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Author : Santíago V. Luis,Eduardo García-Verdugo
Publisher : Royal Society of Chemistry
Page : 213 pages
File Size : 40,7 Mb
Release : 2010
Category : Science
ISBN : 9780854041923
On the contrary, flow continuous processes present a series of advantages leading to new ways to synthesise chemical products.
Author : Roger Prud'homme
Publisher : John Wiley & Sons
Page : 240 pages
File Size : 55,5 Mb
Release : 2013-01-09
Category : Science
ISBN : 9781118588222
The aim of this book is to relate fluid flows to chemical reactions. It focuses on the establishment of consistent systems of equations with their boundary conditions and interfaces, which allow us to model and deal with complex situations. Chapter 1 is devoted to simple fluids, i.e. to a single chemical constituent. The basic principles of incompressible and compressible fluid mechanics, are presented in the most concise and educational manner possible, for perfect or dissipative fluids. Chapter 2 relates to the flows of fluid mixtures in the presence of chemical reactions. Chapter 3 is concerned with interfaces and lines. Interfaces have been the subject of numerous publications and books for nearly half a century. Lines and curvilinear media are less known Several appendices on mathematical notation, thermodynamics and mechanics methods are grouped together in Chapter 4. This summary presentation of the basic equations of simple fluids, with exercises and their solutions, as well as those of chemically reacting flows, and interfaces and lines will be very useful for graduate students, engineers, teachers and scientific researchers in many domains of science and industry who wish to investigate problems of reactive flows. Portions of the text may be used in courses or seminars on fluid mechanics.
Author : Roger Prud'homme
Publisher : John Wiley & Sons
Page : 200 pages
File Size : 53,6 Mb
Release : 2013-10-08
Category : Science
ISBN : 9781118832660
Flows with chemical reactions can occur in various fields such as combustion, process engineering, aeronautics, the atmospheric environment and aquatics. The examples of application chosen in this book mainly concern homogeneous reactive mixtures that can occur in propellers within the fields of process engineering and combustion: – propagation of sound and monodimensional flows in nozzles, which may include disequilibria of the internal modes of the energy of molecules; – ideal chemical reactors, stabilization of their steady operation points in the homogeneous case of a perfect mixture and classical instruments of experimental and theoretical analysis such as population balances, and the distribution of residence and passage times; – laminar and turbulent flames, separating those which are premixed from those which are not and which do not exhibit the same mechanisms, but which also occur in the case of triple flames. Flows and Chemical Reactions in Homogeneous Mixtures provides information on dimensional analysis, statistical thermodynamics with coupling between internal modes and chemical reactions, the apparition and damping of fluid turbulence as well as its statistical processing, bifurcations, flames in a confined medium and diffusion. Contents 1. Flows in Nozzles. 2. Chemical Reactors. 3. Laminar and Turbulent Flames. Appendix 1. Dimensionless Numbers, Similarity. Appendix 2. Thermodynamic Functions. Appendix 3. Concepts of Turbulence. Appendix 4. Thermodynamic functions for a mixture in disequilibrium. Appendix 5. Notion of bifurcation. Appendix 6. Confined flame. Appendix 7. Limits of Validity of the First-order Expansions for Diffusion Flames.
Author : Roger Prud'homme
Publisher : John Wiley & Sons
Page : 204 pages
File Size : 49,7 Mb
Release : 2014-10-30
Category : Science
ISBN : 9781119054269
This book - a sequel of previous publications 'Flows and Chemical Reactions' and 'Chemical Reactions in Flows and Homogeneous Mixtures' - is devoted to flows with chemical reactions in heterogeneous environments. Heterogeneous media in this volume include interfaces and lines. They may be the site of radiation. Each type of flow is the subject of a chapter in this volume. We consider first, in Chapter 1, the question of the generation of environments biphasic individuals: dusty gas, mist, bubble flow. Chapter 2 is devoted to the study at the mesoscopic scale: particle-fluid exchange of momentum and heat with determination of the respective exchange coefficients. In Chapter 3, we establish simplified equations of macroscopic balance for mass, for the momentum and energy, in the case of particles of one size (monodisperse suspension). Radiative phenomena are presented in Chapter 5.
Author : Roger Prud'homme
Publisher : Springer Science & Business Media
Page : 492 pages
File Size : 46,5 Mb
Release : 2010-07-15
Category : Technology & Engineering
ISBN : 9780817646592
The modeling of reactive flows has progressed mainly with advances in aerospace, which gave birth to a new science called aerothermochemistry, as well as through developments in chemical and process engineering. This work examines basic concepts and methods necessary to study reactive flows and transfer phenomena in areas such as fluid mechanics, thermodynamics, and chemistry. The book presents tools of interest to graduate students, researchers in mathematical physics, and engineers who wish to investigate problems of reactive flows. Portions of the text may be used in courses on the physics of liquids or in seminars on mechanics.
Author : Robert J. Kee,Michael E. Coltrin,Peter Glarborg,Huayang Zhu
Publisher : John Wiley & Sons
Page : 792 pages
File Size : 50,6 Mb
Release : 2017-09-27
Category : Science
ISBN : 9781119186298
A guide to the theoretical underpinnings and practical applications of chemically reacting flow Chemically Reacting Flow: Theory, Modeling, and Simulation, Second Edition combines fundamental concepts in fluid mechanics and physical chemistry while helping students and professionals to develop the analytical and simulation skills needed to solve real-world engineering problems. The authors clearly explain the theoretical and computational building blocks enabling readers to extend the approaches described to related or entirely new applications. New to this Second Edition are substantially revised and reorganized coverage of topics treated in the first edition. New material in the book includes two important areas of active research: reactive porous-media flows and electrochemical kinetics. These topics create bridges between traditional fluid-flow simulation approaches and transport within porous-media electrochemical systems. The first half of the book is devoted to multicomponent fluid-mechanical fundamentals. In the second half the authors provide the necessary fundamental background needed to couple reaction chemistry into complex reacting-flow models. Coverage of such topics is presented in self-contained chapters, allowing a great deal of flexibility in course curriculum design. • Features new chapters on reactive porous-media flow, electrochemistry, chemical thermodynamics, transport properties, and solving differential equations in MATLAB • Provides the theoretical underpinnings and practical applications of chemically reacting flow • Emphasizes fundamentals, allowing the analyst to understand fundamental theory underlying reacting-flow simulations • Helps readers to acquire greater facility in the derivation and solution of conservation equations in new or unusual circumstances • Reorganized to facilitate use as a class text and now including a solutions manual for academic adopters Computer simulation of reactive systems is highly efficient and cost-effective in the development, enhancement, and optimization of chemical processes. Chemically Reacting Flow: Theory, Modeling, and Simulation, Second Edition helps prepare graduate students in mechanical or chemical engineering, as well as research professionals in those fields take utmost advantage of that powerful capability.
Author : Rustam Ya Deberdeev
Publisher : Smithers Rapra
Page : 334 pages
File Size : 50,8 Mb
Release : 2013-09-02
Category : Science
ISBN : 9781909030282
This book describes the fundamentals of fast liquid-phase chemical reactions and the principles of their scientific foundation, technical implementation and industrial application of new technologies. In addition, the equipment required to perform these reactions, in a turbulent mode in the chemical, petrochemical and petroleum industries, is also discussed. The macrokinetic approach has been developed with consideration of the diffusion, hydrodynamics, and heat transfer processes. Due to the advancement of fundamental knowledge, equations of practical engineering importance have been obtained for the calculations of mass and heat transfer processes carried out in conditions of high turbulence, and developed for the implementation in fast chemical reactions involving the synthesis of low molecular weight products and polymers. New methods for controlling the molecular characteristics of polymers have been developed based on the tailored regulation of the hydrodynamics of the reactive mixture flow. Typical processes have been used as model examples to reveal the influence of turbulence on the behaviour of fast chemical reactions used for the synthesis of low molecular weight products, in single-phase and two-phase reactive systems. Brand new tubular devices have been developed with the following characteristics: compact size, high productivity, and a quasi-perfect mixing operation mode in turbulent flows. These devices are subdivided into cylindrical, shell-and-tube, 'zone', and diffuser-confusor designs. Original solutions are proposed for the instrumental implementation of fast liquid-phase processes and development of continuous energy- and resource-efficient technologies for the synthesis of some large-scale compounds.
Author : Ferenc Darvas,Volker Hessel,György Dorman
Publisher : Walter de Gruyter GmbH & Co KG
Page : 307 pages
File Size : 55,9 Mb
Release : 2014-08-25
Category : Technology & Engineering
ISBN : 9783110388756
"Flow Chemistry fills the gap in graduate education by covering chemistry and reaction principles along with current practice, including examples of relevant commercial reaction, separation, automation, and analytical equipment. The Editors of Flow Chemistry are commended for having taken the initiative to bring together experts from the field to provide a comprehensive treatment of fundamental and practical considerations underlying flow chemistry. It promises to become a useful study text and as well as reference for the graduate students and practitioners of flow chemistry." Professor Klavs Jensen Massachusetts Institute of Technology, USA Broader theoretical insight in driving a chemical reaction automatically opens the window towards new technologies particularly to flow chemistry. This emerging concept promotes the transformation of present day's organic processes into a more rapid continuous set of synthesis operations, more compatible with the envisioned sustainable world. These two volumes Fundamentals and Applications provide both the theoretical foundation as well as the practical aspects.
Author : Ferenc Darvas,György Dormán,Volker Hessel,Steven V. Ley
Publisher : Walter de Gruyter GmbH & Co KG
Page : 448 pages
File Size : 49,9 Mb
Release : 2021-10-25
Category : Technology & Engineering
ISBN : 9783110693768
The fully up-dated edition of the two-volume work covers both the theoretical foundation as well as the practical aspects. A strong insight in driving a chemical reaction is crucial for a deeper understanding of new potential technologies. New procedures for warranty of safety and green principles are discussed. Vol. 1: Fundamentals.
Author : O. M. Phillips
Publisher : Cambridge University Press
Page : 300 pages
File Size : 53,7 Mb
Release : 1991-02-22
Category : Nature
ISBN : 0521380987
The formation of ore deposits and the patterns of mineral alteration in rocks frequently involves the transport of large amounts of dissolved solids, sometimes transiently, but often over long periods of time. Knowing or suspecting this, we logically seek to resolve several questions: What are the large- and small-scale patterns of flow in geological materials? What is the direction and rate of flow in a given structure? What factors control the rates of chemical reaction within the rocks? What governs the dissolution of materials in some regions and their deposition in other areas that, over eons, leads to the distribution of minerals we see today? The search for answers to these issues involves a combination of approaches and subjects that includes geochemistry, structural geology, and fluid mechanics. In Flow and Reactions in Permeable Rocks, Dr. Owen Phillips provides the first book-length work that connects these different fields of study and applies them to the problem of flow and flow-controlled reaction in rocks. The author begins by specifying the general physical and chemical principles that govern fluid flow and chemical reactions in rocks. He then develops the theoretical underpinnings for a variety of different patterns of flow and for the three basic types of flow-controlled reaction: fronts, gradient reactions, and reactions in mixing zones. In the next chapter he explores some conditions for stability and instability in fluid flow, for instance the conditions under which one state of flow pattern spontaneously evolves into another. Finally, Dr. Phillips describes in detail the two great driving forces of large-scale fluid circulation in rocks: pressure differences and thermal convection. Typical geological examples are given and, wherever possible, compared to numerical results or field observations. The analytical developments require some familiarity with college-level mathematics, but derivations are easy to follow or may even be skipped by the trusting reader.
Author : Roger Norris Keeler
Publisher : Unknown
Page : 208 pages
File Size : 53,7 Mb
Release : 1964
Category : Chemical reactions
ISBN : UOM:39015077590472
Author : Erik Van der Eycken,Upendra K. Sharma
Publisher : John Wiley & Sons
Page : 626 pages
File Size : 43,6 Mb
Release : 2022-03-21
Category : Science
ISBN : 9783527349081
Presents a wide-ranging overview of essential topics and recent advances in MCR chemistry Heterocycles are a central component in natural product chemistry, pharmaceuticals, agrochemicals, and material science. New synthetic methodologies integrating the sequencing of multicomponent reactions (MCRs) are today being used for the rapid synthesis of diversified heterocycles in just one step. Multicomponent Reactions towards Heterocycles presents an up-to-date summary MCR chemistry with a focus on the conjugation between modern synthetic methodologies and MCRs. Featuring contributions by leaders in the field, this comprehensive resource highlights applications of MCRs in natural products and intermediate synthesis, discusses current trends and future prospects in MCR chemistry, outlines novel multicomponent procedures, and more. The authors provide the practical information required for designing new reaction strategies and mechanisms, covering topics including MCR-based green synthetic methods, cyclization and cycloaddition reactions, heterocycle multicomponent syntheses in a continuous flow, catalytic alkynoyl generation, MCR synthesis of saturated heterocycles, and C–H functionalization and multicomponent reactions. Provides a thorough overview of heterocycles as input in multicomponent reactions Discusses recent advances in the field of MCR chemistry and progress in the synthesis and functionalization of heterocycles Demonstrates the use of MCRs to simplify synthetic design and achieve complexity and diversity in novel bioactive molecules Highlights examples of multicomponent polymerizations, target-oriented synthesis, and applications of MCR in medicinal chemistry Explains the methodology of using on-resin MCRs to produce heterocycle compounds Illustrating the key role of MCRs towards heterocycles in natural product synthesis, drug discovery, organic synthesis, and other applications, Multicomponent Reactions towards Heterocycles is required reading for synthetic chemists in academia and industry alike.
Author : Tapan Sengupta,Thierry Poinsot
Publisher : Springer Science & Business Media
Page : 331 pages
File Size : 53,7 Mb
Release : 2010-04-03
Category : Technology & Engineering
ISBN : 9783709101278
The articles in the book treat flow instability and transition starting with classical material dealt with in an innovative and rigorous way, some newer physical mechanisms explained for the first time and finally with the very complex topic of bombustion and two-phase flow instabilities.
Author : Bertrand R Rowe,Andre Canosa,Dwayne E Heard
Publisher : World Scientific
Page : 728 pages
File Size : 51,6 Mb
Release : 2022-05-18
Category : Science
ISBN : 9781800611009
Radioastronomy has painted an extraordinary picture of the Galactic interstellar medium, which displays an amazing organization and structuring of matter from very hot ultra-diluted media to very cold denser milieus considered as the cradles of stars. In these latter environments, the discovery of a chemical diversity of molecules, including those associated with precursors to life itself, immediately brought to light the question of the mechanisms leading to their formation and persistence at temperatures as low as 10 K. The chemical networks developed to understand telescope observations required a great deal of physical and chemical parameters relevant to interstellar conditions, particularly at very low temperatures. These included the rate coefficients of thousands of gas phase chemical reactions. Such data were missing in the 1970s, when the very first molecular discoveries were made. Then, in the early eighties, it was realized that uniform supersonic flows were ideal chemical reactors to study reaction kinetics at interstellar temperatures.Uniform Supersonic Flows in Chemical Physics reviews 40 years of use of such reactors, the so-called CRESU machines, focusing on major breakthroughs brought to chemical physics, physical chemistry, astrophysics and astrochemistry by the various experiments carried out with such apparatuses. The wealth of kinetic data at very low temperatures provided new targets for the predictions of theory, with new theoretical methods being developed to explain observed behavior. The first two chapters describe the physical context of reaction kinetics at very low temperatures and the requirements needed to run optimally such uniform supersonic flows, together with a historical perspective. Chapters 3 to 9 describe the various families of chemical processes that have been explored within the CRESU technique, highlighting major advances and offering an exhaustive up-to-date bibliography. Chapters 10 and 11 show how these experimental results have helped in improving the ideas in quantum chemistry and interstellar modeling. The book concludes with an overview of potential perspectives and new routes to be explored.
Author : Ferenc Darvas,Volker Hessel,György Dorman
Publisher : Walter de Gruyter GmbH & Co KG
Page : 350 pages
File Size : 55,6 Mb
Release : 2014-11-18
Category : Technology & Engineering
ISBN : 9783110367508
"Flow Chemistry fills the gap in graduate education by covering chemistry and reaction principles along with current practice, including examples of relevant commercial reaction, separation, automation, and analytical equipment. The Editors of Flow Chemistry are commended for having taken the initiative to bring together experts from the field to provide a comprehensive treatment of fundamental and practical considerations underlying flow chemistry. It promises to become a useful study text and as well as reference for the graduate students and practitioners of flow chemistry." Professor Klavs Jensen Massachusetts Institute of Technology, USA Broader theoretical insight in driving a chemical reaction automatically opens the window towards new technologies particularly to flow chemistry. This emerging concept promotes the transformation of present day's organic processes into a more rapid continuous set of synthesis operations, more compatible with the envisioned sustainable world. These two volumes Fundamentals and Applications provide both the theoretical foundation as well as the practical aspects.