Electrocatalysis Computational Experimental And Industrial Aspects

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Electrocatalysis: Computational, Experimental, and Industrial Aspects

Author : Carlos Fernando Zinola
Publisher : CRC Press
Page : 664 pages
File Size : 43,6 Mb
Release : 2010-03-25
Category : Science
ISBN : 9781420045451

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Electrocatalysis: Computational, Experimental, and Industrial Aspects by Carlos Fernando Zinola Pdf

Electrocatalysis applications are employed in a large number of industries worldwide, ranging from old technologies such as galvanoplasty to the most up-to-date deployments involving ultracapacitators. Recognizing electrocatalysis as a useful interfacial approach to a dynamic interdisciplinary science, Electrocatalysis: Computational, Experimental, and Industrial Aspects focuses on important developments in the field that are the most relevant to new technologies. Gathering the experiences of a collection of experts who have worked on the basic principles of electrocatalysis as it applies to theoretical physics and theoretical chemistry, the book gives readers a clear view of the problems inside electrocatalytic reactions, presenting both the limitations of electrocatalysis in the laboratory along with its possibilities in industry. Topics discussed include: The current uses of electrocatalysis Future perspectives on the field Surface physical properties and surface relaxation on noble and non-noble surfaces The quantum nature of the electron transfer Müller-Calandra, Srinivasan-Gileadi, and instantaneous nucleation-growth overlap models The production, storage, use, and delivery of hydrogen in industrial electrochemistry Theoretical approaches to current distribution on rough surfaces The use of microradiology to study electrodeposition Principles of electrochemical engineering, fuel cell reactors, and electrocatalytic reactor design Electrocatalysis of electroless plating Fundamental aspects of the corrosion of metals The book reviews four main electrochemical processes (hydrogen production, oxygen electrochemistry, energy conversion/production, and fine electroplating). Surface modified non-noble metal substrates and natural minerals as well as noble mineral catalysts are considered. The text goes beyond other books, which merely focus on progress in the application of surface science and ultra high vacuum techniques to electrochemistry. Instead, this volume offers potential industrial applications of these findings, making it a unique reference for professionals and academia alike.

Computational Catalysis

Author : Aravind Asthagiri,Michael Janik
Publisher : Royal Society of Chemistry
Page : 277 pages
File Size : 52,9 Mb
Release : 2014
Category : Science
ISBN : 9781849734516

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Computational Catalysis by Aravind Asthagiri,Michael Janik Pdf

This book presents a comprehensive review of the methods and approaches being adopted to push forward the boundaries of computational catalysis.

Catalysis in Ionic Liquids

Author : Chris Hardacre,Vasile Parvulescu
Publisher : Royal Society of Chemistry
Page : 620 pages
File Size : 45,8 Mb
Release : 2014-03-20
Category : Science
ISBN : 9781782621324

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Catalysis in Ionic Liquids by Chris Hardacre,Vasile Parvulescu Pdf

Although ionic liquids have only been studied in depth during the last decades, the field is now maturing to such a degree that the focus is on larger scale applications for use in real processes such as catalysis. Current information is scattered across the literature and Catalysis in Ionic Liquids provides a critical analysis of the research published to date on ionic solvents in all areas of the catalytic science. The book covers both catalyst synthesis using ionic liquids as solvents and green syntheses using both ionic liquids as well as mixtures of ionic liquids and carbon dioxide (as a subcritical and supercritical liquid), including enzymatic, homogeneous, and heterogeneous catalysis, electrocatalysis and organocatalysis. As well as the catalysis community, the book will also be of interest to postgraduates, postdoctoral workers and researchers in academia and industry working in organic synthesis, new materials synthesis, renewable sources of energy and electrochemistry. Written by leading experts in the field, this is the reference source to find about catalysis in ionic liquids.

The Science of Defoaming

Author : Peter R. Garrett
Publisher : CRC Press
Page : 587 pages
File Size : 52,5 Mb
Release : 2016-04-19
Category : Science
ISBN : 9781420060423

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The Science of Defoaming by Peter R. Garrett Pdf

In the 20 years since the publication of the author's multi-contributor volume on defoaming, a vast amount of new work has been published and many new insights have been revealed. A cohesive, single-authored book, The Science of Defoaming: Theory, Experiment and Applications provides comprehensive coverage of the topic. It describes the mode of act

Catalysis in Electrochemistry

Author : Elizabeth Santos,Wolfgang Schmickler
Publisher : John Wiley & Sons
Page : 548 pages
File Size : 48,9 Mb
Release : 2011-07-26
Category : Science
ISBN : 9780470406908

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Catalysis in Electrochemistry by Elizabeth Santos,Wolfgang Schmickler Pdf

Catalysis in Electrochemistry: From Fundamental Aspects to Strategies for Fuel Cell Development is a modern, comprehensive reference work on catalysis in electrochemistry, including principles, methods, strategies, and applications. It points out differences between catalysis at gas/surfaces and electrochemical interfaces, along with the future possibilities and impact of electrochemical science on energy problems. This book contributes both to fundamental science; experience in the design, preparation, and characterization of electrocatalytic materials; and the industrial application of electrocatalytic materials for electrochemical reactions. This is an essential resource for scientists globally in academia, industry, and government institutions.

Cyclodextrins

Author : Sahar Amiri,Sanam Amiri
Publisher : John Wiley & Sons
Page : 281 pages
File Size : 47,7 Mb
Release : 2017-10-23
Category : Science
ISBN : 9781119247524

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Cyclodextrins by Sahar Amiri,Sanam Amiri Pdf

The comprehensive resource for understanding the structure, properties, and applications of cyclodextrins Cyclodextrins: Properties and Industrial Applications is a comprehensive resource that includes information on cyclodextrins (CDs) structure, their properties, formation of inclusion complex with various compounds as well as their applications. The authors Sahar Amiri and Sanam Amiri, noted experts in the field of cyclodextrins, cover both the basic and applied science in chemistry, biology, and physics of CDs and offers scientists and engineers an understand of cyclodextrins. Cyclodextrins are a family of cyclic oligosaccharides consisting of (α-1,4)-linked α-D-glucopyranose units. The formation of inclusion complex between CDs as host and guest molecules is based on non-covalent interaction such as hydrogen bonding or van der waals interactions and lead to the formation of supramolecular structures. These supramolecular structures can be used as macroinitiator for initiating various type of reactions. CDs are widely used in many industrial products such as pharmacy, food and flavours, chemistry, chromatography, catalysis, biotechnology, agriculture, cosmetics, hygiene, medicine, textiles, drug delivery, packing, separation processes, environment protection, fermentation, and catalysis. This important resource: Offers a basic understanding of cyclodextrins for researchers and engineers Includes information of the basic structure of cyclodextrins and their properties Reviews how cyclodextrins can be applied in a variety of fields including medicine, chemistry, textiles, packing, and many others Shows how encapsulate corrosion inhibitors became active in corrosive electrolytes to ensure delivery of the inhibitors to corrosion sites and long-term corrosion protection Cyclodextrins offers research scientists and engineers a wealth of information about CDs with particular focus on how cyclodextrins are applied in various ways including in drug delivery, the food industry, and many other areas.

Comprehensive Organic Synthesis

Author : Anonim
Publisher : Newnes
Page : 9815 pages
File Size : 43,8 Mb
Release : 2014-02-14
Category : Science
ISBN : 9780080977430

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Comprehensive Organic Synthesis by Anonim Pdf

The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition, Nine Volume Set an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively

Electromagnetic, Mechanical, and Transport Properties of Composite Materials

Author : Rajinder Pal
Publisher : CRC Press
Page : 430 pages
File Size : 43,6 Mb
Release : 2014-08-27
Category : Science
ISBN : 9781498704458

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Electromagnetic, Mechanical, and Transport Properties of Composite Materials by Rajinder Pal Pdf

In the design, processing, and applications of composite materials, a thorough understanding of the physical properties is required. It is important to be able to predict the variations of these properties with the kind, shape, and concentration of filler materials. The currently available books on composite materials often emphasize mechanical pro

Silicone Dispersions

Author : Yihan Liu
Publisher : CRC Press
Page : 388 pages
File Size : 43,8 Mb
Release : 2017-01-06
Category : Science
ISBN : 9781498715560

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Silicone Dispersions by Yihan Liu Pdf

Silicone is an important class of materials used in applications that range from industrial assembly to everyday consumer products. Silicones are often delivered and synthesized in dispersion forms, the most common being liquid-in-liquid (emulsion), solid-in-liquid (suspension), air-in-liquid (foam) and solid-in air (powder). This book compiles a carefully selected number of topics that are essential to the understanding, creative design and production of silicone dispersions. As such, it provides the first unified description of silicone dispersions in the literature.

Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions

Author : Norihiro Matubayasi
Publisher : CRC Press
Page : 226 pages
File Size : 47,6 Mb
Release : 2013-09-09
Category : Science
ISBN : 9781439880876

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Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions by Norihiro Matubayasi Pdf

Surface tension provides a thermodynamic avenue for analyzing systems in equilibrium and formulating phenomenological explanations for the behavior of constituent molecules in the surface region. While there are extensive experimental observations and established ideas regarding desorption of ions from the surfaces of aqueous salt solutions, a more successful discussion of the theory has recently emerged, which allows the quantitative calculation of the distribution of ions in the surface region. Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions provides a detailed and systematic analysis of the properties of ions at the air/water interface. Unifying older and newer theories and measurements, this book emphasizes the contributions of simple ions to surface tension behavior, and the practical consequences. It begins with a general discussion on Gibbs surface thermodynamics, offering a guide to his theoretical insight and formulation of the boundary between fluids. The text then discusses the thermodynamic formulae that are useful for practical experimental work in the analysis of fluid/fluid interfaces. Chapters cover surface tension of pure water at air/water and air/oil interfaces, surface tension of solutions and the thermodynamic quantities associated with the adsorption and desorption of solutes, and surface tension of simple salt solutions. They also address adsorption of ions at the air/water interface, surface tension of solutions and the effect of temperature, adsorption from mixed electrolyte solutions, and thermodynamic properties of zwitterionic amino acids in the surface region. Focusing on the thermodynamic properties of ions at air/fluid interfaces, this book gives scientists a quantitative, rigorous, and objectively experimental methodology they can employ in their research.

Soil Colloids

Author : Fernando V. Molina
Publisher : CRC Press
Page : 545 pages
File Size : 46,7 Mb
Release : 2016-04-19
Category : Science
ISBN : 9781439851159

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Soil Colloids by Fernando V. Molina Pdf

Within the field of soil science, soil chemistry encompasses the different chemical processes that take place, including mineral weathering, humification of organic plant residues, and ionic reactions involving natural and foreign metal ions that play significant roles in soil. Chemical reactions occur both in the soil solution and at the soil part

Nuclear Magnetic Resonance Studies of Interfacial Phenomena

Author : Vladimir M. Gun'ko,Vladimir V. Turov
Publisher : CRC Press
Page : 1040 pages
File Size : 40,7 Mb
Release : 2013-04-08
Category : Science
ISBN : 9781466551695

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Nuclear Magnetic Resonance Studies of Interfacial Phenomena by Vladimir M. Gun'ko,Vladimir V. Turov Pdf

Properties and applications of high surface area materials depend on interfacial phenomena, including diffusion, sorption, dissolution, solvation, surface reactions, catalysis, and phase transitions. Among the physicochemical methods that give useful information regarding these complex phenomena, nuclear magnetic resonance (NMR) spectroscopy is the most universal, yielding detailed structural data regarding molecules, solids, and interfaces. Nuclear Magnetic Resonance Studies of Interfacial Phenomena summarizes NMR research results collected over the past three decades for a wide range of materials—from nanomaterials and nanocomposites to biomaterials, cells, tissues, and seeds. This book describes the applications of important new NMR spectroscopic methods to a variety of useful materials and compares them with results from other techniques such as adsorption, differential scanning calorimetry, thermally stimulated depolarization current, dielectric relaxation spectroscopy, infrared spectroscopy, optical microscopy, and small-angle and wide-angle x-ray scattering. The text explores the application of NMR spectroscopy to examine interfacial phenomena in objects of increasing complexity, beginning with unmodified and modified silica materials. It then describes properties of various mixed oxides with comparisons to individual oxides and also describes carbon materials such as graphite and carbon nanotubes. Chapters deal with carbon–mineral hybrids and their mosaic surface structures, and interfacial phenomena at the surface of natural and synthetics polymers. They also explore a variety of biosystems, which are much more complex, including biomacromolecules (proteins, DNA, and lipids), cells and tissues, and seeds and herbs. The authors cover trends in interfacial phenomena investigations, and the final chapter describes NMR and other methods used in the book. This text presents a comprehensive description of a large array of hard and soft materials, allowing the analysis of the structure–property relationships and generalities on the interfacial behavior of materials and adsorbates.

Electrokinetic Particle Transport in Micro-/Nanofluidics

Author : Shizhi Qian,Ye Ai
Publisher : CRC Press
Page : 398 pages
File Size : 45,5 Mb
Release : 2012-06-19
Category : Medical
ISBN : 9781439854396

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Electrokinetic Particle Transport in Micro-/Nanofluidics by Shizhi Qian,Ye Ai Pdf

Numerous applications of micro-/nanofluidics are related to particle transport in micro-/nanoscale channels, and electrokinetics has proved to be one of the most promising tools to manipulate particles in micro/nanofluidics. Therefore, a comprehensive understanding of electrokinetic particle transport in micro-/nanoscale channels is crucial to the development of micro-/nanofluidic devices. Electrokinetic Particle Transport in Micro-/Nanofluidics: Direct Numerical Simulation Analysis provides a fundamental understanding of electrokinetic particle transport in micro-/nanofluidics involving electrophoresis, dielectrophoresis, electroosmosis, and induced-charge electroosmosis. The book emphasizes the direct numerical simulation of electrokinetic particle transport phenomena, plus several supportive experimental studies. Using the commercial finite element package COMSOL Multiphysics®, it guides researchers on how to predict the particle transport subjected to electric fields in micro-/nanoscale channels. Researchers in the micro-/nanofluidics community, who may have limited experience in writing their own codes for numerical simulations, can extend the numerical models and codes presented in this book to their own research and guide the development of real micro-/nanofluidics devices. Corresponding COMSOL® script files are provided with the book and can be downloaded from the author’s website.

Applied Surface Thermodynamics, Second Edition

Author : A.W. Neumann,Robert David,Yi Zuo
Publisher : CRC Press
Page : 765 pages
File Size : 42,8 Mb
Release : 2010-10-13
Category : Science
ISBN : 1420009664

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Applied Surface Thermodynamics, Second Edition by A.W. Neumann,Robert David,Yi Zuo Pdf

Surface thermodynamics forms the foundation of any meaningful study of capillarity and wetting phenomena. The second edition of Applied Surface Thermodynamics offers a comprehensive state-of-the-art treatment of this critical topic. It provides students and researchers with fundamental knowledge and practical guidelines in solving real-world problems related to the measurement and interpretation of interfacial properties. Containing 40 percent new material and reorganized content, this second edition begins by presenting a generalized Gibbs theory of capillarity, including discussions of highly curved interfaces. Concentrating on drop-shape techniques, the book discusses liquid-fluid interfacial tension and its measurement. Next, the authors focus on contact angles with chapters on experimental procedures, thermodynamic models, and the interpretation of contact angles in terms of solid surface tension. The book discusses theoretical approaches to determining solid surface tension as well as interfacial tensions of particles and their manifestations. It concludes by discussing drop size dependence of contact angles and line tension. What’s New in the Second Edition: Recent progress in Axisymmetric Drop Shape Analysis (ADSA) Image processing methods for drop shape analysis Advanced applications and generalizations of ADSA Recent studies of contact angle hysteresis Contact angles on inert fluoropolymers Update on line tension and the drop size dependence of contact angles Exploring a range of different aspects of surface science and its applications, the book logically progresses so that knowledge of previous chapters enhances the understanding of subsequent material, yet each chapter is freestanding so that experienced researchers can quickly refer to topics of particular interest.

Green Corrosion Chemistry and Engineering

Author : Sanjay K. Sharma
Publisher : John Wiley & Sons
Page : 415 pages
File Size : 52,5 Mb
Release : 2011-12-02
Category : Technology & Engineering
ISBN : 9783527641796

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Green Corrosion Chemistry and Engineering by Sanjay K. Sharma Pdf

With its unique focus on specifically addressing the problems for societies and economies associated with corrosion and their solution, this book provides an up-to-date overview of the progress in corrosion chemistry and engineering. International experts actively involved in research and development place particular emphasis on how to counter the economic and environmental consequences of corrosion with the help of science and technology, making this a valuable resource for researchers as well as decision makers in industry and politics. Further major parts of the book are devoted to corrosion prevention in the naval and energy sector as well as to corrosion monitoring and waste management.