Surface Tension And Related Thermodynamic Quantities Of Aqueous Electrolyte Solutions

Author : Norihiro Matubayasi
Publisher : CRC Press
Page : 226 pages
File Size : 45,8 Mb
Release : 2013-09-09
Category : Science
ISBN : 9781439880876

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Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions by Norihiro Matubayasi Pdf

Surface tension provides a thermodynamic avenue for analyzing systems in equilibrium and formulating phenomenological explanations for the behavior of constituent molecules in the surface region. While there are extensive experimental observations and established ideas regarding desorption of ions from the surfaces of aqueous salt solutions, a more successful discussion of the theory has recently emerged, which allows the quantitative calculation of the distribution of ions in the surface region. Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions provides a detailed and systematic analysis of the properties of ions at the air/water interface. Unifying older and newer theories and measurements, this book emphasizes the contributions of simple ions to surface tension behavior, and the practical consequences. It begins with a general discussion on Gibbs surface thermodynamics, offering a guide to his theoretical insight and formulation of the boundary between fluids. The text then discusses the thermodynamic formulae that are useful for practical experimental work in the analysis of fluid/fluid interfaces. Chapters cover surface tension of pure water at air/water and air/oil interfaces, surface tension of solutions and the thermodynamic quantities associated with the adsorption and desorption of solutes, and surface tension of simple salt solutions. They also address adsorption of ions at the air/water interface, surface tension of solutions and the effect of temperature, adsorption from mixed electrolyte solutions, and thermodynamic properties of zwitterionic amino acids in the surface region. Focusing on the thermodynamic properties of ions at air/fluid interfaces, this book gives scientists a quantitative, rigorous, and objectively experimental methodology they can employ in their research.

Author : Norihiro Matubayasi
Publisher : CRC Press
Page : 223 pages
File Size : 50,9 Mb
Release : 2013-09-09
Category : Science
ISBN : 9781439880890

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Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions by Norihiro Matubayasi Pdf

Surface tension provides a thermodynamic avenue for analyzing systems in equilibrium and formulating phenomenological explanations for the behavior of constituent molecules in the surface region. While there are extensive experimental observations and established ideas regarding desorption of ions from the surfaces of aqueous salt solutions, a more

Author : Ari L. Horvath
Publisher : Unknown
Page : 640 pages
File Size : 55,8 Mb
Release : 1985
Category : Science
ISBN : STANFORD:36105032948684

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Handbook of Aqueous Electrolyte Solutions by Ari L. Horvath Pdf

Author : Joseph F. Zemaitis, Jr.,Diane M. Clark,Marshall Rafal,Noel C. Scrivner
Publisher : John Wiley & Sons
Page : 876 pages
File Size : 48,6 Mb
Release : 2010-09-16
Category : Technology & Engineering
ISBN : 9780470938409

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Handbook of Aqueous Electrolyte Thermodynamics by Joseph F. Zemaitis, Jr.,Diane M. Clark,Marshall Rafal,Noel C. Scrivner Pdf

Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.

Author : Jennifer A. Faust,J. E. House
Publisher : Elsevier
Page : 490 pages
File Size : 51,8 Mb
Release : 2018-05-31
Category : Science
ISBN : 9780128136423

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Physical Chemistry of Gas-Liquid Interfaces by Jennifer A. Faust,J. E. House Pdf

Physical Chemistry of Gas-Liquid Interfaces, the first volume in the Developments in Physical & Theoretical Chemistry series, addresses the physical chemistry of gas transport and reactions across liquid surfaces. Gas–liquid interfaces are all around us, especially within atmospheric systems such as sea spry aerosols, cloud droplets, and the surface of the ocean. Because the reaction environment at liquid surfaces is completely unlike bulk gas or bulk liquid, chemists must readjust their conceptual framework when entering this field. This book provides the necessary background in thermodynamics and computational and experimental techniques for scientists to obtain a thorough understanding of the physical chemistry of liquid surfaces in complex, real-world environments. Provides an interdisciplinary view of the chemical dynamics of liquid surfaces, making the content of specific use to physical chemists and atmospheric scientists Features 100 figures and illustrations to underscore key concepts and aid in retention for young scientists in industry and graduate students in the classroom Helps scientists who are transitioning to this field by offering the appropriate thermodynamic background and surveying the current state of research

Author : S. Durand-Vidal,J.-P. Simonin,P. Turq
Publisher : Springer Science & Business Media
Page : 344 pages
File Size : 48,7 Mb
Release : 2006-04-11
Category : Science
ISBN : 9780306469404

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Electrolytes at Interfaces by S. Durand-Vidal,J.-P. Simonin,P. Turq Pdf

The aim of this book is to provide the reader with a modern presentation of ionic solutions at interfaces, for physical chemists, chemists and theoretically oriented experimentalists in this field. The discussion is mainly on the structural and thermodynamic properties, in relation to presently available statistical mechanical models. Some dynamic properties are also presented, at a more phenomenological level. The initial chapters are devoted to the presentation of some basic concepts for bulk properties: hydrodynamic interactions, electrostatics, van der Waals forces and thermodynamics of ionic solutions in the framework of a particular model: the mean spherical approximation (MSA). Specific features of interfaces are then discussed: experimental techniques such as in-situ X-ray diffraction, STM and AFM microscopy are described. Ions at liquid/air, liquid/metal and liquid/liquid interfaces are considered from the experimental and theoretical viewpoint. Lastly some dynamic (transport) properties are included, namely the self-diffusion and conductance of small colloids (polyelectrolytes and micelles) and the kinetics of solute transfer at free liquid/liquid interfaces.

Author : Lloyd L Lee
Publisher : World Scientific
Page : 295 pages
File Size : 54,9 Mb
Release : 2021-01-07
Category : Technology & Engineering
ISBN : 9789811233012

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Molecular Thermodynamics Of Electrolyte Solutions (Second Edition) by Lloyd L Lee Pdf

Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-Hückel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications — natural gas treating, and absorption refrigeration, are added to make the book current and relevant.This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study.

Author : Felix Franks
Publisher : Springer Science & Business Media
Page : 482 pages
File Size : 42,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781468429558

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Aqueous Solutions of Simple Electrolytes by Felix Franks Pdf

The chapters making up this volume had originally been planned to form part of a single volume covering solid hydrates and aqueous solutions of simple molecules and ions. However, during the preparation of the manu scripts it became apparent that such a volume would turn out to be very unwieldy and I reluctantly decided to recommend the publication of sepa rate volumes. The most sensible way of dividing the subject matter seemed to lie in the separation of simple ionic solutions. The emphasis in the present volume is placed on ion-solvent effects, since a number of excellent texts cover the more general aspects of electrolyte solutions, based on the classical theories of Debye, Huckel, On sager, and Fuoss. It is interesting to speculate as to when a theory becomes "classical." Perhaps this occurs when it has become well known, well liked, and much adapted. The above-mentioned theories of ionic equilibria and transport certainly fulfill these criteria. There comes a time when the refinements and modifications can no longer be related to physical significance and can no longer hide the fact that certain fundamental assumptions made in the development of the theory are untenable, especially in the light of information obtained from the application of sophisticated molecular and thermodynamic techniques.

Author : Georgiĭ Georgievich Aseev
Publisher : Begell House Publishers
Page : 606 pages
File Size : 49,5 Mb
Release : 1999
Category : Technology & Engineering
ISBN : 1567001068

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Electrolytes, Properties of Solutions by Georgiĭ Georgievich Aseev Pdf

This book is a continuation of a number of the author's works dealing with the study, representation, and methods of calculation of the physicochemical properties of binary and multicomponent electrolyte solutions. It gives data for a great number of electrolytes that are used in modern chemical technology, and is intended for scientific workers and engineers in the chemical and allied industries. Methods for calculating the thermal conductivity and surface tension of multicomponent electrolyte solutions with minimum errors are presented. Related equations for calculating the thermal conductivity of water at the saturation line in the temperature range of zero to 350 degrees C, the activity of water, and the water vapor pressure over pure water in the same temperature range, and over a solution at the saturation line are also considered.

Author : Roberto Fernandez-Prini
Publisher : CRC Press
Page : 222 pages
File Size : 43,6 Mb
Release : 1991-12-19
Category : Science
ISBN : 0849357608

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High-Temperature Aqueous Solutions by Roberto Fernandez-Prini Pdf

This book provides a thorough discussion of the thermodynamics of aqueous solutions and presents tools for analyzing and solving scientific and practical problems arising in this area. It also presents methods that can be used to deal with ionic and nonionic aqueous solutions under sub- or supercritical conditions. Illustrations and tables give examples of procedures employed to predict thermodynamic quantities of the solutions, and an appendix summarizing statistical mechanical equations used to describe the systems is also provided. High-Temperature Aqueous Solutions: Thermodynamic Properties contains essential information for physical chemists, geochemists, geophysicists, chemical technicians, and scientists involved in electric power generation.

Author : Ivan D. Zaytsev,Georgiy G. Aseyev
Publisher : CRC Press
Page : 1784 pages
File Size : 53,8 Mb
Release : 1992-08-24
Category : Science
ISBN : 0849393140

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Properties of Aqueous Solutions of Electrolytes by Ivan D. Zaytsev,Georgiy G. Aseyev Pdf

Properties of Aqueous Solutions of Electrolytes is a handbook that systematizes the information on physico-chemical parameters of multicomponent aqueous electrolyte solutions. This important data collection will be invaluable for developing new methods for more efficient chemical technologies, choosing optimal solutions for more effective methods of using raw materials and energy resources, and other such activities. This edition, the first available in English, has been substantially revised and augmented. Many new tables have been added because of a significantly larger list of electrolytes and their properties (electrical conductivity, boiling and freezing points, pressure of saturated vapors, activity and diffusion coefficients). The book is divided into two sections. The first section provides tables that list the properties of binary aqueous solutions of electrolytes, while the second section deals with the methods for calculating their properties in multicomponent systems. All values are given in PSI units or fractional and multiple units. Metrological characteristics of the experimental methods used for the determination of physico-chemical parameters are indicated as a relative error and those of the computational methods as a relative error or a root-mean square deviation.

Author : Yizhak Marcus
Publisher : Springer Science & Business Media
Page : 224 pages
File Size : 52,9 Mb
Release : 2012-08-13
Category : Science
ISBN : 9789400746473

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Ions in Water and Biophysical Implications by Yizhak Marcus Pdf

Over the past decade, numerous books have attempted to explain ions in aqueous solutions in relation to biophysical phenomena. Ions in Water and Biophysical Implications, from Chaos to Cosmos offers a physicochemical point of view of the spread of this matter and suggests innovative solutions that will challenge the biophysics research establishment. Starting with a throughout discussion of the properties of liquid water, in particular as a structured liquid with an extensive hydrogen bonded structure, the book examines water as a solvent for gases, non-electrolytes, and electrolytes and reviews the properties, sizes and thermodynamics of isolated and aqueous ions, as well as their interactions, including those of polyelectrolytes. The effects of ions on water structure, including those on solvent dynamics and certain thermodynamic quantities, are presented. This volume investigates water surfaces with its vapour, with another liquid, and with a solid, as well as the effects of solutes, including simple ions and the water-miscible non-electrolytes. Surfaces are relevant to biomolecular and colloidal systems and the book discusses briefly surfactants, micelles and vesicles. Finally, the book concludes with a review of the various biophysical implications involving chaotropic and kosmotropic ions in homogeneous solutions and the Hofmeister series for ions concerning biomolecular and colloidal systems and some aspects of protein hydration and K+/Na+ selectivity in ion channels. Ions in Water and Biophysical Implications, from Chaos to Cosmos will appeal to physical chemists, biophysicists, biochemists, as well as to all students and researchers involved in the study of aqueous solutions.

Author : Kenneth S. Pitzer
Publisher : CRC Press
Page : 552 pages
File Size : 49,8 Mb
Release : 2018-05-04
Category : Science
ISBN : 9781351077927

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Activity Coefficients in Electrolyte Solutions by Kenneth S. Pitzer Pdf

This book was first published in 1991. It considers the concepts and theories relating to mostly aqueous systems of activity coefficients.

Author : R.A. Robinson,R.H. Stokes
Publisher : Courier Corporation
Page : 609 pages
File Size : 40,9 Mb
Release : 2002-07-24
Category : Science
ISBN : 9780486422251

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Electrolyte Solutions by R.A. Robinson,R.H. Stokes Pdf

Classic text deals primarily with measurement, interpretation of conductance, chemical potential, and diffusion in electrolyte solutions. Detailed theoretical interpretations, plus extensive tables of thermodynamic and transport properties. 1970 edition.

Author : Poul Bering Petersen
Publisher : Unknown
Page : 448 pages
File Size : 44,6 Mb
Release : 2005
Category : Electronic
ISBN : UCAL:C3503372

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Surface Structure of Aqueous Electrolyte Solutions Probed by UV Second Harmonic Generation by Poul Bering Petersen Pdf