in this kind of spectroscopy. The book first discusses the theory of nuclear magnetic resonance, including dynamic and magnetic properties of atomic nuclei, nuclear resonance, and relaxation process. The manuscript also examines the experimental method. Topics include experimental factors that influence resolution and the shapes of absorption lines; measurement of line positions and identification of the chemical shift; and measurement of intensities. The text reviews the theories of chemical effects in nuclear magnetic resonance spectroscopy and spin-spin multiplicity and the theory and applications of multiple irradiation. The book also tackles the theory of chemical shift, including the classification of shielding effects, local diamagnetic proton shielding, solvent effects, and contact shifts. The publication is a dependable source of data for readers interested in the applications of nuclear magnetic resonance spectroscopy.

Author : Lloyd Miles Jackman,S. Sternhell
Publisher : Pergamon
Page : 484 pages
File Size : 51,6 Mb
Release : 1969
Category : Science
ISBN : CHI:29616297

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Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry by Lloyd Miles Jackman,S. Sternhell Pdf

Author : Anonim
Publisher : Academic Press
Page : 448 pages
File Size : 46,7 Mb
Release : 1999-06-10
Category : Science
ISBN : 0080584217

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Annual Reports on NMR Spectroscopy by Anonim Pdf

Over recent years, no other technique has grown to such importance as that of NMR spectroscopy. It is used in all branches of science where precise structural determination is required, and where the nature of interactions and reactions in solution is being studied. Annual Reports on NMR Spectroscopy has established itself as a means for the specialist and non-specialist alike to become familiar with new applications of the technique in all branches of chemistry, including biochemistry, and pharmaceutics. Once again, the Annual Reports on NMR Spectroscopy represents the best work in the field, both in applied and theoretical NMR spectroscopy. The high calibre reports in Volume 38 show the wide biological and physical applications that benefit from this analytical technique.

Author : Michinori Ōki
Publisher : VCH
Page : 448 pages
File Size : 41,9 Mb
Release : 1985
Category : Chemistry, Organic
ISBN : UCAL:B4378795

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Applications of Dynamic NMR Spectroscopy to Organic Chemistry by Michinori Ōki Pdf

Author : G Davidson
Publisher : Royal Society of Chemistry
Page : 474 pages
File Size : 45,8 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847555151

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Spectroscopic Properties of Inorganic and Organometallic Compounds by G Davidson Pdf

Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique source of information on an important area of chemistry. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in this field, researchers will find this Specialist Periodical Report an invaluable source of information on current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr

Author : Marcel Gielen
Publisher : John Wiley & Sons
Page : 752 pages
File Size : 47,6 Mb
Release : 2008-09-15
Category : Science
ISBN : 9780470758083

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Tin Chemistry by Marcel Gielen Pdf

Tin chemistry retains a place in contemporary science as an important element owing to its wide range of applications. New and exciting research is being generated on an annual basis from all parts of the world – the study of tin and its compounds attracts considerable interest from a range of perspectives such as organic synthesis, medicine, materials chemistry, catalysis and environment. Tin Chemistry – Fundamentals, Frontiers and Applications collects, in one comprehensive volume, authoritative and concise snapshots of modern tin chemistry in a full range of applications. Over forty of the leading tin chemistry experts have contributed reviews in six themes: fundamentals in tin chemistry materials chemistry and structural chemistry of tin compounds medicinal and biocidal applications of tin compounds tin in the environment tin in organic synthesis tin in catalysis Tin Chemistry – Fundamentals, Frontiers and Applications is an essential overview of modern perspectives on this important element for the specialist and non-specialist alike. It will promote cross-disciplinary interactions and at the same time be an essential teaching resource for advanced university classes.