Electrochemical Carbon Dioxide Reduction To Formic Acid In A Flow Cell Using Molecular Catalysts Band 11

Author : Paul Rößner
Publisher : Cuvillier Verlag
Page : 174 pages
File Size : 53,5 Mb
Release : 2023-02-09
Category : Science
ISBN : 9783736967380

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Electrochemical Carbon Dioxide Reduction to Formic Acid in a Flow Cell using Molecular Catalysts (Band 11) by Paul Rößner Pdf

This work adresses the gap between basic research and applied research in the field of CO₂ electrolysis using molecular catalysts. The development of new catalysts includes important aspects of the industrial application as early as possible to unlock the true potential of a catalyst and to prevent potential problems that occur when changing to industrially relevant process conditions. The results show that unexpected phenomena can occur when scaling up a technology from lab scale to pilot, or even industrial scale, advocating an effort to come as close as possible to large scale conditions, already in the lab. That can prevent major setbacks in the process and save valuable time and effort. This aspect is underlined by recent research in the specific field of CO₂ electrolysis using organometallic complexes, as catalysts show different performance characteristics after immobilization, for example. The successful development of future solutions depends on the interdisciplinary collaboration taking into account molecular considerations as well as process engineering aspects.

Author : Paul Rößner
Publisher : Unknown
Page : 0 pages
File Size : 55,9 Mb
Release : 2023
Category : Electronic
ISBN : 3736977387

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Electrochemical Carbon Dioxide Reduction to Formic Acid in a Flow Cell Using Molecular Catalysts by Paul Rößner Pdf

Author : Marc Robert,Kim Daasbjerg,Cyrille Constentin
Publisher : Royal Society of Chemistry
Page : 461 pages
File Size : 46,7 Mb
Release : 2020-10-20
Category : Science
ISBN : 9781788015462

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Carbon Dioxide Electrochemistry by Marc Robert,Kim Daasbjerg,Cyrille Constentin Pdf

Homogeneous and Heterogeneous Catalysis

Author : Samuel C. Perry
Publisher : Walter de Gruyter GmbH & Co KG
Page : 158 pages
File Size : 45,8 Mb
Release : 2021-08-23
Category : Technology & Engineering
ISBN : 9781501522239

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Electrochemical Carbon Dioxide Reduction by Samuel C. Perry Pdf

Carbon dioxide reduction is a key research challenge in the global mission to reduce CO2 emissions. The process presents a unique challenge in that it can produce several different products, presenting the user with the challenge of selectively and efficiently producing on single useful material. This book presents an introduction to the field, covering the chemical reactions involved, the range of innovative materials and reactor designs most recently developed, and the future targets that need to be met.

Author : Yuichiro Himeda
Publisher : John Wiley & Sons
Page : 322 pages
File Size : 46,7 Mb
Release : 2021-06-28
Category : Technology & Engineering
ISBN : 9783527346639

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CO2 Hydrogenation Catalysis by Yuichiro Himeda Pdf

A guide to the effective catalysts and latest advances in CO2 conversion in chemicals and fuels Carbon dioxide hydrogenation is one of the most promising and economic techniques to utilize CO2 emissions to produce value-added chemicals. With contributions from an international team of experts on the topic, CO2 Hydrogenation Catalysis offers a comprehensive review of the most recent developments in the catalytic hydrogenation of carbon dioxide to formic acid/formate, methanol, methane, and C2+ products. The book explores the electroreduction of carbon dioxide and contains an overview on hydrogen production from formic acid and methanol. With a practical review of the advances and challenges in future CO2 hydrogenation research, the book provides an important guide for researchers in academia and industry working in the field of catalysis, organometallic chemistry, green and sustainable chemistry, as well as energy conversion and storage. This important book: Offers a unique review of effective catalysts and the latest advances in CO2 conversion Explores how to utilize CO2 emissions to produce value-added chemicals and fuels such as methanol, olefins, gasoline, aromatics Includes the latest research in homogeneous and heterogeneous catalysis as well as electrocatalysis Highlights advances and challenges for future investigation Written for chemists, catalytic chemists, electrochemists, chemists in industry, and chemical engineers, CO2 Hydrogenation Catalysis offers a comprehensive resource to understanding how CO2 emissions can create value-added chemicals.

Author : Constantinos G. Vayenas,Ralph E. White,Maria E. Gamboa-Aldeco
Publisher : Springer Science & Business Media
Page : 434 pages
File Size : 52,5 Mb
Release : 2008-03-08
Category : Science
ISBN : 9780387494890

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Modern Aspects of Electrochemistry 42 by Constantinos G. Vayenas,Ralph E. White,Maria E. Gamboa-Aldeco Pdf

This volume analyzes and summarizes recent developments in several key interfacial electrochemical systems in the areas of fuel cell electrocatatalysis, electrosynthesis and electrodeposition. The six Chapters are written by internationally recognized experts in these areas and address both fundamental and practical aspects of several existing or emerging key electrochemical technologies. The Chapter by R. Adzic, N. Marinkovic and M. Vukmirovic provides a lucid and authoritative treatment of the electrochemistry and electrocatalysis of Ruthenium, a key element for the devel- ment of efficient electrodes for polymer electrolyte (PEM) fuel cells. Starting from fundamental surface science studies and interfacial considerations, this up-to-date review by some of the pioneers in this field, provides a deep insight in the complex catalytic-electrocatalytic phenomena occurring at the interfaces of PEM fuel cell electrodes and a comprehensive treatment of recent developments in this extremely important field. Several recent breakthroughs in the design of solid oxide fuel cell (SOFC) anodes and cathodes are described in the Chapter of H. Uchida and M. Watanabe. The authors, who have pioneered several of these developments, provide a lucid presentation d- cribing how careful fundamental investigations of interfacial electrocatalytic anode and cathode phenomena lead to novel electrode compositions and microstructures and to significant practical advances of SOFC anode and cathode stability and enhanced electrocatalysis.

Author : M. I. Ismail
Publisher : Elsevier Publishing Company
Page : 574 pages
File Size : 42,7 Mb
Release : 1989
Category : Science
ISBN : STANFORD:36105000610340

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Electrochemical Reactors: Fundamentals, electrolysers, batteries, and fuel cells by M. I. Ismail Pdf

This book provides a guide for professionals interested in energy transfer and electrochemical technology systems. It covers the state-of-the-art of materials, electrochemistry and electrochemical engineering as related to electrochemical reactors, batteries and fuel cells. The fifteen chapters, written by experts in fields related to every aspect affecting reactor performance, are grouped into three parts. The first is devoted to fundamentals of reactors, batteries and fuel cells and covers various aspects of design, parts, construction, materials operation and control systems. The second group is devoted to specific reactors such as aqueous electro-organic and inorganic synthesis, electrochemical polymerization, molten salt electrolysis, electrochemical machining, metal finishing, reactor performance, failure mechanisms, corrosion control, materials selection and techniques. The third group deals with manufacturing techniques and surface treatment of materials for commercial reactors, commercial parts/materials, fastening, assembly and production of reactor parts and mathematical modelling of various reactor processes.

Author : José J. G. Moura,Isabel Moura,Luisa B. Maia
Publisher : Springer Nature
Page : 507 pages
File Size : 40,7 Mb
Release : 2020-12-01
Category : Science
ISBN : 9783030583156

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Enzymes for Solving Humankind's Problems by José J. G. Moura,Isabel Moura,Luisa B. Maia Pdf

This book presents specific key natural and artificial systems that are promising biocatalysts in the areas of health, agriculture, environment and energy. It provides a comprehensive account of the state of the art of these systems and outlines the significant progress made in the last decade using these systems to develop innovative, sustainable and environmentally friendly solutions. Chapters from expert contributors explore how natural enzymes and artificial systems tackle specific targets such as: climate change, carbon footprint and economy and carbon dioxide utilisation; nitrogen footprint and fixation and nitrous oxide mitigation; hydrogen production, fuel cells and energy from bacteria; biomass transformation and production of added-value compounds, as well as biosensors development. This book provides an important and inspiring account for the designing of new natural and artificial systems with enhanced properties, and it appeals not only to students and researchers working in the fields of energy, health, food and environment, but also to a wider audience of educated readers that are interested in these up-to-date and exciting subjects. Chapter “Carbon Dioxide Utilisation—The Formate Route” is available open access under a Creative Commons Attribution 4.0 International License via link.springer.com.

Author : Michele Aresta
Publisher : John Wiley & Sons
Page : 414 pages
File Size : 46,7 Mb
Release : 2010-01-26
Category : Science
ISBN : 3527629920

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Carbon Dioxide as Chemical Feedstock by Michele Aresta Pdf

Filling the need for an up-to-date handbook, this ready reference closely investigates the use of CO2 for ureas, enzymes, carbamates, and isocyanates, as well as its use as a solvent, in electrochemistry, biomass utilization and much more. Edited by an internationally renowned and experienced researcher, this is a comprehensive source for every synthetic chemist in academia and industry.

Author : Ferenc Darvas,Volker Hessel,György Dorman
Publisher : Walter de Gruyter GmbH & Co KG
Page : 307 pages
File Size : 44,5 Mb
Release : 2014-08-25
Category : Technology & Engineering
ISBN : 9783110388756

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Flow Chemistry – Fundamentals by Ferenc Darvas,Volker Hessel,György Dorman Pdf

"Flow Chemistry fills the gap in graduate education by covering chemistry and reaction principles along with current practice, including examples of relevant commercial reaction, separation, automation, and analytical equipment. The Editors of Flow Chemistry are commended for having taken the initiative to bring together experts from the field to provide a comprehensive treatment of fundamental and practical considerations underlying flow chemistry. It promises to become a useful study text and as well as reference for the graduate students and practitioners of flow chemistry." Professor Klavs Jensen Massachusetts Institute of Technology, USA Broader theoretical insight in driving a chemical reaction automatically opens the window towards new technologies particularly to flow chemistry. This emerging concept promotes the transformation of present day's organic processes into a more rapid continuous set of synthesis operations, more compatible with the envisioned sustainable world. These two volumes Fundamentals and Applications provide both the theoretical foundation as well as the practical aspects.

Author : Annemie Bogaerts
Publisher : MDPI
Page : 248 pages
File Size : 49,7 Mb
Release : 2019-04-02
Category : Technology & Engineering
ISBN : 9783038977506

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Plasma Catalysis by Annemie Bogaerts Pdf

Plasma catalysis is gaining increasing interest for various gas conversion applications, such as CO2 conversion into value-added chemicals and fuels, N2 fixation for the synthesis of NH3 or NOx, methane conversion into higher hydrocarbons or oxygenates. It is also widely used for air pollution control (e.g., VOC remediation). Plasma catalysis allows thermodynamically difficult reactions to proceed at ambient pressure and temperature, due to activation of the gas molecules by energetic electrons created in the plasma. However, plasma is very reactive but not selective, and thus a catalyst is needed to improve the selectivity. In spite of the growing interest in plasma catalysis, the underlying mechanisms of the (possible) synergy between plasma and catalyst are not yet fully understood. Indeed, plasma catalysis is quite complicated, as the plasma will affect the catalyst and vice versa. Moreover, due to the reactive plasma environment, the most suitable catalysts will probably be different from thermal catalysts. More research is needed to better understand the plasma–catalyst interactions, in order to further improve the applications.

Author : Wey Yang Teoh,Atsushi Urakawa,Yun Hau Ng,Patrick Sit
Publisher : John Wiley & Sons
Page : 768 pages
File Size : 51,5 Mb
Release : 2021-02-23
Category : Technology & Engineering
ISBN : 9783527813568

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Heterogeneous Catalysts by Wey Yang Teoh,Atsushi Urakawa,Yun Hau Ng,Patrick Sit Pdf

Presents state-of-the-art knowledge of heterogeneous catalysts including new applications in energy and environmental fields This book focuses on emerging techniques in heterogeneous catalysis, from new methodology for catalysts design and synthesis, surface studies and operando spectroscopies, ab initio techniques, to critical catalytic systems as relevant to energy and the environment. It provides the vision of addressing the foreseeable knowledge gap unfilled by classical knowledge in the field. Heterogeneous Catalysts: Advanced Design, Characterization and Applications begins with an overview on the evolution in catalysts synthesis and introduces readers to facets engineering on catalysts; electrochemical synthesis of nanostructured catalytic thin films; and bandgap engineering of semiconductor photocatalysts. Next, it examines how we are gaining a more precise understanding of catalytic events and materials under working conditions. It covers bridging pressure gap in surface catalytic studies; tomography in catalysts design; and resolving catalyst performance at nanoscale via fluorescence microscopy. Quantum approaches to predicting molecular reactions on catalytic surfaces follows that, along with chapters on Density Functional Theory in heterogeneous catalysis; first principles simulation of electrified interfaces in electrochemistry; and high-throughput computational design of novel catalytic materials. The book also discusses embracing the energy and environmental challenges of the 21st century through heterogeneous catalysis and much more. Presents recent developments in heterogeneous catalysis with emphasis on new fundamentals and emerging techniques Offers a comprehensive look at the important aspects of heterogeneous catalysis Provides an applications-oriented, bottoms-up approach to a high-interest subject that plays a vital role in industry and is widely applied in areas related to energy and environment Heterogeneous Catalysts: Advanced Design, Characterization and Applications is an important book for catalytic chemists, materials scientists, surface chemists, physical chemists, inorganic chemists, chemical engineers, and other professionals working in the chemical industry.

Author : Inamuddin,Rajender Boddula,Mohd Imran Ahamed,Abdullah M. Asiri
Publisher : John Wiley & Sons
Page : 496 pages
File Size : 48,7 Mb
Release : 2020-06-10
Category : Science
ISBN : 9781119650980

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Applications of Metal-Organic Frameworks and Their Derived Materials by Inamuddin,Rajender Boddula,Mohd Imran Ahamed,Abdullah M. Asiri Pdf

Metal–organic frameworks (MOFs) are porous crystalline polymers con­structed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable mor­phology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community. This breakthrough new volume aims to explore down-to-earth applications in fields such as bio­medical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strate­gies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must-have for any library.

Author : Inamuddin,Abdullah M. Asiri,Eric Lichtfouse
Publisher : Springer Nature
Page : 216 pages
File Size : 48,8 Mb
Release : 2020-01-01
Category : Science
ISBN : 9783030286224

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Conversion of Carbon Dioxide into Hydrocarbons Vol. 1 Catalysis by Inamuddin,Abdullah M. Asiri,Eric Lichtfouse Pdf

This book presents the catalytic conversion of carbon dioxide into various hydrocarbons and other products using photochemical, electrochemical and thermo-chemical processes. Products include formate, formic acid, alcohols, lower and higher hydrocarbons, gases such as hydrogen, carbon monoxide and syngas.

Author : Peter Styring,Elsje Alessandra Quadrelli,Katy Armstrong
Publisher : Elsevier
Page : 337 pages
File Size : 52,7 Mb
Release : 2014-09-13
Category : Technology & Engineering
ISBN : 9780444627483

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Carbon Dioxide Utilisation by Peter Styring,Elsje Alessandra Quadrelli,Katy Armstrong Pdf

Carbon Dioxide Utilisation: Closing the Carbon Cycle explores areas of application such as conversion to fuels, mineralization, conversion to polymers, and artificial photosynthesis as well as assesses the potential industrial suitability of the various processes. After an introduction to the thermodynamics, basic reactions, and physical chemistry of carbon dioxide, the book proceeds to examine current commercial and industrial processes, and the potential for carbon dioxide as a green and sustainable resource. While carbon dioxide is generally portrayed as a "bad" gas, a waste product, and a major contributor to global warming, a new branch of science is developing to convert this "bad" gas into useful products. This book explores the science behind converting CO2 into fuels for our cars and planes, and for use in plastics and foams for our homes and cars, pharmaceuticals, building materials, and many more useful products. Carbon dioxide utilization is a rapidly expanding area of research that holds a potential key to sustainable, petrochemical-free chemical production and energy integration. Accessible and balanced between chemistry, engineering, and industrial applications Informed by blue-sky thinking and realistic possibilities for future technology and applications Encompasses supply chain sustainability and economics, processes, and energy integration