Esr Spectroscopy In Polymer Research

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ESR Spectroscopy in Polymer Research

Author : Bengt Ranby,Jan F. Rabek
Publisher : Springer Science & Business Media
Page : 422 pages
File Size : 53,7 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642666001

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ESR Spectroscopy in Polymer Research by Bengt Ranby,Jan F. Rabek Pdf

Thirty years ago, Zavoisky, in Moscow (USSR), reported the first successful experi mental observations of the ESR phenomenon. Its application to polymer problems began about 20 years ago. ESR belongs to the most specific and useful methods in the study of polymer reactions. The main purpose of this book is to collect the present available information on the applications of electron spin resonance (ESR) spectroscopy in polymer research. The book has been written both for those who want an introduction to this field, and for those who are aheady familiar with ESR and are interested in application to polymers. Therefore, the fundamental principles of ESR spectroscopy are first out lined, the experimental methods including computer applications are described in more detail, and the main emphasis is on the application of ESR methods to polymer problems. Many results obtained are only briefly treated for lack of space. The authors hope that this book will provide a useful source of information by giving a coherent treatment and extensive references to original papers, reviews, and discussions in monographs and books. In this way we hope to encourage polymer chemists, organic chemists, biochemists, physicists, and material scientists to apply ESR methods to their research problems.

Advanced ESR Methods in Polymer Research

Author : Shulamith Schlick
Publisher : John Wiley & Sons
Page : 300 pages
File Size : 41,9 Mb
Release : 2006-10-06
Category : Science
ISBN : 9780470053492

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Advanced ESR Methods in Polymer Research by Shulamith Schlick Pdf

A definitive work on ESR and polymer science by today's leading authorities The past twenty years have seen extraordinary advances in electron spin resonance (ESR) techniques, particularly as they apply to polymeric materials. With contributions from over a dozen of the world's top polymer scientists, Advanced ESR Methods in Polymer Research is the first book to bring together all the current trends in this exciting field into one comprehensive reference. Part I establishes the fundamentals of ESR, from experimental techniques to data analysis, and serves as a valuable overview for the beginning ESR student. Part II introduces the broad range of ESR applications to polymeric systems, including living radical polymerization, block copoly-mers, polymer solutions, ion-containing polymers, polymer lattices, membranes in fuel cells, degradation, polymer coatings, dendrimers, and conductive polymers. By exposing readers to the great potential of ESR, the authors hope to encourage more extensive application of these methods.

Principles and Applications of ESR Spectroscopy

Author : Anders Lund,Masaru Shiotani,Shigetaka Shimada
Publisher : Springer Science & Business Media
Page : 468 pages
File Size : 49,5 Mb
Release : 2011-01-04
Category : Science
ISBN : 9781402053443

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Principles and Applications of ESR Spectroscopy by Anders Lund,Masaru Shiotani,Shigetaka Shimada Pdf

Principles and Applications of ESR Spectroscopy fills the gap between the detailed monographs in ESR spectroscopy and the general textbooks in molecular physics, physical chemistry, biochemistry or spectroscopy. The latter only briefly explain the underlying theory and do not provide details about applications, while the currently available ESR textbooks are primarily focused on the technique as such. This text is based upon the authors’ long experience of teaching the subject to a mixed audience, in the extreme case ranging from physics to biology. The potential of the method is illustrated with applications in fields such as molecular science, catalysis and environmental sciences, polymer and materials sciences, biochemistry and radiation chemistry/physics. Theoretical derivations have in general been omitted, as they have been presented repeatedly in previous works. The necessary theory is instead illustrated by practical examples from the literature.

ESR Applications to Polymer Research

Author : Per Olof Kinell,Bengt G. Rånby,Vera Runnström-Reio
Publisher : Unknown
Page : 320 pages
File Size : 44,8 Mb
Release : 1973
Category : Electron paramagnetic resonance
ISBN : UCAL:B4163955

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ESR Applications to Polymer Research by Per Olof Kinell,Bengt G. Rånby,Vera Runnström-Reio Pdf

Multi Frequency EPR Spectroscopy of Conjugated Polymers and Their Nanocomposites

Author : Victor I. Krinichnyi
Publisher : CRC Press
Page : 230 pages
File Size : 52,8 Mb
Release : 2016-10-14
Category : Science
ISBN : 9781315349626

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Multi Frequency EPR Spectroscopy of Conjugated Polymers and Their Nanocomposites by Victor I. Krinichnyi Pdf

Conjugated polymeric materials and their nanocomposites are widely used for the creation of alternative sources of renewable energy, cell phone screens, mobile gadgets, video players and OLED-TV, as well as organic diodes, transistors, sensors, etc. with field-dependent and spin-assisted electronic properties. Multifrequency EPR Spectroscopy methods can help researchers optimize their structural, magnetic and electronic properties for the creation of more efficient molecular devices. This book will acquaint the reader with the basic properties of conjugated polymers, the fundamentals of EPR Spectroscopy, and the information that can be obtained at different wavebands of EPR spectroscopy.

Electron Spin Resonance (ESR) Applications in Organic and Bioorganic Materials

Author : B. Catoire
Publisher : Springer Science & Business Media
Page : 305 pages
File Size : 42,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642772146

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Electron Spin Resonance (ESR) Applications in Organic and Bioorganic Materials by B. Catoire Pdf

E.S.R. techniques which are mature from a fundamental point of view. now constitute a routine investigation tool in chemistry as well as in biophysics in order to study and to follow the behaviour of radical species. Among the practical applications. let us mention for instance : -diffusion phenomena (solid -solid. liquid -solid such as the diffusion of molecules through membranes. films fibers ... ). -study of radical species to improve the elaboration of materials with high added value (composites). -detection of ionised food. -liquid crystals. polymers. -radiochemistry. -targetting of drugs. toxicology. A better understanding of basic phenomena allows to optimize industrial products and processes applied as well as in advanced fields as in well established ones. The high sensivity of ESR Spectroscopy and its derived specific techniques (spin labelling. spin probe. spin trapping ... ) offer information on the fme morphological structure of the matter as well as on its behaviour under various treatments otherwise not available. A Symposium was organized in Lyon (France) in January 1990 to promote the use of ESR. Its originality was to deal with the practical applications of ESR to organic and bioorganic materials. The scope of this meeting was to enlarge the field of application from basic research to more applied subjects and this may concern industrial as well as academic researchers. Moreover. the purpose of this symposium was to promote exchanges between European specialists working in public or private areas.

Molecular Motion in Polymers by ESR

Author : Steven E. Keinath,Raymond F. Boyer
Publisher : CRC Press
Page : 360 pages
File Size : 48,9 Mb
Release : 1980
Category : Science
ISBN : 3718600129

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Molecular Motion in Polymers by ESR by Steven E. Keinath,Raymond F. Boyer Pdf

EPR Spectroscopy

Author : Malte Drescher,Gunnar Jeschke
Publisher : Springer Science & Business Media
Page : 247 pages
File Size : 52,7 Mb
Release : 2012-03-06
Category : Science
ISBN : 9783642283468

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EPR Spectroscopy by Malte Drescher,Gunnar Jeschke Pdf

EPR Spectroscopy in Catalysis, by Sabine Van Doorslaer und Damien M. Murphy Radicals in Flavoproteins, by Erik Schleicher und Stefan Weber EPR Spectroscopy in Polymer Science, by Dariush Hinderberger EPR in Protein Science, by Intrinsically Disordered Proteins, by Malte Drescher Site-Directed Spin Labeling of Membrane Proteins, by Enrica Bordignon Structure and Dynamics of Nucleic Acids, by Ivan Krstić, Burkhard Endeward, Dominik Margraf, Andriy Marko und Thomas F Prisner New Directions in Electron Paramagnetic Resonance Spectroscopy on Molecular Nanomagnets, by J. van Slageren

Introduction to Polymer Spectroscopy

Author : W. Klöpffer
Publisher : Springer Science & Business Media
Page : 201 pages
File Size : 53,9 Mb
Release : 2012-12-06
Category : Technology & Engineering
ISBN : 9783642693731

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Introduction to Polymer Spectroscopy by W. Klöpffer Pdf

This book has grown out of several courses oflectures held at the University of Mainz in the years 1978 to 1981, at the Ecole Poly technique Federal, Lausanne, and at the University of Fribourg, Switzerland. The last two courses were held in the framework of the "3e Cycle" lectures in June 1981. According to this genesis, the emphasis of the book lies on a unified and concise approach to introducing polymer spectroscopy rather than on completeness which, by the way, could hardly be achieved in a single volume. In contrast to other books on this subject, equal weight is given to electronic spectroscopy, vibrational spectroscopy and spin resonance techniques. The electronic properties of polymers have been increasingly investigated in the last ten years; until recently, however, these studies and the spectroscopic methods applied have not generally been considered as part of polymer spectroscopy. The increasing use of electronic spectroscopy by polymer researchers, on the other hand, shows that this type of spectroscopy provides efficient tools for gaining insight into the properties of polymers which cannot be obtained by any other means.

Electron Spin Resonance Spectroscopy of Organic Radicals

Author : Fabian Gerson,Walter Huber
Publisher : John Wiley & Sons
Page : 479 pages
File Size : 42,8 Mb
Release : 2006-03-06
Category : Science
ISBN : 9783527605248

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Electron Spin Resonance Spectroscopy of Organic Radicals by Fabian Gerson,Walter Huber Pdf

Electron spin resonance spectroscopy is the method used to determine the structure and life expectancy of a number of radicals. Written by Fabian Gerson and Walter Huber, top experts in the field of electron spin resonance spectroscopy, this book offers a compact yet readily comprehensible introduction to the modern world of ESR. Thanks to its comprehensive coverage, ranging from fundamental theory right up to the treatment of all important classes of organic radicals and triplet-state molecules that can be analyzed using ESR spectroscopy, this unique book is suitable for users in both research and industry. Instead of using complex mathematical derivations, the authors present a readily understandable approach to the field by interpreting sample spectra and classifying experimental data. In short, the ideal book for newcomers to the subject and an absolute must-have for everyone confronted with ESR spectroscopy and wanting to become acquainted with this widely-used method of analysis.

Polymer Science: A Comprehensive Reference

Author : Anonim
Publisher : Newnes
Page : 7752 pages
File Size : 52,7 Mb
Release : 2012-12-05
Category : Technology & Engineering
ISBN : 9780080878621

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Polymer Science: A Comprehensive Reference by Anonim Pdf

The progress in polymer science is revealed in the chapters of Polymer Science: A Comprehensive Reference, Ten Volume Set. In Volume 1, this is reflected in the improved understanding of the properties of polymers in solution, in bulk and in confined situations such as in thin films. Volume 2 addresses new characterization techniques, such as high resolution optical microscopy, scanning probe microscopy and other procedures for surface and interface characterization. Volume 3 presents the great progress achieved in precise synthetic polymerization techniques for vinyl monomers to control macromolecular architecture: the development of metallocene and post-metallocene catalysis for olefin polymerization, new ionic polymerization procedures, and atom transfer radical polymerization, nitroxide mediated polymerization, and reversible addition-fragmentation chain transfer systems as the most often used controlled/living radical polymerization methods. Volume 4 is devoted to kinetics, mechanisms and applications of ring opening polymerization of heterocyclic monomers and cycloolefins (ROMP), as well as to various less common polymerization techniques. Polycondensation and non-chain polymerizations, including dendrimer synthesis and various "click" procedures, are covered in Volume 5. Volume 6 focuses on several aspects of controlled macromolecular architectures and soft nano-objects including hybrids and bioconjugates. Many of the achievements would have not been possible without new characterization techniques like AFM that allowed direct imaging of single molecules and nano-objects with a precision available only recently. An entirely new aspect in polymer science is based on the combination of bottom-up methods such as polymer synthesis and molecularly programmed self-assembly with top-down structuring such as lithography and surface templating, as presented in Volume 7. It encompasses polymer and nanoparticle assembly in bulk and under confined conditions or influenced by an external field, including thin films, inorganic-organic hybrids, or nanofibers. Volume 8 expands these concepts focusing on applications in advanced technologies, e.g. in electronic industry and centers on combination with top down approach and functional properties like conductivity. Another type of functionality that is of rapidly increasing importance in polymer science is introduced in volume 9. It deals with various aspects of polymers in biology and medicine, including the response of living cells and tissue to the contact with biofunctional particles and surfaces. The last volume is devoted to the scope and potential provided by environmentally benign and green polymers, as well as energy-related polymers. They discuss new technologies needed for a sustainable economy in our world of limited resources. Provides broad and in-depth coverage of all aspects of polymer science from synthesis/polymerization, properties, and characterization methods and techniques to nanostructures, sustainability and energy, and biomedical uses of polymers Provides a definitive source for those entering or researching in this area by integrating the multidisciplinary aspects of the science into one unique, up-to-date reference work Electronic version has complete cross-referencing and multi-media components Volume editors are world experts in their field (including a Nobel Prize winner)

Update on Paramagnetic Sensors for Polymers and Composites Research

Author : Alexander L Kovarski
Publisher : Smithers Rapra
Page : 186 pages
File Size : 46,5 Mb
Release : 2013-03-18
Category : Science
ISBN : 9781847357762

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Update on Paramagnetic Sensors for Polymers and Composites Research by Alexander L Kovarski Pdf

This book presents newer applications of paramagnetic sensors for the study of polymer materials structure, microreology and molecular dynamics. Paramagnetic (or spin) sensors have found wide use in structural and dynamic research of condensed media using the spectroscopy of electron paramagnetic resonance (EPR). Stable nitroxide radicals are the most exploited paramagnetic sensors which formed the basis of spin probes and labels technique well known to the experts in fields of chemical and biological materials science. With the proliferation of new materials (composites, nano-dimensional fillers) new trends in the methodology of paramagnetic sensors application have been outlined. This book is devoted to these new trends in polymers and nanocomposites research. It observes the methods of adaptation of EPR spectroscopy of paramagnetic sensors to interface layers investigation, analysis of the systems containing magnetic nanoparticles, identification of composites ingredients by EPR spectra of free radicals, detection of the shear component of polymer materials deformation. This book also presents, at an accessible level, the theory of EPR, the structure and properties of paramagnetic sensors - stable nitroxide radicals and methods of basic parameters calculation from their EPR spectra. Intended for researchers and educators specialized in polymer material science and colloid chemistry. This book can also be used as a practical guide on paramagnetic resonance and paramagnetic sensors application for students and postgraduates.

Applications of EPR in Radiation Research

Author : Anders Lund,Masaru Shiotani
Publisher : Springer
Page : 773 pages
File Size : 53,8 Mb
Release : 2014-10-20
Category : Science
ISBN : 9783319092164

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Applications of EPR in Radiation Research by Anders Lund,Masaru Shiotani Pdf

Applications of EPR in Radiation Research is a multi-author contributed volume presented in eight themes: I. Elementary radiation processes (in situ and low temperature radiolysis, quantum solids); II: Solid state radiation chemistry (crystalline, amorphous and heterogeneous systems); III: Biochemistry, biophysics and biology applications (radicals in biomaterials, spin trapping, free-radical-induced DNA damage); IV: Materials science (polymeric and electronic materials, materials for treatment of nuclear waste, irradiated food); V: Radiation metrology (EPR-dosimetry, retrospective and medical applications); VI: Geological dating; VII: Advanced techniques (PELDOR, ESE and ENDOR spectroscopy, matrix isolation); VIII: Theoretical tools (density-functional calculations, spectrum simulations).

Polymer Degradation and Stabilization

Author : W. L. Hawkins
Publisher : Springer Science & Business Media
Page : 129 pages
File Size : 41,6 Mb
Release : 2012-12-06
Category : Technology & Engineering
ISBN : 9783642693762

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Polymer Degradation and Stabilization by W. L. Hawkins Pdf

The development of polymers as an important class of material was inhibited at the first by the premature failure of these versatile compounds in many applications. The deterioration of important properties of both natural and synthetic polymers is the result of irreversible changes in composition and structure of polymers molecules. As a result of these reactions, mechanical, electrical and/or aesthetic properties are degraded beyond acceptable limits. It is now generally recognized that stabilization against degradation is necessary if the useful life of polymers is to be extended sufficiently to meet design requirements for long-term applications. Polymers degrade by a wide variety of mechanisms, several of which affect all polymers through to varying degree. This monograph will concentrate on those degradation mechanisms which result from reactions of polymers with oxygen in its various forms and which are accelerated by heat and/or radiation. Those stabilization mechanisms are discussed which are based on an understanding of degradation reaction mechanisms that are reasonably well established. The stabilization of polymers is still undergoing a transition from an art to a science as mechanisms of degradation become more fully developed. A scientific approach to stabilization can only be approached when there is an understanding of the reactions that lead to degradation. Stabilization against biodegradation and burning will not be discussed since there is not a clear understanding of how polymers degrade under these conditions.

Electron Spin Resonance

Author : P B Ayscough
Publisher : Royal Society of Chemistry
Page : 450 pages
File Size : 54,8 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847553409

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Electron Spin Resonance by P B Ayscough Pdf

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.