Molecular Chemistry Of The Transition Elements

Author : François Mathey,Alain Sevin
Publisher : Unknown
Page : 256 pages
File Size : 52,6 Mb
Release : 1996-11-21
Category : Science
ISBN : STANFORD:36105019256226

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Molecular Chemistry of the Transition Elements by François Mathey,Alain Sevin Pdf

Using a systematic and theoretical approach, this outstanding textbook offers a succinct introduction to the underlying principles of organometallic chemistry--with a strong emphasis on reactions mechanisms. It links theory with the chemical properties of the compounds, enabling students to classify the variety of compounds and to understand the basic reaction mechanisms of diverse classes of compounds. Chapters with selected applications help students to transfer the theoretical knowledge to real life chemistry. Contains numerous examples.

Author : L. Fabbrizzi,Antonio Poggi
Publisher : Springer Science & Business Media
Page : 445 pages
File Size : 44,8 Mb
Release : 2013-03-09
Category : Science
ISBN : 9789401583800

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Transition Metals in Supramolecular Chemistry by L. Fabbrizzi,Antonio Poggi Pdf

Since the pioneering publications on coordination chemistry by Lehn and Pedersen in the late 1960s, coupled with the more orthodox interest from the transition metal chemists on template reactions (Busch, 1964), the field of supramolecular chemistry has grown at an astonishing rate. The use of transition metals as essential constituents of multi-component assemblies has been especially sharp in recent years, since the metals are prone to quick and reversible redox changes, and there is a wide variety of metal--ligand interactions. Such properties make supramolecular complexes of transition metal ions suitable candidates for exploration as light--energy converters and signal processors. Transition Metals in Supramolecular Chemistry focuses on the following main topics: (1) metal controlled organization of novel molecular assemblies and shapes; (2) design of molecular switches and devices operating through metal centres; (3) supramolecular catalysts that mimic metalloenzymes; (4) metal-containing sensory reagents and supramolecular recognition; and (5) molecular materials that display powerful electronic, optoelectronic and magnetic properties.

Author : Florian P. Pruchnik
Publisher : Springer Science & Business Media
Page : 767 pages
File Size : 47,7 Mb
Release : 2013-06-29
Category : Science
ISBN : 9781489920768

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Organometallic Chemistry of the Transition Elements by Florian P. Pruchnik Pdf

Organometallic chemistry belongs to the most rapidly developing area of chemistry today. This is due to the fact that research dealing with the structure of compounds and chemical bonding has been greatly intensified in recent years. Additionally, organometallic compounds have been widely utilized in catalysis, organic synthesis, electronics, etc. This book is based on my lectures concerning basic organometallic chemistry for fourth and fifth year chemistry students and on my lectures concerning advanced organometallic chemistry and homogeneous catalysis for Ph.D. graduate students. Many recent developments in the area of organometallic chemistry as weIl as homogeneous catalysis are presented. Essential research results dealing with a given class of organometallic compounds are discussed briefly. Results of physicochemical research methods of various organometallic compounds as weIl as their synthesis, properties, structures, reactivities, and applications are discussed more thoroughly. The selection of tabulated data is arbitrary because, often, it has been impossible to avoid omissions. Nevertheless, these data can be very helpful in understanding properties of organometaIlic compounds and their reactivities. All physical data are given in SI units; the interatomic distances are given in pm units in figures and tables. I am indebted to Professor S. A. Duraj for translating and editing this book. His remarks, discussions, and suggestions are greatly appreciated. I also express gratitude to Virginia E. Duraj for editing and proofreading.

Author : Louis S. Hegedus
Publisher : University Science Books
Page : 358 pages
File Size : 44,8 Mb
Release : 1999
Category : Science
ISBN : 1891389041

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Transition Metals in the Synthesis of Complex Organic Molecules by Louis S. Hegedus Pdf

This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.

Author : M. Satake & Y. Mido
Publisher : Discovery Publishing House
Page : 230 pages
File Size : 42,9 Mb
Release : 2010
Category : Electronic
ISBN : 8171412432

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Chemistry Of Transition Elements by M. Satake & Y. Mido Pdf

Contents: The Properties of Transition Elements, Titanium, Zirconium and Hafnium Group IV A, Vanadium, Niobium and Tantalum Group V A, Chromium, Molybdenum and Tungsten Group VI A, Manganese, Technetium and Rhenium Group VII A, Iron, Cobalt and Nickel, The Platinum Metals, Copper, Silver and Gold Group IB, Analytical and Biological Aspects of Transition Metals, Coordination Compounds, Lanthanides & Actinides.

Author : Guillermo Gonzalez-Moraga
Publisher : Springer Science & Business Media
Page : 310 pages
File Size : 55,5 Mb
Release : 2013-11-09
Category : Science
ISBN : 9783642859267

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Cluster Chemistry by Guillermo Gonzalez-Moraga Pdf

Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.

Author : A. Veillard
Publisher : Springer Science & Business Media
Page : 518 pages
File Size : 40,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400946569

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Quantum Chemistry: The Challenge of Transition Metals and Coordination Chemistry by A. Veillard Pdf

Over the last twenty years, developments of the ab initio metho dologies and of the computing capacities have progressively turned quantum chemistry into a predictive tool for molecular systems involving only light elements. The situation appears less advanced for systems containing transition metal elements where specific difficulties arise, like those 1inked to the quasi-degeneracy of the lowest atomic states. Correlation effects, which are important only for quantitative accuracy in the treatment of molecules made of light elements, need sometimes to be considered even for a qualitative des cription of transition metals systems (like the multiple metal-metal bond). The treatment of atoms of a high atomic number has necessited the development of model potential methods. These difficulties ex acerbate for systems containing several trans ition atoms a correct description of the dichromium molecule Crz still represents a challenge to quantum chemists. Yet many advances have been made recently in the theoretical treatment of these systems, despite the fact that our understanding still remains disparate with a variety of models and methodologies used more or less successfully (one-electron models, explicitly correlated ab initio methods, density functional formalisms). For these reasons, a NATO Advanced Research Workshop was organized to review in detail the state-of-the-art techniques and at the same time the most common applications. These encompass many fields including the spectroscopy of diatomics and small aggregates, structure and reactivity problems in organometallic chemistry, the cluster surface analogy with its implications for heterogeneous catalysis and the description of extended structures.

Author : B F G Johnson
Publisher : Royal Society of Chemistry
Page : 434 pages
File Size : 52,5 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847556424

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Inorganic Chemistry of the Transition Elements by B F G Johnson Pdf

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Author : F. Mathey,A. Sevin
Publisher : Unknown
Page : 220 pages
File Size : 52,8 Mb
Release : 1993-12-01
Category : Electronic
ISBN : 0920063535

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Organometallic Chemistry by F. Mathey,A. Sevin Pdf

Author : Eleanor Crabb,Elaine Moore,Lesley Smart
Publisher : Unknown
Page : 162 pages
File Size : 46,5 Mb
Release : 2010
Category : Education
ISBN : UOM:39076002910151

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Concepts in Transition Metal Chemistry by Eleanor Crabb,Elaine Moore,Lesley Smart Pdf

An introduction to transition metals, examining the behaviour of the metals and their aqueous ions and complexes, complete with The Periodic Table DVD.

Author : Hani Amouri,Michel Gruselle
Publisher : John Wiley & Sons
Page : 260 pages
File Size : 45,7 Mb
Release : 2008-11-20
Category : Science
ISBN : 9780470721605

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Chirality in Transition Metal Chemistry by Hani Amouri,Michel Gruselle Pdf

Chirality in Transition Metal Chemistry is an essential introduction to this increasingly important field for students and researchers in inorganic chemistry. Emphasising applications and real-world examples, the book begins with an overview of chirality, with a discussion of absolute configurations and system descriptors, physical properties of enantiomers, and principles of resolution and preparation of enantiomers. The subsequent chapters deal with the the specifics of chirality as it applies to transition metals. Some reviews of Chirality in Transition Metal Chemistry "...useful to students taking an advanced undergraduate course and particularly to postgraduates and academics undertaking research in the areas of chiral inorganic supramolecular complexes and materials." Chemistry World, August 2009 “...the book offers an extremely exciting new addition to the study of inorganic chemistry, and should be compulsory reading for students entering their final year of undergraduate studies or starting a Ph.D. in structural inorganic chemistry.” Applied Organometallic Chemistry Volume 23, Issue 5, May 2009 “...In conclusion the book gives a wonderful overview of the topic. It is helpful for anyone entering the field through systematic and detailed introduction of basic information. It was time to publish a new and topical text book covering the important aspect of coordination chemistry. It builds bridges between Inorganic, organic and supramolecular chemistry. I can recommend the book to everybody who is interested in the chemistry of chiral coordination compounds .” Angew. chem. Volume 48, Issue 18, April 2009 About the Series Chirality in Transition Metal Chemistry is the latest addition to the Wiley Inorganic Chemistry Advanced Textbook series. This series reflects the pivotal role of modern inorganic and physical chemistry in a whole range of emerging areas such as materials chemistry, green chemistry and bioinorganic chemistry, as well as providing a solid grounding in established areas such as solid state chemistry, coordination chemistry, main group chemistry and physical inorganic chemistry.

Author : Yves Jean
Publisher : Oxford University Press on Demand
Page : 288 pages
File Size : 42,7 Mb
Release : 2005-03-24
Category : Science
ISBN : 9780198530930

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Molecular Orbitals of Transition Metal Complexes by Yves Jean Pdf

This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions such as symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter and the structure of the "d block" is used to trace the relationships between the electronic structure and the geometry of the complexes. The third chapter studies the change in analysis when the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (e.g. structure and reactivity). The fifth chapter deals with the "isolobal analogy" which points out the resemblance between the molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some of the complexes studied in the earlier chapters.

Author : B F G Johnson
Publisher : Royal Society of Chemistry
Page : 530 pages
File Size : 47,6 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847556448

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Inorganic Chemistry of the Transition Elements by B F G Johnson Pdf

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Author : P.L. Soni,Vandna Soni
Publisher : CRC Press
Page : 332 pages
File Size : 54,8 Mb
Release : 2021-05-14
Category : Science
ISBN : 9781000404142

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The Chemistry of Coordination Complexes and Transition Metals by P.L. Soni,Vandna Soni Pdf

This book covers all important nomenclature, theories of bonding and stereochemistry of coordination complexes. The authors have made an effort to inscribe the ideas knowledge, clearly and in an interesting way to benefit the readers. The complexities of Molecular Orbital theory have been explained in a very simple and easy manner. It also deals with transition and inner transition metals. Conceptually, all transition and inner transition elements form complexes which have definite geometry and show interesting properties. General and specific methods of preparation, physical and chemical properties of each element has been discussed at length. Group wise study of elements in d-block series have been explained. Important compounds, complexes and organometallic compounds of metals in different oxidation states have been given explicitly. Note: T&F does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka.

Author : D.M. Roundhill
Publisher : Springer Science & Business Media
Page : 364 pages
File Size : 52,6 Mb
Release : 2013-06-29
Category : Science
ISBN : 9781489914958

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Photochemistry and Photophysics of Metal Complexes by D.M. Roundhill Pdf

Focusing on practical applications, the author provides a balanced introduction to the many possible technological uses of metal complexes. Coverage includes the transition metals, lanthanide and actinide complexes, metal porphyrins, and many other complexes. This volume meets the needs of students and scientists in inorganic chemistry, chemical physics, and solid-state physics.