Biomass Derived Heterogeneous And Homogeneous Catalysts
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Biomass Derived Heterogeneous and Homogeneous Catalysts by José María Encinar Martín,Sergio Nogales Delgado Pdf
In this book, the performance of homogeneous and heterogeneous catalysts applied in biomass processing was assessed, paying special attention to the main advantages and challenges related to their use. Indeed, these challenges are opportunities to develop new research lines that could be fruitful in the near future. Thus, different studies are included, dealing with diverse subjects, with one main goal in common: the improvement of different aspects related to biomass processing through the use of catalysts.
Biomass Derived Heterogeneous and Homogeneous Catalysts by José María Encinar Martín,Sergio Nogales Delgado Pdf
In this book, the performance of homogeneous and heterogeneous catalysts applied in biomass processing was assessed, paying special attention to the main advantages and challenges related to their use. Indeed, these challenges are opportunities to develop new research lines that could be fruitful in the near future. Thus, different studies are included, dealing with diverse subjects, with one main goal in common: the improvement of different aspects related to biomass processing through the use of catalysts.
Advanced Functional Solid Catalysts for Biomass Valorization by Chaudhery Mustansar Hussain,Putla Sudarsanam Pdf
Advanced Functional Solid Catalysts for Biomass Valorization presents the basic concepts in catalysis (homogeneous, heterogeneous, and enzymatic) and the properties of various kinds of heterogeneous solid catalysts, including their structure, porosity, particle size, BET surface area, acid-base, and redox properties. Useful information about biorefineries, types of biomass feedstocks, their structures and properties as well as about several potential catalytic routes for biomass upgrading to useful fuels and chemicals is provided in this book. Importantly, this book covers the most recent developments toward functionalization of various solid catalysts, optimization of catalysts’ properties, developing cascade catalytic strategies, exploring reaction kinetics/mechanisms, and evaluating catalysts’ stability/reusability during biomass upgrading. Current challenges and opportunities for the future biorefineries as well as for the design of advanced functional solid catalysts are critically discussed. Describes catalysis as a promising technology for the development of eco-friendly and economically viable strategies for several important energy and environmental applications. Covers heterogeneous solid catalysts because of their versatile benefits in terms of catalysts’ synthesis, production cost, stability, and reusability as compared to homogeneous liquid catalysts. Provides promising strategies for the design of new catalytic materials, such as carbon materials, metal–organic frameworks, zeolites, and mesoporous silicas. Describes functional solid catalysts for developing one-pot cascade processes for efficient biomass valorization and other vital chemical transformations.
Compiled by a well-known expert in the field, Liquid Biofuels provides a profound knowledge to researchers about biofuel technologies, selection of raw materials, conversion of various biomass to biofuel pathways, selection of suitable methods of conversion, design of equipment, selection of operating parameters, determination of chemical kinetics, reaction mechanism, preparation of bio-catalyst: its application in bio-fuel industry and characterization techniques, use of nanotechnology in the production of biofuels from the root level to its application and many other exclusive topics for conducting research in this area. Written with the objective of offering both theoretical concepts and practical applications of those concepts, Liquid Biofuels can be both a first-time learning experience for the student facing these issues in a classroom and a valuable reference work for the veteran engineer or scientist. The description of the detailed characterization methodologies along with the precautions required during analysis are extremely important, as are the detailed description about the ultrasound assisted biodiesel production techniques, aviation biofuels and its characterization techniques, advance in algal biofuel techniques, pre-treatment of biomass for biofuel production, preparation and characterization of bio-catalyst, and various methods of optimization. The book offers a comparative study between the various liquid biofuels obtained from different methods of production and its engine performance and emission analysis so that one can get the utmost idea to find the better biofuel as an alternative fuel. Since the book covers almost all the field of liquid biofuel production techniques, it will provide advanced knowledge to the researcher for practical applications across the energy sector. A valuable reference for engineers, scientists, chemists, and students, this volume is applicable to many different fields, across many different industries, at all levels. It is a must-have for any library.
Chemical Catalysts for Biomass Upgrading by Mark Crocker,Eduardo Santillan-Jimenez Pdf
A comprehensive reference to the use of innovative catalysts and processes to turn biomass into value-added chemicals Chemical Catalysts for Biomass Upgrading offers detailed descriptions of catalysts and catalytic processes employed in the synthesis of chemicals and fuels from the most abundant and important biomass types. The contributors?noted experts on the topic?focus on the application of catalysts to the pyrolysis of whole biomass and to the upgrading of bio-oils. The authors discuss catalytic approaches to the processing of biomass-derived oxygenates, as exemplified by sugars, via reactions such as reforming, hydrogenation, oxidation, and condensation reactions. Additionally, the book provides an overview of catalysts for lignin valorization via oxidative and reductive methods and considers the conversion of fats and oils to fuels and terminal olefins by means of esterification/transesterification, hydrodeoxygenation, and decarboxylation/decarbonylation processes. The authors also provide an overview of conversion processes based on terpenes and chitin, two emerging feedstocks with a rich chemistry, and summarize some of the emerging trends in the field. This important book: -Provides a comprehensive review of innovative catalysts, catalytic processes, and catalyst design -Offers a guide to one of the most promising ways to find useful alternatives for fossil fuel resources -Includes information on the most abundant and important types of biomass feedstocks -Examines fields such as catalytic cracking, pyrolysis, depolymerization, and many more Written for catalytic chemists, process engineers, environmental chemists, bioengineers, organic chemists, and polymer chemists, Chemical Catalysts for Biomass Upgrading presents deep insights on the most important aspects of biomass upgrading and their various types.
Author : Tomas R Reina,Jose A Odriozola Publisher : Royal Society of Chemistry Page : 533 pages File Size : 40,6 Mb Release : 2020-08-27 Category : Science ISBN : 9781788019583
Heterogeneous Catalysis for Energy Applications by Tomas R Reina,Jose A Odriozola Pdf
Heterogeneous catalysis plays a central role in the global energy paradigm, with practically all energy-related process relying on a catalyst at a certain point. The application of heterogeneous catalysts will be of paramount importance to achieve the transition towards low carbon and sustainable societies. This book provides an overview of the design, limitations and challenges of heterogeneous catalysts for energy applications. In an attempt to cover a broad spectrum of scenarios, the book considers traditional processes linked to fossil fuels such as reforming and hydrocracking, as well as catalysis for sustainable energy applications such as hydrogen production, photocatalysis, biomass upgrading and conversion of CO2 to clean fuels. Novel approaches in catalysts design are covered, including microchannel reactors and structured catalysts, catalytic membranes and ionic liquids. With contributions from leaders in the field, Heterogeneous Catalysis for Energy Applications will be an essential toolkit for chemists, physicists, chemical engineers and industrials working on energy.
Reaction Pathways and Mechanisms in Thermocatalytic Biomass Conversion II by Marcel Schlaf,Z. Conrad Zhang Pdf
Volume II presents the latest advances in catalytic hydrodeoxygenation and other transformations of some cellulosic platform chemicals to high value-added products. It presents the theoretical evaluation of the energetics and catalytic species involved in potential pathways of catalyzed carbohydrate conversion, pathways leading to the formation of humin-based by-products, and thermal pathways in deriving chemicals from lignin pyrolysis and hydrodeoxygenation. Catalytic gasification of biomass under extreme thermal conditions as an extension of pyrolysis is also discussed. Marcel Schlaf, PhD, is a Professor at the Department of Chemistry, University of Guelph, Canada. Z. Conrad Zhang, PhD, is a Professor at the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, China.
Advanced Catalysis for Drop-in Chemicals by Putla Sudarsanam,Hu Li Pdf
Biomass conversion into drop-in chemicals using novel heterogeneous bulk- and nano-scale catalysts is currently a hot research topic with the aim of replacing petrochemicals in the chemical industry. Considering the importance of this subject to the scientific community, Advanced Catalysis for Drop-in Chemicals provides the latest developments in the catalytic synthesis of drop-in chemicals mainly from lignocellulose, carbohydrates (cellulose, hemicellulose, C6 and C5 sugars, and their derivatives), lignin, and glycerol. The role of both heterogeneous bulk solid and nanostructured catalysts, along with their advantages and disadvantages for drop-in chemicals synthesis are critically summarized. Addressing the frontiers and prospects for using drop-in chemicals in place of petrochemicals in the chemical industry is also a key topic of this book. • Describes fossil fuels, biomass, drop-in chemicals, catalysis, and nano- and atomic-scale catalysts • Includes pre- and post-treatment strategies for biomass upgrading • Provides green catalytic processes for drop-in chemicals synthesis • Outlines stabilization of nano- and atomic-scale catalysts • Examines using drop-in chemicals in place of petrochemicals in the chemical industry
Production of Biofuels and Chemicals with Bifunctional Catalysts by Zhen Fang,Richard L. Smith Jr.,Hu Li Pdf
This book provides state-of-the-art reviews, current research, prospects and challenges of the production of biofuels and chemicals such as furanic biofuels, biodiesel, carboxylic acids, polyols and others from lignocellulosic biomass, furfurals, syngas and γ-valerolactone with bifunctional catalysts, including catalytic, and combined biological and chemical catalysis processes. The bifunctionality of catalytic materials is a concept of not only using multifunctional solid materials as activators, but also design of materials in such a way that the catalytic materials have synergistic characteristics that promote a cascade of transformations with performance beyond that of mixed mono-functional catalysts. This book is a reference designed for researchers, academicians and industrialists in the area of catalysis, energy, chemical engineering and biomass conversion. Readers will find the wealth of information contained in chapters both useful and essential, for assessing the production and application of various biofuels and chemicals by chemical catalysis and biological techniques.
Nanoporous Catalysts for Biomass Conversion by Feng-Shou Xiao,Liang Wang Pdf
A comprehensive introduction to the design, synthesis, characterization, and catalytic properties of nanoporous catalysts for the biomass conversion With the specter of peak oil demand looming on the horizon, and mounting concerns over the environmental impact of greenhouse gas emissions, biomass has taken on a prominent role as a sustainable alternative fuel source. One critical aspect of the biomass challenge is the development of novel catalytic materials for effective and controllable biomass conversion. Edited by two scientists recognized internationally for their pioneering work in the field, this book focuses on nanoporous catalysts, the most promising class of catalytic materials for the conversion of biomass into fuel and other products. Although various catalysts have been used in the conversion of biomass-derived feedstocks, nanoporous catalysts exhibit high catalytic activities and/or unique product selectivities due to their large surface area, open nanopores, and highly dispersed active sites. This book covers an array of nanoporous catalysts currently in use for biomass conversion, including resins, metal oxides, carbons, mesoporous silicates, polydivinylbenzene, and zeolites. The authors summarize the design, synthesis, characterization and catalytic properties of these nanoporous catalysts for biomass conversions, discussing the features of these catalysts and considering future opportunities for developing more efficient catalysts. Topics covered include: Resins for biomass conversion Supported metal oxides/sulfides for biomass oxidation and hydrogenation Nanoporous metal oxides Ordered mesoporous silica-based catalysts Sulfonated carbon catalysts Porous polydivinylbenzene Aluminosilicate zeolites for bio-oil upgrading Rice straw Hydrogenation for sugar conversion Lignin depolymerization Timely, authoritative, and comprehensive, Nanoporous Catalysts for Biomass Conversion is a valuable working resource for academic researchers, industrial scientists and graduate students working in the fields of biomass conversion, catalysis, materials science, green and sustainable chemistry, and chemical/process engineering.
Biorefineries by Michele Aresta,Angela Dibenedetto,Franck Dumeignil Pdf
Biorefineries compiles the basic science and technologies used to convert terrestrial and aquatic biomass into essential molecular compounds and polymeric materials. The book provides in depth insights into this fairly recent concept of industrial chemistry that aims to achieve optimal economic profits while minimizing the environmental impact. Chapters written by renowned experts cover, amongst others, the application of catalysis, downstream processing, biomass sourced olefins, lignin biorefinery techniques and biogas. The authors thoroughly examine and explain the value chain for biomass conversion into platform molecules and their transformation into final products. A comprehensive thematic overview on the topic giving beginners access to fundamental concepts is presented. Supplemented by numerous full color figures and tables, the contents impart knowledge about the involved techniques. Advanced students and experts in the field will find the summary of state-of-the-art research and current literature of valuable interest. Explores the enormous potential of biomass conversion as a future source for fuels and chemicals Focuses on both general scientific background and current innovations in the field of biorefinery Targets students and researchers in Chemistry, Chemical Engineering, Biotechnology, and Materials Science About the Editors Prof. Michele Aresta, Chair of the Scientific Committee of CIRCC in Italy and holds the IMM Chair at the Department of Chemical and Biomolecular Engineering at NUS, Singapore. He is author of over 200 papers and Author or Editor of nine books. Prof. Angela Dibenedetto, Associate Professor at the Department of Chemistry of the University of Bari (Italy) focused on carbon dioxide utilization by applying biorefinery concepts; and Director of the Interuniversity Consortium on Chemical Reactivity and Catalysis-CIRCC. Prof. Franck Dumeignil, Deputy Director of the CNRS joint Unit of Catalysis and Chemistry of Solid (UCCS) of Lille University (France); project coordinator of several projects on chemistry, including the EuroBioRef Project for designing next generation biorefineries.
John C. Chadwick,Rob Duchateau,Zoraida Freixa,Piet W. N. M. van Leeuwen
Author : John C. Chadwick,Rob Duchateau,Zoraida Freixa,Piet W. N. M. van Leeuwen Publisher : John Wiley & Sons Page : 592 pages File Size : 49,5 Mb Release : 2011-06-09 Category : Science ISBN : 9783527636006
Homogeneous Catalysts by John C. Chadwick,Rob Duchateau,Zoraida Freixa,Piet W. N. M. van Leeuwen Pdf
This first book to illuminate this important aspect of chemical synthesis improves the lifetime of catalysts, thus reducing material and saving energy, costs and waste. The international panel of expert authors describes the studies that have been conducted concerning the way homogeneous catalysts decompose, and the differences between homogeneous and heterogeneous catalysts. The result is a ready reference for organic, catalytic, polymer and complex chemists, as well as those working in industry and with/on organometallics.
Biofuel Extraction Techniques by Lalit Prasad,Subhalaxmi Pradhan,S. N. Naik Pdf
BIOFUEL EXTRACTION TECHNIQUES The energy industry and new energy sources and innovations are rapidly changing and evolving. This new volume addresses the current state-of-the-art concepts and technologies associated with biofuel extraction technologies. Biofuels are a viable alternative to petroleum-based fuel because they are produced from organic materials such as plants and their wastes, agricultural crops, and by-products. The development of cutting-edge technology has increased the need for energy significantly, which has resulted in an overreliance on fossil fuels. Renewable fuels are an important subject of research because of their biodegradability, eco-friendliness, decrease in greenhouse gas (GHG) emissions, and favorable socioeconomic consequences to counteract imitations of fossil fuels. Different extraction techniques are used for the production of biofuel from renewable feedstocks. A good example is biodiesel, a promising biofuel which is produced by transesterification of plant-based oils. Extraction of oil includes traditional methods, solvent extraction, mechanical extraction, microwave-assisted and ultrasonic-assisted methods. Many innovative techniques are also used to overcome the limitations of conventional methods. Microwave-assisted and ultrasonic-assisted are some of the new techniques which include the pre-treatment of the raw material using either ultrasonic waves or radio waves which helps in increasing the efficiency of the extraction of oil and improves the final quality of the oil. Written and edited a team of experts in the field, this exciting new volume covers all of these technologies with a view toward giving the engineer, scientist, or other professional the practical solutions for their day-to-day problems. It also contains the theory behind the practical applications, as well, making it the perfect reference for students and engineers alike. Whether for the veteran engineer or scientist, the student, or a manager or other technician working in the field, this volume is a must-have for any library.
