Frustrated Lewis Pairs Ii

Author : Gerhard Erker,Douglas W. Stephan
Publisher : Springer
Page : 354 pages
File Size : 54,6 Mb
Release : 2014-07-08
Category : Science
ISBN : 9783642366970

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Frustrated Lewis Pairs I by Gerhard Erker,Douglas W. Stephan Pdf

Discovery of Frustrated Lewis Pairs: Intermolecular FLPs for Activation of Small Molecules, by Douglas W. Stephan Intramolecular Frustrated Lewis Pairs: Formation and Chemical Features, by Gerald Kehr, Sina Schwendemann, Gerhard Erker Frustrated Lewis Pair Mediated Hydrogenations, by Douglas W. Stephan, Gerhard Erker Amine-Borane Mediated Metal-Free Hydrogen Activation and Catalytic Hydrogenation, by Victor Sumerin, Konstantin Chernichenko, Felix Schulz, Markku Leskelä, Bernhard Rieger, Timo Repo Hydrogen Activation by Frustrated Lewis Pairs: Insights from Computational Studies, by Tibor András Rokob, Imre Pápai Quantum Chemistry of FLPs and Their Activation of Small Molecules: Methodological Aspects, by Birgitta Schirmer, Stefan Grimme Computational Design of Metal-Free Molecules for Activation of Small Molecules, Hydrogenation, and Hydroamination, by Zhi-Xiang Wang, Lili Zhao, Gang Lu, Haixia Li, Fang Huang Computational Studies of Lewis Acidity and Basicity in Frustrated Lewis Pairs, by Thomas M. Gilbert Solid-State NMR as a Spectroscopic Tool for Characterizing Phosphane - Borane Frustrated Lewis Pairs, by Thomas Wiegand, Hellmut Eckert, Stefan Grimme

Author : Douglas W. Stephan
Publisher : Royal Society of Chemistry
Page : 185 pages
File Size : 47,5 Mb
Release : 2021-11-17
Category : Science
ISBN : 9781839162442

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A Primer in Frustrated Lewis Pair Hydrogenation: Concepts to Applications by Douglas W. Stephan Pdf

Written for senior undergraduate and graduate students, as well as those chemists unfamiliar with "frustrated Lewis pairs (FLPs)", this text serves as an introduction to the both the concept and application of FLPs in hydrogenation catalysis. The book begins by setting the stage as it was around the turn of the century. While the dramatic impacts of catalysis were undeniable, there was dependence of such technologies on transition metal chemistry. Contrastingly, the chemistry of main group elements was dominated by Lewis acid-base behavior. However, these perceptions were altered with the discovery of the ability of "frustrated Lewis pairs (FLPs)" to activate dihydrogen. The basic features, and mechanisms of action of these unique main group systems are chronicled, while the evolution of the initial findings to applications in catalytic hydrogenation is discussed. A subsequent chapter focuses on the breadth of organic substrates for which borane based FLP hydrogenations are effective. This is furthered with a chapter on the metal-free enantioselective reductions. FLP chemistry is not limited to systems involving boranes and this book also catalogues a range of FLP hydrogenation catalysts involving elements from across the periodic table. The final chapter in the book describes other directions of interest where the application of the concept of FLPs hydrogenation are beginning to emerge. Ideal for course use and self study, this book provides synthetic chemists with a fresh, expert introduction to the field. The reader will be left recognizing that hydrogenation catalysts is a domain no longer limited to transition metals.

Author : Gerhard Erker,Douglas W. Stephan
Publisher : Springer
Page : 321 pages
File Size : 44,7 Mb
Release : 2013-12-12
Category : Science
ISBN : 9783642377594

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Frustrated Lewis Pairs II by Gerhard Erker,Douglas W. Stephan Pdf

Frustrated Lewis Pairs: From Dihydrogen Activation to Asymmetric Catalysis, by Dianjun Chen, Jürgen Klankermayer Coexistence of Lewis Acid and Base Functions: A Generalized View of the Frustrated Lewis Pair Concept with Novel Implications for Reactivity, by Heinz Berke, Yanfeng Jiang, Xianghua Yang, Chunfang Jiang, Subrata Chakraborty, Anne Landwehr New Organoboranes in "Frustrated Lewis Pair" Chemistry, by Zhenpin Lu, Hongyan Ye, Huadong Wang Paracyclophane Derivatives in Frustrated Lewis Pair Chemistry, by Lutz Greb, Jan Paradies Novel Al-Based FLP Systems, by Werner Uhl, Ernst-Ulrich Würthwein N-Heterocyclic Carbenes in FLP Chemistry, by Eugene L. Kolychev, Eileen Theuergarten, Matthias Tamm Carbon-Based Frustrated Lewis Pairs, by Shabana Khan, Manuel Alcarazo Selective C-H Activations Using Frustrated Lewis Pairs. Applications in Organic Synthesis, by Paul Knochel, Konstantin Karaghiosoff, Sophia Manolikakes FLP-Mediated Activations and Reductions of CO2 and CO, by Andrew E. Ashley, Dermot O’Hare Radical Frustrated Lewis Pairs, by Timothy H. Warren and Gerhard Erker Polymerization by Classical and Frustrated Lewis Pairs, by Eugene Y.-X. Chen Frustrated Lewis Pairs Beyond the Main Group: Transition Metal-Containing Systems, by D. Wass Reactions of Phosphine-Boranes and Related Frustrated Lewis Pairs with Transition Metal Complexes, by Abderrahmane Amgoune, Ghenwa Bouhadir, Didier Bourissou

Author : J. Chris Slootweg,Andrew R. Jupp
Publisher : Springer Nature
Page : 404 pages
File Size : 48,9 Mb
Release : 2020-11-22
Category : Science
ISBN : 9783030588885

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Frustrated Lewis Pairs by J. Chris Slootweg,Andrew R. Jupp Pdf

This volume highlights the latest research in frustrated Lewis pair (FLP) chemistry and its applications. The contributions present the recent developments of the use of FLPs in asymmetric catalysis, polymer synthesis, homogeneous and heterogeneous catalysis, as well as demonstrating their use as a pedagogical tool. The book will be of interest to researchers in academia and industry alike.

Author : Gerhard Erker,Douglas W. Stephan
Publisher : Unknown
Page : 328 pages
File Size : 48,7 Mb
Release : 2013-06-30
Category : Electronic
ISBN : 3642377602

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Frustrated Lewis Pairs II by Gerhard Erker,Douglas W. Stephan Pdf

Author : Douglas W Stephan
Publisher : Royal Society of Chemistry
Page : 185 pages
File Size : 52,5 Mb
Release : 2021-11-17
Category : Science
ISBN : 9781839165061

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A Primer in Frustrated Lewis Pair Hydrogenation by Douglas W Stephan Pdf

Written for senior undergraduate and graduate students, as well as those chemists unfamiliar with “frustrated Lewis pairs (FLPs)”, this text serves as an introduction to the both the concept and application of FLPs in hydrogenation catalysis. The book begins by setting the stage as it was around the turn of the century. While the dramatic impacts of catalysis were undeniable, there was dependence of such technologies on transition metal chemistry. Contrastingly, the chemistry of main group elements was dominated by Lewis acid-base behavior. However, these perceptions were altered with the discovery of the ability of “frustrated Lewis pairs (FLPs)” to activate dihydrogen. The basic features, and mechanisms of action of these unique main group systems are chronicled, while the evolution of the initial findings to applications in catalytic hydrogenation is discussed. A subsequent chapter focuses on the breadth of organic substrates for which borane based FLP hydrogenations are effective. This is furthered with a chapter on the metal-free enantioselective reductions. FLP chemistry is not limited to systems involving boranes and this book also catalogues a range of FLP hydrogenation catalysts involving elements from across the periodic table. The final chapter in the book describes other directions of interest where the application of the concept of FLPs hydrogenation are beginning to emerge. Ideal for course use and self study, this book provides synthetic chemists with a fresh, expert introduction to the field. The reader will be left recognizing that hydrogenation catalysts is a domain no longer limited to transition metals.

Author : Johannes F. Teichert
Publisher : John Wiley & Sons
Page : 312 pages
File Size : 50,9 Mb
Release : 2019-11-14
Category : Science
ISBN : 9783527814220

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Homogeneous Hydrogenation with Non-Precious Catalysts by Johannes F. Teichert Pdf

A guide and comprehensive review of the most recent advances in homogeneous hydrogenation with non-precious catalysts In recent years a great deal of research has been applied to homogeneous hydrogenation with non-precious catalysis. Homogeneous Hydrogenation with Non-Precious Catalysts offers a review of the latest developments and advances in the field. In addition, the book explores the transition metal catalysis and the concept of frustrated-lewis-pair (FLP) and enzymatic processes. The editor?a noted expert on the topic?discusses the various catalysts and puts the focus on the synthetic vantage point, highlighting the functional group transformation enabled by the respective catalyst. Homogeneous Hydrogenation with Non-Precious Catalysts also presents the industrial view of the topic and includes an overview of the various catalysts by functional group transformations. This important book: -Offers a comprehensive presentation of the newest development in this emerging field -Highlights the transition metal catalysis, the frustrated-lewis-pair (FLP) concept, and enzymatic processes -Provides an industrial perspective of the topic -Includes an overview of the various catalysis by functional group transformations Written for organic chemists, researchers in synthetic chemistry, and industry professionals, Homogeneous Hydrogenation with Non-Precious Catalysts offers a comprehensive and accessible guide to the most recent advances in the field. [/COPY_WEB_CATALOG]

Author : Pedro J. Perez
Publisher : Academic Press
Page : 344 pages
File Size : 44,9 Mb
Release : 2021-04-06
Category : Science
ISBN : 9780323850681

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Advances in Organometallic Chemistry by Pedro J. Perez Pdf

Advances in Organometallic Chemistry, Volume 75, the latest release in this longstanding serial that is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more provides a wide range of information, with this updated release including chapters on Two- and three-coordinate complexes featuring M-C bonds, Polymerization of terpene and terpenoids using well defined organometallic compounds, Bimetallic Frustrated Lewis Pairs, Organometallic based magnetic switches under confinement, Chemical Bonding and Dynamic Magnetism in f-Element Organometallic Sandwich Compounds, Tris-pyridyl Main Group Ligands: Design and Applications, Reactivities of N-heterocyclic carbenes at metal centers, and more. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material

Author : René Peters
Publisher : John Wiley & Sons
Page : 452 pages
File Size : 40,7 Mb
Release : 2015-04-27
Category : Technology & Engineering
ISBN : 9783527336890

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Cooperative Catalysis by René Peters Pdf

Written by experts in the field, this is a much-needed overview of the rapidly emerging field of cooperative catalysis. The authors focus on the design and development of novel high-performance catalysts for applications in organic synthesis (particularly asymmetric synthesis), covering a broad range of topics, from the latest progress in Lewis acid / Br?nsted base catalysis to e.g. metal-assisted organo catalysis, cooperative metal/enzyme catalysis, and cooperative catalysis in polymerization reactions and on solid surfaces. The chapters are classified according to the type of cooperating activating groups, and describe in detail the different strategies of cooperative activation, highlighting their respective advantages and pitfalls. As a result, readers will learn about the different concepts of cooperative catalysis, their corresponding modes of operation and their applications, thus helping to find a solution to a specific synthetic catalysis problem.

Author : Ewan J. M. Hamilton
Publisher : Elsevier
Page : 525 pages
File Size : 46,9 Mb
Release : 2021-04-17
Category : Science
ISBN : 9780128189337

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Synthetic Inorganic Chemistry by Ewan J. M. Hamilton Pdf

Synthetic Inorganic Chemistry: New Perspectives presents summaries of the work of some of the most creative researchers in the field. The book highlights the most novel approaches and burgeoning applications of synthetic inorganic chemistry in development. Topics include non-precious metals in catalysis, smart inorganic polymers, new inorganic therapeutics, new photocatalysts for hydrogen production, and more. As the first volume in the Developments in Inorganic Chemistry series, this work is a valuable resource for students and researchers working in inorganic chemistry and material science. Illustrates the scope and vitality of modern synthetic inorganic chemistry Shows the centrality of inorganic chemistry, addressing a variety of global challenges Serves to define the current, important and expanding roles of synthetic inorganic chemistry in interdisciplinary areas such as materials science, synthetic organic chemistry, homogeneous and heterogeneous catalysis

Author : Anonim
Publisher : Newnes
Page : 7694 pages
File Size : 50,5 Mb
Release : 2013-07-23
Category : Science
ISBN : 9780080965291

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Comprehensive Inorganic Chemistry II by Anonim Pdf

Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973

Author : Alice Feeney
Publisher : Flatiron Books
Page : 288 pages
File Size : 53,8 Mb
Release : 2018-03-13
Category : Fiction
ISBN : 9781250144836

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Sometimes I Lie by Alice Feeney Pdf

My name is Amber Reynolds. There are three things you should know about me: 1. I’m in a coma. 2. My husband doesn’t love me anymore. 3. Sometimes I lie. Amber wakes up in a hospital. She can’t move. She can’t speak. She can’t open her eyes. She can hear everyone around her, but they have no idea. Amber doesn’t remember what happened, but she has a suspicion her husband had something to do with it. Alternating between her paralyzed present, the week before her accident, and a series of childhood diaries from twenty years ago, this brilliant psychological thriller asks: Is something really a lie if you believe it's the truth?

Author : Abhik Ghosh,Steffen Berg
Publisher : John Wiley & Sons
Page : 356 pages
File Size : 48,5 Mb
Release : 2014-08-18
Category : Science
ISBN : 9781118173985

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Arrow Pushing in Inorganic Chemistry by Abhik Ghosh,Steffen Berg Pdf

Involved as it is with 95% of the periodic table, inorganic chemistry is one of the foundational subjects of scientific study. Inorganic catalysts are used in crucial industrial processes and the field, to a significant extent, also forms the basis of nanotechnology. Unfortunately, the subject is not a popular one for undergraduates. This book aims to take a step to change this state of affairs by presenting a mechanistic, logical introduction to the subject. Organic teaching places heavy emphasis on reaction mechanisms - "arrow-pushing" - and the authors of this book have found that a mechanistic approach works just as well for elementary inorganic chemistry. As opposed to listening to formal lectures or learning the material by heart, by teaching students to recognize common inorganic species as electrophiles and nucleophiles, coupled with organic-style arrow-pushing, this book serves as a gentle and stimulating introduction to inorganic chemistry, providing students with the knowledge and opportunity to solve inorganic reaction mechanisms. • The first book to apply the arrow-pushing method to inorganic chemistry teaching • With the reaction mechanisms approach ("arrow-pushing"), students will no longer have to rely on memorization as a device for learning this subject, but will instead have a logical foundation for this area of study • Teaches students to recognize common inorganic species as electrophiles and nucleophiles, coupled with organic-style arrow-pushing • Provides a degree of integration with what students learn in organic chemistry, facilitating learning of this subject • Serves as an invaluable companion to any introductory inorganic chemistry textbook

Author : Boy Cornils,Wolfgang A. Herrmann,Matthias Beller,Rocco Paciello
Publisher : John Wiley & Sons
Page : 1872 pages
File Size : 40,6 Mb
Release : 2017-09-05
Category : Science
ISBN : 9783527651764

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Applied Homogeneous Catalysis with Organometallic Compounds by Boy Cornils,Wolfgang A. Herrmann,Matthias Beller,Rocco Paciello Pdf

The completely revised third edition of this four-volume classic is fully updated and now includes such topics as as CH-activation and multicomponent reactions. It describes the most important reaction types, new methods and recent developments in catalysis. The internationally renowned editors and a plethora of international authors (including Nobel laureate R. Noyori) guarantee high quality content throughout the book. A "must read" for everyone in academia and industry working in this field.

Author : Gilbert Newton Lewis
Publisher : Unknown
Page : 184 pages
File Size : 42,9 Mb
Release : 1923
Category : Science
ISBN : UOM:39015078684720

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Valence and the Structure of Atoms and Molecules by Gilbert Newton Lewis Pdf