Compounds Of The Transition Elements Involving Metal Metal Bonds

Author : D. L. Kepert,K. Vrieze
Publisher : Elsevier
Page : 174 pages
File Size : 52,5 Mb
Release : 2016-06-06
Category : Science
ISBN : 9781483138077

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Compounds of the Transition Elements Involving Metal-Metal Bonds by D. L. Kepert,K. Vrieze Pdf

Compounds of the Transition Elements Involving Metal-Metal Bonds focuses on compounds of the transition elements involving metal-metal bonds. Emphasis is on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. Factors that influence the formation, stability, and properties of such compounds, as well as their application in various fields of chemistry and physics, are discussed. This book is divided into four sections and begins with a classification of metal-metal bonds and some of the physical and chemical methods used to study them, including X-ray crystallography, magnetic susceptibility and electron spin resonance, nuclear spin resonance, Mössbauer measurements, infrared and Raman spectroscopy, visible and ultraviolet spectroscopy, mass spectrometry, electrical conductivity, electrochemistry, and chemical reactivity. Factors influencing the strength of metal-metal bonds in metals and compounds are also examined. The remaining sections deal with metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. This monograph will be a useful resource for inorganic chemists.

Author : David L. Kepert,K. Vrieze
Publisher : Pergamon
Page : 158 pages
File Size : 52,8 Mb
Release : 1975
Category : Metal bonding
ISBN : 008018880X

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Compounds of the Transition Elements Involving Metal-metal Bonds by David L. Kepert,K. Vrieze Pdf

Compounds of the Transition Elements Involving Metal-Metal Bonds deals with compounds of the transition elements involving metal-metal bonds, with particular emphasis on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. Factors that influence the formation, stability, and properties of such compounds, as well as their application in various fields of chemistry and physics, are discussed. This book is divided into four sections and begins with a classification of metal-metal bonds and some of the physical and chemical methods used to study them, inc...

Author : Florian P. Pruchnik
Publisher : Springer Science & Business Media
Page : 767 pages
File Size : 54,8 Mb
Release : 2013-06-29
Category : Science
ISBN : 9781489920768

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Organometallic Chemistry of the Transition Elements by Florian P. Pruchnik Pdf

Organometallic chemistry belongs to the most rapidly developing area of chemistry today. This is due to the fact that research dealing with the structure of compounds and chemical bonding has been greatly intensified in recent years. Additionally, organometallic compounds have been widely utilized in catalysis, organic synthesis, electronics, etc. This book is based on my lectures concerning basic organometallic chemistry for fourth and fifth year chemistry students and on my lectures concerning advanced organometallic chemistry and homogeneous catalysis for Ph.D. graduate students. Many recent developments in the area of organometallic chemistry as weIl as homogeneous catalysis are presented. Essential research results dealing with a given class of organometallic compounds are discussed briefly. Results of physicochemical research methods of various organometallic compounds as weIl as their synthesis, properties, structures, reactivities, and applications are discussed more thoroughly. The selection of tabulated data is arbitrary because, often, it has been impossible to avoid omissions. Nevertheless, these data can be very helpful in understanding properties of organometaIlic compounds and their reactivities. All physical data are given in SI units; the interatomic distances are given in pm units in figures and tables. I am indebted to Professor S. A. Duraj for translating and editing this book. His remarks, discussions, and suggestions are greatly appreciated. I also express gratitude to Virginia E. Duraj for editing and proofreading.

Author : A. P. Hagen
Publisher : John Wiley & Sons
Page : 727 pages
File Size : 54,5 Mb
Release : 2009-09-17
Category : Science
ISBN : 9780470145500

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Inorganic Reactions and Methods, The Formation of Bonds to Transition and Inner-Transition Metals by A. P. Hagen Pdf

Boasting numerous industrial applications, inorganic chemistry forms the basis for research into new materials and bioinorganic compounds such as calcium that act as biological catalysts. Now complete, this highly acclaimed series presents current knowledge in all areas of inorganic chemistry, including chemistry of the elements; organometallic, polymeric and solid-state materials; and compounds relevant to bioinorganic chemistry.

Author : Paul J. Dyson,J. Scott McIndoe
Publisher : CRC Press
Page : 180 pages
File Size : 55,5 Mb
Release : 2018-10-03
Category : Science
ISBN : 9781482283075

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Transition Metal Carbonyl Cluster Chemistry by Paul J. Dyson,J. Scott McIndoe Pdf

Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.

Author : Leslie E. Orgel
Publisher : Unknown
Page : 184 pages
File Size : 44,9 Mb
Release : 1966
Category : Chemistry, Physical and theoretical
ISBN : MINN:31951000521540T

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An Introduction to Transition-metal Chemistry: Ligand-field Theory by Leslie E. Orgel Pdf

Author : Sajjad Haider,adnan Haider
Publisher : BoD – Books on Demand
Page : 121 pages
File Size : 51,5 Mb
Release : 2021-06-09
Category : Technology & Engineering
ISBN : 9781839680489

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Transition Metal Compounds by Sajjad Haider,adnan Haider Pdf

This book explores synthesis, structural changes, properties, and potential applications of transition metal (TM) compounds. Over three sections, chapters cover such topics as the synthesis of pentoxide vanadium (V2O5), the effect of TM compounds on structural, dielectric properties and high-temperature superconductors, and TM-doped nanocrystals (NCs).

Author : Michael Dub,Richard W. Weiss
Publisher : Springer
Page : 845 pages
File Size : 42,8 Mb
Release : 2013-12-01
Category : Science
ISBN : 9783662252291

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Compounds of Transition Metals by Michael Dub,Richard W. Weiss Pdf

The aim of this Compilation has been to provide a comprehensive, non critical source of information concerning organometallic compounds. The scope is limited to the compounds containing at least one carbon-metal bond. The information includes methods of preparation, properties, chemical reactions and applications. The First Edition comprised the literature from 1937 to 1958. The Second Edition is completely revised and extended through 1964. The literature prior to 1937 was thoroughly covered by E. Krause and A. von Grosse in 11 11 Die Chemie der metall-organischen Verbindungen, Verlag von Gebrueder Borntraeger, Berlin, 1937. Our work consists of three volumes. Volume I contains derivatives of the transition metals of Groups III through VIII of the Periodic Table. Volume II contains derivatives of germanium, tin and lead. Volume Ill contains derivatives of arsenic, antimony and bismuth. The Compilation is based on searches through Chemical Abstracts. The collection of references for 1964 was completed before the Subject Indexes to Volumes 60 and 61 of the Abstracts were available; thus some omissions in the coverage of that year are possible. We have attempted to make the coverage of the literature complete in order that the Compilation may have best utility to the chemist, chemical engineer, patent attorney and editor. In the interest of brevity, certain numerical data are omitted, but references to the original literature are given. Yield data are rounded to two significant figures. Wherever possible, tables have been used. The entries in the Bibliography section include references to Chemical Abstracts.

Author : R.D. Adams
Publisher : Elsevier
Page : 458 pages
File Size : 40,9 Mb
Release : 2004-09-16
Category : Science
ISBN : 0080423175

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Heteronuclear Metal-Metal Bonds by R.D. Adams Pdf

The number of organometallic compounds containing heteronuclear metal-metal bonds has grown tremendously in the last ten years. Also known as cluster compounds, these compounds have been found to exhibit a rich diversity of molecular structures and reactivities. Descriptions of the structures and transformations of the complexes are central features. Separate chapters have been prepared for compounds containing bonds between transition metals and the metals of the copper and zinc subgroups. Unlike COMC, this volume contains an entire chapter devoted to studies of heteronuclear metal compounds in catalysis.

Author : A. Veillard
Publisher : Springer Science & Business Media
Page : 518 pages
File Size : 55,8 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400946569

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Quantum Chemistry: The Challenge of Transition Metals and Coordination Chemistry by A. Veillard Pdf

Over the last twenty years, developments of the ab initio metho dologies and of the computing capacities have progressively turned quantum chemistry into a predictive tool for molecular systems involving only light elements. The situation appears less advanced for systems containing transition metal elements where specific difficulties arise, like those 1inked to the quasi-degeneracy of the lowest atomic states. Correlation effects, which are important only for quantitative accuracy in the treatment of molecules made of light elements, need sometimes to be considered even for a qualitative des cription of transition metals systems (like the multiple metal-metal bond). The treatment of atoms of a high atomic number has necessited the development of model potential methods. These difficulties ex acerbate for systems containing several trans ition atoms a correct description of the dichromium molecule Crz still represents a challenge to quantum chemists. Yet many advances have been made recently in the theoretical treatment of these systems, despite the fact that our understanding still remains disparate with a variety of models and methodologies used more or less successfully (one-electron models, explicitly correlated ab initio methods, density functional formalisms). For these reasons, a NATO Advanced Research Workshop was organized to review in detail the state-of-the-art techniques and at the same time the most common applications. These encompass many fields including the spectroscopy of diatomics and small aggregates, structure and reactivity problems in organometallic chemistry, the cluster surface analogy with its implications for heterogeneous catalysis and the description of extended structures.

Author : Stephen T. Liddle
Publisher : John Wiley & Sons
Page : 592 pages
File Size : 46,5 Mb
Release : 2016-03-16
Category : Science
ISBN : 9783527673384

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Molecular Metal-Metal Bonds by Stephen T. Liddle Pdf

Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.

Author : Alan Cottrell
Publisher : CRC Press
Page : 120 pages
File Size : 50,8 Mb
Release : 1995
Category : Science
ISBN : UOM:39015032514880

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Chemical Bonding in Transition Metal Carbides by Alan Cottrell Pdf

This book presents a mainly qualitative understanding of this family of materials which ranges from simple NaCl type compounds to complex chromium carbides.

Author : William A. Nugent,James M. Mayer
Publisher : Wiley-Interscience
Page : 360 pages
File Size : 41,8 Mb
Release : 1988-11-14
Category : Science
ISBN : UOM:39015016060140

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Metal-Ligand Multiple Bonds by William A. Nugent,James M. Mayer Pdf

The only comprehensive one-volume text/reference on metal-ligand multiple bonds. Stresses the unified nature of the field and includes handy new tabulations of data. The flow within each subtopic is oxygen to nitrogen to carbon. Coverage is up-to-date--virtually every subtopic leads to interesting questions for future research. Presents information otherwise scattered through hundreds of publications.

Author : Robert H. Crabtree
Publisher : John Wiley & Sons
Page : 418 pages
File Size : 54,7 Mb
Release : 2011-09-20
Category : Science
ISBN : 9781118210857

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The Organometallic Chemistry of the Transition Metals by Robert H. Crabtree Pdf

"One impressive and compressive book. . . . This review would have to be book size to do full justice to all the insights in this volume." —Journal of Metals Online Fully updated and expanded to reflect recent advances, this Fifth Edition of the classic text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. With increased focus on organic synthesis applications, nanoparticle science, and green chemistry, the Fifth Edition brings this vital resource up to date. New to the Fifth Edition: Chapters have been updated with relevant examples in the field, modern trends, and new applications; the organic applications chapter has been completely rewritten New end-of-chapter problems, along with their solutions Coverage enhanced with developments in nanoparticle science Increased focus on green chemistry An unparalleled pedagogic resource as well as a valuable working reference for professional chemists, with comprehensive coverage and up-to-date information, students and researchers in organic and organometallic chemistry will turn to The Organometallic Chemistry of the Transition Metals, Fifth Edition for the critical information they need on organometallic compounds, their preparation, and their use in synthesis.

Author : François Mathey,Alain Sevin
Publisher : Unknown
Page : 256 pages
File Size : 40,5 Mb
Release : 1996-11-21
Category : Science
ISBN : STANFORD:36105019256226

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Molecular Chemistry of the Transition Elements by François Mathey,Alain Sevin Pdf

Using a systematic and theoretical approach, this outstanding textbook offers a succinct introduction to the underlying principles of organometallic chemistry--with a strong emphasis on reactions mechanisms. It links theory with the chemical properties of the compounds, enabling students to classify the variety of compounds and to understand the basic reaction mechanisms of diverse classes of compounds. Chapters with selected applications help students to transfer the theoretical knowledge to real life chemistry. Contains numerous examples.